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Electrochemical supercapacitors (ESs) have attracted great attention due to the advantages of long cycle life, high charge/discharge rate and high power density compared to batteries. Significant improvement in ES performance has been achieved via development of advanced nanostructured materials, such as MnO2 and composite MnO2-MWCNT and PPy-MWCNT electrodes. In this dissertation, advanced dispersants were developed and investigated for the dispersion, surface modification and electrophoretic deposition (EPD) of metal oxides, multiwalled carbon nanotubes (MWCNT) and polypyrrole (PPy) in different solvents. Nature-inspired strategies have been developed for the fabrication of MWCNT films and composites. The outstanding colloidal stability of MWCNT, dispersed using anionic bile acids, allowed the EPD of MWCNT. Composite MnO2-MWCNT films were obtained by anodic EPD on Ni plaque and Ni foam substrates. Good dispersion of MWCNT during Py polymerization was achieved and allowed the formation of PPy coated MWCNT. The film and bulk electrodes, prepared by EPD and slurry impregnation methods, respectively, showed high capacitance and good capacitance retention at high charge-discharge rates. The mechanisms of dispersion and deposition were investigated. Cathodic and anodic EPD of MWCNT, MnO2, Mn3O4 was achieved using positively and negatively charged dispersants. Co-deposition of MWCNT and MnO2 was performed using a co-dispersant, which dispersed both MWCNT and MnO2 in ethanol. Composite films were tested for ES applications. The efficient dispersion was achieved at relatively low dispersant concentrations due to strong adsorption of the dispersants on the particle surface, which involved the polydentate bonding. We found the possibility of efficient dispersion of MWCNT in ethanol using efficient anionic dispersants. The electrostatic assembly method has been developed, which offers the benefit of improved mixing of MnO2 and MWCNT. The use of different anionic and cationic dispersants allowed the fabrication of electrodes with enhanced capacitance and improved capacitance retention at high charge–discharge rates and high active mass loadings. The asymmetric devices, containing positive MnO2–MWCNT and negative AC–CB electrodes showed promising performance in a voltage window of 1.6 V. We proposed another novel concept based on electrostatic heterocoagulation of Mn3O4- MWCNT composites in aqueous environment. In this case, various dispersants were selected for adsorption and dispersion of MWCNT and Mn3O4 and this allowed the formation of stable aqueous suspensions of positively charged MWCNT and negatively charged Mn3O4, which facilitated the formation of advanced composites with improved mixing of the components. Testing results showed promising performance of Mn3O4–MWCNT composites for applications in electrodes of electrochemical supercapacitors. / Thesis / Doctor of Philosophy (PhD)

The past few decades have seen a rapid sales increase and technological development of electric vehicles (EVs). As the key part of the electrical powertrain systems, the traction machine drive systems in modern EVs are composed of voltage source inverters (VSI) and electric machines. In this thesis, multiphase VSIs are studied and designed to achieve volume reductions when compared with existing 3-phase benchmark VSIs. Different existing switching strategies for arbitrary phase number multiphase VSIs are investigated resulting in an understanding of best practice and a newly proposed switching strategy. Thus, the first contribution of this thesis is switching strategies that support subsequent investigations and experimental validation. DC-link capacitor and heat sink are two bulkiest components in VSIs and hence it is more efficient to decrease their volumes to achieve the compactness improvement. The investigation methodology and procedure for arbitrary phase number VSI DC-link capacitor requirements, i.e. capacitance and RMS current ratings, are firstly developed. Increased phase number decreases the DC-link capacitor requirements and hence the VSI volume significantly. Throughout this analysis, the connected multiphase machine is considered appropriately, though no electric machine design is described in the thesis. While other authors have studied DC-link current ripple, this thesis qualifies and quantifies the system benefits. This is the second contribution. Multiphase VSIs thermal models are built and their respective thermal performances studied and evaluated against a reference 3-phase benchmark VSI. The power loss deviation among different semiconductor dies is lower or even eliminated in the multiphase VSIs. Furthermore, the multiphase integrated design VSIs have a significant heat sink volume reduction when compared to the 3-phase benchmark VSI. This study and concluding benefits are the third contribution. Finally, comparative test validations are made on an experimental set-up designed to illustrate the benefits of a 9-phase against a reference 3-phase system. Here, the test hardware and implementation are carefully designed to representatively illustrate performance benefits. / Thesis / Doctor of Philosophy (PhD)