L'atmosphère est un milieu hautement hétérogène contenant de la matière condensée : les aérosols. Ceux-ci sont des composants importants de l'atmosphère car ils impactent le bilan radiatif planétaire mais aussi la qualité de l'air. En particulier les aérosols organiques secondaires (AOS), produits par la transformation chimique dans l'air de nombreux composés organiques, plus ou moins volatils, représentent une fraction conséquente dans le budget global des aérosols atmosphériques pour laquelle de nombreuses incertitudes persistent. En particulier, leurs voies de formation et de transformation dans la troposphère restent très mal décrites. C'est pourquoi, cette thèse décrit principalement l'étude de trois aspects de la croissance et du vieillissement (transformation) des aérosols : caractérisation de la croissance des AOS par des processus photosensibilisés ; investigations mécanistiques du vieillissement des AOS et de la photochimie des photosensibilisateurs ; analyse chimique des composés issus du vieillissement des AOS / Aerosols are important constituents of the atmosphere and secondary organic aerosols (SOA) represent a main fraction of the organic aerosols in the total budget. This thesis mainly reports the investigation of three aspects of the growth and aging of SOA: the photosensitized SOA growth ; the mechanistic investigation of SOA aging and of the photochemistry of photosensitizers ; the analysis of the chemical composition of aged SOA. The photosensitized growth and aging processes of SOA were investigated using an aerosol flow tube coupled with various aerosol and gas sensing instruments. For further analysis of the aerosol composition and a better understanding of the formation and growth of SOA in these experiments the aerosols produced in the dark and in the light were sampled on filters at the exit of the flow tube

Made available in DSpace on 2017-06-01T18:12:22Z (GMT). No. of bitstreams: 1 pre-textuais.pdf: 634872 bytes, checksum: 72e0f6a88713fff7a8271cb622684910 (MD5) Previous issue date: 2009-05-15 / This assignment concentrates on the importance of the figure of the king of Congo, that has, on this specific focus, its origin in the African socio-political institution in the kingdom of Congo, already existing in Africa, by the constitution of kingdoms and empires, before the arrival of the Portuguese, being the figure of this king introduced in the Portuguese metropolis around the XV century by a theatrical formulation from a Congolese embassy. In this context they had the African communities gathered in Lisbon as actors, around the confraternity of Our Lady of the Rosary that had the athorities approval. The documentation, although rare in the XVI and XVII centuries, often appeared in the XVIII century, and even then simultaneously in Portugal and in Brazil, being this theatrical reproduction inserted by the authority of the Catholic Church as the institution that legitimates the power of this king. This figure arrives in the Brazilian territory as a mediation and control element among the local authorities and the Africans, and it is inside the Catholic Church, with the brotherhoods, that the figure of the king of Congo occupies its first action scenery until the XIX century. In the XX century, with a new dual profile between the sacred and the profane, transits the representation of the king of Congo in a sustentation artifice of an identity culture for the maracatu-nação tradicional, being the Pernambucan xangô or candomblé location of fetichism its fixation instance in the sacred space. Nowadays, right in th XXI century, the figure of the king as its meaning, beyond the religious sphere, the Afro-Pernambucan cultural interaction and the return of theatricality as a symbolic function of the valorization of the African origins. This research ties and analyses, through Peter Berger s concept of social plausibility the idea that reality is a social construction from the representations and the unfoldings of the figure of the king of Congo, in its first instance as an idealized figure, afterwards as a control element, and after 1888, transiting from the sacred sphere of the Pernambucan sangô to the court of maracatu-nação tradicional. In this sense, we try to bring to light the concept of sacred anchore on Mircea Eliade, that makes it possible to translate the history of hierophany of the king of Congo, in the construction and in the trajectory through different spaces of the sacred. / Este trabalho centra-se na importância da figura do rei do Congo , que têm, neste enfoque específico, sua origem na instituição sociopolítica africana no Reino do Congo, já existente na África, pela constituição de reinos ou impérios, antes da chegada dos portugueses, sendo a figura deste rei introduzida na metrópole portuguesa, por volta do século XV, por uma formulação teatral de uma embaixada congolesa. Neste contexto, tinham por atores a comunidade africana reunida em Lisboa, à volta da Confraria de Nossa Senhora do Rosário, que possuía o beneplácito das autoridades. A documentação, embora rara nos séculos XVI e XVII, aparecem com freqüência no século XVIII e, já então simultaneamente em Portugal e no Brasil, sendo esta reprodução teatral inserida pela autoridade da Igreja Católica como a instituição que legitima o poder deste rei. Esta figura chega em território brasileiro como elemento de mediação e controle entre as autoridades locais e os africanos e, é no interior da Igreja Católica, com as irmandades, que a figura do rei do Congo ocupa seu novo cenário de ação, até o século XIX. No século XX, com novo perfil dual, entre o sagrado e o profano, transita a representação da figura do rei do Congo, em um artifício de sustentação de uma cultura identitária, para o maracatu-nação tradicional, sendo os terreiros de xangô pernambucano ou candomblé sua instância de fixação no espaço do sagrado. Na atualidade, em pleno século XXI, a figura do rei tem como significado, para além da esfera religiosa, a interação cultural afro-pernambucana e o retorno a teatralidade como função simbólica da valorização às origens africanas. Esta pesquisa busca analisar através do conceito de plausibilidade social de Peter Berger, a idéia de que a realidade é construção social, a partir das representações e desdobramentos da figura do rei do Congo, em primeira instância como uma figura idealizada , depois como elemento de controle e, após 1888, transitando da esfera do sagrado dos xangôs pernambucanos, para a corte do maracatu-nação. Neste sentido, buscamos trazer à luz, o contexto do sagrado ancorado em Mircea Eliade, que possibilita traduzir a história da hierofania do rei do Congo, na construção e na trajetória por diferentes espaços do sagrado. Palavras-chave: maracatu-nação tradicional, cultura negra, afro-brasileiro, sagrado, rei.

