<p>The 2020 pandemic emphasized the need for accessible and accurate point-of-care diagnostic tests. With the continued development of isothermal nucleic acid amplification tests, this can be achieved. A requirement of these tests includes heating and holding a specific temperature, in this case, 65C for 30 minutes, for amplification to occur. To achieve this, heaters often require external feedback to control the temperature; bringing up the device’s cost. Several self-regulating heaters have been made with materials having a positive thermal coefficient of resistance eliminating the need for complex circuitry. With this property, point-of-care diagnostic tests can be simplified and made more accessible. In this study, ink-based positive thermal coefficient of resistance heaters are developed and characterized using the scalable method of screen printing to achieve 65C and aid in the detection of SARS-CoV-2. Various curing methods and screen-printing parameters were evaluated to improve the stability and understanding of the reproducibility of the heaters. The longevity of the heaters was evaluated with oxidation studies and a COMSOL model was created to study the heat transfer within the device. Furthermore, the heaters were successfully implemented into a second-generation electronic point-of-care diagnostic device. Detection of SARS-CoV-2 using a self-regulating heater removes the need for complex circuitry, improving the accessibility of point-of-care tests with the potential to be expanded to a wide range of pathogen detection. </p>

No description available.

A importância das novas tecnologias de informação, automação, monitoramento e sistemas eletrônicos inteligentes têm aumentado significativamente nos últimos anos. Essas tecnologias desempenham um papel fundamental na sociedade moderna e contribuem de forma decisiva para a resolução de importantes desafios para uma sociedade que quer ser mais próspera, internacionalmente competitiva, saudável, segura e sustentável. Como eixo de \"inovação\", essas tecnologias são fatores importantes para todos os setores produtivos da economia. O motor destas tecnologias, entretanto, é a energia, particularmente a eletricidade. Assim, em uma sociedade cujo estilo de vida é fortemente dependente dela, desenvolver tecnologias que permitam não somente a geração, mas também a distribuição de energia de forma barata e limpa e que garantam seu fornecimento ao longo do tempo com a máxima eficiência é uma questão prioritária. Os sistemas baseados em redes inteligentes (do inglês: Smart Grid) vêm, justamente, atender a esses requisitos, representando o que há de mais moderno no setor elétrico, com aumento e diversificação de fontes de geração distribuída na forma de pequenos geradores, maior interação consumidor-distribuidor de energia, integração de diferentes fontes de geração renováveis (ex.: solar, eólica etc.). O cenário energético nacional está avançando de forma muito rápida. Nas distribuidoras, o foco claramente está na redução de perdas comerciais e de custos operacionais, principalmente por meio da modernização dos ativos e da crescente instalação de dispositivos eletrônicos inteligentes nos clientes de baixa tensão (ex.: medidores eletrônicos, dispositivos eletrônicos inteligentes para monitoramento e diagnóstico, relés digitais etc.). Esta tese de doutorado apresenta uma solução com tecnologia nacional que disponibiliza todos os benefícios do Smart Grid através dos equipamentos mais importantes e estratégicos presentes na topologia das Redes de Distribuição Subterrânea Secundária Trifásica: os Protetores de Redes. A partir do centro nevrálgico das Redes de Distribuição Subterrâneas (RDS), cuja topologia está presente nos centros de alta concentração de carga das principais metrópoles do Brasil, a solução desenvolvida pode viabilizar técnica e economicamente a modernização da automação da RDS, com tecnologia nacional de baixo custo, proporcionando igualmente a incorporação dos avanços do Smart Grid e da Geração Distribuída. Este salto tecnológico significaria para as distribuidoras de energia elétrica entre outros benefícios: Melhor controle do processo para uma melhor otimização da rede, desde integração das intermitentes fontes renováveis até uma interação mais dinâmica com os consumidores; Maior flexibilidade às concessionárias em relação ao uso da energia para atingir o grande objetivo social de redução do efeito estufa e otimização do consumo de energia reduzindo perdas e desperdícios; No curto prazo, os benefícios diretos da melhoria do gerenciamento da indisponibilidade, gerenciamento otimizado dos ativos e do capital, melhoria no planejamento, processos e serviços de fornecimento e usos finais de energia, aumento de eficiência de manutenção, redução de perdas técnicas e