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The shift from an industrial-based to a knowledge-based economy has impacted market conditions and created a demand for a talented and skilled workforce in knowledge-intensive industries. This paper investigates what the role of talent is, when firms decide for a location by carrying out two studies. Firstly, an extensive literature review was conducted where three factors of firm location decision were identified as: clustering, soft and hard factors, and personal networks. The role of talent continuously emerged in the literature in regards to the three firm location decision factors and appeared to be intertwined in these. Consequently, these factors and the role of talent were conceptualized in an analytical framework. Thereafter, the analytical framework was applied to the second study when conducting a multiple-case study of three clean-tech firms in Uppsala, Sweden. This was done in order to investigate the role of talent in the firms’ location decision. The findings of the multiple-case study revealed that the role of talent was important during the location decision of all three firms where talent was intertwined with the identified location factors. Thus, the multiple-case study confirms that the role of talent impacts firm location decision through being intertwined in the identified firm location decision factors.

Steel turning inserts cemented carbides have a binder phase consisting of cobalt (Co). However, in recent years a study from the United States National Toxicity Program (NTP) found that cobalt powder is carcinogenic upon inhalation. The European Union's REACH have therefore also classified cobalt powder as carcinogenic upon inhalation. The worldwide search to find a replacement has therefore lately intensified. It is important that the alternative binder phase has no negative effects on the properties of the insert. In this thesis the adhesion between a multilayer ceramic chemical vapor deposition (CVD) coating and a cemented carbide with the alternative binder phases consisting of iron (Fe), nickel (Ni) and cobalt (Co) has been studied. First of all, the fracture surfaces showed that the CVD coating was able to grow on all cemented carbides, regardless of which binder phase. To evaluate the adhesion, scratch tests were performed on all samples. The results from the scratch tests were not as expected. No chipping of the coating down to the cemented carbide occurred on any of the samples and the samples with the hardest cemented carbide did not get the highest critical load, which it should according to the literature if all other parameters were the same. Instead the sample with the binder phase consisting of 73 wt% iron and 27 wt% nickel had the highest critical load. This is thought to be due to that during the scratch test the binder phase in this cemented carbide would most likely transform into deformation martensite.

The EU regulatory framework for direct taxation is composed of three interconnected elements. First, having satisfied the requirement of a unanimous vote, the EU adopted a range of directives on the basis of the general harmonisation provision (Article 115 TFEU). Therefore, a traditional hard law framework harmonising some aspects of direct taxation exists in the EU. Second, case law is an indirect method of exerting influence on the direct tax field. As long as no positive integration has been brought about, the Member States are free to regulate this sphere as they see fit. The boundaries of their regulatory freedom are imposed, however, by negative integration i.e. by the ECJ applying the Treaty rules on non-discrimination. Jurisprudence has been an influential and dominant regulatory tool. Third, corporate taxation has also been regulated through soft law. The key example of a non-legally binding instrument in the direct tax field is the Code of Conduct for Business Taxation. This thesis investigates interactions between these hard and soft law measures and draws conclusions about the future of EU direct tax regulation. To achieve these aims, two research strands are explored. First, the thesis discusses the nature of the Code. In particular, it is investigated whether the Code can be regarded as an example of a ‘pure’ soft law measure. It is argued that the nature of the Code is not as clear-cut as is officially presented. Behind soft law terminology, the Code operates as a hard law measure. Supported by an examination of the OECD anti-harmful tax competition initiative, the thesis concludes that the use of soft law in tax regulation has not been wholly successful. The introduction of legally binding solutions is restricted by the requirement of unanimity, which is difficult to attain in the expanding EU. Thus, hard law has instead been introduced through the back door, raising valid questions about regulatory legitimacy. Second, this thesis explores the relationships between hard and soft law in the wider context of EU direct tax regulation. The extent to which the Code is embedded in the broader environment of tax regulation is analysed. The Code tends to be characterised as a soft law measure situated within the regulatory environment of taxation that, for years, has been dominated by hard law instruments. At this level, interactions between ECJ jurisprudence and soft law instruments are also explored. Consequently, the thesis demonstrates that hard law and soft law are not necessarily alternative choices; both approaches can be applied simultaneously to influence one regulatory field, and both offer different strengths and values. In a field as politically sensitive as direct taxation, soft law may prove to be insufficient to bring about real change. The addition of a hard law (or legally binding) element might be necessary to secure effectiveness of regulation. This thesis proposes that the current, disingenuous hybrid regulation of direct taxes in the EU should be replaced with a more transparent hybrid, where hard law measures are openly applied and soft law is given the opportunity to regulate in parallel and to its own distinct potential.

