[pt] Com o advento da TV digital no Brasil, a necessidade de reuso dos canais para diferentes entidades, e a importância das emissoras oferecerem a melhor qualidade de serviço para seus usuários, dentre outros fatores, criam um ambiente propício para o estudo de modelos de predição de cobertura para que tanto as emissoras possam dimensionar corretamente suas estações, como os órgãos reguladores possam distribuir os canais de forma harmoniosa. Este trabalho apresenta medidas de campo realizadas nas cidades do Rio de Janeiro, Belo Horizonte e São Paulo e as compara com valores calculados usando os modelos de Deygout-Assis, CRC-Predict, ITU-R P.526 e ITU-R P.1546. / [en] Since the beginning of Digital TV in Brazil, the need of channel reuse for different broadcasters, the importance to offer a service with good quality, among other issues, created a good environment for studying prediction methods for RF coverage, so that broadcasters can correctly specify its stations and also the government regulators can allocate channels without interference. This work presents field measurements made in Rio de Janeiro, Belo Horizonte and São Paulo and compare them with predicted values using the methods of Deygout- Assis, CRC-Predict, ITU-R P.526 e ITU-R P.1546.

The aim of this thesis is to present a simple model for the radiation to light conversion processes in fluorescent layers as an aid in future developments and applications. Optimisation between sensitivity and spatial resolution for fluorescent layers in digital radiology is a delicate task where the extrinsic efficiency for various phosphors needs to be established for varying parameters. The extrinsic efficiency of a fluorescent layer can be expressed as the ratio of the light energy per unit area at the screen surface to the incident xray energy fluence. Particle size is a critical factor in determining the value of the extrinsic efficiency, but in most models it is not treated as an independent variable. Based on the definition of a light extinction factor (ξ), a model is proposed such that, knowing the intrinsic efficiency η, the particle size and the thickness of a certain make of screen, the extrinsic efficiency can be calculated for an extended range of particle sizes and / or screen thicknesses. The light extinction factor ξ is an optical parameter determined from experimental data on extrinsic efficiency. The proposed model is compared to established methods. Further experiments have confirmed the validity of the model. Monte-Carlo simulations have been utilised to refine the calculations of energy imparted to the phosphor by taking into account the escape of scattered and K-radiation generated in the screen and interface effects at the surfaces. The luminance was measured for a set of in-house manufactured screens of varying thicknesses and particle sizes. Utilising the proposed model, the corresponding calculated values deviated ± 14 %.within the studied range.

Solar energy is incident on the earth's surface in both short-wave and long-wave parts of the spectrum. The short-wave part of the spectrum is of special interest to oceanographers since the vertical distribution of temperature in the top layer of the ocean is mostly determined by the vertical attenuation of short-wave radiation. There are numerous studies regarding the temperature evolution as a function of time (see Chapter 2 for details). The diurnal and seasonal variation of the heat content (and hence temperature) of the ocean is explored in this thesis. The basis for such heat budget simulation lies in the fact that the heat budget is the primary driver of ocean currents (maybe secondary to wind effects) and these circulation features affect the biological and chemical effects of that region. The vertical attenuation of light (classified to be in the 300-700 nm range) in the top layer of the ocean has been parameterized by several authors. Simpson and Dickey (1981) in their paper have listed the various attenuation schemes in use till then. This includes a single-exponential form, a bimodal exponential form, and a spectral decomposition into nine spectral bands, each with their specific exponential functions with depth. The effects of vertical light attenuation have been investigated by integrating the light models into a 1D and a 3D turbulence closure model. The main part of the thesis is the inclusion of a bottom effect in the shallow waters. Bottom serves two purposes, it reflects some light based on its albedo and it radiates the rest of the light as heat. 1-D simulation including bottom effects clearly indicates the effect of light on the temperature profile and also the corresponding effect on salinity profiles. An extension of the study includes a 3D simulation of the heat budget and the associated circulation and hydrodynamics. Intense heating due to the bottom leads to the formation of hyper-saline waters that percolate down to depths of 50 m in the summer. Such plumes have been simulated by using a 3D numerical ocean model and it is consistent with observations from the Bahamas banks.

