The main material of electric arc furnace steel makers is scrap steel. The scrap steel was melted and reduced into molten steel and the substance of lower melting and boiling points are concentrated in fly ash. The ash collected by dust collector contains also, other than organic pollutants like polycyclic aromatic hydrocarbons, (PAHs), inorganic heavy metal pollutants, such as zinc, cobalt and lead. It is found that the content of zinc and cobalt in the ash are exceeding statutory standard of 5 mg/L and 1 mg/L. They are hazardous industrial waste.In the Steel Basic Industry Collected Dust Storage Extending Review Operation Key Point as amended on July 1, 2010 by Environmental Protection Administration, all the steel mills shall complete treatment of the stored collected dust before June 30, 2014 and no further storage will be permitted. Due to the fact that domestic capacity of treating collected dust is insufficient to meet the statutory requirements, the final treatment and disposition of collect duct has become a serious question to the steel mills.In this research, we press the dust collected in the process of arc furnace steel making into ingot and place into arc furnace for further melting and refining. Under temperature of 1600 ¢Jpart of the heavy metal is gasified and returned to waste gas and become collected dust and part of Silicon Dioxide and Magnesium Oxide are sintered into slag and turn the hazardous industrial waste into recycled industrial waste for further utilization, so that they may be disposed. After melting treatment, the collected dust, the regenerated dust has the zinc compound content increased to 13.45% and therefore increases the recycling value of collected dust. In this process, Iron Oxide is reduced 9.41% which can be turned into steel billet (product) and Silicon Dioxide and Magnesium Oxide are reduced 2.67% and were turned into slag.Results of this research indicated that after melting treatment of collected dust, it will be reduced 0.26% and is therefore good for waste reduction.