comerciais, otimização do investimento na compra de novos protetores com menores custos podendo superar a demanda reprimida pelos altos custos de alternativas importadas. / The importance of new technologies in the field of, automation, monitoring, information technology and electronic systems have increased significantly in recent years. These technologies play a basic role in the modern society and contribute of decisive way for the resolution of important challenges for a society that is in search of a more prosperous life, internationally competitive, healthful, safe and sustainable. As a key of \"innovation\", these technologies are key factors for all the productive sectors of the economy in the society. The fuel for the engine of these technologies, however, is the energy, particularly the electricity. Thus, in a society whose life style is strongly dependent of electricity, to develop technologies that not only allow the generation, but also the distribution of energy in a cheap and clean way and which could guarantee its supply throughout the time with the maximum efficiency is a priority issue. The systems based on intelligent networks fully meet these requirements, representing what there is of most modern in the electric sector. The Brazilian energy scenario is quickly changing over the recent years toward modernization, with more distributed generation, in the form of smaller generators, more customer interaction, the integration of more variable resources such as wind and solar, and more renewables overall. For the Power Utilities, especially in the Distribution Sector, the focus is clearly in the reduction of commercial losses and operational costs, mainly by means of the modernization of the assets and an increase in the installation of intelligent electronic devices at consumers side (e.g.: electronic energy meters, intelligent electronic devices for condition monitoring, digital relays etc.). This work presents a solution developed based on Brazilian technology that incorporates all the benefits of smart grid to the most important equipment that is present in the topology of the Low-Voltage Secondary Network Distribution System: the Network Protector. From the neuralgic center of these Low-Voltage Secondary Network Systems, which topology is used in the most important cities in Brazil, which has a high load concentration, the solution presented here make it feasible technically and economically the use of smart grid topology profiting from its great benefits such as: Allow utilities to better optimize the grid to support a number of public policies, from intermittent renewable integration to more dynamic interfaces with customers; Offer utilities more flexibility relative to how they use energy toward the greater societal objectives of reducing greenhouse gases and energy consumption. In the short and mid term, a smarter grid offers utilities operational benefits (outage management, improved processes, maintenance and workforce efficiency, reduced losses, etc.) as well as benefits associated with improved asset management (system planning, better capital asset utilization, etc.), lower investment to acquire new Network Protectors.

A importância das novas tecnologias de informação, automação, monitoramento e sistemas eletrônicos inteligentes têm aumentado significativamente nos últimos anos. Essas tecnologias desempenham um papel fundamental na sociedade moderna e contribuem de forma decisiva para a resolução de importantes desafios para uma sociedade que quer ser mais próspera, internacionalmente competitiva, saudável, segura e sustentável. Como eixo de \"inovação\", essas tecnologias são fatores importantes para todos os setores produtivos da economia. O motor destas tecnologias, entretanto, é a energia, particularmente a eletricidade. Assim, em uma sociedade cujo estilo de vida é fortemente dependente dela, desenvolver tecnologias que permitam não somente a geração, mas também a distribuição de energia de forma barata e limpa e que garantam seu fornecimento ao longo do tempo com a máxima eficiência é uma questão prioritária. Os sistemas baseados em redes inteligentes (do inglês: Smart Grid) vêm, justamente, atender a esses requisitos, representando o que há de mais moderno no setor elétrico, com aumento e diversificação de fontes de geração distribuída na forma de pequenos geradores, maior interação consumidor-distribuidor de energia, integração de diferentes fontes de geração renováveis (ex.: solar, eólica etc.). O cenário energético nacional está avançando de forma muito rápida. Nas distribuidoras, o foco claramente está na redução de perdas comerciais e de custos operacionais, principalmente por meio da modernização dos ativos e da crescente instalação de dispositivos eletrônicos inteligentes nos clientes