Abstract not available

I Sverige finns idag en vedertagen metod för att bestämma dimensionerande flöde för dammanläggningar. De teoretiska beräkningarna av dimensionerande flöde för dammanläggningar tillhörande flödesdimensioneringsklass I baseras på HBV-modellen, en begreppsmässig hydrologisk beräkningsmodell som beskriver samspelet mellan de meteorologiska och hydrologiska förhållanden som råder inom ett avrinningsområde. Begreppsmässiga hydrologiska modeller baseras på vattenbalansen och används för att bestämma tillrinning till vattendrag, sjöar eller andra vattenförekomster. Vid hydrologisk modellering med begreppsmässiga modeller tas ingen explicit hänsyn till vattendragets geometri. Trånga sektioner i naturliga vattendrag kan hindra vattnets framfart och orsaka dämning uppströms den trånga sektionen. Till följd av det kan en del av flödestoppen kvarhållas i terrängen och därmed dämpas och fördröjas. Hydrauliska modeller beskriver vattnets flöde genom vattendraget. Högupplöst höjddata utgör grunden i en hydraulisk modell och vid hydraulisk modellering tas således hänsyn till avrinningsområdets topografi såväl som vattendragets batymetri. Syftet med detta examensarbete var att analysera tillförlitligheten i beräknade dimensionerande flöden framtagna enligt Flödeskommitténs Riktlinjer för bestämning av dimensionerande flöden för dammanläggningar. Genom att upprätta hydrauliska modeller över två specifika vattendragssträckor som berörs av trånga sektioner kunde det undersökas huruvida de trånga sektionerna orsakar någon flödesdämpning samt om flödesdämpningen beror av storleken på vattenflödet. De områden som var föremål för denna studie var en delsträcka av Övre Lagan samt en del av Bolmån som är Lagans största tillflöde. Resultaten visade att flödestopparna dämpades och att det var de trånga sektionerna som orsakade den huvudsakliga flödesdämpningen. Vidare visade resultaten att den relativa dämpningen beror av storleken på inflödet i de hydrauliska modellerna. Den relativa dämpningen av det dimensionerandet flödet vid Övre Lagan var marginell, 1,2 % respektive 2,0 %, medan den vid Bolmån uppgick till 6,7 %. Det faktum att de dimensionerande flödena emellertid dämpades i de båda fallen bör vara skäl nog att se över metoden för bestämmandet av dimensionerande flöden för dammanläggningar tillhörande flödesdimensioneringsklass I och undersöka huruvida det är möjligt att innefatta hydraulisk modellering i den idag vedertagna beräkningsmetodiken. / In Sweden there is currently an accepted method for determining the design floods for dams which is described in The Swedish Design Flood Guidelines. The theoretical calculations of the design floods for dams associated with Flood Design Category I are based on the HBV model, a conceptual hydrological model that describes the interaction between the meteorological and hydrological conditions within a basin. Conceptual hydrological models are based on the water balance and are used to determine runoff to streams, lakes or other bodies of water. Conceptual hydrological models do not take explicit account for the geometry of the watercourse. Narrow sections in natural streams may prevent water flow and cause impoundment upstream from the narrow section. Following that, a part of the flow peak can be retained in the terrain and thereby attenuated and delayed. Hydraulic models describe the flow of water through the watercourse. High resolution elevation data is the foundation of a hydraulic model and hydraulic models thus take into account the basin topography as well as the watercourse bathymetry. The objective of this study was to analyze the reliability of design floods that have been determined according to The Swedish Design Flood Guidelines. By establishing hydraulic models of two specific streams affected by narrow sections it could be examined whether the narrow sections cause flow attenuation and whether the flow attenuation depends on the size of the water flow. The areas which were the subject of this study were a subsection of River Lagan and part of River Bolmån, which is River Lagan’s largest tributary. The results of the hydraulic model simulations showed that the flow peaks were attenuated and that it was the narrow sections that caused the main flow attenuation. Furthermore, the results showed that the relative attenuation depends on the size of the inflow in the hydraulic models. The relative attenuation of the design floods was 1.2 % and 2.0 % at River Lagan and 6.7 % at River Bolmån. The relative attenuation of the design flood was thus marginal at River Lagan. The fact that the design floods nevertheless were attenuated at both areas which were the subject of this study should be reason enough to review the method for the determination of design floods for dams associated with Flood Design Category I and examine whether it is possible to include hydraulic modeling in today’s conventional calculation methodology.