This works examines the question whether a vapour-liquid phase transition exists in systems of particles with purely dipolar interactions, a topic which has been the subject of a longstanding debate. Monte Carlo simulation results for two modi operandi to tackle this issue are presented. One approach examines the phase behaviour of fluids of charged hard dumbbells (CHD), each made up of two oppositely charged hard spheres with diameters σ and separation d. In the limit d/σ → 0, and with the temperature scaled accordingly, the system corresponds to dipolar hard spheres (DHS) while for larger values of d ionic interactions are dominant. The crossover between ionic and dipolar regimes is examined and a linear variation of the critical temperature T*c in dipolar reduced units as a function of d is observed, giving rise to an extrapolated T*cDHS ≈ 0:15. The second approach focuses on the dipolar Yukawa hard sphere (DYHS)fluid, which is given by a dipolar hard sphere and an attractive isotropic interaction Y of the Yukawa tail form. In this case, the DHS limit is obtained for Y → 0. It is found that T*c depends linearly on the isotropic interaction strength Y over a wide range, coinciding with the results for the CHD model and extrapolating to a similar value of T*c;DHS. However, with the use of specially adapted biased Monte Carlo techniques which are highly efficient, it is shown that the linear variation of T*c is violated for very small values of the Yukawa interaction strength, almost two orders of magnitude smaller than the characteristic dipolar interaction energy. It is found that phase separation is not observable beyond a critical value of the Yukawa energy parameter, even though in thermodynamic and structural terms, the DYHS and DHS systems are very similar. It is suggested that either some very subtle physics distinguishes the DYHS and DHS systems, or the observation of a phase transition in DHSs is precluded by finite-size effects. In the context of phase separation in highly correlated fluids, new flat-histogram Monte Carlo simulation techniques based on the Wang-Landau algorithm are evaluated and shown to be useful tools. This work presents a general and unifying framework for deriving Monte Carlo acceptance rules which facilitate flat histogram sampling. The framework yields uniform sampling rules for thermodynamic states given either by the mechanically extensive variables appearing in the Hamiltonian or, equivalently, uniformly sample the thermodynamic fields which are conjugate to these mechanical variables.

Given an undirected edge-weighted graph G and a positive integer m, the Constrained Forest Problem (CFP) seeks a lowest-cost (or minimum-weight) forest F which spans G while satisfying the requirement that each tree in F contain at least m vertices. This problem has been shown to be NP-hard for values of m greater than three, giving rise to a number of approximation strategies for finding reasonable m-forest solutions. This research presents a new genetic algorithm (GA) which can consistently find equal-or-better solutions to the problem when compared to non-genetic alternatives. This GA is unique in that it uses chromosomes which are actual candidate solutions (m-forests) and performs genetic operations (random creation, selection, recombination, and mutation) on these candidate solutions. Experiments were run using 180 different GA configurations on 50 benchmark graphs to determine which operators and techniques would be most successful in solving the m-forest problem. The "heaviest edge first" or HEF algorithm run against the minimum spanning tree (MST) of a graph was used as a performance metric. Previously, the HEF(MST) algorithm had been shown to produce the best results on m-forest problems. When the GA was able to find better results than HEF(MST) on the same problem instance, this was considered a GA success. Since the GA's initial population included heuristic candidate solutions such as HEF(MST), the GA never did worse than the best of these. GA solution quality did vary, however, often finding several different better-than-HEF(MST) solutions, illustrating the stochastic nature of the process. Based on data collected from the 9000 initial problem instances, several factors were shown to significantly improve the quality of the GA solution. Problem instances which did not include mutation had a much lower success rate than those which did. Adding calculated heuristic solutions such as HEF(MST) to the initial population allowed the GA to converge more quickly and improved its likelihood of finding better-than-HEF(MST) solutions. Building an initial population using randomly-generated candidate solutions whose edges were restricted to the problem graph's MST proved equally successful. GA configuration options were analyzed using all 9000 test cases and again using only those 403 cases in which the GA was able to find the very best solution for each graph. These analyses were consistent, and resulted in the identification of a single "best" GA configuration which combined the best overall initial population strategy, random seeding algorithms, mutation and crossover strategy. The selected configuration was then further tested using various values of m to ensure that the resulting GA could in fact find better-than-HEF(MST) solutions for the majority of problem instances.

