[Truncated abstract. Please see pdf format for complete text.] Over the years much work has been done on studying sequence effects under multilevel loading. Yet, the underlying fatigue mechanisms responsible for such interactions are not fully understood. The study of fatigue under complex loading histories begins by investigating strain interaction effects arising from simple 2-step loading sequences. Fatigue for all investigations were conducted under uniaxial push-pull mode in strain-control. Fatigue is traditionally classified as either low or high cycle fatigue (LCF and HCF respectively). The boundary for LCF and HCF is not well-defined even though the fatigue life of LCF is typically dominated by crack “initiation”, while for HCF, fatigue life is usually dominated by stable crack growth. The terms LCF and HCF, apart from referring to the low and high number of fatigue cycles required for failure, also bear little physical meaning in terms of describing the state of fatigue imposed. As a result, conventional definitions of the two distinct regimes of fatigue are challenged and a new method of classifying the boundary between the two regimes of fatigue is proposed. New definitions are proposed and the terms plastically dominant fatigue (PDF) and elastically dominant fatigue (EDF) are introduced as suitable replacements for LCF and HCF respectively. PDF refers to the condition of a material undergoing significant reverse plasticity during cyclic loading, while for EDF, minimal reverse plasticity is experienced. Systematic testing of three materials, 316 L stainless steel, 6061-T6 aluminium alloy and 4340 high strength steel, was performed to fully investigate the cycle ratio trends and “damage” accumulation behaviour which resulted from a variety of loading conditions. Results from this study were carried over to investigate more complex multilevel loading sequences and possible mechanisms for interaction effects observed both under 2-step and multi-step sequences were proposed. Results showed that atypical cycle ratio trends could result from loading sequences which involve combinations of strain amplitudes from different fatigue regimes (i.e. PDF or EDF). Mean strain effects on fatigue life were also studied. The objective of this study was to identify regimes of fatigue which are significantly influenced by mean strains. Results indicated that mean strains affected EDF but not PDF. 2-step tests, similar to those performed in earlier studies were conducted to investigate the effects of mean strain on variable amplitude loading. Again, atypical cycle ratio trends were observed for loading sequences involving combinations of PDF and EDF. It is understood that fatigue crack growth interaction behaviour and mean stress effects are two dominant mechanisms which can be used to explain cycle ratio trends observed. The significance and importance of proper PDF/EDF definition and specification are also stressed. The study of fracture mechanics is an important component of any fatigue research. Fatigue crack growth in 4140 high strength steel CT specimens, under conditions of plane stress and plane strain were studied. In this investigation, the effects of R and overload ratios were also studied for both plane stress and plane strain conditions. Results indicate that differences in the point of crack “initiation” under both plane stress and plane strain conditions decrease with increasing load range, while the extent of crack retardation as a result of overloading, is greater under plane stress than plane strain conditions. The extent of crack growth retardation increases with decreasing R ratios and increasing overload ratios. The final phase of this project involves the proposal of two practical models used to predict cumulative “damage” and fatigue crack propagation in metals. The cumulative “damage” model proposed takes the form of a power law and the exponent which governs “damage” accumulation can easily be calculated by knowing the failure life, Nf, for a given strain or load level. Predictions for the “damage” model performed better when compared to other popular cumulative “damage” models. The second model proposed predicts fatigue crack growth behaviour from known monotonic and smooth specimen fatigue data. There are several benefits of having a model that can predict fatigue crack growth from monotonic and smooth specimen fatigue data: a) traditionally, engineers had to rely on expensive and time-consuming crack propagation tests to evaluate and select materials for maximum fatigue resistance, and b) monotonic and smooth specimen fatigue data are readily available. The crack propagation model is proposed to alleviate the material selection process by providing engineers a means to rapidly eliminate and narrow down selections for possible material candidates.

