La technique TWSTFT a démontré des performances remarquables par sa contribution dans l'organisation du TAI/UTC, en termes de stabilité des liens micro-ondes et d'incertitude combinée sur l'écart entre [UTC-UTC(k)]. Cependant, l'étroitesse de la bande passante des codes utilisés ne permet pas la comparaison à moins d'un jour des étalons primaires de fréquence, et le recours à l'utilisation de la phase des porteuses est une piste privilégiée. Ce travail de thèse consiste à étudier et développer la méthode two-way phase, choisie selon un ensemble de critères cohérents comme la disponibilité et la configuration adaptée de deux stations terriennes, la distribution adaptée des signaux d'horloges de hautes performances, la disposition d'un simulateur de satellite caractérisé et l'utilisation d'une même bande de fréquence satellite. La technique utilisée s'appuie simultanément sur des mesures two-way entre stations distantes et sur des mesures de ranging effectuées par chaque station, l'ensemble étant basé sur le principe de propagation liée à la vitesse des porteuses. De plus, une analyse expérimentale par le code et par la phase est effectuée et des solutions efficaces conduisant à la réduction du bruit des liens sont proposées. Les principaux résultats de mesures obtenus par la mise en œuvre de cette technique au laboratoire montrent une stabilité de fréquence de 1 x 10-12 à 1 s et de 3 x 10-14 à 100 s, avec deux stations alimentées par un même maser à hydrogène actif. Ce travail s'achève par notre contribution dans l'application de la technique de transfert de temps two-way sur un lien fibré long de 540 km en collaboration avec le LPL, révélant des résultats très prometteurs

The absorption spectra of a recently designed low-bandgap conjugated polymer has been studied using the semi-empirical method ZINDO and TDDFT/B3LYP/6-31G. The vertical excitation energies have been calculated for monomer up to hexamer. Two main absorption peaks can be seen, the one largest in wavelength corresponding to a HOMO to LUMO transition, and one involving higher order excitations. TDDFT results are red-shifted compared to the ZINDO results. Comparison with experiment yields that short conjugation lengths are dominating. This is possibly due to steric interactions between polymer chains, breaking the conjugation length. Such effects are also studied.

This thesis describes the development of electronic modules for fusion neutron spectroscopy as well as several implementations of artificial neural networks (NN) for neutron diagnostics for the Joint European Torus (JET) experimental reactor in England. The electronics projects include the development of two fast light pulser modules based on Light Emitting Diodes (LEDs) for the calibration and stability monitoring of two neutron spectrometers (MPRu and TOFOR) at JET. The particular electronic implementation of the pulsers allowed for operation of the LEDs in the nanosecond time scale, which is typically not well accessible with simpler circuits. Another electronic project consisted of the the development and implementation at JET of 32 high frequency analog signal amplifiers for MPRu. The circuit board layout adopted and the choice of components permitted to achieve bandwidth above 0.5 GHz and low distortion for a wide range of input signals. The successful and continued use of all electronic modules since 2005 until the present day is an indication of their good performance and reliability. The NN applications include pulse shape discrimination (PSD), deconvolution of experimental data and tomographic reconstruction of neutron emissivity profiles for JET. The first study showed that NN can perform neutron/gamma PSD in liquid scintillators significantly better than other conventional techniques, especially for low deposited energy in the detector. The second study demonstrated that NN can be used for statistically efficient deconvolution of neutron energy spectra, with and without parametric neutron spectroscopic models, especially in the region of low counts in the data. The work on tomography provided a simple but effective parametric model for describing neutron emissivity at JET. This was then successfully implemented with NN for fast and automatic tomographic reconstruction of the JET camera data. The fast execution time of NN, i.e. usually in the microsecond time scale, makes the NN applications presented here suitable for real-time data analysis and typically orders of magnitudes faster than other commonly used codes. The results and numerical methods described in this thesis can be applied to other diagnostic instruments and are of relevance for future fusion reactors such as ITER, currently under construction in Cadarache, France.

Electric breakdown in power transformers is preceded by pre-breakdown events such as streamers. The understanding of these phenomena is important in order to optimize liquid insulation systems. Earlier works have derived a model that describes streamers in transformer oil and utilized a finite element method to produce numerical solutions. This research investigates the consequences of changing the numerical method to a finite volume-based solver implemented in OpenFOAM. Using a standardized needle-sphere geometry, a number of oil and voltage combinations were simulated, and the results are for the most part similar to those produced by the previous method. In cases with differing results the change is attributed to the more stable numerical performance of the OpenFOAM solver. A proof of concept for the extension of the simulation from a two-dimensional axial symmetry to three dimensions is also presented. / Elektriska genomslag i högspänningstransformatorer föregås av bildandet av elektriskt ledande kanaler som kallas streamers. En god förståelse av detta fenomen är viktigt vid konstruktionen av oljebaserad elektrisk isolation. Tidigare forskning i ämnet har tagit fram en modell för fortplantningen av streamers. Denna modell har sedan lösts numeriskt av ett beräkningsverktyg baserat på finita elementmetoden. I denna uppsats undersöks konsekvenserna av att byta metod till finita volymsmetoden genom att implementera en lösare i OpenFOAM. En standardiserad nål-sfär-geometri har ställts upp och ett flertal kombinationer av oljor och spänningar har simulerats. De flesta resultaten visar god överensstämmande med tidigare forskning medan resultat som avviker har tillskrivits de goda numeriska egenskaperna hos OpenFOAM-lösaren. En ny typ av simulering har även genomförts där simulationen utökas från en tvådimensionell axisymmetrisk geometri til tre dimensioner.

