III-V semiconductor nanowires (NWs) are often referred to as one-dimensional (1-D) materials because of their high aspect ratios and excellent quantum confinement properties. Spacing between NWs in a NW array is on the order of ~102 nm, which is close to the wavelength of visible light. These properties make NWs have excellent light trapping effects and suitability for optoelectronic applications, such as solar cells and photodetectors. Gallium arsenide (GaAs) has high electron mobility and a band gap of 1.424 eV, which makes it an ideal material for solar cells. Since GaAs NWs can be grown on either GaAs substrates or foreign substrates such as silicon (Si) substrates without lattice mismatch issues, they are being widely studied for photovoltaic applications. GaAs NWs could be achieved by the vapor-liquid-solid (VLS) method in molecular beam epitaxy (MBE), or etching a GaAs substrate by inductively coupled plasma reactive ion etching (ICP-RIE). Cyclotene was used as the filling material in gaps between NWs to support a low sheet resistance front contact and prevent shunts. An In/ITO contact was developed to achieve a lower contact resistance to n-GaAs NWs than an ITO contact, while it had a similar transmittance as ITO. A crack test also showed that insertion of a thin indium layer between ITO and GaAs NWs solved the ITO crack issue during heating that resulted from a large difference in coefficients of thermal expansion (CTE) between ITO and cyclotene. Energy dispersive x-ray spectrometry (EDS) was used to determine indium diffusion into NWs, and it showed that indium diffusion was not so significant to damage the features in NWs. A novel method to achieve substrate-free NW arrays by combining ICP-RIE and selective chemical etching together was also introduced. This method made it possible to measure the transmittance of NW arrays and contact layers for the first time. Absorption of GaAs NW arrays with various NW diameters and periods were also determined experimentally. / Thesis / Master of Applied Science (MASc)

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This current study examined the relationships among Freshmen students' contact with their parents, stress, adjustment, emotional and behavioral functioning, and self-esteem. As part of this study, 121 ethnically diverse college Freshmen completed measures assessing the aforementioned variables. Analyses of variance suggested that college Freshmen varied in their ratings of these variables based on their gender and living situation(i.e., whether they lived on campus, in the community, or in their parents' home). Correlational analyses suggested that there were significant relationships among parental involvement and college students' stress, adjustment, emotional and behavioral problems, and self-esteem. Hierarchical regression analyses suggested that gender, living situation, parental support, and perceived stress were valuable predictors of college students' outcomes. This information will serve to provide insight into mechanisms by which parents can help foster more positive outcomes for their college students.

The purpose of this study is to analyze the behavior of a reversible two-cylinder refrigerant compressor manufactured by Bristol Compressor Incorporated. This compressor contains a specialized linkage that causes the compressor to transition from a two-cylinder compressor to a single-cylinder compressor when the direction of rotation of the crankshaft is reversed. The linkage accomplishes this by reducing the throw of one cylinder to zero. Of interest are the conditions to which this linkage is subjected when the direction of rotation is again reversed, causing the compressor to return to its two-cylinder functioning. When this reversal takes place, a collision occurs within the linkage. These repeated collisions are thought to be the cause of fatigue failure of the linkage in many of these compressors. To verify that this collision is the problem, an understanding of the stress state during the collision is needed. This thesis begins the work necessary to determine the dynamic stress state present within the system. A FORTRAN program was developed that modeled the kinematic behavior of the system under operating conditions. The program predicts the accelerations, velocities, positions, and internal forces present within the system during startup conditions. Also, a method has been developed to model rotary sliding contact between two cylindrical surfaces. This method is developed and investigated in hopes that it will facilitate the modeling of the behavior of the compressor linkage in a dynamic finite element analysis. / Master of Science

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<p> A general study of theory of reliability has been made. The mechanism of failure of mechanical components, the properties of mechanical components, and the interaction of properties responsible for failure have been investigated. Elements of probability and statistics pertinent to reliability theory have been reviewed in brief. The various testing methods for determining component reliability using exponential, normal and Weibull distributions have been investigated. Acceptance sampling procedures for satisfying the necessary reliability requirements have been presented. Use of statistical methods in predicting fatigue life of mechanical components in general and rolling contact bearings in particular have been discussed. </p> / Thesis / Master of Engineering (MEngr)

