Doctor of Philosophy / Department of Mechanical and Nuclear Engineering / Douglas S. McGregor / Cadmium Zinc Telluride (CdZnTe) has been used for many applications, such as medical imaging and astrophysics, since its first demonstration as a room temperature operating gamma-ray detector in 1992. The wide band gap, high effective Z-number and high resistivity of CdZnTe make it a good candidate for use as a room temperature operated detector with good absorption efficiency, while maintaining a low bulk leakage current at high electric fields. Nevertheless, the low mobility lifetime products mu tau of holes in CdZnTe makes detectors position sensitive, unless advanced detector designs are employed. Among those designs is the Frisch collar technology which turns the detector into a single carrier device by negating the degrading effects of hole trapping and low mobility. The superiority of the Frisch collar technology over other methods include its inexpensive associated electronics and straight forward fabrication process. The main objective of this research study is to develop a large volume gamma-ray detector with an array of individual CdZnTe Frisch collar gamma-ray spectrometers while still using a single readout. Several goals were to be accomplished prior to the main objective. One goal is to develop a reliable low cost method to fabricate bulk CdZnTe crystals into Frisch collar detectors. Another goal was to investigate the limitations of crystal geometry and the crystal electrical properties to obtain the best spectroscopic performance from CdZnTe Frisch collar detectors. Still another goal was to study all other external parameters such as the collar length, anode to cathode ratio, the insulator thickness and applied voltage on performance of CdZnTe Frisch collar detectors. The final goal was to construct the CdZnTe Frisch collar devices into an array and to show its feasibility of being used for large volume detector.

Cadmium Zinc Telluride (CdxZn1-xTe or CZT) is a ternary semiconductor with a tunable bandgap of 1.44-2.26 eV. Solar cells with efficiencies of 20% or higher can be achieved by using a tandem solar cell structure which consists of a top cell and a bottom cell connected in series. In this kind of a structure, the light passes through the top cell first which has a wider bandgap to absorb light of shorter wavelengths and the remaining light passes through the bottom cell with a lower bandgap to absorb light of higher wavelengths. For a tandem cell structure, the ideal bandgap for the top and bottom cell is 1.7 eV and 1 eV respectively. Cadmium Zinc Telluride is a suitable candidate for the top cell and Copper Indium Gallium Diselenide (CIGS) with a bandgap of around 1 eV is a suitable candidate for the bottom cell. This work involves characterization and optimization of CZT solar cells by Close Spaced Sublimation (CSS). Cadmium Zinc Telluride is deposited by the co sublimation of Cadmium Telluride (CdTe) and Zinc Telluride (ZnTe) chunks. Cadmium Zinc Telluride solar cells were fabricated using Tin Oxide (SnO2), Zinc Oxide (ZnO) and Zinc Stannate (Zn2SnO4) films as substrates. The as-deposited CZT films were studied by XRD, EDS and SEM measurements. The devices were characterized by Current-Voltage (I-V) and Spectral Response measurements.

High efficiency solar cells can be attained by the development of two junctions one stacked on top of each other into tandem structures. So that, if a photon is not able to excite an electron-hole pair in the top cell can create a pair in the bottom cell, which has a smaller bandgap. For a two junction tandem device structure, the bandgap of the top cell should be 1.6-1.8eV and for the bottom cell should be 1eV to attain efficiencies in the range of 25%. Cadmium Zinc Telluride which has a tunable bandgap of 1.45- 2.2eV is a candidate for the top cell of the tandem structure. Cadmium Zinc Telluride (Cd1-xZnxTe) films were deposited by co-sputtering of CdTe and ZnTe. Deposition of Cd1-xZnxTe was studied in Ar and Ar/N2 ambient. Characterization of the films was done using transmission response, X-ray diffraction (XRD), Atomic Force Microscopy (AFM), Secondary Electron Microscopy (SEM), current-voltage (I-V) and spectral response measurements. CZT deposited on CdS/SnO2 substrates showed improved performance compared to other heterojunction partners. Doped graphite and copper were utilized as back contacts for CZT devices. Post deposition annealing treatments with ZnCl2 on CZT films were done and their effect on the devices was also studied. The best combination of Voc and Jsc were 530mV and 3.66mA/cm² respectively.