Methyl tert-butyl ether (MTBE) has been used as a gasoline additive to improve the combustion efficiency and to replace lead since 1978. It is the most commonly used oxygenate now due to its low cost, convenience of transfer, and ease of blending and production. MTBE has become a prevalent groundwater contaminant because it is widely used and it has been disposed inappropriately. MTBE has been demonstrated an animal carcinogen. The US Environmental Protection Agency (US EPA) has temporarily classified MTBE as a possible human carcinogen and has set its advisory level for drinking water at 20-40 µg/L based on taste and odor concerns. The Taiwan Environmental Protection Administration (TEPA) also classifies it as the Class IV toxic chemical substances. Currently, natural attenuation (NA) as well as natural bioremediation or enhanced bioremediation are attractive remediation options for contaminated sites due to their economic benefit and environmental friendly. In general, in situ microorganisms at the contaminated site play a very important role in site restoration. Although early studies suggested that the biodegradability of MTBE was not significant, recent laboratory and field reports reveal that MTBE can be biodegraded under aerobic and anaerobic conditions. In addition, evidences and some successful cases of MTBE attenuation have been reported that make natural attenuation a considerable remedial strategy. However, the biodegrading rate might decrease if the nutritional and physiological requirements are not met. Thus, it is important to assess the biodegradability of natural microorganisms under various site conditions to obtain optimal remedial conditions. Contributions of intrinsic biodegradation and other abiotic mechanisms to the removal and control of contaminants should also be evaluated to provide sufficient information for remedial option determination. Moreover, isolation and identification of the dominant native microorganisms will be helpful to following remediation tasks. In the first part of this study, microcosm study and microbial identification technologies (denaturing gradient gel electrophoresis, DGGE) were applied to assess the biodegradability of MTBE by indigenous microbial consortia and to identify the dominant microorganisms at a MTBE-contaminated site (Site A). In the second part of this study, thorough field investigations were performed to evaluate the occurrence of natural attenuation of MTBE at two MTBE-contaminated sites (Site A and Site B). In addition, a natural attenuation model, BIOSCREEN, was performed to assess the effectiveness of natural attenuation on MTBE containment. The main objectives of this study contained the following: (1)Evaluate MTBE biodegradability under different redox conditions by the indigenous microorganisms. (2)Determine the dominant native microorganisms in MTBE biodegradation for further application. (3)Assess the feasibility of using natural attenuation to control the MTBE plume. (4)Evaluate the contributions of intrinsic biodegradation patterns on natural attenuation processes by BIOSCREEN. Results from the microcosm study reveal that MTBE could be biodegraded by aquifer sediments without the addition of extra carbon sources under aerobic conditions. The production of tert-butyl alcohol (TBA), a degradation byproduct of MTBE, was detected. Complete removal of TBA was also observed by the end of the experiment. Results from aerobic microcosms study indicate that oxygen might be the major limiting factor of MTBE biodegradation at Site A. Thus, MTBE at this site could be removed via natural biodegradation processes with the supplement of sufficient oxygen. Microcosm study with extracted supernatant of aquifer sediments as the inocula show that the indigenous microorganisms were capable of using MTBE as the sole carbon and energy source. The calculated MTBE degradation rate was 0.597 mg/g cells/h or 0.194 nmole/mg cells/h. No MTBE removal was observed under various anaerobic conditions. Results suggest that aerobic biodegradation was the dominant