Soft materials have gained increasing prominence in science and technology over the last few decades. This shift from traditional rigid materials to soft, compliant materials have led to the emergence of a new class of devices which can interact with humans safely, as well as reduce the disparity in mechanical compliance at the interface of soft human tissue and rigid devices.<br><br>One of the largest application of soft materials has been in the field of flexible electronics, especially in wearable sensors. While wearable sensors for physical attributes such as strain, temperature, etc. have been popular, they lack applications and significance from a healthcare perspective. Point-of-care (POC) devices, on the other hand, provide exceptional healthcare value, bringing useful diagnostic tests to the bedside of the patient. POC devices, however, have been developed for only a limited number of health attributes. In this dissertation I propose and demonstrate wireless, wearable POC devices to measure and communicate the level of various analytes in and the properties of multiple biofluids: blood, urine, wound exudate, and sweat.<br><br>Along with sensors, another prominent area of soft materials application has been in actuators and robots which mimic biological systems not only in their action but also in their soft structure and actuation mechanisms. In this dissertation I develop design strategies to improve upon current soft robots by programming the storage of elastic strain energy. This strategy enables us to fabricate soft actuators capable of programmable and low energy consuming, yet high speed motion. Collectively, this dissertation demonstrates the use of soft compliant materials as the foundation for developing new sensors and actuators for human use and interaction.

The rapid progress of electronics and computer science in the last years has brought humans and machines closer than ever before. Current trends like the Internet of Things and artificial intelligence are closing the gap even further, by providing ubiquitous data processing and sensing. As this ongoing revolution advances, novel forms of human-machine interactions are required in an ever more connected world. A crucial component to enable these interactions is the field of flexible electronics, which aims to establish a seamless link between living and artificial entities using electronic skins (e-skins). E-skins combine the functionality of commercial electronics with the soft, stretchable and biocompatible characteristics of human skin or tissue. Until lately, the focus had been to replicate the standard functions associated with human skin, such as, temperature, pressure and chemical detection. Yet, recent developments have also introduced non-standard sensing capabilities like magnetic field detection to create the field of magnetosensitive e-skins. The addition of a supplementary information channel—an electronic sixth sense—has sparked a wide range of applications in the fields of cognitive psychology and human-machine interactions. In this thesis, we expand the concept of magnetosensitive e-skins to include the notion of directionality, which utilizes the full interaction potential of the magnetic field vector. Also, we introduce the use of flexible magnetoelectronics in virtual/augmented reality and human-computer interfaces. Three main results are attained in the course of this work: (i) we first demonstrate how magnetosensitive e-skins can be used as humanmachine interfaces driven by permanent magnet sources in the range of 5 mT. (ii) Building upon this milestone, we realize the first magnetosensitive e-skins which are driven by the earth’s magnetic field of 50 μT. (iii) We fabricate magnetosensitive e-skins which push the detection limit below 1 μT. The magnetosensitive e-skins in this work open exciting possibilities for sensory substitution experiments and sensory processing disorder therapies. Futhermore, for human-machine interactions, they provide a new interactive platform for touchless and gestural control in virtual and augmented reality scenarios beyond the limitations of optics-based systems. / Der rasante Fortschritt der Elektronik und der Informatik in den letzten Jahren hat Mensch und Maschine nähergebracht als je zuvor. Aktuelle Trends wie das Internet der Dinge und künstliche Intelligenz schließen die Lücke noch weiter, indem sie eine allgegenwärtige Datenverarbeitung und -erfassung ermöglichen. Mit fortschreitender Revolution sind neue Formen der Mensch-Maschine-Interaktion in einer immer vernetzter werdenden Welt erforderlich. Eine entscheidende Komponente, um diese Interaktionen zu ermöglichen, ist das Gebiet der flexiblen Elektronik, das darauf abzielt, mithilfe elektronischer Häute (e-skins) eine nahtlose Verbindung zwischen lebenden und künstlichen Entitäten herzustellen. E-skins verbinden die Funktionalität kommerzieller Elektronik mit den weichen, dehnbaren und biokompatiblen Eigenschaften menschlicher Haut oder menschlichen Gewebes. Bis vor kurzem lag der Schwerpunkt auf der Nachbildung der mit der menschlichen Haut verbundenen Standardfunktionen wie Temperatur-, Druck- und Chemikalienerkennung. Jüngste Entwicklungen haben jedoch auch nicht standardmäßige Erfassungsfähigkeiten wie die Magnetfelderkennung eingeführt, um das Feld magnetoempfindlicher e-skins zu erzeugen. Die Hinzufügung eines zusätzlichen Informationskanals - eines elektronischen sechsten Sinns - hat eine breite Palette von Anwendungen auf den Gebieten der kognitiven Psychologie und der Mensch-Maschine-Interaktionen ausgelöst. In dieser Arbeit erweitern wir das Konzept der magnetoempfindlichen e-skins um den Begriff der Richtwirkung, bei dem das volle Wechselwirkungspotential des Magnetfeldvektors genutzt wird. Außerdem führen wir die Verwendung flexibler Magnetoelektronik in der virtuellen Realität / erweiterten Realität und in Mensch-Computer-Schnittstellen ein. Im Verlauf dieser Arbeit werden drei Hauptergebnisse erzielt: (i) Wir demonstrieren erstmals, wie magnetoempfindliche e-skins als Mensch-Maschine-Schnittstellen verwendet werden können, die von Permanentmagnetquellen im Bereich von 5 mT angetrieben werden. (ii) Aufbauend auf diesem Meilenstein realisieren wir die ersten magnetoempfindlichen e-skins, die vom Erdmagnetfeld von 50 μT angetrieben werden. (iii) Wir fertigen magnetoempfindliche e-skins, bei denen die Nachweisgrenze unter 1 μT liegt. Die magnetoempfindlichen e-skins in dieser Arbeit eröffnen aufregende Möglichkeiten für sensorische Substitutionsexperimente und Therapien bei sensorischen Verarbeitungsstörungen. Darüber hinaus bieten sie für die Mensch-Maschine-Interaktion eine neue interaktive Plattform für die berührungslose und gestische Steuerung in virtuellen und Augmented Reality-Szenarien, die über die Grenzen optikbasierter Systeme hinausgehen.