Title from PDF of title page. / Document formatted into pages; contains 70 pages. / Thesis (M.S.E.E.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: Currently thin film solar cells have efficiencies in the range of 16-18%. Higher efficiencies of 20% or more can be achieved by two junction solar cells in which two p-n junctions are connected in series one on top of the other in a tandem structure. The ideal bandgaps for optimum efficiency in a tandem structure are about 1eV for the top cell and 1.7 eV for the bottom cell. Copper Indium Gallium di-Selenide (CIGS) with a bandgap of 1 eV is a suitable candidate for the bottom cell and Cadmium Zinc Telluride (CZT) with a tunable bandgap of 1.44-2.26 eV is a suitable candidate for the top cell. This work involves characterization of cadmium zinc telluride films and solar cells prepared by close spaced sublimation. CZT is deposited by co-sublimation of CdTe and ZnTe. The process has been investigated on various wide bandgap semiconductor materials including cadmium sulphide, cadmium oxide and zinc selenide. / ABSTRACT: Different post deposition heat treatments were carried out to determine their effect on film and device properties. Characterization of the CZT devices was done using XRD, EDS, SIMS, J-V and spectral response measurements. CZT (Eg 1.7 eV) /CdS exhibited best performance when compared to the other window layers investigated. The best device exhibited Voc=640mV, FF=40% and Jsc=4.5 mA/cm2. The theoretical performance of CZT based solar cells were investigated using SCAPS. The effect of bulk and interface defects on the device parameters were studied. / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.

The infrared portion of the electro-magnetic spectrum is a challenging region in which to perform optical techniques, limited by both device efficiency and availability. In this dissertation, a new optical technique is introduced to facilitate polarization state measurement across the mid-IR. In addition, cadmium zinc telluride (CZT) is investigated as a potential new material suitable for electro-optic devices which function in the mid-IR, while also being characterized by other optical analysis methods. Thin film interference is discussed as it relates to optical techniques and electronic devices. A Stokes polarimeter is used to study the oxide development on the surface of CZT electronic devices, and the effect of natural thin films on substrates used in optical techniques is discussed. In particular, the impact of thin film interference on sum-frequency generation spectroscopy measurements of methyl group orientation are assessed. An FTIR source operated in step-scan mode is used to create a broadband, IR Stokes polarimeter which measures the polarization state of light from 2.5-11 μm simultaneously. Its design, involving two photo-elastic modulators and an analyzer, and theory are described in detail. This instrument is demonstrated by measuring linearly polarized light, and is applied to the measurement of the refractive index dispersion of quartz from 2.5-4 μm, which goes beyond the limits of literature values. Electro-optic crystals of CZT with electrodes of gold and indium are characterized at each wavelength in the mid-IR in terms of their electro-optic effects and apparent depolarization using the Stokes polarimeter. The material displays high-resistivity, allowing it to be operated with up to 5 kV applied DC voltage. The linear electro-optic effect is observed, but overall properties of the samples are found to be heavily dependent on the choice of metal for the electrodes. With a high-work function electrode material in gold, a large depletion region is created when high voltage is applied, which leads to a gradient in electric field throughout the material. This causes a beam of light transmitted through it to experience a distribution of electro-optic behaviours, which leads to overall depolarization of the light. Indium’s work function is lower than gold’s, and is closer to that of CZT. With indium electrodes, the electric field is found to be more consistent, and behaviour is much closer to ideal. The electro-optic effect of CZT is also characterized with AC applied voltage in order to assess its suitability to AC applied voltage applications. The power supply used for this was limited to 60 Hz, which precludes a complete characterization in this regard, but unexpected behaviour was seen. A methodology utilizing an oscilloscope and FTIR was developed in order to more completely understand the material response, and divergent behaviour with positive and negative voltage was found. / Graduate / 2018-12-18

This thesis processes heating of the apartment house in Rožnov pod Radhoštěm, Vsetín district. Revit program was used for the design of the heating. Some calculations were made in Revit too. Then the correctness of the calculations was checked. The Revit families were made in this thesis. These families support the calculations and design automation. Then these procedures were applied to the apartment house. It is five floors building with 1012 m2 of built area. Thesis solves design of heating and technical room equipment. The technical room is placed in first floor. Heat supply is solved as central heat supply system. The ventilation is mechanical, equal pressure. Thesis is in – cooperation with the house planner and the air – conditioning system design.