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This diploma thesis is mainly focused on the digestate thickening in a biogas plant. First, overview of the biogas technology in the Czech Republic is presented. Furthermore, problems with waste heat utilization and processing of fermentation residues (digestate) are described in more detail. Based on the research, multi-stage flash (MSF) evaporation was chosen as the technology for the digestate thickening. The main part deals with the integration of the chosen technology into a biogas plant process. The programming language Python was used to simplify the given task. In the preliminary stage, a complex mathematical model of a biogas plant was created, focusing particularly on the mass and energy balances. Subsequently, a computational model of the MSF evaporator was programmed. A procedure for the integration was suggested using the sensitivity analyses. Additionally, the model of a biogas plant was extended with the MSF evaporator. The key outcome of the thesis is a technical-economic analysis in which the impact of digestate transport price and electricity feed-in tariff on payback period is investigated. The results suggest profitability of MSF evaporator for biogas plants without subsidized feed-in tariff. Contrastingly, installation of MSF evaporator in older biogas plants with subsidized feed-in tariff can be economically viable only in cases of significantly longer transport distances.

My diploma thesis focuses in its theoretical part on the analysis of photovoltaic cells, panels, their properties and defects . Further there are described materials from which the cells and panels are produced today but also there are mentioned materials which could affect the near future. There are also state the methods of measurement of photovoltaic cells . The practical part analyzes selected photovoltaic panels, determines the level of degradation by measurement and calculation with using the intensity of solar radiation. All results are entred into graphs and tables.