Till följd av den hårda utbyggnaden av vårt samhälle åtgår en stor mängd naturresurser. Samtidigt som samhället utveckas sätts allt högre krav på att det ska hushållas med naturresurser, inte minst genom införandet av miljömålet en ”God bebyggd miljö”. Enligt detta miljömål ska användningen av såväl mark som naturresurser ske på ett så hållbart sätt som möjligt. Samtidigt med detta skapar den svenska stålindustrin över en miljon ton slagg årligen, varav en stor del deponeras. Då deponeringen är kostsam pågår i dagsläget många försök att finna användningsområden för slagg så att deponeringskostanden ska undvikas. Bland annat har slagg i vissa fall visats kunna ersätta naturmaterial i formav sten, grus och sand vid till exempel vägbyggen och deponitäckningar. Slagg har i försök även visat på en vattenrenande förmåga då föroreningar fastläggs på slaggen.Detta har lett till försök med att använda slagg som filtermaterial i reaktiva filter där sand traditionellt sett ofta används. Denna studie avsåg att undersöka om slagg från Avesta Jernverk fungerar att använda i reaktiva filter för att rena vatten som är förorenade med till exempel tungmetaller och fosfor. Detta gjordes genom att skaka tre olika slagger som produceras i Avesta med ett lakvatten från en kommunal deponi med behov att renas från bland annat fluor, fosfor, kadmium, klorider, nickel och zink. I försöken användes en EAF-slagg och två AOD-slagger. För att undersöka om upptaget av föroreningar påverkades av om slaggen hade nya ytor användes både nykrossad slagg och slagg som varit placerade utomhus under 71 dagar. Resultaten visade att slaggerna som bildas vid Avesta Jernverk har en vattenrenandeförmåga och att samtliga av de testade slaggerna sorberade aluminium, fosfor och zink. Utöver dessa ämnen sorberade flera av slaggerna även arsenik, fluor, koppar och magnesium. Resultatet visade också på ett tidsberoende hos sorptionen, då mer föroreningar togs upp om slagg och lakvatten skakades i fem dygn jämfört med om skaktiden var femton minuter eller fyra timmar. Det gick dock inte att avgöra om slagg med nygjorda ytor sorberade bättre än slaggen som stått utomhus. Beräkningar utfördes och visade att ett slaggfilter dimensionsmässigt skulle vara möjligt att bygga och att en kornstorlek som sand skulle behövas för att få rätt uppehållstid. / As a result of the harsh exploitation and development of our society, a large amount of natural resources are needed. While the society develops it becomes more and more important to economise natural resources. This is also stated as an environmental objective, called "A good built environment" by the Swedish government. According to this environmental objective, the use of both land and natural resources should be undertaken in the most sustainable way possible. At the same time the Swedish steel industry produces over one million tonnes of slag annually, which is mostly deposited. Slag is a byproduct from the steel manufacturing process. When disposal is costly, many attempts to find usage for slag are done instead. For instance, in some cases it has been as replacement for natural resources as stone, gravel and sand in road constructions and landfill covers. Slag has also been shown to have a water-purifying capacity since contamination can be sorbed by the slag. This has led to attempts to use slag as filter material in reactive filters where sand traditionally is widely used. This study aimed to investigate whether slag from Avesta Works could be used in reactivefilters to purify water that is contaminated with heavy metals and phosphorus. This was done by shaking a number of slags produced in Avesta with leachate water from amunicipal landfill, Karlslund. The leachate water needs to be purified from i.a. fluorine, phosphorus, cadmium, chloride, nickel and zinc. In the experiments an EAF slag and two AOD slags were used. To investigate if the sorption of contamination in the leachate water was affected by the age of the particle surfaces, both slags with freshly made and aged surfaces were tested. The aging of the slags was created by placing the slags outdoor for 71 days. The results showed that the slags formed at Avesta Works has a water-purifying ability and that all of the tested slags sorbed aluminum, phosphorus and zinc. Beside these substances, some of the slags also sorbed arsenic, fluorine, copper and magnesium. Theresults also showed a time-dependence of the sorption: More contaminations were sorbed after reacting slag and leachate water for five days compared with fifteen minutes or four hours. It was not possible to determine if the slags with fresh surfaces sorbed better than the slags with aged surfaces. Calculations showed that a filter containing slag should be possible to build dimensionally and that the grain size of sand would be needed to get the required retention time.

This investigates the voltage flicker problem of a large steel plant and presents the mitigation strategy by applying the static var compensator (SVC) and cogenerator. The fluctuation of real power and reactive power consumption by an arc furnace has been measured and recorded during the steel production process. The dynamic load model of the A/C arc furnace is derived based on the actual field data and has been included in the computer simulation by the CYME software package for load flow analysis. The block diagrams of SVC controller and the excitation system of cogenerators are considered to solve the response of reactive power compensation according to the voltage fluctuation of the control bus. To maintain the electric service reliability of arc furnace when an external utility fault occurs, the tie line tripping and load shedding is implemented to prevent the tripping of cogenerator after system disturbance. It is found that the dynamic load behavior of arc furnace in the isolated industrial power system can be well compensated by the cogenerator with adaptive control of exciter and governor to generate proper reactive power and real power according to the fluctuation of bus voltage and system frequency respectively.