Currently thin film solar cells have efficiencies in the range of 16-18%. Higher efficiencies of 20% or more can be achieved by two junction solar cells in which two p-n junctions are connected in series one on top of the other in a tandem structure. The ideal bandgaps for optimum efficiency in a tandem structure are about 1eV for the top cell and 1.7 eV for the bottom cell. Copper Indium Gallium di-Selenide (CIGS) with a bandgap of 1 eV is a suitable candidate for the bottom cell and Cadmium Zinc Telluride (CZT) with a tunable bandgap of 1.44-2.26 eV is a suitable candidate for the top cell. This work involves characterization of cadmium zinc telluride films and solar cells prepared by close spaced sublimation. CZT is deposited by co-sublimation of CdTe and ZnTe. The process has been investigated on various wide bandgap semiconductor materials including cadmium sulphide, cadmium oxide and zinc selenide. Different post deposition heat treatments were carried out to determine their effect on film and device properties. Characterization of the CZT devices was done using XRD, EDS, SIMS, J-V and spectral response measurements. CZT (Eg~1.7 eV) /CdS exhibited best performance when compared to the other window layers investigated. The best device exhibited Voc=640mV, FF=40% and Jsc=4.5 mA/cm2. The theoretical performance of CZT based solar cells were investigated using SCAPS. The effect of bulk and interface defects on the device parameters were studied.

Background: The irradiation of cancer patients with charged particles, mainly protons and carbon ions, has become an established method for the treatment of specific types of tumors. In comparison with the use of X-rays or gamma-rays, particle therapy has the advantage that the dose distribution in the patient can be precisely controlled. Tissue or organs lying near the tumor will be spared. A verification of the treatment plan with the actual dose deposition by means of a measurement can be done through range assessment of the particle beam. For this purpose, prompt gamma-rays are detected, which are emitted by the affected target volume during irradiation. Motivation: The detection of prompt gamma-rays is a task related to radiation detection and measurement. Nuclear applications in medicine can be found in particular for in vivo diagnosis. In that respect the spatially resolved measurement of gamma-rays is an essential technique for nuclear imaging, however, technical requirements of radiation measurement during particle therapy are much more challenging than those of classical applications. For this purpose, appropriate instruments beyond the state-of-the-art need to be developed and tested for detecting prompt gamma-rays. Hence the success of a method for range assessment of particle beams is largely determined by the implementation of electronics. In practice, this means that a suitable detector material with adapted readout electronics, signal and information processing, and data interface must be utilized to solve the challenges. Thus, the parameters of the system (e.g. segmentation, time or energy resolution) can be optimized depending on the method (e.g. slit camera, time-of-flight measurement or Compton camera). Regardless of the method, the detector system must have a high count rate capability and a large measuring range (>7 MeV). For a subsequent evaluation of a suitable method for imaging, the mentioned parameters may not be restricted by the electronics. Digital signal processing is predestined for multipurpose tasks, and, in terms of the demands made, the performance of such an implementation has to be determined. Materials and methods: In this study, the instrumentation of a detector system for prompt gamma-rays emitted during particle therapy is limited to the use of a cadmium zinc telluride (CdZnTe, CZT) semiconductor detector. The detector crystal is divided into an 8x8 pixel array by segmented electrodes. Analog and digital signal processing are exemplarily tested with this type of detector and aims for application of a Compton camera to range assessment. The electronics are implemented