degradation process and aerobic bioremediation might be a more appropriate option for the site remediation. According to the results of DGGE analysis, aerobic MTBE-biodegrading bacteria, Pseudomonas sp. and Xanthomonas sp., might exist at this site. Although results of microcosm study show that MTBE could not be degraded under anaerobic conditions, the microbial identification indicates that some novel anaerobic microbes, which could degraded MTBE, might be present at this site. In addition, anaerobic microbes caused the consumption of electron acceptors (e.g., nitrate, ferric iron) and removal of benzene, toluene, ethylbenzene, xylenes (BTEX), 1,2,4-trimethyl benzene (1,2,4-TMB), and 1,3,5-trimethyl benzene (1,3,5-TMB) (TMBs) in the anaerobic microcosms. These results also indicate that the potential of anaerobes activities was high at Site A. Based on the results from the field investigation, natural attenuation of MTBE was occurring at both sites. MTBE plume at Site B could be effectively controlled via natural attenuation processes. Nevertheless, MTBE plume at Site A has migrated to a farther downgradient area and passed the boundary of the site. Field investigation results indicate that the natural attenuation mechanisms of MTBE at both sites were occurring with the first-order attenuation rates of 0.0021 and 0.0048 1/day at Sites A and B, respectively. According to BIOSCREEN simulation, biodegradation was responsible for 78% and 59% of MTBE mass reduction at Sites A and B, respectively. The intrinsic biodegradation had significant contributions on the control of MTBE plumes. Moreover, the dilution and dispersion processes might be the major mechanisms for the attenuation of MTBE in the downgradient areas. However, results also reveal that intrinsic biological processes might still fail to contain the plume if the selected point of compliance is not appropriate. Results of this study suggest that natural attenuation might be feasible to be used as a remedial option for the remediation of MTBE-contaminated site on the premise that (1) detailed site characterization has been conducted, and (2) the occurrence and effectiveness of natural attenuation processes have been confirmed. Based on the results from the field investigation and laboratory microcosm studies, MTBE could be biodegraded by natural microbial populations at the studied sites under both aerobic and anaerobic conditions and natural attenuation would be applied as a remedial option at MTBE-contaminated sites. Results from this study would be useful in determining the favorable bioremediation conditions and designing an efficient and cost-effective bioremediation system such as monitored natural attenuation (MNA) or in situ or on-site MTBE bioremediation system for field application.

ABSTRACT INVESTIGATION OF LIGHT ATTENUATION IN LAKE EYMIR Selen ATIKER M.Sc, Department of Environmental Engineering Supervisor: Assoc. Prof. Dr. Ayseg&uuml / l Aksoy Co-Supervisor: Assoc. Prof. Dr. Selim Sanin January 2012, 164 pages. Light penetration and attenuation has significant impact on the water quality of lakes. Algal activity, which is important for the levels of several water quality parameters, is dependent on light penetration besides availability of nutrients. In this study, change in light penetration and attenuation in Lake Eymir was studied. The relationships of extinction coefficient (ke), and water quality parameters were investigated. The effect of ke on Chl-a over nutrients were investigated. The water quality parameters measured were / total suspended solid (TSS), phosphate, ammonium, nitrate, photosynthetically active radiation (PAR), chlorophyll-a (Chl-a), Secchi disk depth and lake Depth. The measurements were conducted at five different stations in Lake Eymir. Secchi disk, PAR and lake depth measurements were done on site, while TSS, Chl-a and phosphate analyses were done in laboratory, using standard methods. Nitrate and ammonium analyses were conducted through laboratory kits. Linear and non-linear regression models of ke and Chl-a were developed to understand their relationships with the the measured parameters, using XLSTAT software. Analyses of the data at sampling stations revealed that Station 2 and 3 were the most representative stations in general. The model results indicated that ke is as important as nutrients for Chl-a abundance. Secchi disk and Chl-a are the most correlated parameters with ke. Moreover Secchi disk depth is nonlinearly correlated with ke, while linearly correlation is present between Chl-a and ke. &emsp