The acoustic environment generated during launch is the most demanding structural load case for large, lightweight satellite reflector antennas. The reflector is exposed to extremely high sound pressure levels originating from the structural excitation of the rocket engines and exterior air flow turbulence. This thesis aims to predict the structural responses in the reflector due to the acoustic pressure load with a model based on Finite Element Modelling (FEM). The FE-model is validated against a previously performed Boundary Element Method (BEM) analysis. An approach called Split Loading together with a combination of BEM and FEM will be utilized to handle the surrounding air mass and the applied sound pressures. The idea of Split Loading is to divide the structure into several patches and apply a unit pressure load to each patch separately. In the last step the unit pressure is scaled and correlated by a power spectral density calculated from the acoustic pressures. Split Loading will be implemented in software packages MSC.NASTRAN/PATRAN. The model developed in this thesis handles both the added mass of the surrounding air and the sound pressure applied to the reflector. The model can qualitatively well reproduce the results of the BEM-analysis and the test data. However, the model tends to overestimate responses at low frequencies and underestimate them at high frequencies. The end results is that the model becomes too conservative at low frequencies to be used without further development.

No description available.

Molecular beam epitaxy has recently been applied to the growth and self assembly of nanostructures on crystal substrates. This highlights the importance of understanding how microscopic rules of atomic motion and assembly lead to macroscopic surface shapes. In this thesis, we present results from two computational studies of these mechanisms. We identify a kinetic mechanism responsible for the emergence of low-angle facets in recent epitaxial regrowth experiments on patterned surfaces. Kinetic Monte Carlo simulations of vicinal surfaces show that the preferred slope of the facets matches the threshold slope for the transition between step flow and growth by island nucleation. At this crossover slope, the surface step density is minimized and the adatom density is maximized, respectively. A model is developed that predicts the temperature dependence of the crossover slope and hence the facet slope. We also examine the "step bunching" instability thought to be present in step flow growth on surfaces with a downhill diffusion bias. One mechanism thought to produce the necessary bias is the inverse Ehrlich Schwoebel (ES) barrier. Using continuum, stochastic, and hybrid models of one dimensional step flow, we show that an inverse ES barrier to adatom migration is an insufficient condition to destabilize a surface against step bunching.

The interaction between light and organometallic chromophores has been investigated theoretically in a strive for fast optical filters. The main emphasis is on two-photon absorption and excited state absorption as illustrated in the Jablonski diagram. We stress the need for relativistic calculations and have developed methods to address this issue. Furthermore, we present how quantum chemical calculations can be combined with Maxwell's equations in order to simulate propagation of laser pulses through a materials doped with chromophores with high two-photon absorption cross sections. Finally, we also discuss how fast agile filters using spin-transition materials can be modeled in order to accomplish theoretical material design. / <p>Report code: LIU-TEK-LIC-2006:55. On the day of the defence date the status on article III was Manuscript, article IV was Accepted and article V was Submitted.</p>

A great interest has been shown for self-assembled organic nano-structures that can be used in a variety of optoelectronic applications, from element detection to home electronics. It is known from experimental research that sexiphenyl (6P) grown on muscovite mica substrate form uniaxially self-assembled nanofibers which together with sexithiophene (6T) deposited on top gives the possibility to tune their polarized emission. A key to continue develop and explore the full potential of this technique is to understand the mechanisms behind the growth. This thesis investigate the initial growth of 6P and 6T on a 6Pˆ<img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Cleft(11%20%5Cbar%7B1%7D%20%5Cright)%20%20%20" /> nanofiber substrate through Molecular Dynamics (MD) simulations. The adsorption of the molecules has been simulated with Simulated Annealing (SA) where 6P align perfectly with the substrate for all coverage while 6T starts to align after a certain amount of coverage. Both molecules show a monotonic increase in the adsorption energy per molecule with an increasing coverage. The surface diffusion of the molecules has been studied and shows a higher movement for both in the direction of the longmolecular axis. / Project P25154-N20 "Hetero-epitaxy of organic-organic nanofibers"

Dans cette thèse, nous présentons une étude rigoureuse des barres d'erreurs et des sensibilités de paramètres neutroniques (tels le k-eff) aux données nucléaires de base utilisées pour les calculer. Notre étude commence au niveau fondamental, i.e. les fichiers de données ENDF et leurs incertitudes, fournies sous la forme de matrices de variance/covariance, et leur traitement. Lorsqu'un calcul méthodique et consistant des sensibilités est consenti, nous montrons qu'une approche déterministe utilisant des formalismes bien connus est suffisante pour propager les incertitudes des bases de données avec un niveau de précision équivalent à celui des meilleurs outils disponibles sur le marché, comme les codes Monte-Carlo de référence. En appliquant notre méthodologie à trois exercices proposés par l'OCDE, dans le cadre des Benchmarks UACSA, nous donnons des informations, que nous espérons utiles, sur les processus physiques et les hypothèses sous-jacents aux formalismes déterministes utilisés dans cette étude.