This dissertation thesis deals with the development of technology which could tackle two major issues related to biogas plants. These issues concern the insufficient use of waste heat from biogas combustion and its subsequent processing. It also concerns the use of the fermentation residues which are formed in large quantities and whose use is restricted by law. Based on a literary search of separation methods, a vacuum evaporator was selected as the most suitable technology. Its advantages include its simple construction, operational reliability and robustness, low costs of thickening medium pre-treatment, potential for a quick commercial application and, especially, the chance to use a low-potential waste heat. A primary purpose of this technological unit is the reduction in the volume of fermentation residues. Other benefits include the efficient use of waste heat from a biogas plant, which would otherwise be wasted. Evaporators with a low consumption of electrical energy (which is a main product of a biogas plant) seem to be the best option for applications in the biogas plants. Three of these technologies were subjected to a more thorough analysis, which included the development of computational models and their quantification for conditions in a sample biogas plant. A one-stage evaporator with a forced circulation (680 – 712 kWhth/m3, 25.9 – 30.5 kWhel/m3) was evaluated as the least suitable option in terms of energy demands. The energy intensity of a three-stage evaporator with a falling film (241 – 319 kWhth/m3, 12.0 – 23.6 kWhel/m3) and a nine-stage flash evaporator (236 – 268 kWhth/m3, 13.6 – 18.4 kWhel/m3) is significantly lower. A multi-stage flash evaporator (MSF) was then chosen for development and will form the central focus of this thesis. The reasons for the choice are as follows: the low requirements on the heat transfer surface, good operational experience in the field of desalination, its simple construction, modularity and evaporation outside the heat transfer surface. A thorough technical-economic evaluation was also performed on the integration of the evaporator into the biogas plant. The main part of the work included the experimental development of a MSF evaporator prototype. The main objective of this development was to achieve a stable flow rate of the thickening liquid digestate fraction and the continuous formation of the distillate. This was not an easy objective to achieve, especially due to the properties of the liquid digestate, which has a non-newtonian characteristic and increased density and viscosity compared to water. The tendency of the liquid digestate to form foam was also the subject of analysis. The development of the evaporator and first successful operational test are described in the thesis in detail. This required the use of an anti-foaming product. A fully-developed prototype of the MSF evaporator allowed us to achieve continuous operation with a distillate production, reaching from 5 to 10 kg/h at a liquid digestate flow rate of 0.4–0.5 m3/h. The main drawback of this technology is the pollution of the distillate with ammonia nitrogen, and it is for this reason that the basic procedures of its subsequent elimination was selected for further analysis.

<p>U tezi je rešavan centralni problem &ndash; detekcija nule dvobitnom<br />stohastičkom digitalnom mernom metodom (SDMM). Formulisane su<br />dve metode detekcije nule primenom dvobitne SDMM. Po prvoj metodi<br />dinamička rezerva je oko 100 dB a po drugoj ne manje od 160 dB. Obe<br />metode su proverene teorijski, simulaciono i eksperimentalno. Pored<br />rešenja centralnog problema, dato je i nekoliko rešenja problema<br />koji su sa njim vezani. Hipoteza ove teze &ndash; &bdquo;dvobitna SDMM je u opsegu<br />0 % - 10% FS bolja od standardne sempling metode (SSM)&ldquo; &ndash; je potpuno<br />potvrđena u svim razmatranim slučajevima.</p> / <p>The main goal of this thesis was null-detection using a two-bit stochastic<br />digital measurement method (SDMM). Two methods of null-detection, using<br />two-bit SDMM, were formulated. Using the first method around 100 dB of<br />dynamic reserve was achieved and using the second one no less than<br />160 dB. Both methods were theoretically, using simulation and experimentally<br />confirmed. In addition to the solution of the main problem, several other<br />related problems were also solved. The hypothesis of this thesis &ndash; &ldquo;two-bit<br />SDMM in range from 0 % - 10 % FS is better than the standard sampling<br />method (SSM)&rdquo; has been fully confirmed in all considered cases.</p>