This study aimed to describe the educational experiences of deaf adolescent learners attending a school for the deaf in South Africa. The specific objectives of the current study included: (a) obtaining a detailed description of the educational experiences of deaf adolescent learners; (b) establishing with which rhetoric (medical vs. cultural) the deaf adolescents could best identify; (c) establishing the potential influence on individual identity development of the established affiliations with the opposing models of deafness. Ten deaf adolescents ranging between 14 and 16 years, attending a single school for the deaf were selected as participants for the current study. A basic research design and a qualitative approach, embedded within the theory of social constructivism were employed. Two pilot studies were conducted in order to establish the feasibility of the current study. Thereafter, interviews as per the ‘interview guide approach’ were administered. Field observations within the school context and file reviews were also conducted. Thematic content analysis was employed and the identified themes were described qualitatively. Results revealed the emergence of three themes. Within these themes, the adolescents’ experiences included: limited SASL role models both at home and at school, negative educational encounters as well as positivity and hope for the future. Experiences characteristic of the medical model and socio-cultural model of deafness were reported and factors affecting these affiliations were described. The researcher concluded that a level of affiliation with both the medical and the sociocultural models of deafness existed for the participants. The impact of these affiliations on identity construction was explored and a model of identity development, the multiculturalexperience model, was proposed. The education of deaf individuals in South Africa shows room for significant growth. By adjusting government education policies for deaf education as well as supporting the goals of early intervention, deaf learners can reach their full potential regardless of the mode of communication favoured.

Most of the seafloor is soft sediment, so hard substrata are isolated and island-like. In this dissertation, I explore how species distribution patterns on isolated marine hard substrata resemble terrestrial island communities, drawing on classical island biogeography theory and assembly rules, and describe how benthic invertebrate communities assemble in these island-like habitats. Higher species richness occurred on larger substrata (dropstones and shipwrecks), paralleling terrestrial island communities. However, while larger islands have greater habitat diversity and primary productivity, marine hard substrata are simpler habitats. Greater elevation in the benthic boundary layer may expose fauna to faster current, higher food supply and larval flux. Substrata located closer together had more similar communities, another pattern that resembles terrestrial islands. Dropstone fauna had a clumped distribution, indicating that larvae may disperse among substrata located close together, resulting in similar communities. In Svalbard fjords, benthic megafaunal communities were significantly different between Arctic- and Atlantic-influenced fjords. Depth and temperature had the greatest influence, with the highest diversity occurring in cold Rijpfjorden and on the north Svalbard shelf. Recruitment in Svalbard fjords was spatially and temporally variable, with lower recruitment in Rijpfjorden than in Atlantic-influenced fjords and lower recruitment at greater depth. Most of the recruits in Svalbard fjords were fast-growing, poor-competitive opportunists. On shipwrecks, communities showed two mechanisms of colonization: mobile fauna with long-dispersing planktotrophic larvae, and encrusting fauna with lecithotrophic larvae. Encrusting species reproduce asexually to cover the wreck surface, and philopatry may build up dense populations, leading to uneven communities. On terrestrial islands, non-random co-occurrence is attributed to interspecific competition, but for marine substrata, there may not be a relationship. Fauna were distributed randomly on settlement plates in Svalbard fjords, even when interspecific competition was observed. On dropstones, some morphotypes co-occurred non-randomly in the absence of overgrowth competition. Non-random co-occurrence on isolated marine hard substrata may be a result of restricted larval dispersal (for pairs co-occurring less than by chance) or epibiontism (for pairs co-occurring more often than by chance). While species distribution patterns on island-like marine hard substrata resemble terrestrial islands, the mechanisms are not necessarily the same.