The harbour land fill in Halmstad has been described in the news as one of the most polluted areas in Halland County based on the a survey from the Swedish environmental protection agency. In order to identify the extent and severity of the situation several environmental investigations have been performed in this area. This report is based on available data from investigations and environmental reports from WSP, Höganäs AB, HEM and Halmstad municipality. This investigation focus on an “Area C” within the land fill where the main land fill material is i.a. slag from a steel work, construction waste, dredge spoil, waste from glass production and a casting shop. Of these material the focus have been on the metal rich slag from the steel work and its possible environmental impact. The environmental exposure of Hg, Pb, Cd, Cr, Zn, Ni, Mo and V have been calculated as an annual load from Area C. Unfortunately the data available for this investigation has not been complete, e.g. slag concentration data with corresponding leachate data was only obtained for one year. The groundwater data and land fill metal concentrations have been measured only once. This made it impossible to investigate e.g. annual variations like ageing effects of the material or weather variations, variation in the properties of the deposed slag material and statistical significance in differences could not be calculated. Further characterisation of the land fill would be worthwhile in order to be able to draw some conclusions. Calculations of the environmental load has been performed based on concentration in the slag, the land fill, the leachate data of the slag and groundwater concentrations. A model has been developed to calculate the weighted land fill metal concentration. The partitioning coefficient, Kd; between soil and liquid has been calculated and used to estimate the environmental load. It was assumed that the groundwater data was the most reliable data, which indicated that the exposure may be higher than from common soil, especially for Pb and Mo. Relating the environmental exposure values with guideline values based on MKM (less sensitive land use)-land using HQ (hazard quotient) indicates a decreasing risk in the order Pb>V>Mo. However, the exposure is well below that from MKM soil which could be assumed, according to Swedish environmental protection agency guideline values, to be an acceptable exposure.

This dissertation forms part of the ongoing process at UP to model and control the electric arc furniture process. Previous work focused on modelling the furnace process from empirical thermodynamic principles as well as fitting the model to actual plant data. Automation of the process mainly focused on subsystems of the process, for example the electric subsystem and the off-gas subsystem. The modelling effort, especially the model fitting resulted in parameter values that are described with confidence intervals, which gives rise to uncertainty in the model, because the parameters can potentially lie anywhere in the confidence interval space. Robust model predictive control is used in this dissertation, because it can explicityly take the model uncertainty into account as part of the synthesis process. Nominal model predictive control – not taking model uncertainty into account – is also applied in order to determine if robust model predictive control provides any advantages over the nominal model predictive control. This dissertation uses the process model from previous wok together with robust model predictive control to determine the feasibility of automating the process with regards to the primary process variables. Possible hurdles that prevent practical implementation are identified and studied. / Dissertation (MEng (Electronic Engineering))--University of Pretoria, 2007. / Electrical, Electronic and Computer Engineering / MEng / unrestricted

This dissertation forms part of the ongoing process at UP to model and control the electric arc furniture process. Previous work focused on modelling the furnace process from empirical thermodynamic principles as well as fitting the model to actual plant data. Automation of the process mainly focused on subsystems of the process, for example the electric subsystem and the off-gas subsystem. The modelling effort, especially the model fitting resulted in parameter values that are described with confidence intervals, which gives rise to uncertainty in the model, because the parameters can potentially lie anywhere in the confidence interval space. Robust model predictive control is used in this dissertation, because it can explicityly take the model uncertainty into account as part of the synthesis process. Nominal model predictive control – not taking model uncertainty into account – is also applied in order to determine if robust model predictive control provides any advantages over the nominal model predictive control. This dissertation uses the process model from previous wok together with robust model predictive control to determine the feasibility of automating the process with regards to the primary process variables. Possible hurdles that prevent practical implementation are identified and studied. / Dissertation (MEng (Electronic Engineering))--University of Pretoria, 2007. / Electrical, Electronic and Computer Engineering / MEng / unrestricted

The aim of this report was to investigate new methods for measuring the condition of the scrap in the electric arc furnace. This was done by evaluating three different methods theoretically and chooses two of them for test in the electric arc furnace in Avesta. Due to lack of time and equipment only Total harmonic distortion (THD) measurements was used. The results show that THD reaches low values during refining. This suggests that all the scrap is melted and the arcs are stable.