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QFormat="true" Name="Intense Emphasis"/> <w:LsdException Locked="false" Priority="31" SemiHidden="false" UnhideWhenUsed="false" QFormat="true" Name="Subtle Reference"/> <w:LsdException Locked="false" Priority="32" SemiHidden="false" UnhideWhenUsed="false" QFormat="true" Name="Intense Reference"/> <w:LsdException Locked="false" Priority="33" SemiHidden="false" UnhideWhenUsed="false" QFormat="true" Name="Book Title"/> <w:LsdException Locked="false" Priority="37" Name="Bibliography"/> <w:LsdException Locked="false" Priority="39" QFormat="true" Name="TOC Heading"/> </w:LatentStyles></xml><![endif]--><!--[if gte mso 10]><style> /* Style Definitions */ table.MsoNormalTable{mso-style-name:"Table Normal";mso-tstyle-rowband-size:0;mso-tstyle-colband-size:0;mso-style-noshow:yes;mso-style-priority:99;mso-style-qformat:yes;mso-style-parent:"";mso-padding-alt:0in 5.4pt 0in 5.4pt;mso-para-margin:0in;mso-para-margin-bottom:.0001pt;mso-pagination:widow-orphan;font-size:11.0pt;font-family:"Calibri","sans-serif";mso-ascii-font-family:Calibri;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:Calibri;mso-hansi-theme-font:minor-latin;mso-bidi-font-family:"Times New Roman";mso-bidi-theme-font:minor-bidi;}</style><![endif]-->U tezi se razmatra kriterijum optimalnosti stohastičkog fleš A/D konvertora (SFADC) koji predstavlja osnovu stohastičke digitalne metode merenja (SDMM). Razvijen je matematički i simulacioni model višebitnog SFADC i određen optimum broja bita rezolucije. Napravljen je hardverski prototip 4-bitnog stohastičkog mernog instrumenta (SMI), koji je ispitan brojnim eksperimentima i upoređen sa teorijski određenim vrednostima performansi merenja. Hipoteza ove teze &ndash; da postoji optimalni broj bita rezolucije SMI pri kome se ostvaruje maksimalna dobit u preciznosti merenja po ceni dupliranja potrebnog hardvera &ndash; potpuno je potvrđena.</p> / <p><!--[if gte mso 9]><xml> <w:WordDocument> <w:View>Normal</w:View> <w:Zoom>0</w:Zoom> <w:TrackMoves/> <w:TrackFormatting/> <w:PunctuationKerning/> <w:ValidateAgainstSchemas/> <w:SaveIfXMLInvalid>false</w:SaveIfXMLInvalid> <w:IgnoreMixedContent>false</w:IgnoreMixedContent> <w:AlwaysShowPlaceholderText>false</w:AlwaysShowPlaceholderText> <w:DoNotPromoteQF/> <w:LidThemeOther>EN-US</w:LidThemeOther> <w:LidThemeAsian>X-NONE</w:LidThemeAsian> <w:LidThemeComplexScript>X-NONE</w:LidThemeComplexScript> <w:Compatibility> <w:BreakWrappedTables/> <w:SnapToGridInCell/> <w:WrapTextWithPunct/> <w:UseAsianBreakRules/> <w:DontGrowAutofit/> <w:SplitPgBreakAndParaMark/> <w:DontVertAlignCellWithSp/> <w:DontBreakConstrainedForcedTables/> <w:DontVertAlignInTxbx/> <w:Word11KerningPairs/> 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Normal";mso-tstyle-rowband-size:0;mso-tstyle-colband-size:0;mso-style-noshow:yes;mso-style-priority:99;mso-style-qformat:yes;mso-style-parent:"";mso-padding-alt:0in 5.4pt 0in 5.4pt;mso-para-margin:0in;mso-para-margin-bottom:.0001pt;mso-pagination:widow-orphan;font-size:11.0pt;font-family:"Calibri","sans-serif";mso-ascii-font-family:Calibri;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";mso-fareast-theme-font:minor-fareast;mso-hansi-font-family:Calibri;mso-hansi-theme-font:minor-latin;mso-bidi-font-family:"Times New Roman";mso-bidi-theme-font:minor-bidi;}</style><![endif]--><span style="font-size:9.0pt;mso-bidi-font-size:10.0pt;font-family:&quot;Arial&quot;,&quot;sans-serif&quot;;mso-fareast-font-family:&quot;Times New Roman&quot;;mso-font-kerning:10.0pt;mso-ansi-language:EN-US;mso-fareast-language:EN-US;mso-bidi-language:AR-SA">The thesis considers the criterion of optimality of the stochastic flash A/D converter (SFADC), which is the basis of the stochastic digital measurement method (SDMM). The mathematical and simulation model of the multibit SFADC was developed and the optimal number of bits of resolution was determined. A hardware prototype of a 4-bit stochastic measuring instrument (SMI) was made, tested in numerous experiments and compared with theoretically determined measurement performance values. The hypothesis of this thesis - that there is an optimal number of SMI resolution bits in which the maximum benefit of the measurement precision is achieved at the price of duplication of the required hardware - is fully confirmed</span></p>

During the design and verification of the Hyperstone S5 flash memory controller, we developed a highly effective way to use the SystemVerilog direct programming interface (DPI) to integrate an instruction set simulator (ISS) and a software debugger in logic simulation. The processor simulation was performed by the ISS, while all other hardware components were simulated in the logic simulator. The ISS integration allowed us to filter many of the bus accesses out of the logic simulation, accelerating runtime drastically. The software debugger integration freed both hardware and software engineers to work in their chosen development environments. Other benefits of this approach include testing and integrating code earlier in the design cycle and more easily reproducing, in simulation, problems found in FPGA prototypes.