The automotive manufacturing industry is facing an interesting period of trial when a lot of improvement is expected of them in a short period of time to contribute to a cleaner planet by applying technologies that will reduce fossil fuel consumption. Electrification was good, but this must be accompanied by substantial curb weight reduction, which was provided by alloys such as A365, Aural 5 (AlSi8MnMg), Aural 2 (AlSi10MnMg), and Mercalloy 367 (AlSi9MgMnSr) for making structural parts. The use of these Al alloys is accompanied with extensive heat treatment which on its own involves fossil fuel consumption. In this research, test plates were made utilizing high vacuum high pressure die casting (HVHPDC) and a unique Al-Fe based eutectic alloy with Zn and Mg as precipitation strengtheners. Experimental results demonstrated that they age naturally, with their mechanical properties rising to the industry requirement within three days. DSC experiments carried out at various ages gave further experimental evidence to this natural ageing phenomenon. A portion of the samples was then given an experimental "paint bake" treatment at different ages. This is typical on an assembly line where the coated parts are baked at a temperature range of 120 - 200oC for thirty minutes. It was evidently defensible that samples of various ages respond to the treatment in different ways. The mechanical characteristics of the samples decreased after treatment to same value and progressively increased to match the values of the control samples. During the duration of the experiment, some samples rose quickly while others remained "nearly dead" in the state of low mechanical characteristics or climbed sluggishly to catch up with the natural ageing curve. The poorest results were seen in samples handled at the early stage when the initial clusters are forming indicating that it might not be a good idea to interfere with the NA process at those times. / Thesis / Master of Applied Science (MASc) / Fueled by the desire to produce an Al alloy with good mechanical properties arising from natural ageing, high vacuum high pressure die casting (HVHPDC) was used in making castings of this alloy which contains Fe for improvement on its castability and recyclability, contains Zn and Mg which act as the precipitating strengtheners driving the natural ageing phenomenon. Tests and experiments like uniaxial tensile tests, differential scanning calorimetry and electrical conductivity tests were carried out to ascertain its suitability to be used for structural automotive parts without heat treatment. The results showed that the new Nemalloy HE700 met with the minimum industry requirements for mechanical properties of materials for structural automotive applications within 3 days of natural ageing. The alloy was then subjected to experimental paint bake treatment to observe its reaction to paint bake process and the results were able to show when to do paint bake for best outcome.

A global shift towards reducing carbon (CO2) emissions in the automotive industry while increasing fuel efficiency and range security has triggered the exploration of new processing routes and material alternatives for automotive components. To achieve such goals, manufacturing processes such as high vacuum high pressure die casting (HV-HPDC) have gained attention in recent years to fabricate cast Al alloys for structural automotive components. HV-HPDC allows for increased and more economical production as compared to other manufacturing methods due to the minimal steps involved in the process. Higher degrees of tolerance and precision can be upheld with HV-HPDC, ceasing the need for secondary operations to form the component into desired complex shapes. In this research, the effect of pre-solidified grains (PSG) and heightened metal residence time on the microstructure and mechanical properties were investigated in a new heat-treatable casting alloy, (Al-1.1wt%Fe-4.7wt%Zn-0.95wt%Mg)-0.07wt%Ti, also known as Nemalloy HE700 alloy, manufactured via HV-HPDC. Developed at McMaster University in conjunction with Nemak USA/CAN and CanmetMATERIALS, Nemalloy HE700 alloy is intended for structural automotive applications with its higher strength and increased light weighting capabilities. Nemalloy HE700 serves as a suitable candidate to replace existing Al-Si alloys such as Aural-5 (Al-8wt%Si-Mg-Mn), currently used in the market today. As-cast test plate castings adhering to two geometries: a 3-step plate geometry (nominal plate thicknesses of 3 mm, 2.5 mm, and 2.3 mm) and a singular plate (2.5 mm) with increasing shot delay intervals of 3 additional seconds to a total of 10 seconds from normal operating conditions (i.e., 1, 4, 7, and 10 seconds) were fabricated with the intention of increasing PSG content within the final cast components to study the underlying effects. Experimental efforts through metallography revealed that, much like traditional high pressure die cast (HPDC) components, PSG gravitated toward the centers of the castings in all operating conditions with heightened agglomerations and potential abnormal grain growth in higher delay samples. Moreover, distributions of PSG became more dispersed through the cross-sections as the delay time was increased. Size distributions of PSG adhered to a standard characteristic grain of 100 µm to sizes of 1000+ µm. Larger sizes of PSG grew substantially in equivalent circular diameter (ECD) and extent in higher delay interval samples. Affected area percentage as a result of an increase in PSG content uncovered higher degrees of porosity presenting themselves as shrinkage and gas porosities in the microstructure. A rise in gas porosity size and quantity was realized with higher delay intervals. Uniaxial mechanical testing of tensile specimens from both geometries indicated a directional relationship of PSG where samples were increasingly more brittle and demonstrated adverse mechanical properties when testing was performed parallel to the metal flow direction as opposed to when performed perpendicularly. Moreover, Nemalloy HE700 alloy exhibited a lower propensity of formation of PSG than Aural-5 in higher levels of shot delay times, primarily due to compositional and differing solidification behaviours of the two alloys. The research presented characterizes the nature of PSG formation in HV-HPDC Al alloys with increased metal residence time and the resultant adverse effects on performance. As efforts shift toward manufacturing structural Al components using HV-HPDC, a greater understanding of such effects will aid in alloy development, die mould design, and disseminate information on HV-HPDC to produce components of heightened quality. Additionally, the resultant findings aim to address gaps in current literature as automotive manufacturers transition from non-structural HPDC components to structural HV-HPDC products for commercial use. / Thesis / Master of Applied Science (MASc)