Les métaux déposés base nickel sont utilisés pour assembler des composants du circuit primaire des centrales nucléaires à Réacteurs à Eau sous Pression (REP). Un nombre croissant de cas de fissuration par Corrosion Sous Contrainte (CSC) des soudures en alliages base nickel 182 et 82 est rapporté dans le retour d'expérience international ce qui motive le développement d'un modèle permettant de prévoir la fissuration par CSC de ces matériaux. Ce mécanisme de dégradation fait intervenir des paramètres matériaux, mécaniques ou environnementaux qui peuvent interagir entre eux. L'objectif de cette étude est de mieux comprendre les mécanismes physiques locaux (aux joints de grains) impliqués dans l'amorçage de fissures de CSC. Un essai de traction sur une éprouvette en alliage 182 préalablement oxydée en milieu primaire simulé a mis en évidence une dispersion de la sensibilité à l'oxydation des différents joints de grains. L'analyse couplée entre oxydation et fissuration a permis, à l'aide de calculs de micro-mécanique sur un agrégat polycristallin synthétique, de proposer un critère de rupture des joints de grains oxydés défini par un couple profondeur d'oxydation/ contrainte locale critique. Compte tenu du rôle clé que tient l'oxydation intergranulaire dans le mécanisme de fissuration par CSC et de la dispersion observée entre les différents joints de grains, une cinétique d'oxydation intergranulaire des alliages base nickel 182 et 82 a été identifiée prenant en compte la précipitation de carbures de chrome, la température ou encore la teneur en hydrogène dissous. Ce modèle cinétique permet d'aborder statistiquement l'oxydation des joints de grains et est intégré à un modèle d'amorçage local. Dans ce dernier l'amorçage, défini par la fissuration de l'oxyde intergranulaire est suivi d'une phase de propagation lente puis rapide jusqu'à une certaine profondeur de fissure. Des hypothèses simplificatrices ont été faites lors de l'identification des lois embarquées dans le modèle de CSC. Toutefois, celles-ci s'avèreront utiles pour cibler les conditions des futurs essais à mener afin de conforter l'identification des différents paramètres. / Nickel base welds are widely used to assemble components of the primary circuit of Pressurized Water Reactors (PWR) plants. International experience shows an increasing number of Stress Corrosion Cracks (SCC) in nickel base welds 182 and 82 which motivates the development of models predicting the time to SCC initiation for these materials. SCC involves several parameters such as materials, mechanics or environment interacting together. The goal of this study is to have a better understanding of the physical mechanisms occurring at grains boundaries involved in SCC. In-situ tensile test carried out on oxidized alloy 182 evidenced dispersion in the susceptibility to corrosion of grain boundaries. Moreover, the correlation between oxidation and cracking coupled with micro-mechanical simulations on synthetic polycrystalline aggregate, allowed to propose a cracking criterion of oxidized grain boundaries which is defined by both critical oxidation depth and local stress level. Due to the key role of intergranular oxidation in SCC and since significant dispersion is observed between grain boundaries, oxidation tests were performed on alloys 182 and 82 in order to model the intergranular oxidation kinetics as a function of chromium carbides precipitation, temperature and dissolved hydrogen content. The model allows statistical analyses and is embedded in a local initiation model. In this model, SCC initiation is defined by the cracking of the intergranular oxide and is followed by slow and fast crack growth until the crack depth reaches a given value. Simplifying assumptions were necessary to identify laws used in the SCC model. However, these laws will be useful to determine experimental conditions of future investigations carried out to improve the calibration used parameters.

The current shortage of crude oil from conventional sources has increased interest in developing unconventional resources such as oil sands. Heavy crudes and bitumen are found in Northern Alberta and their exploration, processing, and transport to market pose challenges in the use of these resources. Part of the solution to these challenges involves the reactive thermal processing of heavy crudes and bitumen. This thesis focused on mild thermal cracking reactions, and two studies regarding these reactions were presented. The first was an experimental study performed in a pilot-scale semi-batch reactor. The three crude oils were heated to 350, 400, 425, and 450°C at 1240 kPa. A five-lump reaction model combined with a process simulator with VLE calculations was fitted with the experimental data obtained. The goodness of fit between the model predicted values and experimental values for the Hardisty (MBL), Albian Heavy Synthetic (AHS), and Christina Lake Dilute Bitumen (CDB) were determined to be 0.99, 0.99, and 0.98, respectively. Moreover, 80, 85, and 89% of the optimized model’s predicted values had less than 10% error for MBL, AHS, and CDB, respectively. The second study described the implementation of a mild thermal cracking reaction model to the development of a train car fire-model for the assessment of safety aspects in the design of train cars used to transport crude oil. Case studies were conducted using the UniSim® depressuring utility and a previously developed mild thermal cracking reaction model to demonstrate the effect of compositional change. Three crude oils with varying properties and representative of the types of crudes transported by rail in Canada were used here: MBL, AHS, and CDB. The case studies conducted showed the performance of a train car fire-model to be dependent on the crude oil characteristics: up to -57% and -99% difference in model predicted variables for AHS and CDB, respectively, when compared to MBL. Furthermore, the model’s performance was also shown to be affected by the compositional change of a given crude oil due to mild thermal cracking reactions: up to 42% difference in model predicted variables when compared to the base case.

