This letter presents the design and characterization results of a multi-octave power amplifier fabricated in a 0.13μm SiGe-BiCMOS technology. The single stage power amplifier is implemented as the stack of a cascode amplifier combining broadband input matching network with resistive feedback, and a common-base amplifier with base capacitive feedback. Measurement results show that the design delivers a peak saturated output power level of 20.2 dBm, with output 1 dB compression at 19.4 dBm. The measured 3 dB power bandwidth is from 4 GHz to 32 GHz, covering three octaves. The corresponding power fractional bandwidth is 156 %. The measured peak power added efficiency is 20.6 %, and peak small signal gain is 18.6 dB. The fabricated integrated circuit occupies an area of 0.71mm2. To compare state-of-the-art multi-octave power amplifiers, the power amplifier figure of merit defined by the international technology roadmap for semiconductors is modified to include power fractional bandwidth and area. To the knowledge of the authors, the presented design achieves the highest figure of merit among multi-octave power amplifiers in a silicon based integrated circuit technology reported in literature.

This thesis addresses basic scientific research in the field of transmitter front-end circuits for electro-optical data communication. First, the theoretical fundamentals are presented and analyzed. Based on the theoretical considerations, conceptual circuit designs are studied. Finally, in order to prove the described concepts, the circuits were experimentally characterized and subsequently compared to other works in the literature. The analysis covers key theoretical aspects regarding transmitter front-end circuits. It starts from the basic physical effects inside a transistor and ends with the design of high-swing modulator drivers. Furthermore, it comprises the fundamentals of optical modulators as well as the integration of the electrical driver with the modulator. First, the concept of a basic monolithically integrated transmitter consisting of a Mach-Zehnder modulator (MZM) and an electrical driver is presented. The circuit reaches a bit-error-free data rate of 37 Gb/s, which is a record among other monolithically integrated transmitters reported in the literature. It was shown that by employing a high-swing driver, high extinction ratios (ER) can be achieved (namely 8.4 dB at 25 Gb/s and 7.6 dB at 35 Gb/s) while using short-length phase shifters (2 mm of length). It was therefore proved that one of the main drawbacks of the MZM-based transmitters, namely their large chip area, can be mitigated by using high-swing drivers, however without sacrificing the ER. Next, an improved modulator driver design is investigated, the focus of the study being the linearity. In addition to a high peak-to-peak differential output voltage swing of 7.2 Vpp,d, the driver achieves record-low total harmonic distortion (THD) values of 1% (at 1 GHz, for the output swing of 6.5 Vpp,d) and 1.7% (at 1 GHz, for the output swing of 7 Vpp,d). Moreover, the driver reaches a bandwidth of 61.2 GHz and shows a high power efficiency when relating its DC power consumption to its output voltage swing. The achievement of a high linearity and bandwidth without an increased power consumption is due to the fact that the bias currents of the emitter-follower (EF) stages are provided by means of resistors instead of the conventional current sources. The two approaches were first analyzed mathematically and subsequently compared by means of circuit simulations. It was shown that the proposed approach for the realization of the EFs – i.e. by means of resistors – allows a reduction of the DC power consumption by 19% compared to the current-source approach for an equivalent performance in terms of linearity and bandwidth. Finally, a modulator driver concept suitable for higher-order modulation formats is studied, namely the 8-level pulse amplitude modulation (PAM-8). The circuit was realized as a 3-bit digital-to-analog converter (DAC), thus being able to yield 8-level output signals. Moreover, the circuit is able to function as a PAM-4 driver as well, thanks to the tunable tail currents of the DAC core. It achieves a symbol rate of 50 Gbaud, which corresponds to a bit rate of 150 Gb/s for the PAM-8 modulation and 100 Gb/s for PAM-4. The study showed that a modulator driver can be realized that is able to switch between different modulation formats (namely PAM-8 and PAM-4), without requiring extra power or additional circuit parts. Moreover, the use of on-chip single-to-differential converters (SDCs) targets the relaxation of the requirements on the stages that precede the driver. Finally, relating its DC power consumption (590 mW, including the SDCs) to its output voltage swing (4 Vpp,d), the driver shows one of the highest power efficiencies among PAM modulator drivers in the literature.