Phosphorus (P) in stormwater runoff has detrimental effects on water quality and ecosystem health when it reaches surface waters and promotes algal blooms. Constructed wetlands (CWs) have been utilized to combat this problem by containing stormwater and removing excess nutrients. Including filter materials in the design of CWs has shown promise for increasing their capacity for nutrient removal. This mesocosm scale study was conducted outdoors over a 12-month period to evaluate the effectiveness of three filter materials in their ability to adsorb phosphorus, retain water, and support plant life. The filter materials examined were electric arc furnace (EAF) slag, engineered biochar, and sand. All treatments demonstrated positive plant response and the ability to retain water. The EAF slag and biochar removed significant amounts of P from effluent and appear to be suitable materials for integrating into CW design. Sand was found to be ineffective as a P filter.

<p>Recent experiment in our laboratory demonstrates that an increase in slag foamingwith carbon injection rate is limited by slag volume. The current work has identified arelationship between foam height, carbon injection rate and slag volumes, whichpredicts the critical injection rate above which foaming become inefficient. Theprediction of critical injection rate employs an extension of understanding mechanismof bubble movement in the foam by estimating average/steady-state bubble size andwall thickness. The carbon gasification model developed in our laboratory by King etal., which has been extended to include greater consideration of gas bubble burstingwhen to predict bubble size, and further improvement for calculating how fast bubblecan burst instantaneously in carbon-gas-slag halo system, has found that has importantinfluence on the predicting foaming parameters in King’s model, which is crucial taskfor continuous development in future.</p> / Master of Applied Science (MASc)

In this work, feasibility of utilizing municipal incinerator fly ash (MIFA) of different sources as a substitute of raw materials for steel-making in a mini-mill was studied. Also studied included the efficacy of this mode of melting treatment and recycling. Under the condition of adding 1 wt% MIFA to scrap iron/scrap steel for partial replacement of lime, the L9 orthogonal arrays of Taguchi methods were utilized to investigate the effects of MIFA melting treatment of different sources by an electric arc furnace (EAF). Four experimental factors (i.e., scrap iron mass, lime mass, coke mass, and MIFA mass) were selected to study their effects on Pb leaching of EAF dust and slag. Test results for MIFA obtained from Plants K1, K2, and K3 show that EAF dust remains hazardous as it is originally a listed waste. On the other hand, slag so generated remains nonhazardous based on the TCLP results. The experimental results of EAF dust and slag were further subjected to the analysis of variance (ANOVA) and regular analysis. Using this process, the optimal operating conditions with respect to the leached Pb concentration would be as follows: (1) Plant K1(injection mode operation)--87 tons of scrap iron, 1.4 tons of lime, 0.4 ton of coke, and 0.9 ton of MIFA; (2) Plant K2(injection mode operation)--90 tons of scrap iron, 1.4 tons of lime, 0.7 ton of coke, and 1.1 tons of MIFA; (3) Plant K2(one-time-charge mode operation)--90 tons of scrap iron, 1.4 tons of lime, 0.9 ton of coke, and 0.7 ton of MIFA; (4) Plant K3(injection mode operation)--85 tons of scrap iron, 1.4 tons of lime, 0.7 ton of coke, and 0.9 ton of MIFA; and (5) Plant K3(one-time-charge mode operation)--87 tons of scrap iron, 1.5 tons of lime, 0.4 ton of coke, and 0.7 ton of MIFA. In this study, using MIFA from Plant K2 as an example, it was found that it required 29-35 kg of lime per ton of steel billets produced when MIFA was added. Under a normal operation of EAF steel-making, however, it required 35-45 kg of lime per ton of steel billets produced based on the past experience. In average, when MIFA is added, it needs only 32 kg of lime per ton of steel billets produced as compared to 40 kg of lime for regular steel-making. In other words, it would result in a reduction of 8 kg of lime per ton of steel billets produced by using this novel process. Based on an average monthly production of 20,973 tons of steel billets and a unit cost of 2,200 NT$ per ton of lime, a monthly saving of lime cost would be 369,125 NT$. Namely, about 4.4 million NT$ per year. In addition, it was also found that using this novel process to melt MIFA would not deteriorate the quality of steel billets and bars produced.