The pursuit of optimizing soft contact lens performance has been extensive, given that approximately over 140 million contact lens wearers globally seek the convenience and visual acuity they offer. However, a persistent challenge is the prevalence of ocular dryness and discomfort experienced by almost half of these wearers, particularly towards the end of the day. The occurrence of these symptoms is primarily attributed to diminished compatibility between the contact lens and the ocular surface leading to contact lens discontinuation. A promising method to improve overall contact lens properties is to incorporate novel monomers with unique functionalities during the initial manufacturing stage. Monomers bearing ionic functional groups have been extensively explored to improve bulk and surface properties of biomaterials. The incorporation of cationic and zwitterionic monomers in the fabrication of hydrogel materials has shown to have anti-fouling and anti-bacterial properties and improved surface wetting. In this work, a series of novel materials using cationic and zwitterionic monomers were prepared and their impact on bulk and surface properties of contact lens materials were assessed. Furthermore, the impact of a novel hydrophilic silicone-based monomer bearing zwitterionic phosphocholine was investigated for water-based extraction, physiochemical and structural stability in candidate contact lens materials. In Chapter 2, a library of eleven positively charged (cationic) and electrically neutral with both positive and negative charges (zwitterionic) functional methacrylate ester monomers was produced through the reaction of 2-(dimethylamino) ethyl methacrylate (DMAEMA) with different alkyl halides. The Menshutkin reaction was carried out with a high level of success, resulting in moderate to high yields of the desired monomers. The monomers were purified and characterized using analytical techniques, including 1H-NMR (proton nuclear magnetic resonance), 13C-NMR (carbon-13 nuclear magnetic resonance), LCMS (liquid chromatography-mass spectrometry), and XRD (X-ray diffraction). Six monomers were chosen based on controlled end group hydrophilicity and chain length to investigate the relationship between chemical structure and overall performance in hydrogel and silicone hydrogel systems. In Chapters 3 and 4, model hydrogel and silicone hydrogel systems via UV free-radical polymerization at increasing input concentrations (10 and 20 wt%) were manufactured using the monomers and HEMA (hydrogel) or HEMA + SIGMA (silicone hydrogel). The novel materials demonstrated an increase in bulk equilibrium water content, reduced contact angle and nonspecific lysozyme and albumin adsorption, while maintaining optical transparency at higher than 90%. In vitro studies demonstrated the ionically charged hydrogel materials did not show any toxicity to human corneal epithelial cells. In Chapter 5, a super hydrophilic silicone-based SIGMAPC monomer was synthesized using the siloxane functional monomer (SIGMA) as the main building block. The introduction of the novel hydrophilic SIGMAPC monomer led to significant improvements in the silicone materials. The hydrogels showed increased water content and reduced water contact angles, indicating their superior hydrophilicity. Moreover, the rate of dehydration was decreased, and the nonspecific deposition of lysozyme and albumin was minimized. Importantly, the optical transparency of the hydrogel silicone remained above 90%. Based on these findings, it can be concluded that the siloxane-based monomer bearing a zwitterionic phosphocholine has great potential for applications in contact lenses, given its desirable properties and biocompatibility. Furthermore, in Chapter 6, 31P-NMR and weight extraction analysis showed model contact lens materials made with SIGMAPC were effectively extracted in aqueous media at elevated temperature. Candidate materials showed good dimensional and optical stability pre- and post-thermal sterilization and over 6-month storage period. / Thesis / Doctor of Philosophy (PhD)

Hot stamping and die quenching (HS/DQ) process of AA7075 aluminum alloy is one of attractive forming techniques for producing high strength automotive structural components to encounter their poor formability at room temperature. In this technique, quenching rate of this alloy is very crucial as it affects precipitation kinetics after artificial ageing of part formed, which in turn determines the final in-service mechanical properties and corrosion performance of part. Thermal contact resistance (TCR) between two solid surfaces is the main parameter that controls heat transfer between hot AA7075 sheet and cold steel dies, and thus affects quenching rate of part formed. Therefore, the final properties of automotive parts produced by hot stamping is indirectly influenced by TCR. The common methods of determining TCR in HS/DQ are often impracticable as they require thermocouples to be inserted into complex-shaped stamping dies, punches and thin aluminum sheet (blank) to be formed. A potential mechanistic approach for determining TCR could be an attractive alternative due to its avoidance of embedded thermocouples into the tooling and blank. The mechanistic method emphasizes on physical mechanisms (roughness etc.) governing interfacial heat transfer between cold forming tools and hot blank. The proposed work focuses on utilizing the mechanistic method to predict TCR between multiple cylindrical asperities on a nominally flat (and heated) AA7075 blank surface and a rigid, flat, asperity-free (and cold) steel die surface. The asperities were considered to deform elastoplastically, increasing contact area. Subsequently, TCR correlation as a function of temperature, contact load, and contact area was formulated. To validate the mechanistic model, a series of surface asperity flattening experiments using thermocouple-embedded AA7075 blank and polished stainless steel planar dies were carried out. Good agreement between mechanistic model predictions and experimental results in term of contact area and TCR as a function of contact load were observed. / Thesis / Doctor of Philosophy (PhD)