In this work, Slow Strain Rate Test (SSRT) testing, Light Optical Microscopy (LOM) and Scanning Electron Microscopy (SEM) were used to study the effect of micro-structure, corrosive environments and cathodic polarisation on stress corrosion cracking (SCC) of two grades of high strength steels, Type A and Type B. Type A is manufactured by quench and tempered (Q&T) method. Type B, a normalize steel was used as reference. This study also supports electrochemical polarisation resistance method as an effective testing technique for measuring the uniform corrosion rate. SSRT samples were chosen from base metal, weld metal and Heat Affected Zone (HAZ). SSRT tests were performed at room temperature under free corrosion potential and cathodic polarisation using 4 mA/cm2 in 1 wt% and 3.5 wt% NaCl solutions. From the obtained corrosion rate measurements performed in 1 wt% and 3.5 wt% NaCl solutions it was observed that increased chloride concentration and dissolved oxygen content enhanced the uniform corrosion for all tested materials. Moreover, the obtained results from SSRT tests demonstrate that both Q&T and normalized steels were not susceptible to SCC in certain strain rate(1×10-6s-1) in 1 wt% and 3.5 wt% NaCl solutions under free corrosion potential. It was con-firmed by a ductile fracture mode and high reduction in area. The weld metal of Type A with acicular ferrite (AF), pro-eutectoid (PF) and bainite microstructure showed higher susceptibility to hydrogen assisted stress corrosion cracking compared to base metal and HAZ. In addition, typical brittle intergranular cracking with small reduction in area was observed on the fracture surface of the Type A due to hydrogen charging.

Low temperature cracking is an important form of asphalt pavement deterioration in cold regions. The cracks develop when thermally induced stresses exceed the fracture resistance of the asphalt pavement. In this study, by incorporating HMA fracture mechanics into thermal cracking model, a new integrated model is introduced to investigate low temperature cracking performance. To evaluate its reliability and accuracy, the predicted thermally induced stress and failure temperature are compared with the fracture stress and fracture temperature obtained from thermal stress restrained specimen test. The findings indicate that this HMA fracture mechanics-based thermal cracking model has a great potential to reliably evaluate the performance of asphalt mixtures subjected to thermally induced damage.

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Tools that automate processes are always sough after across the entire IT field. This project's aim was to build and evaluate a semi-automated reconnaissance tool based on a Raspberry Pi 4, for use in penetration testing and/or digital forensics. The software is written in Python 3 and utilizes Scapy, PyQt5 and the Aircrack-ng suite along with other pre-existing tools. The device is targeted against wireless networks and its main purpose is to capture what is known as the WPA handshake and thereby crack Wi-Fi passwords. Upon achieving this, the program shall then connect to the cracked network, start packet sniffing and perform a host discovery and scan for open ports. The final product underwent three tests and passed them all, except the step involving port scanning - most likely due to hardware and/or operating system faults, since other devices are able to perform these operations. The main functionalities of this device and software are to: identify and assess nearby network access points, perform deauthentication attacks, capture network traffic (including WPA handshakes), crack Wi-Fi passwords, connect to cracked networks and finally to perform host discovery and port scanning. All of these steps shall be executed automatically after selecting the target networks and pressing the start button. Based on the test results it can be stated that this device is well suited for practical use within cyber security and digital forensics. However, due to the Raspberry Pi's limited computing power users may be advised to outsource the cracking process to a more powerful machine, for the purpose of productivity and time efficiency.

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No description available.

Stress corrosion, SC, in some cases gives rise to stress corrosion cracking, SCC, which differs from purely stress intensity driven cracks in many aspects. They initiate and grow under the influence of an aggressive environment in a stressed substrate. They grow at low load and may branch. The phenomenon of SCC is very complex, both the initiation phase and crack extension itself of SCC is seemingly associated with arbitrariness due to the many unknown factors controlling the process. Such factors could be concentration of species in the environment, stress, stress concentration, electrical conditions, mass transport, and so on.In the present thesis, chemically assisted crack initiation and growth is studied with special focus on the initiation and branching of cracks. Polycarbonate plates are used as substrates subjected to an acetone environment. Experimental procedures for examining initiation and branching in polycarbonate are presented. An optical microscope is employed to study the substrate.The attack at initiation is quantified from pits found on the surface, and pits that act as origin for cracks is identified and the distribution is analysed. A growth criterion for surface cracks is formulated from the observations, and it is used to numerically simulate crack growth. The cracks are seen to coalesce, and this phenomenon is studied in detail. Branching sites of cracks growing in the bulk of polycarbonate are inspected at the sample surface. It is found that the total width of the crack branches are approximately the same as the width of the original crack. Also, angles of the branches are studied. Further, for comparison the crack growth in the bulk is simulated using a moving boundary problem based algorithm and similar behaviour of crack branching is found. / <p>Both papers in thesis as manuscript, paper II with title "Branching cracks in a layered material - Dissolution driven crack growth in polycarbonate"</p>