with commercial off-the-shelf (COTS) components. If applicable, functional units of the detector system were digitalized and implemented in a field-programmable gate array (FPGA). An efficient implementation of the algorithms in terms of timing and logic utilization is fundamental to the design of digital circuits. The measurement system is characterized with radioactive sources to determine the measurement dynamic range and resolution. Finally, the performance is examined in terms of the requirements of particle therapy with experiments at particle accelerators. Results: A detector system based on a CZT pixel detector has been developed and tested. Although the use of an application-specific integrated circuit is convenient, this approach was rejected because there was no circuit available which met the requirements. Instead, a multichannel, compact, and low-noise analog amplifier circuit with COTS components has been implemented. Finally, the 65 information channels of a detector are digitized, processed and visualized. An advanced digital signal processing transforms the traditional approaches of nuclear electronics in algorithms and digital filter structures for an FPGA. With regard to the characteristic signals (e.g. varying rise times, depth-dependent energy measurement) of a CZT pixel detector, it could be shown that digital pulse processing results in a very good energy resolution (~2% FWHM at 511 keV), as well as permits a time measurement in the range of some tens of nanoseconds. Furthermore, the experimental results have shown that the dynamic range of the detector system could be significantly improved compared to the existing prototype of the Compton camera (~10 keV..7 MeV). Even count rates of ~100 kcps in a high-energy beam could be ultimately processed with the CZT pixel detector. But this is merely a limit of the detector due to its volume, and not related to electronics. In addition, the versatility of digital signal processing has been demonstrated with other detector materials (e.g. CeBr3). With foresight on high data throughput in a distributed data acquisition from multiple detectors, a Gigabit Ethernet link has been implemented as data interface. Conclusions: To fully exploit the capabilities of a CZT pixel detector, a digital signal processing is absolutely necessary. A decisive advantage of the digital approach is the ease of use in a multichannel system. Thus with digitalization, a necessary step has been done to master the complexity of a Compton camera. Furthermore, the benchmark of technology shows that a CZT pixel detector withstands the requirements of measuring prompt gamma-rays during particle therapy. The previously used orthogonal strip detector must be replaced by the pixel detector in favor of increased efficiency and improved energy resolution. With the integration of the developed digital detector system into a Compton camera, it must be ultimately proven whether this method is applicable for range assessment in particle therapy. Even if another method is more convenient in a clinical environment due to practical considerations, the detector system of that method may benefit from the shown instrumentation of a digital signal processing system for nuclear applications.:1. Introduction 1.1. Aim of this work 2. Analog front-end electronics 2.1. State-of-the-art 2.2. Basic design considerations 2.2.1. CZT detector assembly 2.2.2. Electrical characteristics of a CZT pixel detector 2.2.3. High voltage biasing and grounding 2.2.4. Signal formation in CZT detectors 2.2.5. Readout concepts 2.2.6. Operational amplifier 2.3. Circuit design of a charge-sensitive amplifier 2.3.1. Circuit analysis 2.3.2. Charge-to-voltage transfer function 2.3.3. Input coupling of the CSA 2.3.4. Noise 2.4. Implementation and Test 2.5. Results 2.5.1. Test pulse input 2.5.2. Pixel detector 2.6. Conclusion 3. Digital signal processing 3.1. Unfolding-synthesis technique 3.2. Digital deconvolution 3.2.1. Prior work 3.2.2. Discrete-time inverse amplifier transfer function 3.2.3. Application to measured signals 3.2.4. Implementation of a higher