de baixa tensão (ex.: medidores eletrônicos, dispositivos eletrônicos inteligentes para monitoramento e diagnóstico, relés digitais etc.). Esta tese de doutorado apresenta uma solução com tecnologia nacional que disponibiliza todos os benefícios do Smart Grid através dos equipamentos mais importantes e estratégicos presentes na topologia das Redes de Distribuição Subterrânea Secundária Trifásica: os Protetores de Redes. A partir do centro nevrálgico das Redes de Distribuição Subterrâneas (RDS), cuja topologia está presente nos centros de alta concentração de carga das principais metrópoles do Brasil, a solução desenvolvida pode viabilizar técnica e economicamente a modernização da automação da RDS, com tecnologia nacional de baixo custo, proporcionando igualmente a incorporação dos avanços do Smart Grid e da Geração Distribuída. Este salto tecnológico significaria para as distribuidoras de energia elétrica entre outros benefícios: Melhor controle do processo para uma melhor otimização da rede, desde integração das intermitentes fontes renováveis até uma interação mais dinâmica com os consumidores; Maior flexibilidade às concessionárias em relação ao uso da energia para atingir o grande objetivo social de redução do efeito estufa e otimização do consumo de energia reduzindo perdas e desperdícios; No curto prazo, os benefícios diretos da melhoria do gerenciamento da indisponibilidade, gerenciamento otimizado dos ativos e do capital, melhoria no planejamento, processos e serviços de fornecimento e usos finais de energia, aumento de eficiência de manutenção, redução de perdas técnicas e comerciais, otimização do investimento na compra de novos protetores com menores custos podendo superar a demanda reprimida pelos altos custos de alternativas importadas. / The importance of new technologies in the field of, automation, monitoring, information technology and electronic systems have increased significantly in recent years. These technologies play a basic role in the modern society and contribute of decisive way for the resolution of important challenges for a society that is in search of a more prosperous life, internationally competitive, healthful, safe and sustainable. As a key of \"innovation\", these technologies are key factors for all the productive sectors of the economy in the society. The fuel for the engine of these technologies, however, is the energy, particularly the electricity. Thus, in a society whose life style is strongly dependent of electricity, to develop technologies that not only allow the generation, but also the distribution of energy in a cheap and clean way and which could guarantee its supply throughout the time with the maximum efficiency is a priority issue. The systems based on intelligent networks fully meet these requirements, representing what there is of most modern in the electric sector. The Brazilian energy scenario is quickly changing over the recent years toward modernization, with more distributed generation, in the form of smaller generators, more customer interaction, the integration of more variable resources such as wind and solar, and more renewables overall. For the Power Utilities, especially in the Distribution Sector, the focus is clearly in the reduction of commercial losses and operational costs, mainly by means of the modernization of the assets and an increase in the installation of intelligent electronic devices at consumers side (e.g.: electronic energy meters, intelligent electronic devices for condition monitoring, digital relays etc.). This work presents a solution developed based on Brazilian technology that incorporates all the benefits of smart grid to the most important equipment that is present in the topology of the Low-Voltage Secondary Network Distribution System: the Network Protector. From the neuralgic center of these Low-Voltage Secondary Network Systems, which topology is used in the most important cities in Brazil, which has a high load concentration, the solution presented here make it feasible technically and economically the use of smart grid topology profiting from its great benefits such as: Allow utilities to better optimize the grid to support a number of public policies, from intermittent renewable integration to more dynamic interfaces with customers; Offer utilities more flexibility relative to how they use energy toward the greater societal objectives of reducing greenhouse gases and energy consumption. In the short and mid term, a smarter grid offers utilities operational benefits (outage management, improved processes, maintenance and workforce efficiency, reduced losses, etc.) as well as benefits associated with improved asset management (system planning, better capital asset utilization, etc.), lower investment to acquire new Network Protectors.

