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Urbanization and increase of impervious areas impact stormwater runoff and can pollute receiving waters. Total suspended solids (TSS) are of particular concern as they can act as a transport agent for other pollutants. Moreover, the existence of the first flush phenomenon (FF), whereby the first stage of storm runoff is the most concentrated, can also have profound ecological effects on receiving waters. Understanding the various types of pollutants in watershed stormwater, their correlation with rainfall parameters (precipitation depth and previous dry days) and with TSS, and the existence of FF is crucial to the design of the most suitable structural best management practice (BMP) that can mitigate their harm. Personal Computer Storm Water Management Model (PCSWMM) is a well-known computer model that can simulate urban runoff quantity and quality and model BMPs. The use of PCSWMM to simulate the first flush phenomenon and to evaluate the effectiveness of structural BMPs has not been previously investigated for a large urban watershed with seriously polluted stormwater runoff. This research is concerned with the study of a framework for designing structural best management practices (BMPs) for stormwater management in a large watershed that is based on comprehensive analysis of pollutants of concern, rainfall parameters of influence, and the existence of FF. The framework was examined using the PCSWMM computer model in the St Anthony Park watershed, an urban watershed in St Paul, Minnesota with a large drainage area of 3,418 acres that discharges directly into the Mississippi River via a storm tunnel. A comprehensive study was undertaken to characterize the overall St. Anthony Park watershed stormwater quality trends for the period of record 2005-2013 for heavy metals, nutrients (ammonia and total phosphorus), sediment (TSS), and bacteria (E. coli). Stormwater was found to be highly contaminated as measured by exceedance of the Minnesota Pollution Control Agency (MPCA) water quality standards and as compared to data obtained from the National Stormwater Quality Database (NSQD). None of the examined parameters significantly correlated with precipitation depth. Concentrations of most heavy metals, total phosphorus and TSS positively correlated with previous dry days, and most pollutants correlated positively with TSS, which provided a strong rationale for using TSS as a representative pollutant in PCSWMM and in examining BMP efficiency. Moreover, BMPs that targeted the particulate fraction in stormwater would be the most efficient in reducing stormwater pollution. A PCSWMM model was built based on the existing drainage system of the watershed, which consisted of inlet structures, manholes, pipes and deep manholes that connect the network pipes to a deep drainage tunnel discharging directly into Mississippi River. The model was calibrated and validated using recorded storm and runoff data. FF was numerically investigated by simulating pollutant generation and washoff. Using three different numerical definitions of FF, the existence of FF could be simulated, and was subsequently reduced by simulating extended dry detention ponds in the watershed. Extended dry detention ponds (EDDPs) are basins whose outlets are designed to detain stormwater runoff for a calculated time that allows particles and associated pollutants to settle. Extended dry detention ponds are a potential BMP option that could efficiently control both water quantity (by diverting initial volumes of stormwater, thus addressing FF) and quality (by reducing suspending pollutants, thus addressing TSS and co-contaminants). Moreover, they are the least-expensive stormwater treatment practice on a cost per treated unit area. Two location-based designs were examined. The first was an EDDP at the main outfall (OFmain), while the second was a set of seven smaller EDDPs within the vicinity of deeper manholes of the deep tunnel (distributed EDDPs). Distributed EDDPs were similar to the OFmain EDDP at reducing peak stormwater flow (52-61%) but superior in reducing TSS loads (20-25% for small particles and 43-45% for larger particles based on the particle sedimentation rate removal constant k) and in reducing peak TSS loads (67-75%). These efficiencies were obtained using the dynamic and kinematic wave routing methods, indicating that they could be used interchangeably for this watershed. The steady state routing method produced unrealistic results and was subsequently excluded from FF analysis. Finally, distributed EDDPs were superior to OFmain EDDP at eliminating FF per the stringent fifth definition (Δ > 0.2). This was true for small values of k. However, larger values of k and other FF tests (above the 45º no-flush line and FF coefficient b < 1) showed that BMP implementation overall failed to completely eliminate FF. This suggested that the extended time required by EDDPs to efficiently remove pollutants from stormwater via settling would compromise their ability to completely eliminate FF. In conclusion, a comprehensive framework was applied so as to better design the most efficient BMPs by characterizing the overall St. Anthony Park watershed stormwater pollutants, their correlation with rainfall parameters and with TSS, and the magnitude of FF. A cost-effective, rapid, and accurate method to simulate FF and study the optimal BMP design was thus implemented for a large urban watershed through the PCSWMM model.