<div>Roll-to-roll processes provide a low-cost and high-throughput scheme for scalable flexible devices manufacturing. Multiple processes are used in roll-to-roll manufacturing, such as functional printing, evaporation/drying, UV curing, hot embossing, laser/heat annealing, laser ablation, plasma/ chemical growth, and sputtering. These processes change the web temperature field and/ or local properties. In addition, residual stresses by the process and web tension can destabilize the process and lead to wrinkling or undesirable performance of the products.</div><div>This dissertation investigates three different multi-physics problems relevant to the roll-to-roll processes, which are web thermomechanics, air-coupled web vibrations, and the measuring of nonuniform web tension. First, a mathematical model for predicting the in-plane temperature and heat induced stress distributions in a flexible, axially moving web under arbitrary shape of heat flux is presented. The computational approach is validated on experiments performed on moving paper and PET webs with infrared laser heating source. Second, a closed-form, semi-analytical, universal hydrodynamic functions is developed to accurately predict the lowest symmetric and anti-symmetric transverse frequency responses for any uniaxially tensioned web of arbitrary material and aspect ratio used in roll-to-roll processes with the surrounding air acting as distributed added mass. Experimental validation is carried out by using pointwise laser measurements of acoustically excited webs with different pre-tensions, web materials, and aspect ratios. Finally, we develop and test a non-contact resonance method and a gentle contact stiffness mapping method based on the first principles mechanical models of a tensioned plate to accurately measure the average web tension and its linear variation for a wide range of web properties, web path, web tension, measurement configurations, and environmental conditions. The two methods are cross-validated on a stationary test stand and the non-contact resonance method is used to study the web tension distribution within a commercial roll-to-roll system.</div><div><br></div>

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<p>Textiles have gained popularity in wearable products due to their potential for wearability, comfort, flexibility, breathability, and seamless fit to the human body. The growing demand for remote telehealth monitoring has led to advancements in the field of e-textiles. Various approaches, such as dip coating, screen printing, inkjet printing, and vapor deposition, are utilized to overcoat fabrics with active nanomaterials. However, practical deployment still faces challenges due to a lack of rapid prototyping for scalable and customizable e-textiles. To meet the requirements of large-scale batch production, high-resolution electrode line width, and long-term durability, new platform technologies have been established to convert existing textiles into multifunctional e-textiles. These studies have also revealed the process-structure-property relationships of various e-textiles.</p> <p>Chapter I overviews the recent results and current limitations of e-textiles in wearable sensing and display. Since people stay and work in various circumstances, continuous monitoring of physical, electrophysiological signals on skin in ambulatory manners is necessary to evaluate hazardous situation or chronicle symptoms. For these reasons, fabrication of smart e-textiles is crucial. In this chapter, various conductive materials, overcoating methods, and sensor structures for physical and electrophysiological sensors are reviewed. In addition, as a useful user communication tool with different sensor system, e-textile formats of displays are developed. The comprehensive e-textile displays from DC-driven to AC-driven are presented.</p> <p>Chapter II introduces a dual-regime spray technique that enables the direct writing of functional nanoparticles onto commercial 4-way stretchable textiles up to a meter scale with high-resolution mask-free patterning. The resulting e-textiles maintain the intrinsic properties of the fabric and can conform to various body shapes, enabling high-fidelity recording of physiological and electrophysiological signals under ambulatory conditions. Field tests have shown the potential of these e-textiles for minimally obtrusive remote telehealth monitoring of large animals.</p> <p>Chapter III presents an in-situ polymerization and patterning technique that utilizes the dual-regime spray method to synthesize conductive polymers directly onto commercial stretch textiles. The resulting e-textiles are utilized for strain sensors that conform closely to the human body, providing exceptional measurement accuracy and fidelity in capturing physical signals and motion detections.</p> <p>Conclusion section summarizes this dissertation with pointing out important results and discussions of each study. As an innovative additive manufacturing technology, dual-regime spray system, was established and developed to open new field in manufacture of e-textile. At last of this section, the potential research opportunities and perspectives are addressed. </p>