Die Kombination von Positronen-Emissions-Tomographie (PET) und Röntgen-Computertomographie (CT) in Form moderner PET/CT-Geräte ermöglicht die Nutzung der CT-Information zur Korrektur der Photonenschwächung in der PET. Allerdings können Bewegungen, die zum Beispiel durch die Atmung hervorgerufen werden können, zu einer fehlerhaften Schwächungskorrektur führen. Die Einführung von zeitlich aufgelöster Bildgebung für beide Modalitäten (4D-PET/4D-CT) ermöglicht nicht nur die Auflösung von periodischen Bewegungen, sondern auch die Reduktion dieser Fehler in der Schwächungskorrektur. Dazu werden die einzelnen Datensätze des 4D-PET, die jeweils einer bestimmten Bewegungsphase entsprechen, mit dem entsprechenden CT-Datensatz dieser Atemphase schwächungskorrigiert. In der vorliegenden Arbeit wurde diese phasenkorrelierte Schwächungskorrektur des 4D-PET mit dem 4D-CT am Universitästsklinikum Dresden installierten PET/CT ermöglicht und anhand von Phantomexperimenten mit anderen Schwächungskorrekturmethoden für 4D-PET verglichen. Dazu musste zunächst die Aufnahme von 4D-CT an dem verwendeten PET/CT ermöglicht und dessen Synchronität mit dem 4D-PET hergestellt werden. Außerdem wurde ein vorhandenes Atemphantom so modifiziert, dass es typische Bewegungen von Bronchialkarzinomen in zwei Dimensionen und mit zwei möglichen Atemmustern simuliert. Die phasenkorrelierte Schwächungskorrektur führte zu einer quantitativ korrekten Wiederherstellung des Aktivitätsvolumens, der darin enthaltenen Aktivität sowie der Bewegungsamplitude und stellt somit die beste der hier verglichenen 4D-PET-Schwächungskorrekturmethoden dar. Diese Ergebnisse lassen vermuten, dass die phasenkorrelierte Schwächungskorrektur auch bei klinischer Anwendung eine signifikante Verbesserung in oben genannten Punkten darstellt. Dies sollte in Zukunft an Patientendaten überprüft werden. / The combination of Positron Emission Tomography (PET) and Computed Tomography (CT) in one device allows the use of CT-information for attenuation correction in PET. Though motion, for example induced by respiration, can cause inaccurate attenuation correction. The implementation of time-resolved imaging methods for both modalities (4D-PET/4D-CT) enables not only the resolution of motion but also the reduction of artifacts caused by attenuation correction. Therefore, the single datasets of the 4D-PET that are related to a individual respiratory phase, are attenuation corrected with the corresponding dataset of the 4D-CT. This phase correlated attenuation correction of the 4D-PET with the 4D-CT was implemented at the PET/CT installed at the Universitätsklinikum Dresden. For that purpose the acquisition of 4D-CT was implemented at the PET/CT and its synchronisation with the 4D-PET was verified. Furthermore the new attenuation correction method was compared with other attenuation correction methods by performing phantom experiments. Therefore an exisisting respiratory phantom had to be modified to perform typical lung tumor motion in two dimensions with two possible patterns of respiration. The phase correlated attenuation correction leads to a quantitatively correct restauration of the activity volume, its total activity and its motion amplitude. Compared with other correction methods, the phase correlated attenuation correction shows the best results in all examined criteria. This findings suggest that the clinical application of the phase correlated attenuation correction will also lead to a significant improvement in all mentioned points. This has to be verified by analyzing patient data.