In dieser Arbeit wird die Solvatationsdynamik einer solvatochromen molekularen Sonde diskutiert, und zwar als Methode für den Erhalt von lokalen IR-THz-Spektren von komplexen Systemen. Durch Femtosekundenanregung wird die Ladungsverteilung der Sonde verändert, und als Folge davon wird ein elektrisches Feld induziert. Zu diesem Zeitpunkt wirkt die im Lösungsmittel gelöste Sonde als Lichtquelle mit THz-Frequenzen. Da durch die Anregung das Gleichgewicht des Systems gestört wird, reorganisieren sich die Lösungsmittelmoleküle, sodass ein neues Gleichgewicht im angeregten Zustand entsteht. Die Bewegung der Lösungsmittelmoleküle ist (in gemittelter Form) als Stokes-Verschiebung des Fluoreszenz-Bandes beobachtbar. Durch eine geeignete Transformation der zeitaufgelösten Stokes-Verschiebung erhält man ein lokales IR-THz-Spektrum. Das Sondenmolekül wirkt daher auch als ein Detektor. Der Vorteil eines solchen "molekularen Spektrometers" ist sein mikroskopischer Aufenthaltsort, der u.a. sehr wichtig wird, wenn Messungen in Wasser durchgeführt werden: In diesem Fall macht eine intensive Absorption durch das Lösungsmittel das Eindringen von externen THz Strahlen tief in die Probe unmöglich. / Solvation dynamics of a solvatochromic molecular probe is discussed as a method to yield local IR-THz spectra of complex systems. After femtosecond excitation, the charge distribution of the probe is altered and, as a consequence, an electric field is generated. At this stage the solute acts as a light source with THz frequencies. Since by excitation the equilibrium of the system is perturbed, solvent molecules reorganize such that a new equilibrium is created in the excited state. This motion of solvent molecules can be seen (in an averaged form) by recording the Stokes shift of the fluorescence band. By an appropriate transformation of the time-resolved Stokes shift, a local IR-THz spectrum is obtained. The probe molecule therefore also acts as a detector. The advantage of such a “molecular spectrometer” is its locality, which becomes important when measurements are made in water. In this case, intense absorption by the solvent makes impossible the penetration of external THz beams deep into the sample.

Metal–organic frameworks (MOFs) are emerging as an appealing class of highly tailorable electrically conducting materials with potential applications in optoelectronics. Yet, the realization of their proof-of-concept devices remains a daunting challenge, attributed to their poor electrical properties. Following the authors’ recent report on a semiconducting Fe₃(THT)₂(NH₄)₃ (THT: 2,3,6,7,10,11-triphenylenehexathiol) 2D MOF with record-high mobility and band-like charge transport, here, Fe₃(THT)₂(NH₄)₃ MOF-based photodetector operating in photoconductive mode capable of detecting a broad wavelength range from UV to NIR (400–1575 nm) is demonstrated. The narrow IR bandgap of the active layer (≈0.45 eV) constrains the performance of the photodetector at room temperature by band-to-band thermal excitation of charge carriers. At 77 K, the device performance is significantly improved; two orders of magnitude higher voltage responsivity, lower noise equivalent power, and higher specific detectivity of 7 × 10⁸ cm Hz¹/² W⁻¹ are achieved under 785 nm excitation. These figures of merit are retained over the analyzed spectral region (400–1575 nm) and are commensurate to those obtained with the first demonstrations of graphene and black phosphorus based photodetectors. This work demonstrates the feasibility of integrating conjugated MOFs as an active element into broadband photodetectors, thus bridging the gap between materials’ synthesis and technological applications.

Die extrem große Bandbreite, die UWB-Systeme zur Übertragung von Daten nutzen können, ermöglicht theoretisch eine sehr hohe Datenrate. Eine mögliche Umsetzung der UWB-Technologie ist die sogenannte Multiband-Impuls-Radio-Architektur (MIRA). Dieses UWB-System basiert auf der Übertragung von Daten mittels kurzer Impulse parallel in mehreren Frequenzbändern. Als Empfänger kommen einfache Energiedetektoren zum Einsatz. Diese Komponenten haben entscheidenden Einfluss auf die Leistungsfähigkeit des gesamten Systems. Deshalb liegt der Schwerpunkt dieser Arbeit auf der Untersuchung der Leistungsfähigkeit und im speziellen der Herleitung der Bitfehlerwahrscheinlichkeiten für Energiedetektoren in unterschiedlichen UWB-Kanälen. Aufgrund des sehr einfachen Aufbaus eines Energiedetektors wird dieser auch in vielen anderen Bereichen eingesetzt. So werden Energiedetektoren zur Detektion von freien Bereichen im Übertragungsspektrum bei Cognitive Radio und für weitere unterschiedliche Übertragungssysteme wie z.B. Sensorsysteme mit geringer Datenrate und Übertragungssysteme die zusätzlich Ortung ermöglichen, genutzt.

