Le but de ce travail est de quantifier le potentiel et les capacités de la technologie térahertz à contrôler des colis afin de détecter les menaces telles que les armes et les explosifs, sans avoir besoin d'ouvrir le colis.Dans cette étude, nous présentons la spectroscopie térahertz résolue en temps et l'imagerie multi-spectrale pour la détection des explosifs. Deux types d’explosifs, ainsi que leurs mélanges binaires sont analysés. En raison de la complexité de l'extraction des informations face à tels échantillons, trois outils de chimiométrie sont utilisés: l’analyse en composantes principales (ACP), l'analyse des moindres carrés partiels (PLS) et l'analyse des moindres carrés partiels discriminante (PLS-DA). Les méthodes sont appliquées sur des données spectrales térahertz et sur des images spectrales pour : (i) décrire un ensemble de données inconnues et identifier des similitudes entre les échantillons par l'ACP ; (ii) créer des classes, ensuite classer les échantillons inconnus par PLS-DA ; (iii) créer un modèle capable de prédire les concentrations d’un explosif, à l'état pur ou dans des mélanges, par PLS.Dans la deuxième partie de ce travail, nous présentons l'imagerie par les ondes millimétriques pour la détection d'armes dans les colis. Trois techniques d'imagerie différentes sont étudiées : l'imagerie passive, l’imagerie active par des ondes continues (CW) et l’imagerie active par modulation de fréquence (FMCW). Les performances, les avantages et les limitations de chacune de ces techniques, pour l’inspection de colis, sont présentés. En outre, la technique de reconstruction tomographique est appliquée à chacune de ces trois techniques, pour visualiser en 3D et inspecter les colis en volume. Dans cet ordre, un algorithme de tomographie spécial est développé en prenant en considération la propagation gaussienne de l'onde. / The aim of this work is to demonstrate the potential and capabilities of terahertz technology for parcels screening and inspection to detect threats such as weapons and explosives, without the need to open the parcel.In this study, we first present terahertz time-domain spectroscopy and spectral imaging for explosives detection. Two types of explosives as well as their binary mixture is analyzed. Due to the complexity of extracting information when facing such mixtures of samples, three chemometric tools are used: principal component analysis (PCA), partial least square analysis (PLS) and partial least squares-discriminant analysis (PLS-DA). The analyses are applied to terahertz spectral data and to spectral-images in order to: (i) describe a set of unknown data and identify similarities between samples by PCA; (ii) create a classification model and predict the belonging of unknown samples to each of the classes, by PLS-DA; (iii) create a model able to quantify and predict the explosive concentrations in a pure state or in mixtures, by PLS.The second part of this work focuses on millimeter wave imaging for weapon detection in parcels. Three different imaging techniques are studied: passive imaging, continuous wave (CW) active imaging and frequency modulated continuous wave (FMCW) active imaging. The performances, the advantages and the limitations of each of the three techniques, for parcel inspection, are exhibited. Moreover, computed tomography is applied to each of the three techniques to visualize data in 3D and inspect parcels in volume. Thus, a special tomography algorithm is developed by taking in consideration the Gaussian propagation of the wave.

