This dissertation focuses on the effects of superhydrophobic (SHPo) surfaces on thermal transport. The work is divided into two main categories: thermal transport without phase change and thermal transport with phase change. Thermal transport without phase change is the topic of four stand-alone chapters. Three address jet impingement at SHPo surfaces and the fourth considers natural convection at a vertical, SHPo wall. Thermal transport with phase change is the topic of a single stand-alone chapter exploring pool boiling at SHPo surfaces.Two chapters examining jet impingement present analytical models for thermal transport; one considered an isothermal wall and the other considered an isoflux wall. The chapter considering the isothermal scenario has been archivally published. Conclusions are presented for both models. The models indicated that the Nusselt number decreased dramatically as the temperature jump length increased. Further, the influence of radial position, jet Reynolds number, Prandtl number and isoflux versus isothermal heating become negligible as temperature jump length increased. The final chapter concerning jet impingement reports an experimental exploration of jet impingement at post patterned SHPo surfaces with varying microfeature pitch and cavity fraction. The empirical results show a decrease in Nusselt number relative to smooth hydrophobic surfaces for small pitch and cavity fraction and the isoflux model agrees well with this data when the ratio of temperature jump length to slip length is 3.1. At larger pitch and cavity fractions, the empirical results have higher Nusselt numbers than the SHPo surfaces with small pitch and cavity fraction but remain smaller than the smooth hydrophobic surface. We attribute this to the influence of small wetting regions. The chapter addressing natural convection presents an analytical model for buoyant flow at a vertical SHPo surface. The Nusselt number decreased dramatically as temperature jump length increased, with greater decrease occurring near the lower edge and at higher Rayleigh number. Thermal transport with phase change is the topic of the final stand-alone chapter concerning pool boiling, which has been archivally published. Surface heat flux as a function of surface superheat was reported for SHPo surfaces with rib and post patterning at varying microfeature pitch, cavity fraction, and microfeature height. Nucleate boiling is more suppressed on post patterned surfaces than rib patterned surfaces. At rib patterned surfaces, transition superheat decreases as cavity fraction increases. Increasing microfeature height modestly increases the transition superheat. Once stable film boiling is achieved, changes in surface microstructure negligibly influence thermal transport.

Presented here are the results from the steady state flow boiling of R245FA in a laboratory scale horizontal stainless-steel test tube with an inner diameter of 8.5 mm and a length of 900 mm at a saturation temperature of 35 °C and 40 °C. Experiments were conducted at mass fluxes ranging between 200 and 300 kg/m²s at inlet vapour qualities from 0.2 to 0.7 under uniform, and non-uniform imposed heat flux cases that are expected to exist in horizontal parabolic trough solar collectors. Nine (9) different heat flux distributions were investigated. Local and average heat transfer coefficients (HTC’s) were determined based on wall temperature measurements taken along the length and around the circumference of the test section. Through the choice of the fluid being linked to the possible usage of DSG technology in organic Rankine cycles, the qualitative trends and observed performance variations can be used to predict the same for a working fluid such as water. It was found that the non-uniformity of the heat flux greatly alters the HTC’s of the fluid undergoing boiling but has no effect on the pressure drop characteristics of the fluid undergoing boiling. Heating only on the sides of the tube yielded HTC’s that were 46 % lower than achieved under uniform heating. Heating only from the top proved to be more effective in heat transmission to the fluid than heating only from the bottom (as is the case on PTC solar fields), by only a slight margin, and both these cases yielded HTC’s that were 30 % lower than the uniform heating case. Applying a bell curve heat flux distribution over the tube walls yielded overall HTC’s that differed from the uniform case by a maximum of 5 %, even as the peak heat flux position changes around the circumference of the tube. A further study may be done to quantify the degree to which the non-uniformity of the heat flux influences the local HTC’s, and to develop correlations that may aid in predicting these cases. An integration with flow pattern mapping may also be done to solidify the understanding of the phenomenon governing these observations. / Dissertation (MEng)--University of Pretoria, 2021. / Department for International Development (DFID) through Royal Society-DFID Africa Capacity Building Initiative. / The UK Engineering and Physical Sciences Research Council (EPSRC) [grant numbers EP/T03338X/I and EP/P004709/1]. / Russian Government "Megagrant" project 075-15-2019-1888. / Mechanical and Aeronautical Engineering / MEng / Unrestricted

