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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
141

Processes for Light Alkane Cracking to Olefins

Peter Oladipupo (8669685) 12 October 2021 (has links)
<p>The present work is focused on the synthesis of small-scale (modular processes) to produce olefins from light alkane resources in shale gas.</p> <p>Olefins, which are widely used to produce important chemicals and everyday consumer products, can be produced from light alkanes - ethane, propane, butanes etc. Shale gas is comprised of light alkanes in significant proportion; and is available in abundance. Meanwhile, shale gas wells are small sized in nature and are distributed over many different areas or regions. In this regard, using shale gas as raw material for olefin production would require expensive transportation infrastructure to move the gas from the wells or local gas gathering stations to large central processing facilities. This is because existing technologies for natural gas conversions are particularly suited for large-scale processing. One possible way to take advantage of the abundance of shale resource for olefins production is to place small-sized or modular processing plants at the well sites or local gas gathering stations.</p> <p>In this work, new process concepts are synthesized and studied towards developing simple technologies for on-site and modular processing of light alkane resources in shale gas for olefin production. Replacing steam with methane as diluent in conventional thermal cracking processes is proposed to eliminate front-end separation of methane from the shale gas processing scheme. Results from modeling studies showed that this is a promising approach. To eliminate the huge firebox volume associated with thermal cracking furnaces and allow for a compact cracking reactor system, the use of electricity to supply heat to the cracking reactor is considered. Synthesis efforts led to the development of two electrically powered reactor configurations that have improved energy efficiency and reduced carbon footprints over and compare to conventional thermal cracking furnace configurations.</p> <p>The ideas and results in the present work are radical in nature and could lead to a transformation in the utilization of light alkanes, natural gas and shale resources for the commercial production of fuels and chemicals.</p>
142

FUTURISTIC AIR COMPRESSOR SYSTEM DESIGN AND OPERATION BY USING ARTIFICIAL INTELLIGENCE

Babak Bahrami Asl (5931020) 16 January 2020 (has links)
<div>The compressed air system is widely used throughout the industry. Air compressors are one of the most costly systems to operate in industrial plants in therms of energy consumption. Therefore, it becomes one of the primary target when it comes to electrical energy and load management practices. Load forecasting is the first step in developing energy management systems both on the supply and user side. A comprehensive literature review has been conducted, and there was a need to study if predicting compressed air system’s load is a possibility. </div><div><br></div><div>System’s load profile will be valuable to the industry practitioners as well as related software providers in developing better practice and tools for load management and look-ahead scheduling programs. Feed forward neural networks (FFNN) and long short-term memory (LSTM) techniques have been used to perform 15 minutes ahead prediction. Three cases of different sizes and control methods have been studied. The results proved the possibility of the forecast. In this study two control methods have been developed by using the prediction. The first control method is designed for variable speed driven air compressors. The goal was to decrease the maximum electrical load for the air compressor by using the system's full operational capabilities and the air receiver tank. This goal has been achieved by optimizing the system operation and developing a practical control method. The results can be used to decrease the maximum electrical load consumed by the system as well as assuring the sufficient air for the users during the peak compressed air demand by users. This method can also prevent backup or secondary systems from running during the peak compressed air demand which can result in more energy and demand savings. Load management plays a pivotal role and developing maximum load reduction methods by users can result in more sustainability as well as the cost reduction for developing sustainable energy production sources. The last part of this research is concentrated on reducing the energy consumed by load/unload controlled air compressors. Two novel control methods have been introduced. One method uses the prediction as input, and the other one doesn't require prediction. Both of them resulted in energy consumption reduction by increasing the off period with the same compressed air output or in other words without sacrificing the required compressed air needed for production.</div><div><br></div>
143

Akumulace energie z OZE / Accumulation of Energy from Renewable Energy Sources

Heller, Ondřej January 2010 (has links)
The objective of the first part of master’s thesis is mapping the potential of various types of renewable sources in Europe and Czech Republic, especially solar energy, wind energy, water energy and biomass. There are described principals and ways of energy generation from these sources, brief overview of current technologies, and also their advantages and limitations. An important part is electric supply continuity from renewable sources, there are large differences and the resulting to restrictions on construction and connecting the units to the power system. In this work there are mentioned some impacts on network and rates of change of supply, some sources are also evaluated in terms of maximum power, that can be connected to the power system in our country. The conclusion of the first part is dedicated to energy storage technologies, which are suitable and usable for renewable sources, there are described their principals, properties, status of development and types of aplications, in which these technologies are used. This chapter also focusses on the price level of each technology. The second part of the thesis deals with 1 MWp on-grid photovoltaic power plant design. This design includes also the redox flow batteries accumulation, the first variant calculates on 24-hour steady energy supply, the second optimalized variant calculates on daily energy supply. There are the accumulation system costs estimated and also the payback period for the both variants. Additionally there is also determined minimum penalization for cost-effective operation. The last part is dedicated to changes of impact on the local grid and changes of system impacts, after the accumulation system is installed.
144

Analysis of a novel thermoelectric generator in the built environment

Lozano, Adolfo 05 October 2011 (has links)
This study centered on a novel thermoelectric generator (TEG) integrated into the built environment. Designed by Watts Thermoelectric LLC, the TEG is essentially a novel assembly of thermoelectric modules whose required temperature differential is supplied by hot and cold streams of water flowing through the TEG. Per its recommended operating conditions, the TEG nominally generates 83 Watts of electrical power. In its default configuration in the built environment, solar-thermal energy serves as the TEG’s hot stream source and geothermal energy serves as its cold stream source. Two systems-level, thermodynamic analyses were performed, which were based on the TEG’s upcoming characterization testing, scheduled to occur later in 2011 in Detroit, Michigan. The first analysis considered the TEG coupled with a solar collector system. A numerical model of the coupled system was constructed in order to estimate the system’s annual energetic performance. It was determined numerically that over the course of a sample year, the solar collector system could deliver 39.73 megawatt-hours (MWh) of thermal energy to the TEG. The TEG converted that thermal energy into a net of 266.5 kilowatt-hours of electricity in that year. The second analysis focused on the TEG itself during operation with the purpose of providing a preliminary thermodynamic characterization of the TEG. Using experimental data, this analysis found the TEG’s operating efficiency to be 1.72%. Next, the annual emissions that would be avoided by implementing the zero-emission TEG were considered. The emission factor of Michigan’s electric grid, RFCM, was calculated to be 0.830 tons of carbon dioxide-equivalent (CO2e) per MWh, and with the TEG’s annual energy output, it was concluded that 0.221 tons CO2e would be avoided each year with the TEG. It is important to note that the TEG can be linearly scaled up by including additional modules. Thus, these benefits can be multiplied through the incorporation of more TEG units. Finally, the levelized cost of electricity (LCOE) of the TEG integrated into the built environment with the solar-thermal hot source and passive ground-based cold source was considered. The LCOE of the system was estimated to be approximately $8,404/MWh, which is substantially greater than current generation technologies. Note that this calculation was based on one particular configuration with a particular and narrow set of assumptions, and is not intended to be a general conclusion about TEG systems overall. It was concluded that while solar-thermal energy systems can sustain the TEG, they are capital-intensive and therefore not economically suitable for the TEG given the assumptions of this analysis. In the end, because of the large costs associated with the solar-thermal system, waste heat recovery is proposed as a potentially more cost-effective provider of the TEG’s hot stream source. / text

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