order IIR filter 3.2.5. Conclusion 3.3. Digital pulse synthesis 3.3.1. Prior work 3.3.2. FIR filter structures for FPGAs 3.3.3. Optimized fixed-point arithmetic 3.3.4. Conclusion 4. Data interface 4.1. State-of-the-art 4.2. Embedded Gigabit Ethernet protocol stack 4.3. Implementation 4.3.1. System overview 4.3.2. Media Access Control 4.3.3. Embedded protocol stack 4.3.4. Clock synchronization 4.4. Measurements and results 4.4.1. Throughput performance 4.4.2. Synchronization 4.4.3. Resource utilization 4.5. Conclusion 5. Experimental results 5.1. Digital pulse shapers 5.1.1. Spectroscopy application 5.1.2. Timing applications 5.2. Gamma-ray spectroscopy 5.2.1. Energy resolution of scintillation detectors 5.2.2. Energy resolution of a CZT pixel detector 5.3. Gamma-ray timing 5.3.1. Timing performance of scintillation detectors 5.3.2. Timing performance of CZT pixel detectors 5.4. Measurements with a particle beam 5.4.1. Bremsstrahlung Facility at ELBE 6. Discussion 7. Summary 8. Zusammenfassung / Hintergrund: Die Bestrahlung von Krebspatienten mit geladenen Teilchen, vor allem Protonen oder Kohlenstoffionen, ist mittlerweile eine etablierte Methode zur Behandlung von speziellen Tumorarten. Im Vergleich mit der Anwendung von Röntgen- oder Gammastrahlen hat die Teilchentherapie den Vorteil, dass die Dosisverteilung im Patienten präziser gesteuert werden kann. Dadurch werden um den Tumor liegendes Gewebe oder Organe geschont. Die messtechnische Verifikation des Bestrahlungsplans mit der tatsächlichen Dosisdeposition kann über eine Reichweitenkontrolle des Teilchenstrahls erfolgen. Für diesen Zweck werden prompte Gammastrahlen detektiert, die während der Bestrahlung vom getroffenen Zielvolumen emittiert werden. Fragestellung: Die Detektion von prompten Gammastrahlen ist eine Aufgabenstellung der Strahlenmesstechnik. Strahlenanwendungen in der Medizintechnik finden sich insbesondere in der in-vivo Diagnostik. Dabei ist die räumlich aufgelöste Messung von Gammastrahlen bereits zentraler Bestandteil der nuklearmedizinischen Bildgebung, jedoch sind die technischen Anforderungen der Strahlendetektion während der Teilchentherapie im Vergleich mit klassischen Anwendungen weitaus anspruchsvoller. Über den Stand der Technik hinaus müssen für diesen Zweck geeignete Instrumente zur Erfassung der prompten Gammastrahlen entwickelt und erprobt werden. Die elektrotechnische Realisierung bestimmt maßgeblich den Erfolg eines Verfahrens zur Reichweitenkontrolle von Teilchenstrahlen. Konkret bedeutet dies, dass ein geeignetes Detektormaterial mit angepasster Ausleseelektronik, Signal- und Informationsverarbeitung sowie Datenschnittstelle zur Problemlösung eingesetzt werden muss. Damit können die Parameter des Systems (z. B. Segmentierung, Zeit- oder Energieauflösung) in Abhängigkeit der Methode (z.B. Schlitzkamera, Flugzeitmessung oder Compton-Kamera) optimiert werden. Unabhängig vom Verfahren muss das Detektorsystem eine hohe Ratenfestigkeit und einen großen Messbereich (>7 MeV) besitzen. Für die anschließende Evaluierung eines geeigneten Verfahrens zur Bildgebung dürfen die genannten Parameter durch die Elektronik nicht eingeschränkt werden. Eine digitale Signalverarbeitung ist für universelle Aufgaben prädestiniert und die Leistungsfähigkeit einer solchen Implementierung soll hinsichtlich der gestellten Anforderungen bestimmt werden. Material und Methode: Die Instrumentierung eines Detektorsystems für prompte Gammastrahlen beschränkt sich in dieser Arbeit auf die Anwendung eines Cadmiumzinktellurid (CdZnTe, CZT) Halbleiterdetektors. Der Detektorkristall ist durch segmentierte Elektroden in ein 8x8 Pixelarray geteilt. Die analoge und digitale Signalverarbeitung wird beispielhaft mit diesem Detektortyp erprobt und zielt auf die Anwendung zur Reichweitenkontrolle mit einer Compton-Kamera. Die Elektronik wird mit seriengefertigten integrierten Schaltkreisen umgesetzt. Soweit möglich, werden die Funktionseinheiten des Detektorsystems digitalisiert und in einem field-programmable gate array (FPGA) implementiert. Eine effiziente Umsetzung der Algorithmen in Bezug auf Zeitverhalten