This diploma thesis deals with the design and implementation of a computer-controlled device for testing gas boiler control units, especially in the development phase. The reason for creating a test facility is the inadequacy of older test systems and the automation of existing testing. The test device in development consists of individual different cards. Each of the cards inserted into the motherboard performs its function in the system. Each of the cards has a special functionality which simulates the real conditions of the developed product. The basis of most cards is a microcontroller with a Cortex-M core, which communicates with the connected computer using the MODBUS protocol on the RS-485 communication interface. All cards on the bus are connected in parallel and behaves as a SLAVE, while the computer behaves as a MASTER and requests data or sends commands to the cards. The cards represent status switches (switching sensors), resistance and analog temperature sensors, PWM inputs and outputs (for simulation of feedback pumps or flow meters with pulse output). The cards also include a flame simulator, which reliably simulates the electrical properties of the flame and at the same time acts as a fan simulator. The input of the control unit is taken care of by the input card, which is intended for digital detection of the voltage presence in the range of 5 to 230 V DC and AC. Simultaneously, a card for connecting the power supply at zero voltage and disconnecting at zero current is created to supply the tested device with alternating voltage. A schematic diagram was designed or simulated for each card, then the function was verified and on this basis the whole card was created, including the microcontroller firmware. The most suitable solution and function of each card is carefully described and evaluated. All the requirements of the assignment within the work were met and the whole test equipment was manufactured and verified in four versions. In the future, the device is ready for the implementation of an automatic flame simulator and other improvements of individual module cards.

Les travaux de la présente thèse porteront sur le raffinement du modèle du potentiel source-puits (SSP) proposé par Ernzerhof en 2006. Cette méthode permet de calculer la conductance qualitative de dispositifs électroniques moléculaires (MEDs). Dans la première partie de ce travail, le modèle SSP sera amélioré en y intégrant la description de l’interaction d’un champ électromagnétique fort avec le MED. Des expériences récentes ont démontré que des molécules pouvaient interagir fortement avec des plasmons de polaritons de surface (SPP). Ces interactions créent des états liés électron-SPP qui seront exploités pour contrôler la conductance de MEDs. Des formules analytiques expliqueront l’impact des paramètres physiques de ces circuits optoélectroniques sur la conductance de ceux-ci. Dans le même esprit, la seconde partie de cette thèse inclura les interactions électron-noyau au modèle SSP afin de décrire entre autres le courant décohérent d’un MED. Dans ce modèle les interactions noyau-électron seront décrites à partir de l’approximation harmonique et intégrées à l’hamiltonien de façon non-pertubative. Des formules analytiques seront dérivées afin de décrire la conductance de tels MEDs. Finalement, les conséquences du bris de la symétrie de la parité et du temps de la matrice hamiltonienne de la méthode SSP seront découvertes dans la densité spectrale et les fonctions d’ondes des MEDs. / The purpose of this thesis is to expand the scope of the source-sink potential (SSP) method originally proposed by Ernzerhof in 2006. The SSP model allows the computation of the qualitative conductance of molecular electronics devices (MEDs). In the first part of this work, the SSP model will be improved by including the description of interaction between the strong electromagnetic field and the MED. Recent experiments have shown that molecules could strongly interact with surface plasmon of polaritons (SPPs). These interactions will create so-called dressed states that can be used to control the conductance of MEDs. In the second part of this work, the SSP model will be augmented by including electron-nucleus interactions to describe the inelastic current. In this model, the electron-nuclueus interaction will be account for with the help of the harmonic approximation and incorporated into the hamiltonian non-pertubatively. Analytical formulas will be derived that will allow one to understand the impact of physical parameters on the conductance of MEDs. Lastly, the impact of the parity and time symmetry breaking of the SSP matrix hamiltonian will be studied and related to change in the spectral density and in the eigenfunctions of the MEDs.