In this study Monte Carlo solutions to the radiative transfer equations are used to model translational and rotational motion seismogram envelopes in random elastic media with deterministic background structure assuming multiple anisotropic scattering. The results of the Monte Carlo radiative transfer theory simulations are verified by comparisons with 3D full wave field finite difference simulations. The observation and modeling of the three additional components of rotational ground motions can provide independent information about seismic wave propagation in the Earth’s structure. Rotational motions around the vertical axis observed in the P-wave coda are of particular interest as they can only be excited by horizontally polarized shear waves and therefore indicate the conversion from P- to SH-energy by multiple scattering at 3D-heterogeneities. Scattering and attenuation parameters in south-east Germany beneath the Gräfenberg array and in the Vogtland region are estimated by comparisons of synthesized multi-component seismogram envelopes to seismic data from local and regional swarm earthquakes and to teleseismic events. In a first step, frequency dependent scattering and attenuation parameters from a local data set are estimated for the Vogtland region using nearby swarm earthquakes. The results from the elastic simulations are compared to outcomes from acoustic radiative transfer simulations. Both methods yield similar results and suggest that intrinsic attenuation dominates scattering attenuation. From the elastic simulations it is observable, that forward scattering is required to explain the data. However, the amount of forward scattering strength remains unresolvable. In a second step scattering and attenuation parameters beneath the Gräfenberg array are estimated using a nonlinear genetic inversion of seismogram envelopes from regional events at high frequencies (4–8 Hz). The preferred model of crustal heterogeneity consists of a random medium described by an exponential auto correlation function with a transport mean free path length of ∼ 420 km. The quality factor for elastic S-wave attenuation Q iS is around 700. In a final step simulations of teleseismic P-wave arrivals, using this estimated set of scattering and attenuation parameters, are compared to observed seismogram envelopes from deep events. Simulations of teleseismic events with the parameters found from the regional inversion show good agreement with the measured seismogram envelopes. This includes ringlaser observations of vertical rotations in the teleseismic P-wave coda that naturally result from the proposed model of wave scattering. The model also predicts, that the elastic energy recorded in the teleseismic P-coda is not equipartitioned, unlike the coda of regional events, but contains an excess of shear energy. The combined results from the three different data sets suggest that scattering generating the seismic coda mainly occurs in the crustal part of the lithosphere beneath the receivers. The observations do not require scattering of high frequency waves in the mantle, but weak scattering in the lithospheric mantle cannot be ruled out. / In dieser Studie werden Monte Carlo Lösungen für die Energietransfergleichungen genutzt, um Seismogrammeinhüllende von Translations- und Rotationsbewegungen zu modellieren. Die Ergebnisse der Monte Carlo Simulationen werden durch einen Vergleich mit 3D finiten Differenzen Simulationen verifiziert. Diese Modellierung findet in einem elastischen Zufallsmedium mit deterministischer Hintergrundstruktur unter Annahme multipler anisotroper Streuung statt. Die Beobachtung und Modellierung der drei zusätzlichen Komponenten der Rotationsbodenbewegungen kann unabhängige Informationen über die Ausbreitung seismischer Wellen im Erdkörper liefern. Rotationsbewegungen um die vertikale Achse in der P-Wellen Koda sind in diesem Zusammenhang von speziellem Interesse, da sie nur von horizontal polarisierten Scheerwellen angeregt werden können. Die gemessenen Rotationsbewegungen deuten folglich auf Konversionen von P- zu SH-Energie durch multiple Streuung an 3D-Heterogenitäten hin. Für die Bestimmung von Streu- und Dämpfungsparametern im Südosten Deutschlands (Gräfenberg Array, Vogtland) werden synthetisch erzeugte, mehrspurige Seismogrammeinhüllende mit Daten lokaler und regionaler Schwarmbeben und teleseismicher Ereignisse verglichen. In einem ersten Schritt werden