In this paper we investigate the relationship between classes of tree-to-tree-series (for short: t-ts) and o-tree-to-tree-series (for short: o-t-ts) transformations computed by restricted deterministic bottom-up weighted tree transducers (for short: deterministic bu-w-tt). Essentially, deterministic bu-w-tt are deterministic bottom-up tree series transducers [EFV02, FV03, ful, FGV04], but the former are de ned over monoids whereas the latter are de ned over semirings and only use the multiplicative monoid thereof. In particular, the common restrictions of non-deletion, linearity, totality, and homomorphism [Eng75] can equivalently be de ned for deterministic bu-w-tt. Using well-known results of classical tree transducer theory (cf., e.g., [Eng75, Fül91]) and also new results on deterministic bu-w-tt, we order classes of t-ts and o-t-ts transformations computed by restricted deterministic bu-w-tt by set inclusion. More precisely, for every commutative monoid we completely specify the inclusion relation of the classes of t-ts and o-t-ts transformations for all sensible combinations of restrictions by means of inclusion diagrams.

Four-month mesocosm experiment from June 1st to September 25th, 2009, was conducted to determine the effect of water level dierence in combination with fish predation pressure, on submerged macrophyte development, in an eutrophic shallow lake. Effect of water level fluctuation was simulated by placing enclosures to the different water depths that included 0.8 m, 1.6 m and 2.3 m on Lake Eymir. These enclosures having a cylindirical shape and 1.2 m diameter, were open to sediment and atmosphere interaction. The highest water level mesocosms were cancelled after fifth sampling due to rapture in the bags, hence this thesis does not include the results of 2.3 m. At each depth, half of the enclosures were stocked with planktivo-omnivorous fish (Tinca tinca, Alburnus spp.) which are natural fauna of Lake Eymir. Before stocking of fish, ten shoots of Potamageton pectinatus were added to all of the enclosures in order to observe submerged macrophyte development. Sampling for physico-chemical parameters, zooplankton, chlorophyll a, PVI% and periphyton was conducted weekly for the first five weeks, last six samplings were done biweekly. Macrophyte harvesting for dry weight estimation was done at the end of the experiment. Throughout the experiment water level decreased 0.41 &plusmn / 0.06 m in each enclosures. Water level was so critical for macrophyte development that no significant macrophyte growth was observed in enclosures located at 1.6 m (HW). However, fish predation did not prevent the growth of macrophyte in enclosures located at 0.8 m (LW) but it was important in HW enclosure for affecting water clarity. Fish predation affected chlorophyll a, zooplankton and nutrient concentrations and the effect was mostly pronounced at LW enclosures. They had high chlorophyll a and nutrient concentrations but it did not repress macrophyte growth as in temperate lakes. Despite high water clarity in HW fishless enclosures, very low macrophyte biomass may be attributed to enhanced periphyton development. Zooplankton community shifted to small sized ones under fish predation while fishless enclosures had higher zooplankton /phytoplankton ratio for each depth. Hence, regarding these results it can be stated that decrease in water level can compensate the negative effects of fish predation on macrophyte growth in warm Mediterranean lakes.