und Logikverbrauch ist grundlegend für den Entwurf der digitalen Schaltungen. Das Messsystem wird mit radioaktiven Prüfstrahlern hinsichtlich Messbereichsdynamik und Auflösung charakterisiert. Schließlich wird die Leistungsfähigkeit hinsichtlich der Anforderungen der Teilchentherapie mit Experimenten am Teilchenbeschleuniger untersucht. Ergebnisse: Es wurde ein Detektorsystem auf Basis von CZT Pixeldetektoren entwickelt und erprobt. Obwohl der Einsatz einer anwendungsspezifischen integrierten Schaltung zweckmäßig wäre, wurde dieser Ansatz zurückgewiesen, da kein verfügbarer Schaltkreis die Anforderungen erfüllte. Stattdessen wurde eine vielkanalige, kompakte und rauscharme analoge Verstärkerschaltung mit seriengefertigten integrierten Schaltkreisen aufgebaut. Letztendlich werden die 65 Informationskanäle eines Detektors digitalisiert, verarbeitet und visualisiert. Eine fortschrittliche digitale Signalverarbeitung überführt die traditionellen Ansätze der Nuklearelektronik in Algorithmen und digitale Filterstrukturen für einen FPGA. Es konnte gezeigt werden, dass die digitale Pulsverarbeitung in Bezug auf die charakteristischen Signale (u.a. variierende Anstiegszeiten, tiefenabhängige Energiemessung) eines CZT Pixeldetektors eine sehr gute Energieauflösung (~2% FWHM at 511 keV) sowie eine Zeitmessung im Bereich von einigen 10 ns ermöglicht. Weiterhin haben die experimentellen Ergebnisse gezeigt, dass der Dynamikbereich des Detektorsystems im Vergleich zum bestehenden Prototyp der Compton-Kamera deutlich verbessert werden konnte (~10 keV..7 MeV). Nach allem konnten auch Zählraten von >100 kcps in einem hochenergetischen Strahl mit dem CZT Pixeldetektor verarbeitet werden. Dies stellt aber lediglich eine Begrenzung des Detektors aufgrund seines Volumens, nicht jedoch der Elektronik, dar. Zudem wurde die Vielseitigkeit der digitalen Signalverarbeitung auch mit anderen Detektormaterialen (u.a. CeBr3) demonstriert. Mit Voraussicht auf einen hohen Datendurchsatz in einer verteilten Datenerfassung von mehreren Detektoren, wurde als Datenschnittstelle eine Gigabit Ethernet Verbindung implementiert. Schlussfolgerung: Um die Leistungsfähigkeit eines CZT Pixeldetektors vollständig auszunutzen, ist eine digitale Signalverarbeitung zwingend notwendig. Ein entscheidender Vorteil des digitalen Ansatzes ist die einfache Handhabbarkeit in einem vielkanaligen System. Mit der Digitalisierung wurde ein notwendiger Schritt getan, um die Komplexität einer Compton-Kamera beherrschbar zu machen. Weiterhin zeigt die Technologiebewertung, dass ein CZT Pixeldetektor den Anforderungen der Teilchentherapie für die Messung prompter Gammastrahlen stand hält. Der bisher eingesetzte Streifendetektor muss zugunsten einer gesteigerten Effizienz und verbesserter Energieauflösung durch den Pixeldetektor ersetzt werden. Mit der Integration des entwickelten digitalen Detektorsystems in eine Compton-Kamera muss abschließend geprüft werden, ob dieses Verfahren für die Reichweitenkontrolle in der Teilchentherapie anwendbar ist. Auch wenn sich herausstellt, dass ein anderes Verfahren unter klinischen Bedingungen praktikabler ist, so kann auch dieses Detektorsystem von der gezeigten Instrumentierung eines digitalen Signalverarbeitungssystems profitieren.:1. Introduction 1.1. Aim of this work 2. Analog front-end electronics 2.1. State-of-the-art 2.2. Basic design considerations 2.2.1. CZT detector assembly 2.2.2. Electrical characteristics of a CZT pixel detector 2.2.3. High voltage biasing and grounding 2.2.4. Signal formation in CZT detectors 2.2.5. Readout concepts 2.2.6. Operational amplifier 2.3. Circuit design of a charge-sensitive amplifier 2.3.1. Circuit analysis 2.3.2. Charge-to-voltage transfer function 2.3.3. Input coupling of the CSA 2.3.4. Noise 2.4. Implementation and Test 2.5. Results 2.5.1. Test pulse input 2.5.2. Pixel detector 2.6. Conclusion 3. Digital signal processing 3.1. Unfolding-synthesis technique 3.2. Digital deconvolution 3.2.1. Prior work 3.2.2. Discrete-time inverse amplifier transfer function 3.2.3. Application to measured signals 3.2.4. Implementation of a higher