Titanium and its alloys are widely used in applications ranging from aeroengines and offshore equipment to biomedical implants and sporting goods, owing to their high ratio of strength to density, excellent corrosion resistance, and biomedical compatibility. Among the titanium alloys used in aerospace, Ti-6Al-4V (an α+β alloy) is the most widely used, in applications in which the temperature may reach 350°C, at which point it retains good fatigue and fracture properties as well as moderate tensile strength and ductility. These alloy properties are dependent on variables such as crystalline structure, alloy chemistry, manufacturing techniques and environmental conditions during service. These variables influence the microstructure and mechanical properties of titanium alloys. With regard to the alloy chemistry and operating environment, the focus of the present work is to understand the influence of boron and hydrogen on the microstructure and selected mechanical properties of cast Ti-6Al-4V. The addition of boron to cast Ti-6Al-4V (0.06 and 0.11 wt% in this work) refines the coarse “as cast” microstructure, which is evaluated quantitatively using FoveaPro image analysis software. Compression testing was performed using a Gleeble 1500 instrument, by applying a 10% strain at different strain rates (0.001, 0.1 and 1 s-1) for temperatures in the range 25-1100°C. The tests were performed to evaluate the effect of boron on the mechanical properties of the alloy. It was observed that there is an increase in the compressive strength, predominantly at room temperature, of cast Ti-6Al-4V after the addition of boron. Metallographic evaluation showed that this increase in strength is a likely result of reductions in both the prior β grain and α colony dimensions, which is caused by boron addition. Studies in a hydrogen environment at 150 bar showed that cast Ti-6Al-4V exhibited lower yield strength and lower ultimate tensile strength in comparison with those properties measured in an air environment. No significant change in the ductility was observed. It was also noted that in a high strain range (≈2%) the low cycle fatigue (LCF) life was significantly reduced in hydrogen compared with air. Microstructural and fractographic characterization techniques were used to establish the role of hydrogen on the deformation mechanism by analysing the crack propagation path through the microstructure. It is seen that cracks tend to propagate along the interface between prior β grain boundaries and/or along the α colony boundaries

Purpose: The purpose of the thesis is to identify Swedish foundries’ challenges regarding circularity and sustainability demands and explore how SME foundries can be more sustainable and circular. Method: The research approach used in this study is an exploratory multiple-case study. The research questions are answered by using qualitative data through interviews and observations as data collection methods. Findings: The study’s findings present many challenges for Swedish foundries. The main challenges identified are fluctuations in demand, Just-in-Time, extra transports, and the availability of suitable supply chain partners. The challenge of demand fluctuations for SME foundries resulted in a recommendation on how SMEs can face the challenge. The recommendation aims to reallocate capacity by warehousing, followed by increasing communication in the supply chain. The study concludes that Swedish foundries are far from achieving circular supply chains but strive for sustainable foundries. Practical Implications: Organizations could use this thesis as a point of reference to compare and reflect on their foundry operations. Since SMEs are targeted for facing challenges in the industry, practical implications could provide a recommendation for organizations and managers in the foundry industry to collaborate more efficiently with OEMs. Theoretical Implications: This study contributes to the existing knowledge with a new perspective as the challenges connected to sustainability and circularity have been a gap for academia in the foundry industry. Delimitations: This thesis delimitates within the supply chain of one SME and two OEMs in the Swedish foundry industry. The SME’s role in the supply chain is a supplier of casted components, while the OEMs are both a producer of castings and a customer of components. The areas within the supply chain studied are castings, materials, logistics, production, and sustainability & circularity.