Conselho Nacional de Desenvolvimento Científico e Tecnológico / A captação de águas pluviais não constitui nova estratégia ou tecnologia. No entanto, recentemente tem sido proposta em regiões bem desenvolvidas ou em desenvolvimento (peri-urbanas) em resposta a grandes períodos de estiagens, aumento da demanda por água, maior conscientização pública das enchentes urbanas e sua gênese e, aumento do interesse em práticas de construções sustentáveis, que integram também o uso racional da água. As escolas constituem uma importante fundação da nação, e tem influência no desenvolvimento da sociedade e da sensibilização/ conscientização sobre as questões ambientais. Muitos dos usos da água nas escolas envolvem usos menos nobres da água. Neste contexto, nessa dissertação de mestrado além da análise de marcos legais nesse assunto, foi realizada pesquisa de opinião (entrevista e questionário) junto a atores que interferem no processo decisório da utilização das águas pluviais nas escolas para fins não potáveis. Foram observadas as condições físicas-construtivas das escolas do município do Rio de Janeiro, sobretudo na região da 7a. CRE, que abrange a região da Baixada de Jacarepaguá, área de expansão da cidade. Foi implementada uma unidade para coleta e caracterização da qualidade das águas pluviais, além da caracterização e estudo dos volumes de primeiro descarte (first flush). Os parâmetros de qualidade da água pH, T, OD, ORP, Tu, STD, Condutividade e Salinidade, foram observados com auxílio de sonda multiparâmetros e, através de análise laboratorial de acordo com o Standard Methods, os coliformes termotolerantes. No estudo de percepção foi verificada uma grande aceitação do aproveitamento de águas pluviais para fins não potáveis, embora diretores de escola tenham apresentado informações/percepção divergentes sobre consumo e contas de água das escolas, de sua coordenadoria. Na análise dos parâmetros de qualidade da água versus registros pluviométricos foi observada variabilidade nos eventos pluviométricos observados que limitaram a correlação entre os mesmos, e acabou limitando as conclusões dos estudos de volumes para primeira lavagem e descarte (first flush). Os resultados da pesquisa permitem recomendar a implementação de políticas públicas para aproveitamento de águas pluviais para fins não potáveis nas escolas, mas, com o devido apoio tecnológico. Recomenda-se o aperfeiçoamento e automatização do sistema de coleta de águas pluviais para os estudos de first-flush e otimização dos volumes de descarte. / Rainwater harvesting does not constitute a new strategy or technology. However, recently it has been proposed in well-developed regions or in development (peri-urban) in response to long periods of dryness, increased demand for water, greater public awareness of urban flooding and its genesis, and increased interest in sustainable construction practices, incorporating also the rational use of water. Schools are an important foundation of the nation and has influence in the development of society and awareness about environmental issues. Many of the uses of water in schools involve less noble uses of water. In this context, this dissertation in addition to the analysis of legal frameworks in this matter was held survey (interview and questionnaire) with actors who interfere in the decision-making process of the use of rainwater for non potable purposes in schools. Schools physical- constructive conditions were observed of the municipality of Rio de Janeiro, especially in the region of the 7th CRE, which covers the region of Baixada de Jacarepaguá, area in expansion of the city. It was implemented a unit for collection and characterization of rainwater quality, plus the characterisation and study of volumes of first flush. The water quality parameters pH, T, DO, ORP, Tu, TDS, Conductivity and Salinity, were observed with the aid of multi-parameter probe and, through laboratory testing in accordance with the Standard Methods, the fecal coliforms. In the study of perception was verified a wide acceptance of the use of rainwater for drinking purposes, although school directors have submitted divergent perception/information about consumption and water bills of the schools in its coordination. In the analysis of water quality parameters versus rainfall records was observed a certain variability in the rainfall events observed that limited the correlation between them, and ended up limiting the conclusions of the studies of volumes for the first washing and disposal (first flush). The search results allowed to recommend the implementation of public policies for rainwater utilization for potable purposes in schools, but with a technological support. It is recommended the improvement and automation of the rainwater collection system for studies of first-flush and optimization of disposition volumes.