L’objectif de ce travail de thèse est l’élaboration du silicium polycristallin en phase liquide, sur substrat de verre borosilicate, en utilisant l’irradiation par laser continu de forte puissance d’un film de silicium amorphe. Des simulations numériques modélisant l’interaction laser-silicium amorphe ont été effectuées grâce à un modèle que nous avons développé sur l’outil COMSOL. Nous avons ainsi pu suivre l’évolution des transferts thermiques dans les différentes structures Si/verre irradiées par laser et ainsi pu évaluer l’impact des paramètres expérimentaux tels que la vitesse de balayage, la puissance du laser, la température du substrat sur les seuils de transition de phase du Si amorphe (fusion, cristallisation, évaporation). Ces résultats de simulation ont été confrontés à des données réelles obtenues en réalisant différentes expériences d’irradiation de films Si amorphe. Les résultats de cette comparaison ont été largement discutés. Dans une deuxième partie, nous avons étudié les propriétés structurales et morphologiques de films Si polycristallin obtenus par l’irradiation laser de films Si amorphe. En particulier, nous avons mis en évidence les effets de la présence d’impuretés tels que l’hydrogène ou l’argon présent dans les couches Si amorphe préalablement au traitement laser. Nous avons également montré que la croissance des cristaux silicium s’opère par épitaxie à partir d’un effet de gradient thermique latéral et longitudinal, produit respectivement par le profil énergétique du faisceau laser et la diffusion thermique par conduction, et par convection thermique dans la direction de balayage. L’optimisation des conditions opératoires nous a permis de réaliser des films Si polycristallin à larges grains, jusqu’à plusieurs centaines de µm de long sur plusieurs dizaines de µm de large. Ces structures sont très intéressantes pour des applications en électronique et en photovoltaïque. / The objective of this thesis is the elaboration of polycrystalline silicon, on borosilicate glass substrate, by a Continuous Wave laser annealing of amorphous silicon operating in the liquid phase regime. Numerical simulations of the laser-amorphous silicon interaction have been carried out using COMSOL tool. We were able to monitor the evolution of the heat transfer in the different laser irradiated Si/glass structures. Thus, we have evaluated the effects of experimental parameters such as the scan speed, the laser power, the substrate temperature on the phase transition thresholds (melting, crystallization, evaporation). The modeling data were compared to the experimental data obtained on laser irradiated amorphous Si films, and the results were thoroughly discussed. In a second part, we have investigated the structural and morphological properties of polysilicon films prepared by CW laser irradiation of different amorphous silicon. We have shown that the presence of impurities such as hydrogen or argon in the amorphous silicon affects strongly the quality of the formed polysilicon film. We also found that the Si crystal growth occurs epitaxially from lateral and longitudinal thermal gradient produced respectively by the laser beam profile and thermal conduction, and by thermal convection in the scanning direction. The optimization of the experimental procedure led to the formation of polysilicon films with large grains up to several hundred microns long and tens microns in width. Such materials are of great interest to electronic and photovoltaic devices.

Dans l'objectif de développer des nouveaux capteurs d'image 3D pour des applications émergeantes, nous avons étudié un pixel de mesure de distance de type « temps de vol ». Nous avons proposé une nouvelle architecture de pixel basée sur la méthode « Continuous-Wave modulation » à trois échantillons par pixel. Cette méthode repose sur la mesure d'un déphasage entre la source lumineuse modulée en amplitude envoyée (source proche infrarouge) et le signal réfléchi par la scène à capturer. Le pixel de dimensions 6,2μm x 6,2μm intègre une photodiode pincée, trois chemins de transfert de charges pour l'échantillonnage successif du signal modulé reçu, et d'un quatrième chemin pour évacuer les charges excédentaires. Les différents chemins de transfert sont constitués d'une grille de transfert de charges de la photodiode vers une mémoire de stockage à canal enterré pour améliorer le rendement et la vitesse de transfert de charges; d'une mémoire à stockage en volume à base de tranchées capacitives profondes afin d'augmenter la dynamique; d'un substrat dont l'épaisseur et le profil de dopage ont été optimisés afin de collecter efficacement les charges photogénérées et ainsi augmenter les performances de démodulation. Un véhicule de test constitué d'une matrice de résolution de 464x197 pixels (QVGA) a été fabriqué, différentes variantes de pixels et différents essais technologiques ont été étudiées et analysées. La fonctionnalité du pixel a été vérifiée pour des fréquences de démodulation de 20MHz à 165MHz, utilisant une source laser de longueur d'onde 850nm ou 950nm. Une première image de profondeur acquise utilisant une matrice de test est une validation du pixel proposé / In order to develop new 3D image sensors for emerging applications, we studied “time of flight” pixel for distance measurement. We have proposed a new pixel architecture based on the "Continuous-Wave Modulation" method with three samples per pixel. This method is based on the measurement of a phase shift between the transmitted amplitude modulated light source (near-infrared source) and the signal reflected by the scene to be captured. The pixel of dimensions 6.2 μm x 6.2 μm integrates a pinned photodiode, three charge transfer paths for successive sampling of the received modulated signal, and a fourth path for anti-blooming purpose. The different paths are controlled by a buried-channel transfer gate for charges transfer from the photodiode to memory in order to improve the efficiency and speed of the charge transfer; A fully depleted memory based on capacitive deep trenches is used to increase the memory storage capacitance; thickness and doping profile of the substrate have been optimized to efficiently collect photogenerated and increase demodulation performance. The designed 464x197-pixel (QVGA) test chip has been fabricated, different pixel variants and different technology trials have been studied and analyzed. Pixel functionality has been verified for demodulation frequencies from 20 to 165MHz, using a laser source of wavelength 850nm or 950nm. A first acquired depth image using the test chip made is a validation of the proposed pixel