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Die vorliegende Ausgabe beschäftigt sich mit dem Thema Umweltkennzahlensysteme für die Umweltleistungsmessung. Ziel der Arbeit ist es, Unternehmen ein Hilfsmittel zur Integration von Umweltaspekten ins allgemeine Unternehmensgeschehen an die Hand zu geben. Angestrebt ist die Konzeption eines Umweltkennzahlensystems zur Umweltleistungsmessung für Prozesse. Im ersten Schritt wird ein Öko-Controlling-Modell vorgestellt und Umweltkennzahlensysteme in dieses eingeordnet. Umweltkennzahlensysteme sind der Informationsversorgung zuzurechnen. Sie dienen der Information der Informationsverwender, die mit ihrer Hilfe Planen, Steuern und Kontrollieren sollen. Es wird ein Anforderungsprofil für Umweltkennzahlensysteme erstellt, dieses Anforderungsprofil beinhaltet allgemeine Anforderungen, wie die ?Anforderungen der Informationsverwender? und ?formale und logische Anforderungen? und spezielle Anforderungen. Vorhandene Ansätze zu Umweltkennzahlensystemen werden vorgestellt und hinsichtlich des Anforderungsprofils analysiert. Aus dieser Analyse ergibt sich der Schluss, dass es kein Umweltkennzahlensystem gibt, das alle Anforderungen erfüllt. Die Auswertung der an ausgewählte Führungskräfte der SIEMENS AG verschickten Fragebögen zu Umweltkennzahlen bestätigt die gewonnene Aussage der Nicht-Existenz einer first-best-Lösung hinsichtlich eines Umweltkennzahlensystems für alle Unternehmen, da sie verdeutlicht, dass schon die Kennzahlensysteme innerhalb eines Unternehmens stark (aufgrund zu unterschiedlicher Strukturen, Ziele und Strategien) differieren. An die Auswertung der Analyse der vorhandenen Ansätze und der Fragebögen schließt sich die Entwicklung einer Vorgehensweise zur Konzeption von Umweltkennzahlensystemen in Unternehmen an, die in den Schritten Festlegung der Umweltleistung von Unternehmen, Definition der Zielebene, Festlegung und Auswahl von Kennzahlen abläuft.

Visual attention can be voluntarily focused on a location or automatically attracted by salient features in a visual scene. Studies using functional Magnetic Resonance Imaging (fMRI) suggest two networks of visual attention involved in these complementary mechanisms: a dorsal frontoparietal network and a ventral frontoparietal network of visuospatial attention respectively. However, most studies so far have applied non‐natural schematic stimuli. The present study investigates visual attention in images of natural environmental scenes. Adopting previously used eye‐tracker paradigms, we study the influence of task instruction and luminance contrast modifications in pictures on both eye movements and neural activity using Eye‐Tracking and functional Magnetic Resonance Imaging simultaneously. We expect increased top‐down control of attention in a search task compared to a free viewing condition visible in enhanced neural activation in the intraparietal sulcus (IPS) as part of the dorsal frontoparietal network. Strong modifications of luminance contrast should foster bottom‐up processing activating the temporoparietal junction (TPJ) a crucial area in the ventral frontoparietal network of visual attention. Although the obtained eye‐tracking data shows the expected shift of fixations towards locations of increased luminance contrast, we do not find an influence of luminance contrast modifications on neural processing. Comparison of instructions reveals diverse results across participants possibly due to the long presentation duration of stimuli which allowed participant’s attention to wander independently of task instruction. We find bilateral activation in IPS and parahippocampal place area (PPA) as well as bilateral deactivation in the TPJ region independent of task context. This might indicate similar contributions of these areas to free viewing of and search in visual scenes. However, dissociation of target detection and attention during search by deconvolution analysis of data obtained in this study might reveal a more detailed picture of functional involvement of the IPS and TPJ region in processes of visual attention. Remarkably, results show robust activation of the PPA in both tasks, suggesting that the PPA region might not only be activated by houses and open scenes but by narrow scenes (bushes, leaves) of natural outdoor environment as well.