Conselho Nacional de Desenvolvimento Científico e Tecnológico / A captação de águas pluviais não constitui nova estratégia ou tecnologia. No entanto, recentemente tem sido proposta em regiões bem desenvolvidas ou em desenvolvimento (peri-urbanas) em resposta a grandes períodos de estiagens, aumento da demanda por água, maior conscientização pública das enchentes urbanas e sua gênese e, aumento do interesse em práticas de construções sustentáveis, que integram também o uso racional da água. As escolas constituem uma importante fundação da nação, e tem influência no desenvolvimento da sociedade e da sensibilização/ conscientização sobre as questões ambientais. Muitos dos usos da água nas escolas envolvem usos menos nobres da água. Neste contexto, nessa dissertação de mestrado além da análise de marcos legais nesse assunto, foi realizada pesquisa de opinião (entrevista e questionário) junto a atores que interferem no processo decisório da utilização das águas pluviais nas escolas para fins não potáveis. Foram observadas as condições físicas-construtivas das escolas do município do Rio de Janeiro, sobretudo na região da 7a. CRE, que abrange a região da Baixada de Jacarepaguá, área de expansão da cidade. Foi implementada uma unidade para coleta e caracterização da qualidade das águas pluviais, além da caracterização e estudo dos volumes de primeiro descarte (first flush). Os parâmetros de qualidade da água pH, T, OD, ORP, Tu, STD, Condutividade e Salinidade, foram observados com auxílio de sonda multiparâmetros e, através de análise laboratorial de acordo com o Standard Methods, os coliformes termotolerantes. No estudo de percepção foi verificada uma grande aceitação do aproveitamento de águas pluviais para fins não potáveis, embora diretores de escola tenham apresentado informações/percepção divergentes sobre consumo e contas de água das escolas, de sua coordenadoria. Na análise dos parâmetros de qualidade da água versus registros pluviométricos foi observada variabilidade nos eventos pluviométricos observados que limitaram a correlação entre os mesmos, e acabou limitando as conclusões dos estudos de volumes para primeira lavagem e descarte (first flush). Os resultados da pesquisa permitem recomendar a implementação de políticas públicas para aproveitamento de águas pluviais para fins não potáveis nas escolas, mas, com o devido apoio tecnológico. Recomenda-se o aperfeiçoamento e automatização do sistema de coleta de águas pluviais para os estudos de first-flush e otimização dos volumes de descarte. / Rainwater harvesting does not constitute a new strategy or technology. However, recently it has been proposed in well-developed regions or in development (peri-urban) in response to long periods of dryness, increased demand for water, greater public awareness of urban flooding and its genesis, and increased interest in sustainable construction practices, incorporating also the rational use of water. Schools are an important foundation of the nation and has influence in the development of society and awareness about environmental issues. Many of the uses of water in schools involve less noble uses of water. In this context, this dissertation in addition to the analysis of legal frameworks in this matter was held survey (interview and questionnaire) with actors who interfere in the decision-making process of the use of rainwater for non potable purposes in schools. Schools physical- constructive conditions were observed of the municipality of Rio de Janeiro, especially in the region of the 7th CRE, which covers the region of Baixada de Jacarepaguá, area in expansion of the city. It was implemented a unit for collection and characterization of rainwater quality, plus the characterisation and study of volumes of first flush. The water quality parameters pH, T, DO, ORP, Tu, TDS, Conductivity and Salinity, were observed with the aid of multi-parameter probe and, through laboratory testing in accordance with the Standard Methods, the fecal coliforms. In the study of perception was verified a wide acceptance of the use of rainwater for drinking purposes, although school directors have submitted divergent perception/information about consumption and water bills of the schools in its coordination. In the analysis of water quality parameters versus rainfall records was observed a certain variability in the rainfall events observed that limited the correlation between them, and ended up limiting the conclusions of the studies of volumes for the first washing and disposal (first flush). The search results allowed to recommend the implementation of public policies for rainwater utilization for potable purposes in schools, but with a technological support. It is recommended the improvement and automation of the rainwater collection system for studies of first-flush and optimization of disposition volumes.