The spins of phosphorus doped in silicon are potential candidates for a quantum computing device, with models based on the use of nuclear and/or electron spins suggested. For a quantum computing device, several essential criteria must be demonstrated before any physical implementation, and these include qubit control gates, long decoherence time and scalability. Scalability and compatibility with existing fabrication technologies are strong points in favour of a silicon based system. For spin based schemes, silicon has the potential to provide a host with zero nuclear spin (isotopically purifed 28Si) and also the phosphorus donor provides both nuclear and electron half integer spins (ideal case). In this work, a magnetic resonance method (electron spin resonance) was utilised to investigate these critical issues (controllable quantum gates and decoherence time) for the electron spins of phosphorus donors in silicon. Electron spin resonance (ESR) studies of an ensemble of phosphorus electron spins in silicon were conducted via both continuous wave and pulsed methods. For pulsed ESR operations, two low temperature (4 K and millikelvin) X-band pulsed ESR systems were built. They were designed especially to suit Si:P decoherence time measurements. The design, modelling, construction and evaluation of the probe heads are described. With the aid of computer simulations, the performance of the probe heads was optimised and a rectangular loop gap resonator was found to be the most suitable for wafer type samples. The resonant frequency, quality factor, and coupling coeffcient were calculated via simulation and are in reasonable agreement with experimental results. This demonstrates the effectiveness of such simulations as a tool for optimising the probe head performance. A millikelvin pulsed ESR system was set up through the combination of a dilution refrigerator, superconducting magnet and the in-house construction of a pulsed ESR spectrometer. This novel system allows pulsed ESR experiments on an ensemble system to be realised down to the millikelvin temperature range, hence providing conditions considered most favourable for quantum computing studies. The use of light in combination with the pulsed ESR systems was also explored in an endeavour to overcome the problem of very long spin-lattice relaxation time, T1, allowing the decoherence time to be measured more effciently. With these novel low temperature pulsed ESR units, two-pulse electron spin echo experiments were conducted on phosphorus donors in silicon (both natural silicon (natSi) and 28Si) with the phosphorus concentration in the range of 1015- 1016 P/cm3 and to lower temperatures than previously investigated. Decoherence times measured for both natSi:P and 28Si:P (with similar donor concentrations) were longer than previously reported. Discussions on several effective ways to obtain even longer Si:P decoherence times including variations to sample configurations and experimental conditions are presented. In addition to the pulsed ESR studies, the Si:P controllable quantum gate functions, A gate and J gate, were examined by the continuous wave technique via Stark shift and exchange interaction experiments respectively. Stark shift experiments on bulk samples were carried out to investigate possible manipulation of the spins by the applied electric field. Continuous wave ESR was also used to examine low energy ion implanted Si:P devices, both by single (P+) and dimer (P+2 ) implanted donors. The outcomes from these studies provide materials information useful in formulating a strategy toward the Si:P device fabrication via the top down approach.

Until recent years, terahertz (THz) waves were an undiscovered, or most importantly, an unexploited area of electromagnetic spectrum. This was due to difficulties in generation and detection of THz waves. Recent advances in hardware technology have started to open up the field to new applications such as THz imaging. This non-destructive and non-contact imaging technique can penetrate through diverse materials such that internal structures, in some cases invisible to other imaging modalities, can be visualized. Today, there are variety of techniques available to generate and detect THz waves in both pulsed and continuous fashion in two different geometries; transition, and reflection modes. In this thesis continuous wave THz imaging was employed for higher spatial resolution. However, with any new technology comes its challenges; automated processing of THz images can be quite cumbersome. Low contrast and the presence of a widely unknown type of noise make the analysis of these images difficult. In this work, there is an attempt to detect defects in composite material via segmentation by using a Terahertz imaging system. According to our knowledge, this is the first time that this type of materials are being tested under Terahertz cameras to detect manufacturing defects in aerospace industry. In addition, segmentation accuracy of THz images have been investigated by using a phantom. Beyond the defect detection for composite materials, this can establish some general knowledge about Terahertz imaging, its capabilities and limitations. To be able to segment the THz images successfully, pre-processing techniques are inevitable. In this thesis, a variety of different image processing techniques, self-developed or available from literature, have been employed for image enhancement. These methods range from filtering to contrast adjustment to fusion of phase and amplitude images by using fuzzy set theory, to just name a few. The result of pre-procssing and segmentation methods demonstrates promising outcome for future work in this field.