<p>  </p> <p>Cold chain logistics comprise a large portion of transported pharmaceutical medications and raw materials which must be preserved at specified temperatures to maintain consumer safety and efficacy. An immutable record of temperatures of transported pharmaceutical goods allows for mitigation of temperature-related issues of such drugs and their raw components. The recording of this information on a blockchain creates such an immutable record of this information which can be readily accessed by any relevant party. This can allow for any components which have not been kept at the appropriate temperatures to be removed from production. These data can also be used as inputs for smart contracts or for data analytic purposes. </p> <p>A theoretical framework for such a system, referred to as “TempEnsure” is described, which provides digital capture of the internal temperature of temperature-controlled shipping containers. The data are recorded in a blockchain system. Real world testing of this system was not possible due to monetary constraints, but the functional elements of the system, as well as potential improvements for the system, are discussed.</p>

Cette thèse porte sur l’évaluation des techniques pour la tomographie chimique par STEM EDX : mise au point des procédures expérimentales, traitement des données, reconstruction des volumes, analyse de la qualité des résultats obtenus et évaluation de la complexité globale. Les performances très limitées de l’analyse STEM EDX font que peu d’études, jusqu’à aujourd’hui, se sont portées sur cette technique. Cependant, les avancées très notables procurées par les nouveaux détecteurs ‘SDD’ ainsi que les sources électroniques X-FEG haute brillance, rendant l’analyse STEM EDX 2D très rapide, ont relancé la possibilité de la tomographie chimique ; la technique demande toutefois à être mise au point et évaluée (performances et complexité). Nous avons travaillé sur un microscope Tecnai Osiris permettant d’acquérir des cartographies chimiques EDX de centaines de milliers de pixels avec une résolution de l’ordre du nanomètre en quelques minutes. Nous avons choisi de préparer par FIB des échantillons en forme de pointe et d’utiliser un porte-objet permettant une exploration angulaire de 180° sans ombrage. Puis, à l’aide d’échantillons modèles (billes de SiO2 dans une résine), nous avons évalué les déformations d’échantillon par l’irradiation du faisceau électronique. Ceci nous a permis de proposer une méthode pour limiter cet effet par déposition d’une couche de 20 nm de chrome. Des simulations d’images ont permis d’évaluer les logiciels et méthodes de reconstruction. La méthodologie de chaque étape d’une analyse de tomographie STEM EDX a ensuite été expliquée, et l’intérêt de la technique démontré grâce à la comparaison de l’analyse 2D et 3D d’un transistor FDSOI 28 nm. La qualité des reconstructions (rapport signal-sur-bruit, résolution spatiale) a été évaluée en fonction des paramètres expérimentaux à l’aide de simulations et d’expériences. Une résolution de 4 nm est démontrée grâce à l’analyse d’une mire et d’un transistor « gate all around ». Pour ce même transistor, la possibilité et l’intérêt d’analyse de défaillance à l’échelle nanométrique est prouvée. Une analyse d’un défaut de grille d’une SRAM ou de trous dans un pilier en cuivre permettent d’expliquer l’intérêt d’une combinaison d’un volume HAADF (morphologie et résolution < 4 nm) et du volume EDX (information chimique). La conclusion est que cette technique, qui reste encore à améliorer du point de vue de sa simplicité, montre déjà son utilité pour l’analyse et la mise au point des technologies avancées (nœud 20 nm et après). / This thesis focuses on the evaluation of the STEM EDX chemical tomography technique: development of experimental procedures, data processing and volumes reconstruction, quality analysis of the results and evaluation of the overall complexity. Until now, STEM EDX analysis performances were very limited, so only few studies about this technique have been realized. However, very significant progress procured by the new SDD detectors as well as by the high brightness electronic sources (X-FEG), making the STEM EDX 2D analysis very fast, have revived the possibility of the chemical tomography, although the technique has to be developed and evaluated (performance and complexity). We have worked on a Tecnai Osiris which acquires EDX chemical mapping of hundreds of thousands of pixels with resolution of one nanometer and in a few minutes. We chose to prepare the rod-shaped samples by FIB and use a sample holder allowing an angle of exploration of 180° without shadowing effects. Then, using model samples (SiO2 balls in resin), we evaluated the sample deformation due to the electron beam irradiation. This allowed us to propose a method to reduce this effect by depositing a 20 nm chromium layer. Images simulations were used to evaluate the software and the reconstruction methods. The methodology of each step of the STEM EDX tomography analysis is then explained and the technique interest is demonstrated by comparing the 2D and the 3D analysis of a transistor 28 nm FDSOI. The quality of the reconstructions (signal-to-noise ratio, spatial resolution) was evaluated, in function of experimental parameters, using simulations and experiments. A resolution of 4 nm is demonstrated through the analysis of a test pattern and a "gate all around” transistor. For the same transistor, the possibility and the interest of a failure analysis at the nanoscale is proven. Analyses of a SRAM gate fail or of the holes in a copper pillar explain the benefits of a combination between a HAADF volume (morphology and resolution < 4 nm) and an EDX volume (chemical information). To conclude, this technique, which still needs to be improved in terms of simplicity, is already showing its usefulness for the analysis and the development of advanced technologies (20nm node and beyond).