frequenzabhängige Krustenparameter für die Vogtlandregion mittels eines lokalen Datensatzes von nahen Schwarmbeben bestimmt. Die Resultate mittels elastischer Energietransfertheorie werden mit Ergebnissen aus Simulationen mittels akustischer Energietransfertheorie verglichen. Beide Methoden liefern ähnliche Parameter und sagen einen größeren Einfluss der intrinsichen Dämpfung im Vergleich zur Streudämpfung voraus. Aus den elastischen Simulationen geht hervor, dass für die Beschreibung der Daten Vorwärtsstreung angenommen werden muss, die Stärke dieser lässt sich jedoch nicht auflösen. In einem zweiten Schritt werden die Streu- und Dämpfungseigenschaften der Erdkruste im Untergrund des Gräfenberg Arrays untersucht. Hierzu wird eine nicht-lineare genetische Inversion von Seismogrammeinhüllenden regionaler Ereignisse bei hohen Frequenzen (4–8 Hz) verwendet. Das bevorzugte Modell der Krustenheterogenität wird durch ein exponentielles Zufallsmedium, einer mittleren freien Transportweglänge von ca. 420 km und einem Qualitätsfaktor für S-Wellen Q iS von ca. 700 beschrieben. Ein letzter Schritt vergleicht Simulationen von teleseismischen P-Welleneinsätzen mit beobachteten Seismogrammeinüllenden von tiefen Erdbeben unter der Nutzung der Parameter aus der regionalen Inversion. Die Simulationen der teleseismischen Ereignisse mit den Parametern der regionalen Inversion zeigen eine gute Übereinstimmung mit den gemessenen Seismogrammeinhüllenden. Dieser Vergleich beinhaltet Ringlaserbeobachtungen der Rotationsbewegungen um die vertikale Achse, welche aus dem angenommenen Streumodell resultieren. Das Modell sagt voraus, dass die elastische Energie in der teleseismischen P-Wellen Koda im Gegensatz zur Koda lokaler oder regionaler Ereignisse nicht gleichverteilt ist, sondern einen Überschuss an Scheerenergie beinhaltet. Die Resultate aus den Untersuchungen der lokalen, regionalen und teleseismischen Datensätze zeigen, dass die Streuereignisse, welche die seismische Koda erklären, hauptsächlich in der Kruste unterhalb der seismischen Empfänger stattfinden. Streuung des Wellenfeldes im Mantel wird für die Erklärung der Daten nicht benötigt, schwache Streuung im lithosphärischen Mantel kann jedoch nicht ausgeschlossen werden.

Nearly 250,000 sites with past and present potentially polluting activities need urgent remediation within Europe. Major pollutants include organochlorines (OCls), e.g. chlorinated ethenes (CEs) and hexachlorocyclohexanes (HCHs), mainly used as industrial solvents and pesticides, respectively. Due to improper handling and disposal, OCls contaminants are present in the soil or groundwater surrounding sites, where they have been produced or used. CEs and HCHs can undergo degradation by microorganisms indigenous to the soil or groundwater. Therefore natural attenuation (NA), relying on the in situ biodegradation of pollutants, is considered as a cost effective remediation strategy, yet it requires accurate monitoring methods. Compound specific isotope analysis (CSIA) is a powerful tool to provide information on the extent of degradation and, when combining two isotope systems (2D-CSIA), such as carbon (δ13C) and chlorine (δ37Cl), on reaction mechanisms. The diagnostic reaction-specific isotope enrichment factors (εC and εCl) were determined in laboratory experiments for the anaerobic degradation of PCE, TCE (Paper II) and α-HCH (Paper III) by mixed bacterial cultures enriched from CEs and HCHs contaminated sites, respectively. The related mechanism-specific εCl/εC ratios were calculated as 0.35 ± 0.11 (PCE), 0.37 ± 0.11 (TCE) and 0.52 ± 0.23 (α-HCH). These values are smaller than previously reported values for pure cultures. This is explained by the microbial community composition changes observed during degradation of PCE and α-HCH, which also reflect the variability of the microbial community at the field level. Furthermore, εCl/εC ratio might be bacteria specific. These values allowed the estimation of the extent of contaminant degradation at the respective study sites (Paper III and IV). Application of both isotope systems (δ13C and δ37Cl) led to comparable estimates. However the choice of representative ε values is crucial for an accurate assessment. These studies show that CSIA is useful to quantify in situ degradation of OCls contaminants and identify reaction pathways, by combining δ13C and δ37Cl. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 4: Manuscript.</p>