Thesis (D. Tech. ( Mechanical Engineering )) - Central University of technology, Free State, 2012 / In this study an alternative indirect Rapid Tooling process is proposed. It essentially consists of producing sand moulds by Additive Manufacturing (AM) processes followed by casting of tools in the moulds. Various features of this tool making method have been investigated. A process chain for the proposed tool manufacturing method was conceptually developed. This process chain referred to as Rapid Casting for Tooling (RCT) is made up of five steps including Computer Aided Design (CAD) modeling, casting simulation, AM of moulds, metal casting and finishing operations. A validation stage is also provided to determine the suitability of the tool geometry and material for RCT. The theoretical assessment of the RCT process chain indicated that it has potential benefits such as short manufacturing time, low manufacturing cost and good quality of tools in terms of surface finish and dimensional accuracy. Focusing on the step of AM of the sand moulds, the selection of available AM processes between the Laser Sintering (LS) using an EOSINT S 700 machine and Three Dimensional Printing using a Z-Corporation Spectrum 550 printer was addressed by means of the Analytic Hierarchy Process (AHP). The criteria considered at this stage were manufacturing time, manufacturing cost, surface finish and dimensional accuracy. LS was found to be the most suitable for RCT compared to Three Dimensional Printing. The overall preferences for these two alternatives were respectively calculated at 73% and 27%. LS was then used as the default AM process of sand moulds in the present research work. A practical implementation of RCT to the manufacturing of foundry tooling used a case study provided by a local foundry. It consisted of the production of a sand casting pattern in cast iron for a high pressure moulding machine. The investigation confirmed the feasibility of RCT for producing foundry tools. In addition it demonstrated the crucial role of casting simulation in the prevention of casting defects and the prediction of tool properties. The challenges of RCT were found to be exogenous mainly related to workmanship. An assessment of RCT manufacturing time and cost was conducted using the case study above mentioned as well as an additional one dealing with the manufacturing of an aluminium die for the production of lost wax patterns. Durations and prices of RCT steps were carefully recorded and aggregated. The results indicated that the AM of moulds was the rate determining and cost driving step of RCT if procurement of technology was considered to be a sunk cost. Overall RCT was found to be faster but more expensive than machining and investment casting. Modern surface analyses and scanning techniques were used to assess the quality of RCT tools in terms of surface finish and dimensional accuracy. The best surface finish obtained for the cast dies had Ra and Rz respectively equal to 3.23 μm and 11.38 μm. In terms of dimensional accuracy, 82% of cast die points coincided with die Computer Aided Design (CAD) data which is within the typical tolerances of sand cast products. The investigation also showed that mould coating contributed slightly to the improvement of the cast tool surface finish. Finally this study also found that the additive manufacturing of the sand mould was the chief factor responsible for the loss of dimensional accuracy. Because of the above, it was concluded that light machining will always be required to improve the surface finish and the dimensional accuracy of cast tools. Durability was the last characteristic of RCT tools to be assessed. This property was empirically inferred from the mechanical properties and metallographic analysis of castings. Merit of durability figures of 0.048 to 0.152 were obtained for the cast tools. It was found that tools obtained from Direct Croning (DC) moulds have merit of durability figures three times higher than the tools produced from Z-Cast moulds thus a better resistance to abrasion wear of the former tools compared to the latter.