An extensive investigation with parallel field andlaboratory exposures has been conducted to elucidateatmospheric corrosion and metal runoff processes on copper andzinc used for roofing applications. Detailed studies have beenperformed to disclose the effect of various parameters on therunoff rate including: surface inclination and orientation,natural patination (age), patina composition, rain duration andvolume, rain pH, and length of dry periods inbetween rainevents. Annual and average corrosion rates and runoff rateshave been determined consecutively during urban field exposuresin Stockholm on naturally patinated copper and zinc of varyingage and patina composition. The corrosion rate was found todecrease with time, amounting to 6.7 g Cu/(m2.y) and 5.0 gZn/(m2.y) after 48 weeks of exposure, whereas the runoff ratewas relatively constant with time on a yearly basis, being 1.3g/(m2.y) and 3.1 g/(m2.y) for copper and zinc, respectively.The annual runoff rate was found to be significantly lower thanthe corresponding corrosion rate for both copper and zinc.Somewhat higher runoff rates of copper were determined fromnaturally green-patinated copper (&gt;40 years old, 2.0g/(m2.y)) compared to brown-patinated copper (1 year old). Themain reasons are specific environmental conditions combinedwith characteristics of the patina layer, which increase themagnitude of dissolved species flushed from the surface duringthe first flush volume of a rain event. No intrinsic effect ofpanel age on the runoff rate was seen for naturally patinatedzinc. However, differences in prevailing environmentalconditions during the initial exposure period and, hence,differences in formation rate and surface coverage of thecorrosion patina, resulted in variations in runoff rate. Thisinitial difference remained also during prolonged exposureperiods and was referred to as a memory effect. Model roof investigations and laboratory studies showedsurface orientation and inclination to have a detrimentaleffect on the runoff rate with high runoff rates from surfacesof low inclination from horizon and surfaces exposed towardsthe wind direction. Based on fieldexposures and literature data, a correlationwas established between the runoff rate and the prevailingSO2-concentration. The runoff rate increases with increasingSO2 level for exposure sites of similar annual precipitationquantities (500-1000 mm/y). A rain device, using artificialrain, was shown to successfully simulate outdoor rain events ofvarying intensity and pH and result in realistic runoff ratesof both copper and zinc. The device was used to monitor changesin metal concentration and quantity of runoff water duringindividual rain events. High metal concentrations are found inthe initial rain volume flushing the surface (first flush),which decreased to rather constant metal concentrations duringthe subsequent rain volume (steady-state). The magnitude offirst flush depends primarily on environmental conditions priorto a rain event and the characteristics of the corrosionpatina. The metal concentration in runoff water increases withrain acidity, decreases with rain intensity and increases withlength of the dry period preceding a rain event. A comparison between instantaneous corrosion rates,monitored by electrochemical impedance spectroscopy using a2-electrode set-up, and runoff rates during a continuous rainevent was performed for naturally patinated copper panels.Corrosion rates were found to be approximately 10 (brownishpatina) and 25 times (greenish patina) lower than correspondinginstantaneous runoff rates. A schematic description of the first flush and steady-stateregion of the runoff process was established. The magnitude ofthe concentration during first flush is primarily affected byprevailing environmental conditions prior to a rain event,while rain pH and intensity primarily affect the concentrationduring steady-state. <b>Key words:</b>atmospheric corrosion, corrosion rate, runoffrate, copper, zinc, field study, laboratory study, roof, firstflush, rain quantity, rain intensity, rain pH, dry and wetdeposition, corrosion and runoff process.

<p>An extensive investigation with parallel field andlaboratory exposures has been conducted to elucidateatmospheric corrosion and metal runoff processes on copper andzinc used for roofing applications. Detailed studies have beenperformed to disclose the effect of various parameters on therunoff rate including: surface inclination and orientation,natural patination (age), patina composition, rain duration andvolume, rain pH, and length of dry periods inbetween rainevents. Annual and average corrosion rates and runoff rateshave been determined consecutively during urban field exposuresin Stockholm on naturally patinated copper and zinc of varyingage and patina composition. The corrosion rate was found todecrease with time, amounting to 6.7 g Cu/(m2.y) and 5.0 gZn/(m2.y) after 48 weeks of exposure, whereas the runoff ratewas relatively constant with time on a yearly basis, being 1.3g/(m2.y) and 3.1 g/(m2.y) for copper and zinc, respectively.The annual runoff rate was found to be significantly lower thanthe corresponding corrosion rate for both copper and zinc.Somewhat higher runoff rates of copper were determined fromnaturally green-patinated copper (>40 years old, 2.0g/(m2.y)) compared to brown-patinated copper (1 year old). Themain reasons are specific environmental conditions combinedwith characteristics of the patina layer, which increase themagnitude of dissolved species flushed from the surface duringthe first flush volume of a rain event. No intrinsic effect ofpanel age on the runoff rate was seen for naturally patinatedzinc. However, differences in prevailing environmentalconditions during the initial exposure period and, hence,differences in formation rate and surface coverage of thecorrosion patina, resulted in variations in runoff rate. Thisinitial difference remained also during prolonged exposureperiods and was referred to as a memory effect.