Diese Arbeit konzentriert sich auf die Anwendbarkeit eines hochmodernen 100 kHz BB-VSFG-Spektrometers, das kürzlich im SALSA Photonics Lab entwickelt wurde, für die Analyse der Grenzflächenstruktur von Alkylketten, des sie umgebenden Wassers und der Phosphatkopfgruppen von Phospholipidschichten. Zunächst wurden Phospholipid-Doppelschichten, die mehrere Komponenten enthalten, bei Laserwiederholraten von 5, 10, 50 und 100 kHz mit konstanter Pulsenergie untersucht. Die BB-VSFG-Spektren legen nahe, dass die Phospholipid-Doppelschichten während der Messungen ohne wärmeinduzierte Veränderungen stabil waren. Darüber hinaus bot die Erhöhung der Laserwiederholungsrate eine praktikable Möglichkeit, Spektren in kurzen Datenerfassungszeiten zu erhalten, ohne dass das Signal-Rausch-Verhältnis beeinträchtigt wurde. Die extrem kurze Aufnahmezeit von 500 ms, die hohe spektrale Auflösung und alle verwendeten Pulsparameter sorgen dafür, dass bei Messungen unter Umgebungsbedingungen keine thermisch bedingten Photoschäden auftreten. Es wurde eine systematische Untersuchung von ein- und zweikomponentigen Phospholipid-Monoschichten in Abhängigkeit von der Oberflächenspannung und dem Mischungsverhältnis für verschiedene Kombinationen an Polarisationen durchgeführt und die Abhängigkeit der Schwingungsspektren untersucht. Die Struktur von Alkylketten und umgebendem Wasser wurde anhand derselben Modellsystemen analysiert. Bislang nicht beobachtete Schwingungsbanden und Spektren von Monolagen mit geringer Oberflächenbedeckung wurden mit einem bisher nicht erreichten Signal-Rausch-Verhältnis gemessen und beschrieben. Die Struktur von Phospholipid-Monolagen mit identischen Kopfgruppen und unterschiedlichen Ketten wurde analysiert und verglichen. Die Spektren bestätigten die Anwesenheit von Wassermolekülen in der Nähe der Phosphat- und Cholingruppen der Phospholipid-Monolagen. / This thesis focuses on the applicability of a state-of-the-art 100 kHz BB-VSFG spectrometer recently developed at the SALSA Photonics Lab and on the analysis of the interfacial structure of alkyl chains, surrounding water, and the phosphate head groups of phospholipid layers. First, multi-component phospholipid bilayers were studied at laser repetition rates of 5, 10, 50, and 100 kHz at constant pulse energy. The spectra suggest that the phospholipid bilayers were stable during the measurements with no heat-induced distortions. Moreover, an increase in the laser repetition rate provided a feasible route to obtain spectra in short data acquisition times without compromising the signal-to-noise ratio. The extremely short acquisition time of 500 ms, the high spectral resolution, and all applied pulse parameters ensured no thermal induced photodamages occur during the measurements. A systematic study of one- and two-component phospholipid monolayers as a function of surface tension and mixture ratio at different polarization combinations was performed and the dependence of the vibrational spectra was explored. The structure of alkyl chains and surrounding water was analyzed using the same model systems. Vibrational modes that were previously unseen and spectra of monolayers at low surface coverage were reported for the first time with an unprecedented signal-to-noise ratio. The structure of phospholipid monolayers containing identical head groups and different chains was analyzed and compared. The order of the phospholipid molecules as a function of the composition of the monolayers was inferred from the spectral data. The influence of the hydration and/or changes in the orientation of the phosphate group was visible from the spectra as well.