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While computational chemistry methods have a wide range of applications within the set of traditional physical sciences, very little is being done in terms of expanding their usage into other areas of science where these methods can help clarify research questions. One such promising field is Forensic Science, where detailed, rapidly acquired sets of chemical data can help in decision-making at a crime scene. As part of an effort to create a database that fits these characteristics, the present work makes use of computational chemistry methods to increase the information readily available for the rapid identification and scheduling of drugs to the forensic scientist. Ab initio geometry optimizations, vibrational spectra calculations and ESI-MS fragmentation prediction of a group of common psychedelics are here presented. In addition, we describe an under development graphical user interface to perform ab initio calculations using the GAMESS software package in a more accessible manner. Results show that the set of theoretical techniques here utilized, closely approximate experimental data. Another aspect covered in this work is the implementation of a boiling point estimation method based on group contributions to generate chemical dispersion areas with the ALOHA software package. Once again, theoretical results showed to be in agreement with experimental boiling point values. A computer program written to facilitate the execution of the boiling point estimation method is also shown.

Liquid jet impingement is a technique ubiquitously used to rapidly remove large amounts of heat from a surface. Several different regions of heat transfer spanning from forced convection to nucleate, transition, and film boiling can occur very near to one other both temporally and spatially in quenching or high wall heat flux scenarios. Heat transfer involving jet impingement has previously shown dependency both on jet characteristics such as flow rate and temperature as well as surface material properties. Water droplets are known to bead up upon contact with superhydrophobic (SH) surfaces. This is due to reduced surface attraction caused by micro- or nanostructures that, combined with a natively hydrophobic surface chemistry, reduce liquid-solid contact area and attraction, promoting droplet mobility. This remarkable capability possessed by SH surfaces has been studied in depth due to its potential for self-cleaning and shear reduction, but previous research regarding heat transfer on such surfaces shows that it has varying effects on thermal transport. This thesis investigates the effect that quenching initially hot SH surfaces by water jet impingement has on heat transfer, particularly regarding phase change. Two comparative studies are presented. The first examines differences in transient heat transfer from hydrophilic, hydrophobic, and SH surfaces over a range of initial surface temperatures and with jets of varying Reynolds number (ReD), modified by adjusting flow rate. Comparisons of instantaneous local heat flux from the surfaces are made by performing an energy balance over differential control volumes across the surfaces. General trends show increased heat flux, jet spreading velocity and maximum jet spread radius when ReD is increased. An increase in inital surface temperature resulted in increased heat flux across all surfaces, but slowed jet spreading. The local heat flux, average heat rate, and total thermal energy transfer from the surface all confirmed that SH surfaces allow significantly less heat to transfer to the jet compared to hydrophilic surfaces, due to the enhanced Leidenfrost condition and reduced liquid-solid contact on SH surfaces which augments thermal resistance. The second study compares jet impingement heat transfer from SH surfaces of varying microstructures. Similar thermal effects due to modified jet ReD and initial surface temperature were observed. Modifying geometric pattern from microposts to microholes, altering cavity fraction, and changing feature pitch and width had little impact on heat transfer. However, reducing feature height on the post surfaces facilitated water penetration within the microstructure, slightly enhancing thermal transport.

Gasoline and gasoline-like fuels (naphtha) have high volatility, which results in flash boiling spray in gasoline engines when operated at throttling or low load conditions. Flash boiling can achieve better atomization, thus benefit fuel evaporation and fuel-air mixing. However, when flash boiling occurs, spray morphology, and fuel distribution are dramatically varied from the injectors' intentional design. This difference will affect the performance of combustion and emissions. Thus it is essential to investigate the spray collapse phenomenon regarding varied conditions. The currently developing gasoline compression ignition (GCI) engines, also has throttled stoichiometric spark ignition operation mode, which inevitably has flash boiling possibility. However, there is a lack of research on flash boiling spray with a GCI injector, which has a large designed cone angle. This work aims to understand the spray collapse phenomenon and fill the gap in GCI flash boiling spray. Simultaneous side-view diffused back illumination (DBI) and front-view mie-scattering are used to capture the liquid spray development. Simultaneous shadowgraph from side and front view are used for recording the liquid+vapor phase spray development. Criteria for distinguishing different spray regimes have been established from these results. It shows this GCI injector is more resistant to collapse than the other conventional gasoline direct injection (GDI) injectors reported in the literature. A combination of DBI and space-time tomographic algorithm is validated in this work, achieving 3D reconstruction of the spray volume development from non-flashing to collapsed spray regime at low cost. The 3D results help elucidate the spray collapse procedure and provide validation data for CFD simulation. Structured laser illumination planar imaging (SLIPI) is firstly implemented in flash boiling spray study in this work to suppress the multiple scattering effect. Reconstructed 3D results from slice sweeping by SLIPI methods exposes the hollow structure in the spray's collapsed central jet, which has not been reported previously by other methods. Different spray motion types are summarized for the transitional and collapsed spray regime from the SLIPI slice and confirmed by the particle image velocimetry (PIV) technique.

Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 1980. / Includes bibliographical references. / by Ifiyenia Kececioglu. / Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 1980.

Superhydrophobic (SH) surfaces are characterized by their extraordinary water repellent qualities. When water comes in contact with these surfaces, it beads up and rolls around. This phenomenon is due partially to surface chemistry which promotes weak adhesive forces between liquid and solid. However, micro- and nanoscale surface roughness also plays a crucial role by trapping air beneath the liquid, reducing liquid-solid contact. Many advantages of these surfaces have been identified, including drag reduction and self-cleaning properties, and the body of research regarding them has grown rapidly over the past few decades.This thesis is concerned with water droplets impinging superheated, superhydrophobic surfaces. In these scenarios, boiling is common in the droplet, producing vapor bubbles which burst through the droplet lamella and cause a spray of miniscule water particles known as thermal atomization. The work contained in this thesis uses an image processing technique to quantify trends in thermal atomization intensity during droplet impingement scenarios for a range of surface microstructure configurations, superheat temperatures, and Weber numbers.In one study, droplet impingement on a smooth hydrophobic and three post-patterned SH surfaces of similar solid fraction is considered. In general, as pitch (center-to-center distance between posts) increases, atomization intensity decreases. This is attributed to the enhanced ability for vapor escape beneath the droplet that is present for wider pitch surfaces. Atomization intensity increases with increasing Weber number for each of the surfaces considered. Additionally, the Leidenfrost point is found to increase with increasing Weber number and decreasing pitch.Next, thermal atomization on SH surfaces with two distinct microstructure configurations is considered: square posts (which allow vapor escape between structures) and square holes (which block vapor escape). Tests are done for each configuration with varying microstructure height, and structure spacing and solid fraction are held constant. Comparing the two configurations at each structure height and Weber number, the post-patterned surfaces suppress atomization for a large number of scenarios compared to the hole surfaces, supporting the theory that vapor escape through microstructures suppresses atomization. Microstructure height significantly affects trends in atomization intensity with surface temperature and Weber number. The LFP is seen to decrease with increasing height.

<p> An experimental investigation is reported for water boiling at atmospheric pressure on a copper surface. Bubble nucleation at an artificial site was observed for five heat fluxes between 11,000 and 20,000 BTU/Hr Ft^2, and subcooling from 0° to about 30°F. Using Wiebe's correlation for heat flux and superheat layer thickness, four mathematical models were tested. The measured results are found to provide excellent agreement with the Han and Griffith model for bubble nucleation.</p> / Thesis / Master of Engineering (MEngr)

Under normal operating conditions a CANDU reactor pressure tube (PT) is insulated from its outer calandria tube (CT) by a CO2 gas annulus. If the primary loop coolant flow is compromised the PT can overheat and, if still pressurized, balloon into contact with the CT. At this point the moderator acts as an emergency heat sink. If the heat transferred from the CT to the moderator exceeds the critical heat flux (CHF) the CT can overheat, begin to strain due to the contact pressure, and eventually fail. A mechanistic model is presented that describes ballooning contact of the PT and CT, the resulting thermal contact conductance, heat flux to the moderator, and, if CHF is exceeded, the development of film boiling and potential CT strain. The goal is to create a software package that predicts fuel channel failure during a pressure tube overheat event. / Thesis / Master of Applied Science (MASc) / Computer software was developed to predict CANDU fuel channel failure in the event of a total station blackout. The model created successfully predicted the available experimental data.