</p><p>Model roof investigations and laboratory studies showedsurface orientation and inclination to have a detrimentaleffect on the runoff rate with high runoff rates from surfacesof low inclination from horizon and surfaces exposed towardsthe wind direction.</p><p>Based on fieldexposures and literature data, a correlationwas established between the runoff rate and the prevailingSO2-concentration. The runoff rate increases with increasingSO2 level for exposure sites of similar annual precipitationquantities (500-1000 mm/y). A rain device, using artificialrain, was shown to successfully simulate outdoor rain events ofvarying intensity and pH and result in realistic runoff ratesof both copper and zinc. The device was used to monitor changesin metal concentration and quantity of runoff water duringindividual rain events. High metal concentrations are found inthe initial rain volume flushing the surface (first flush),which decreased to rather constant metal concentrations duringthe subsequent rain volume (steady-state). The magnitude offirst flush depends primarily on environmental conditions priorto a rain event and the characteristics of the corrosionpatina. The metal concentration in runoff water increases withrain acidity, decreases with rain intensity and increases withlength of the dry period preceding a rain event.</p><p>A comparison between instantaneous corrosion rates,monitored by electrochemical impedance spectroscopy using a2-electrode set-up, and runoff rates during a continuous rainevent was performed for naturally patinated copper panels.Corrosion rates were found to be approximately 10 (brownishpatina) and 25 times (greenish patina) lower than correspondinginstantaneous runoff rates.</p><p>A schematic description of the first flush and steady-stateregion of the runoff process was established. The magnitude ofthe concentration during first flush is primarily affected byprevailing environmental conditions prior to a rain event,while rain pH and intensity primarily affect the concentrationduring steady-state.</p><p><b>Key words:</b>atmospheric corrosion, corrosion rate, runoffrate, copper, zinc, field study, laboratory study, roof, firstflush, rain quantity, rain intensity, rain pH, dry and wetdeposition, corrosion and runoff process.</p>

Magistriniame moksliniame tiriamajame darbe „Paviršinių nuotekų Vilniaus mieste užterštumo tyrimai“ buvo apžvelgta mokslinė – techninė literatūra, kurioje aprašoma paviršinių nuotekų užterštumo skendinčiosiomis medžiagomis kaita lietaus metu. Literatūroje taip pat išanalizuotas pirmojo teršalų antplūdžio reiškinys, t.y., kuomet po tam tikro sausojo periodo, lyjant lietui, urbanizuotoje teritorijoje susiformuoja ypač užterštos pirmosios paviršinių nuotekų porcijos. Ištyrus pirmojo teršalų antplūdžio reiškinio dėsningumą, patikimumą ir universalumą, galima būtų šias žinias panaudoti valytino paviršinių nuotekų kiekio nustatymui. Žinodami, kad didžioji dalis miesto teršalų transportuojama lietaus pradžioje, o likusioji dalis neturi reikšmingos įtakos upių ekosistemoms, valymo įrenginius galėtume projektuoti taip, kad į juos nukreiptume tik pirmąsias paviršinių nuotekų porcijas. Tai suteiktų galimybę efektyviau ir ekonomiškiau tvarkyti paviršines nuotekas. Šiame tiriamajame darbe atsitiktiniu būdu tyrimo objektu buvo pasirinkti Vilniaus miesto šiaurinės dalies vienas didžiausių (Verkių g. Nr. 1) ir vienas mažiausių (Sporto g. Nr. 2) paviršinių nuotekų surinkimo baseinų išleistuvai. Tyrimų rezultatai parodė, kad paviršinių nuotekų debito bei skendinčiųjų medžiagų koncentracijos kaita priklauso nuo urbanizuotos teritorijos baseino charakteristikų, nuo tinklo akumuliacinių savybių, nuo lietaus intensyvumo bei nuo sausojo periodo. ... [toliau žr. visą tekstą] / This work of scientific research named „The research of the pollution of storm water runoff in Vilnius city“ overlooks the fluctuation of concentration of suspended solids in a storm water runoff. There was also the concept of the first flush phenomenon investigated, which means, that the store of pollutants that had accumulated on paved surface in dry weather are quickly washed off during the beginning of the storm. Investigation of the first flush phenomenon consistent reliability and universality would help to determine the amount of storm water runoff that needs to be purified. Knowing that most of the urban pollutant load is transported in the beginning of a storm and the rest of storm water runoff do not have a significant impact on river ecosystem, water treatment facilities could be designed so that they accept only the first portions of the storm water runoff. In this case, a much smaller volume of runoff storage would be needed to treat and remove urban pollutants. This would allow more efficient and economical control of storm water runoff. The study areas where selected to be the representative drainage basin for a large (Verkių g. Nr1) and small (Sporto g. Nr.2) commercial-residential district. Research results showed that storm water runoff flow and suspended solids concentration change depends on the characteristics of the urban catchment’s area, also from the network storage properties and from the intensity of rainfall... [to full text]