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The advances in modern communication systems have brought about devices with more functionality, better performance, smaller size, lighter weight and lower cost. Meanwhile, the requirement for newer devices has become more demanding than ever. Tunability and flexibility are both long-desired features. Tunable devices are ‘smart’ in the sense that they can adapt to the dynamic environment or varying user demand as well as correct the minor deviations due to manufacturing fluctuations, therefore making it possible to reduce system complexity and overall cost. It is also desired that electronics be flexible to provide conformability and portability. Previously, tunable devices on flexible substrates have been realized mainly by dicing and assembling. This approach is straightforward and easy to carry out. However, it will become a “mission impossible” when it comes to assembling a large amount of rigid devices on a flexible substrate. Moreover, the operating frequency is often limited by the parasitic effect of the interconnection between the diced device and the rest of the circuit on the flexible substrate. A recent effort utilized a strain-sharing Si/SiGe/Si nanomembrane to transfer a device onto a flexible substrate. This approach works very well for silicon based devices with small dimensions, such as transistors and varactor diodes. Large-scale fabrication capability is still under investigation. A new transfer technique is proposed and studied in this research. Tunable BST (Barium Strontium Titanate) IDCs (inter-digital capacitors) are first fabricated on a silicon substrate. The devices are then transferred onto a flexible LCP (liquid crystalline polymer) substrate using iv wafer bonding of the silicon substrate to the LCP substrate, followed by silicon etching. This approach allows for monolithic fabrication so that the transferred devices can operate in millimeter wave frequency. The tunability, capacitance, Q factor and equivalent circuit are studied. The simulated and measured performances are compared. BST capacitors on LCP substrates are also compared with those on sapphire substrates to prove that this transfer process does not impair the performance. A primary study of a reflectarray antenna unit cell is also conducted for loss and phase swing performance. The BST thin film layout and bias line positions are studied in order to reduce the total loss. Transferring a full-size BST-based reflectarray antenna onto an LCP substrate is the ultimate goal, and this work is ongoing at the University of Central Florida (UCF). HFSS is used to simulate the devices and to prove the concept. All of the devices are fabricated in the clean room at UCF. Probe station measurements and waveguide measurements are performed on the capacitors and reflectarray antenna unit cells respectively. This work is the first comprehensive demonstration of this novel transfer technique.

Due to their low-temperature processing capability and ionic bonding configuration, amorphous oxide semiconductors (AOS) are well suited for applications within future mechanically flexible electronics. Over the past couple of years, amorphous zinc tin oxide (ZTO) has been proposed as indiumand gallium-free and thus more sustainable alternative to the widely deployed indium gallium zinc oxide (IGZO). The present study specifically focuses on the strain-dependence of elastic and electrical properties of amorphous zinc tin oxide thin-films sputtered at room temperature. Corresponding MESFETs have been compared regarding their operation stability under mechanical bending for radii ranging from 5 to 2 mm. Force-spectroscopic measurements yield a plastic deformation of ZTO as soon as the bending-induced strain exceeds 0.83%. However, the electrical properties of ZTO determined by Hall effect measurements at room temperature are demonstrated to be unaffected by residual compressive and tensile strain up to 1.24 %. Even for the maximum investigated tensile strain of 1.26 %, the MESFETs exhibit a reasonably consistent performance in terms of current on/off ratios between six and seven orders of magnitude, a subthreshold swing around 350 mV/dec and a field-effect mobility as high as 7.5 cm2V−1s−1. Upon gradually subjecting the transistors to higher tensile strain, the channel conductivity steadily improves and consequently, the field-effect mobility increases by nearly 80% while bending the devices around a radius of 2 mm. Further, a reversible threshold voltage shift of about −150 mV with increasing strain is observable. Overall, amorphous ZTO provides reasonably stable electrical properties and device performance for bending-induced tensile strain up to at least 1.26% and thus represent a promising material of choice considering novel bendable and transparent electronics.

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