Until recent years, terahertz (THz) waves were an undiscovered, or most importantly, an unexploited area of electromagnetic spectrum. This was due to difficulties in generation and detection of THz waves. Recent advances in hardware technology have started to open up the field to new applications such as THz imaging. This non-destructive and non-contact imaging technique can penetrate through diverse materials such that internal structures, in some cases invisible to other imaging modalities, can be visualized. Today, there are variety of techniques available to generate and detect THz waves in both pulsed and continuous fashion in two different geometries; transition, and reflection modes. In this thesis continuous wave THz imaging was employed for higher spatial resolution. However, with any new technology comes its challenges; automated processing of THz images can be quite cumbersome. Low contrast and the presence of a widely unknown type of noise make the analysis of these images difficult. In this work, there is an attempt to detect defects in composite material via segmentation by using a Terahertz imaging system. According to our knowledge, this is the first time that this type of materials are being tested under Terahertz cameras to detect manufacturing defects in aerospace industry. In addition, segmentation accuracy of THz images have been investigated by using a phantom. Beyond the defect detection for composite materials, this can establish some general knowledge about Terahertz imaging, its capabilities and limitations. To be able to segment the THz images successfully, pre-processing techniques are inevitable. In this thesis, a variety of different image processing techniques, self-developed or available from literature, have been employed for image enhancement. These methods range from filtering to contrast adjustment to fusion of phase and amplitude images by using fuzzy set theory, to just name a few. The result of pre-procssing and segmentation methods demonstrates promising outcome for future work in this field.

Parmi les approches possibles pour réaliser des sources térahertz dans la gamme0,2 - 2 THz, nous nous sommes intéressés à la voie optoélectronique qui consiste à générerl’onde térahertz par le photomélange de deux ondes lasers à des fréquences optiques. Letravail présenté dans cette thèse concerne l’étude de lasers bi-fréquence capables d’émettreles deux ondes requises simultanément. Nous commençons par développer un modèlethéorique décrivant la compétition de gain entre les modes laser grâce au calcul de différentscoefficients de couplage. Sur le plan expérimental, nous montrons tout d’abord qu’endésalignant légèrement un des miroirs de la cavité laser, il est possible d’obtenir un régimestable d’émission sur deux fréquences pourtant en compétition dans le milieu à gain, ici uncristal dopé néodyme. Nous nous intéressons ensuite au régime impulsionnel et montronsque les impulsions peuvent être synchronisées grâce à l’action d’un laser externe. Enfin, leprocessus de photomélange a été réalisé et des ondes électromagnétiques ont été généréesdans le domaine des radio-fréquences autour de 20 GHz. / Among the possible solutions to build terahertz sources in the 0,2 - 2 THz range,we studied the optoelectronic way consisting in the generation of a terahertz wave by photomixingtwo laser waves at optical frequencies. The work presented in this PhD concernsthe study of dual-frequency lasers able to emit the two required waves simultaneously.We begin by developing a theoretical model describing the gain competition between thelaser modes by calculating different coupling coefficients. Experimentally, we first showthat a slight misalignment of the output mirror of the laser cavity allows to obtain a stableemission at two frequencies competing in the gain medium, which is a neodymium-dopedcrystal. Then, we focus on the pulsed regime and we show that the pulses can be synchronizedby the action of an external laser. Finally, the photomixing process has been achievedand electromagnetic waves have been generated in the radio frequencies range around 20GHz.