Un dels problemes més importants en la Compatibilitat Electromagnètica és el control de les interferències emeses i/o rebudes per un equip electrònic a través dels seus terminals d'alimentació monofàsica. Aquestes interferències es classifiquen en mode comú i mode diferencial. La manera més usual de mitigar-les és mitjançant la utilització de filtres de xarxa. Els mètodes actuals de disseny de filtres de xarxa tracten la mitigació d'aquest tipus d'interferències per separat: no tenen en compte que ambdós tipus de senyals (mode comú i diferencial) interaccionen entre sí i es transfereixen energia en qualsevol tipus d'asimetria originada pels equips electrònics o pels mateixos filtres. Aquest fet produeix freqüentment situacions inesperades: inefectivitat dels filtres de xarxa, aparició d'interferències en mode comú o diferencial inexplicables per la topologia dels circuits, selectivitat en freqüència del filtratge de les interferències, processos de radiació, etc. Aquest tipus de situacions poden ser analitzades i corregides a partir d'un anàlisi multimodal, que tingui en compte simultàniament el mode comú i el diferencial, i la seva interacció. El treball exposat aquí pretén:- Desenvolupar sistemes de mesura multimodal per a equips electrònics i filtres de xarxa. Aquests sistemes han de tenir en compte tant el mode comú, com el diferencial, com la seva interacció, i han de millorar les prestacions dels sistemes de mesura normatius actuals.- Trobar models equivalents des d'un punt de vista multimodal (tenint en compte simultàniament el mode comú, el diferencial i la seva interacció) tant d'equips electrònics com de filtres de xarxa.- Desenvolupar una metodologia de predicció de les interferències conduïdes que l'equip electrònic subministra a la xarxa elèctrica a través del filtre de xarxa al qual es troba connectat a partir dels models multimodals equivalents proposats per a ambdós dispositius.PARAULES CLAU: Compatibilitat electromagnètica, filtre de xarxa, equip electrònic, circuit equivalent, emissió conduïda, mode comú, mode diferencial, impedància d'entrada, paràmetres S. / Uno de los problemas más importantes en Compatibilidad Electromagnética es el control de las interferencias emitidas y/o recibidas por un equipo electrónico a través de sus terminales de alimentación monofásica. Estas interferencias se clasifican en modo común y modo diferencial. La manera más usual de mitigarlas es mediante el empleo de filtros de red. Los métodos actuales de diseño de filtros de red abordan la mitigación de este tipo de interferencias por separado: no tienen en cuenta que ambos tipos de señales (modo común y diferencial) interaccionan entre sí y se transfieren energía en cualquier tipo de asimetría originada por los equipos electrónicos o por los mismos filtros. Este hecho produce frecuentemente situaciones inesperadas: inefectividad de los filtros de red, aparición de interferencias en modo común o diferencial inexplicables por la topología de los circuitos, selectividad en frecuencia del filtrado de las interferencias, procesos de radiación, etc. Este tipo de situaciones pueden ser analizadas y corregidas a partir de un análisis multimodal, que tenga en cuenta simultáneamente el modo común y el diferencial, y su interacción. El trabajo aquí expuesto pretende:- Desarrollar sistemas de medida multimodal para equipos electrónicos y filtros de red. Dichos sistemas deben tener en cuenta tanto el modo común, como el diferencial, como su interacción, y deben mejorar las prestaciones de los sistemas de medida normativos actuales.- Hallar modelos equivalentes desde un punto de vista multimodal (teniendo en cuenta simultáneamente el modo común, el diferencial y su interacción) tanto de equipos electrónicos como de filtros de red.