order IIR filter 3.2.5. Conclusion 3.3. Digital pulse synthesis 3.3.1. Prior work 3.3.2. FIR filter structures for FPGAs 3.3.3. Optimized fixed-point arithmetic 3.3.4. Conclusion 4. Data interface 4.1. State-of-the-art 4.2. Embedded Gigabit Ethernet protocol stack 4.3. Implementation 4.3.1. System overview 4.3.2. Media Access Control 4.3.3. Embedded protocol stack 4.3.4. Clock synchronization 4.4. Measurements and results 4.4.1. Throughput performance 4.4.2. Synchronization 4.4.3. Resource utilization 4.5. Conclusion 5. Experimental results 5.1. Digital pulse shapers 5.1.1. Spectroscopy application 5.1.2. Timing applications 5.2. Gamma-ray spectroscopy 5.2.1. Energy resolution of scintillation detectors 5.2.2. Energy resolution of a CZT pixel detector 5.3. Gamma-ray timing 5.3.1. Timing performance of scintillation detectors 5.3.2. Timing performance of CZT pixel detectors 5.4. Measurements with a particle beam 5.4.1. Bremsstrahlung Facility at ELBE 6. Discussion 7. Summary 8. Zusammenfassung

The demand for wide bandgap semiconductors for radiation detector applications has significantly increased in recent years due to an ever-growing need for safeguard measures and medical imaging systems amongst other applications. The need for these devices to be portable and efficient, and to operate at room temperature is important for practical applications. For radiation detectors, the semiconductor materials are mainly required to have an optimal energy gap, high average atomic number, good electrical resistivity and charge transport properties as well as purity and homogeneity. Cadmium zinc telluride (CZT) distinctly stands out among the other choices of semiconductor materials for radiation detector applications, due to its attractive material properties and the room temperature operation possibility. A tremendous amount of research is being conducted to improve CZT technology and its implementation into more commercial systems. Applications of CZT detector technology in national security, high energy physics, nuclear spectroscopy, and medical imaging systems are of special interests. However, CZT devices still face challenges that need to be understood and overcome in order to have more efficient radiation detector systems. One such challenge lies in the understanding of the surfaces of CZT detectors and surface recombination effects on charge transport, charge collection efficiency, and detector performance. Another common issue is the degradation of CZT detectors due to the presence of defects which can act as traps for the charge carriers and cause incomplete charge collection from the detectors. Thus, a major challenge is that, the commercial CZT crystals have large concentrations of defects and impurities that need to be characterized, and their effects on the detector performance should be studied. Photoluminescence (PL) spectroscopy is a sensitive, non-contact and non-destructive method, suitable to characterize lower concentrations of point defects, such as substitutional impurities (donors, acceptors) and native defects in CZT crystals. A PL spectrum provides information regarding the defect nature of the crystal by determining the presence and the type of vacancies, interstitials, and impurities in the lattice. The main objective of this thesis is to address the presence of the defects in CZT crystals, identify their types, and study their roles in the performance of x-ray radiation detectors using PL spectroscopy. Additionally, using PL method and different excitation sources including UV excitation, this thesis studies the surface of CZT samples and investigates the PL signature of the surface oxide of the samples, in an effort to optimize the surface processing and thereby improve CZT detector performance. / Graduate

The dissertation deals with heating of the administrative building. The building is heated with the floor heating and the panel heating units. The heating source is an air to water heat pump with a bivalent heating from the central heat supplying (CZT). I deal in the project with design, dimension and connection of all these parts.