La tomographie optique diffuse (TOD) est une modalité d’imagerie biomédicale 3D peu dispendieuse et non-invasive qui permet de reconstruire les propriétés optiques d’un tissu biologique. Le processus de reconstruction d’images en TOD est difficile à réaliser puisqu’il nécessite de résoudre un problème non-linéaire et mal posé. Les propriétés optiques sont calculées à partir des mesures de surface du milieu à l’étude. Dans ce projet, deux méthodes de reconstruction non-linéaire pour la TOD ont été développées. La première méthode utilise un modèle itératif, une approche encore en développement qu’on retrouve dans la littérature. L’approximation de la diffusion est le modèle utilisé pour résoudre le problème direct. Par ailleurs, la reconstruction d’image à été réalisée dans différents régimes, continu et temporel, avec des mesures intrinsèques et de fluorescence. Dans un premier temps, un algorithme de reconstruction en régime continu et utilisant des mesures multispectrales est développé pour reconstruire la concentration des chromophores qui se trouve dans différents types de tissus. Dans un second temps, un algorithme de reconstruction est développé pour calculer le temps de vie de différents marqueurs fluorescents à partir de mesures optiques dans le domaine temporel. Une approche innovatrice a été d’utiliser la totalité de l’information du signal temporel dans le but d’améliorer la reconstruction d’image. Par ailleurs, cet algorithme permettrait de distinguer plus de trois temps de vie, ce qui n’a pas encore été démontré en imagerie de fluorescence. La deuxième méthode qui a été développée utilise l’apprentissage machine et plus spécifiquement l’apprentissage profond. Un modèle d’apprentissage profond génératif est mis en place pour reconstruire la distribution de sources d’émissions de fluorescence à partir de mesures en régime continu. Il s’agit de la première utilisation d’un algorithme d’apprentissage profond appliqué à la reconstruction d’images en TOD de fluorescence. La validation de la méthode est réalisée avec une mire aux propriétés optiques connues dans laquelle sont inséres des marqueurs fluorescents. La robustesse de cette méthode est démontrée même dans les situations où le nombre de mesures est limité et en présence de bruit. / Abstract : Diffuse optical tomography (DOT) is a low cost and noninvasive 3D biomedical imaging technique to reconstruct the optical properties of biological tissues. Image reconstruction in DOT is inherently a difficult problem, because the inversion process is nonlinear and ill-posed. During DOT image reconstruction, the optical properties of the medium are recovered from the boundary measurements at the surface of the medium. In this work, two approaches are proposed for non-linear DOT image reconstruction. The first approach relies on the use of iterative model-based image reconstruction, which is still under development for DOT and that can be found in the literature. A 3D forward model is developed based on the diffusion equation, which is an approximation of the radiative transfer equation. The forward model developed can simulate light propagation in complex geometries. Additionally, the forward model is developed to deal with different types of optical data such as continuous-wave (CW) and time-domain (TD) data for both intrinsic and fluorescence signals. First, a multispectral image reconstruction algorithm is developed to reconstruct the concentration of different tissue chromophores simultaneously from a set of CW measurements at different wavelengths. A second image reconstruction algorithm is developed to reconstruct the fluorescence lifetime (FLT) of different fluorescent markers from time-domain fluorescence measurements. In this algorithm, all the information contained in full temporal curves is used along with an acceleration technique to render the algorithm of practical use. Moreover, the proposed algorithm has the potential of being able to distinguish more than 3 FLTs, which is a first in fluorescence imaging. The second approach is based on machine learning techniques, in particular deep learning models. A deep generative model is proposed to reconstruct the fluorescence distribution map from CW fluorescence measurements. It is the first time that such a model is applied for fluorescence DOT image reconstruction. The performance of the proposed algorithm is validated with an optical phantom and a fluorescent marker. The proposed algorithm recovers the fluorescence distribution even from very noisy and sparse measurements, which is a big limitation in fluorescence DOT imaging.

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Recovering speech in the absence of the acoustic speech signal itself, i.e., silent speech, holds great potential for restoring or enhancing oral communication in those who lost it. Radar is a relatively unexplored silent speech sensing modality, even though it has the advantage of being fully non-invasive. We therefore built a custom stepped frequency continuous wave radar hardware to measure the changes in the transmission spectra during speech between three antennas, located on both cheeks and the chin with a measurement update rate of 100 Hz. We then recorded a command word corpus of 40 phonetically balanced, two-syllable German words and the German digits zero to nine for two individual speakers and evaluated both the speaker-dependent multi-session and inter-session recognition accuracies on this 50-word corpus using a bidirectional long-short term memory network. We obtained recognition accuracies of 99.17% and 88.87% for the speaker-dependent multi-session and inter-session accuracy, respectively. These results show that the transmission spectra are very well suited to discriminate individual words from one another, even across different sessions, which is one of the key challenges for fully non-invasive silent speech interfaces.