- Desarrollar una metodología de predicción de las interferencias conducidas que el equipo electrónico suministra a la red eléctrica a través del filtro de red al cual está conectado a partir de los modelos multimodales equivalentes propuestos para ambos dispositivos.PALABRAS CLAVE: Compatibilidad electromagnética, filtro de red, equipo electrónico, circuito equivalente, emisión conducida, modo común, modo diferencial, impedancia de entrada, parámetros S. / One of the most important problems in EMC is the control of the common and differential mode interferences emitted or received by an electronic device through its single phase power-line cable. These interferences are mitigated using power-line filters. The present power-line filter methodologies treat separately the mitigation of this kind of interferences: they do not take into account that both modes interact and exchange energy at any kind of asymmetry originated by the devices connected to the power-line, or by the power-line filters themselves. This fact leads to unexpected situations: power-line filter infectivity, appearance of common and differential mode interferences not accountable by the circuit topology, frequency selectivity of the interferences, radiation processes, etc. This kind of situations can be analyzed and corrected using multimodal analysis, which takes into account at the same time the common mode, the differential mode and their interaction. This project aims to:- Develop accurate multimodal measurement systems for both electronic devices and power-line network filters. They have to consider the common and differential modes, and their interaction, and have to improve the features of present normative measurement systems. - Derive equivalent models from a multimodal point of view (taking into account simultaneously the common mode, the differential mode and their interaction) for both electronic devices and power-line filters.- Develop a methodology for predicting the level of conducted emissions that an electronic device supplies to the power-line network through the power-line filter to which it is connected, using the equivalent multimodal models proposed for both devices.KEYWORDS: Electromagnetic compatibility, power-line filter, electronic device, equivalent circuit, conducted emissions, common mode, differential mode, input impedance, S parameters.

The ultra high barrier films for packaging find applications in a wide variety of areas where moisture and oxygen barrier is required for improved shelf-life of food/beverage products and for microbial free pharmaceutical containers. These materials also find applications in micro electro mechanical systems such as ICs, and for packaging in industrial and space electronics. Flexible and portable organic electronics like OLEDs (Organic Light Emitting Diodes), OPVDs (Organic Photo Voltaic Devices) and dye sensitized solar cells (DSSCs) have a good potential in next generation solar powered devices. In fact, organic insulators, semiconductors, and metals may be a large part of the future of electronics. However, these classes of materials are just an emerging class of materials mainly because of their life time constraints. Thus significant research is required to bring them into the forefront of electronic applications. If the degradation problems can be diminished, then these polymers could play a major role in the worldwide electronic industry. A flexible polymer film itself cannot be used as an encapsulation material owing to its high permeability. While a glass or metal substrate possesses ultra high barrier properties, it cannot be used in many electronic applications due to its brittleness and inflexibility. Polymer/ nanocomposites based hybrid materials are thus a promising class of material that can be used for device encapsulation. Chapter I summarizes some of the recent developments in the polymer/nanocomposites based materials for packaging and specifically its use in flexible as well as portable organic electronic device encapsulation. While the development of low permeable encapsulant materials is a chemistry problem, an engineering/instrumentation problem is the development of an accurate technique that can measure the low levels of permeability required for electronic application. Therefore, there is a keen interest in the development of an instrument to measure permeability at these limits. The existing techniques to measure the low permeabilities of barrier films, their importance and accuracy of measurements obtained by these instruments have been briefly discussed in this chapter. Different polymer based hybrid composite materials have been developed for the encapsulation of organic devices and their materials properties have been evaluated. Broadly, two diverse strategies have been used for the fabrication of the composites: in-situ curing and solution casting. Chapters II, III and IV discuss the fabrication of nanocomposite films based on in-situ curing while chapter V discusses fabrication based on solution casting. In chapter II, amine functionalized alumina was used as a cross-linking agent and reinforcing material for the polymer matrix in order to fabricate the composites to be used for encapsulation of devices. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy were used to elucidate the surface chemistry. Thermogravimetric and CHN analysis were used to quantify the grafting density of amine groups over the surface of the nanoparticles. Mechanical characterizations of the composites with various loadings were carried out with dynamic mechanical analyzer (DMA). It was observed that the composites have good thermal stability and mechanical flexibility, which are important for an encapsulant. The morphology of the composites was evaluated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The work presented in chapter III is a technique based on grafting between surface decorated γ-alumina nanoparticles and the polymer to make these nanocomposites. Alumina was functionalized with allyltrimethoxysilane and used to conjugate polymer molecules (hydride terminated polydimethylsiloxane) through platinum catalyzed hydrosilylation reaction. As in the previous chapter, the surface chemistry of the nanoparticles after surface modification was characterized by different techniques (FTIR, XPS and Raman). The grafting density of alkene groups over the surface of the modified nanoparticles was calculated using CHN analyzer. Thermal stability of the composites was also evaluated using thermogravimetric analysis. Nanoindentation technique was used to analyze the mechanical characteristics of the composites. The densities of the composites were evaluated using density gradient column and the morphology of composites was evaluated using SEM. All these studies reveal that the composites have good thermal stability and mechanical flexibility and thus can be potentially used for encapsulation of organic photovoltaic devices. In addition, rheological studies of the composites were carried out to investigate the curing reaction. The platinum-catalyzed hydrosilylation reaction was studied using both DSC and rheological measurements. The competitive reactions occurring in the system was also monitored in real time through DSC and rheology. Based on the curing curves obtained from these two studies, the mechanistic detail of the curing process was proposed. In addition, swelling studies and contact angle measurements of the composites were also carried out to determine the capability of these materials as encapsulants. Chapter IV deals with a thermally stable and flexible composite that has been synthesized by following a hydrosilylation coupling between silicone polymer containing internal hydrides and mesoporous silica. The results of the characterization of the composites indicates that the composites are thermally stable, hydrophobic, flexible and can be potentially used for encapsulating flexible electronic devices. Chapter V discusses the solution casting method for the development of composites. This chapter is divided into two parts: Part I discusses the synthesis and characterization of flexible and thermally stable composites using polyvinyl alcohol as the base polymer matrix and reactive zinc oxide nanoparticles as the dispersed phase. Various studies like thermal analysis, mechanical analysis, surface analysis and permeability studies were used to characterize the composite films for their possible use as a passivation material. The material was used to encapsulate Schottky structured devices and the performance of these encapsulated devices under accelerated weathering was studied. Part II of this chapter discusses the fabrication of hybrid organic/inorganic based polymer-composite films, based on polyvinylbutyral (PVB) and organically modified mesoporous silica. PVB and amine functionalized mesoporous silica were used to synthesize the composite. An additional polyol (‘tripentaerythritol’) component was also used to enhance the –OH group content in the composite matrix. The thermal, barrier and mechanical properties of these composites were investigated. The investigation of these films suggests that these can be used as a moisture barrier layer for encapsulation. Chapter VI gives the concluding remarks of the results presented. The advantages as well as disadvantages of the in-situ cured and solution casted films and the scope for future work is discussed in this chapter.