"New, economical semi-solid metal (SSM) processes rely on forced convection during solidification to influence non-dendritic growth. The fundamental mechanisms that produce SSM microstructures in the presence of forced convection (due to fluid flow) are not fully understood. The objective of this work is to elucidate these mechanisms through the use of a new semi-solid slurry-making technique. Employing an apparatus developed at WPI, two alloy melts are mixed within a static reactor that induces convection and rapid cooling. Experiments carried out with this apparatus, named the “Continuous Rheoconversion Process” (CRP), result in globular semi-solid microstructures throughout a wide range of processing conditions. These conditions include the superheat in the melts before mixing, cooling rate of the slurry through the SSM range, and the presence or absence of inoculants in the melts. The results comprise repeatable sets of semi-solid microstructures having fine particle size and shape factors approaching unity. Even in the absence of melt inoculants, uniform distributions of α-Al particle sizes of about 60µm are attainable. Entrapped liquid is not present in the majority of the samples obtained with the CRP, and irregular particles that form in the process are of a limited distribution. Variation of slurry analysis methods indicates that these structures can be obtained consistently for both thixocasting and rheocasting applications. The design of the mixing reactor leads to turbulent fluid flow just as solidification commences. The results suggest that the following factors must be considered in identifying the mechanisms operating under the above conditions: copious nucleation of the primary phase; dispersion of nuclei throughout the bulk liquid; and inhibited remelting of nuclei due to temperature uniformity. In the CRP, these factors consistently lead to suppression of dendritic growth, significant grain refinement, and globular slurries. The exact fundamental mechanism leading to this effect is yet to be uncovered; however it is clear that temperature gradients ahead of the liquid are such that a cellular, non-dendritic morphology is the most stable growth form. Through further exploration of the process and identification of the operating mechanisms, future development of economical, continuous rheocasting methods will be facilitated."

"This research investigated the relationship between T5 heat treatment and elongation in thixocast and rheocast SSM components as a means to reduce the energy, time, and cost associated with T6 treatments while still producing improved properties over the as-cast condition. Temperature and time were varied as a part of work to optimize aging conditions for SSM materials. Both conventional furnace and fluidized bed heat treatments were employed. Tensile bars were fabricated from the heat treated A356 components and were pulled. Extensive SEM and stereo microscopy were performed to examine the factors which produced favorable results in the T5 condition. Data generated for T6 and as-cast components were also collected for purposes of comparison. Quality index calculations were employed to help evaluate the results. Optimized procedures and aging parameters have been presented"

Thesis (MScEng (Industrial Engineering))--University of Stellenbosch, 2008. / This thesis forms part of the AMTS Project on Investment Casting Capabilities for Light Metal Alloys in South Africa, the focus area being Rapid Tooling Development. Various issues of the investment casting process are being discussed from an industrial engineering point of view. These issues are related to the possibilities of improving the investment casting process’ lead times by shortening it while still maintaining affordable costs and required quality. Hereby the possibilities given by the newly developed “rapid technologies” are investigated. The focus is on Rapid Pattern Making as one of the most essential components for accelerated development of new products. Three of the most widely used layer manufacturing processes available in South Africa are selected for the study, namely Three Dimensional Printing – Drop-on-Bed (ZCorporation), Selective Laser Sintering (EOS) and Three Dimensional Printing – Drop-on-Drop (ThermoJet - 3D Systems). These three methods represent different materials; therefore different mechanical properties, different process economics as well as different technological characteristics. A standard benchmark part is used as a study base. Four patterns are produced by these three methods. A comprehensive measurement programme is conducted, followed by an appropriate statistical analysis and evaluation regarding accuracy and surface finish. Rapid Die Making is analysed with the possibilities of using additive methods for rapid tooling. Two dies are built with the same technology – Selective Laser Sintering (EOS), but in different materials. The same evaluation methodology is used for the statistical analysis and comparison. The two dies are injected with wax in order to produce the original benchmark part. The best wax patterns from each die are selected and evaluated, using the same methodology for analysis and comparison. The current state of Direct Shell Production is shortly discussed. The research concludes that RP&T techniques can successfully be used for creating accurate patterns and dies in order to shorten lead times in the investment casting process chain. Each RP&T process has its own set of advantages and disadvantages. All users should evaluate their requirements and the capabilities of the variety of techniques before deciding on a process to apply.

In its first part the work deals with the frequent defects of heavy steel castings. Experiments were carried out in very heavy bearing rings casting of cement kilns in order to reduce consumption of liquid metal and to increase the internal quality of castings. The progress was achieved by introducing new technologies; this thesis describes the technologies used and subsequently performs their comparison.

This diploma thesis is focusing on possibilities of influencing casting’s structure of nickel superalloy Inconel 713LC by force effects caused by vibration and rotation during crystallization. In this research were cast three test castings of turbine wheels with different solidification conditions that have affected the size and distribution of the grains. The aim was to compare the different microstructure and macrostructure of castings and then compare the dependence of grain refinement on mechanical properties. Changes in the structure were analyzed by means of light and electron microscopy methods after the fracture of test bars.