The utility of 193 nm ultraviolet photodissociation (UVPD) and negative electron transfer dissociation (NETD) for the characterization of peptide anions was systematically evaluated. UVPD outperformed NETD in nearly all metrics; however, both methods provided complementary information to traditional collision induced dissociation (CID) of peptide cations in high throughput analyses. In order to enhance the performance of NETD, activated ion negative electron transfer dissociation (AI-NETD) methods were developed and characterized. The use of low-level infrared photoactivation or collisional activation during the NETD reaction period significantly improved peptide anion sequencing capabilities compared to NETD alone. Tyrosine deprotonation was shown to yield preferential electron detachment upon NETD or UVPD, resulting in N - C[alpha] bond cleavage N-terminal to the tyrosine residue. LC-MS/MS analysis of a tryptic digest of BSA demonstrated that these cleavages were regularly observed under high pH conditions. Transmission mode desorption electrospray ionization (TM-DESI) was coupled with 193 nm UVPD and CID for the rapid analysis and identification of protein digests. Comparative results are presented for TM-DESI-MS/CID and TM-DESI-MS/UVPD analyses of five proteolyzed model proteins. In some cases TM-DESI/UVPD outperformed TM-DESI-MS/CID due to the production of an extensive array of sequence ions and the ability to detect low m/z product ions. 193 nm UVPD was implemented in an Orbitrap mass spectrometer for characterization of intact proteins. Near-complete fragmentation of proteins up to 29 kDa was achieved. The high-energy activation afforded by UVPD exhibited far less precursor ion charge state dependence than conventional methods, and the viability of 193 nm UVPD for high throughput top-down proteomics analyses was demonstrated for the less 30 kDa protein from a fractionated yeast cell lysate. The use of helium instead of nitrogen as the C-trap and HCD cell bath gas and trapping ions in the HCD cell prior to high resolution mass analysis significantly reduced the signal decay rate for large protein ions. As a result, monoclonal IgG1 antibody was isotopically resolved and mass accurately determined. A new high mass record for which accurate mass and isotopic resolution has been achieved (148,706.3391 Da ± 3.1 ppm) was established. / text

This master thesis analyses two citizen initiatives; the flood action plan of LLanddowror, Wales and the mount plan of the Overdiepse Polder, the Netherlands. It uses the collaboration theory, the ladder of citizen participation, cross-scale interaction and community resilience to explain the role of citizens in flood risk management. The aim of this research is to see how governments facilitate citizens and if culture and context influence the roles of governments and citizens. The Welsh system is bottom-up with an increasing role for market and civil society to take responsibilities. Citizens generally insure themselves against flood damage. The Welsh system has enhanced community engagement and creating awareness is important. Dealing with big strategic issues seems to be difficult. The Dutch flood governance is more top-down which means less room for citizen initiatives. Citizens are not insured for flood damage since the government profiles itself responsible for floods therefore awareness amongst citizens is low. The Dutch system has benefits when dealing with large scaled projects but has issues with creating awareness as well as engaging citizens in water development. Assumingly there are opportunities for both countries to learn from each others’ way of dealing with flood risk management and citizen engagement.

<p>Our main results are that splay trees are faster for sorted insertion, where AVL trees are faster for random insertion. For searching, skip lists are faster than single class top-down splay trees, but two-class and multi-class top-down splay trees can behave better than skip lists.</p>

Previous studies have demonstrated that observers may ignore highly salient feature singletons during a conjunction search task through focusing the attentional window (Belopolsky, Zwaan, Theeuwes, & Kramer, 2007), or by the suppression of bottom-up information (Treisman & Sato, 1990). In the current study, observers’ eye movements were monitored while performing a search task in which a feature singleton was present and corresponded with the target at a chance level. With practice, observers were less likely to make an initial saccade toward the singleton item, but initial saccades directed at the target were likely throughout. Results demonstrate that, in an effort to ignore the singleton, observers were more likely to suppress bottom-up information than adjust the size of the attentional window.

Fluorescent carbon dots (C-dots) are well known for their low cell-cytotoxicity, biocompatibility, low preparation cost, excitation dependent photoluminescence, and excellent photostability. Typically, raw C-dots have low quantum efficiency and thus researchers have been utilizing biocompatible polymers such as polyethylene glycol (PEG) as a passivation agent in order to increase fluorescence signal. In this work, we report fluorescent self-passivated carbon nanodots (CNDs) synthesized from PEG by using it as a carbon source as well as a passivating agent. Importantly, the addition of graphene quantum dots (GQDs) during the synthesis of self-passivated CNDs can tune photoluminescence property. The results of bioimaging and cytotoxicity test of self-passivated CNDs hold promises for biomedicine applications.