New restrictions and regulations regarding internal combustion engines introduced severe mechanical and thermo-mechanical loads on engine parts, mostly on piston rings, leading to high wear and premature damage, thus causing oil leakage into the combustion chamber and increasing emissions. One of the most viable solutions to overcome these issues is the use of coatings to change surface properties. Coatings produced by High Power Impulse Magnetron Sputtering (HiPIMS) and Direct Current Magnetron Sputtering (dcMS) have shown promising results to form dense coatings with high hardness and high wear resistance. Those properties can be further enhanced by using a periodic structure in the form of multilayers of different materials. In this study, we proposed a hybrid process with HiPIMS and dcMS to produce multilayer coatings of CrN and CrAlN. Different target combinations and negative substrate bias were studied. Furthermore, the base layer influence and an evaluation of the periodicity effects were presented. Structure and morphology of the coatings were characterized with X-Ray Diffraction, Scanning Electron Microscopy and Atomic Force Microscopy. Meanwhile, instrumented nanohardness, corrosion and wear tests were performed to characterize mechanical, electrochemical and tribological properties. Results showed that the choice of target combination and bias values are fundamental for enhancing mechanical and tribological properties. On the other hand, we found no evidence of superlattice hardening when changing periodicity but an increase in corrosion resistance when reducing periodicity was found. The combination of targets, substrate bias, base layer and periodicity presented here showed promising results on wear tests, especially when compared with the current coating under the same engine conditions. / Novas restrições e regulamentações de motores de combustão interna introduziram severas cargas mecânicas e termomecânicas no motor, principalmente nos anéis de pistão, o que leva a um alto desgaste e ao dano prematuro dos mesmos e causa vazamentos de óleo na câmara, aumentando as emissões de poluentes. Uma das soluções mais viáveis para solucionar este problema é o uso de recobrimentos para alterar as propriedades da superfície. Recobrimentos produzidos pelas técnicas High Power Impulse Magnetron Sputtering (HiPIMS) e Direct Current Magnetron Sputtering (dcMS) mostraram resultados promissores na formação de filmes densos com elevada dureza e resistência ao desgaste. Essas propriedades podem ser melhoradas com a utilização de estruturas periódicas na forma de multicamadas. Nesse estudo, foi proposto um processo híbrido de HiPIMS e dcMS para produzir recobrimentos multicamadas de CrN/CrAlN. Diferentes combinações de alvos e de valores de polarização negativa do substrato (bias) foram estudadas. Além disso, foram apresentadas a influência da camada base e a avaliação dos efeitos da mudança de periodicidade. Estrutura e morfologia dos recobrimentos foram caracterizadas por Difração de Raios-X, Microscopia Eletrônica de Varredura e Microscopia de Força Atômica. As caracterizações mecânica, eletroquímica e tribológica foram realizadas com ensaios de Nanodureza Instrumentada, Corrosão e Desgaste. Os resultados mostram que a escolha da combinação de alvos e de valores de bias são fundamentais para a melhoria das propriedades mecânicas e tribológicas. Por outro lado, não foram encontradas evidências de endurecimento devido ao efeito de super-redes com a variação de periodicidade, mas um aumento da resistência à corrosão foi evidenciado. A combinação de alvos, bias, camada base e periodicidade apresentadas aqui mostraram resultados promissores em testes de desgaste, principalmente quando comparadas com os recobrimentos utilizados comercialmente nas mesmas condições de trabalho do motor.

This work aims to investigate the effects of current density, electrolyte temperature and substrate composition on the morphology of porous anodic films formed on AA 2024-T3 alloy in sulphuric acid electrolytes and the factors that determine the transition between linear and sponge-like film porosities. Comparisons were made with pure aluminium. Particular attention is given to understanding the rising voltage that occurs during galvanostatic hard anodizing of the alloy and the role of oxygen in the anodizing process. Conditions were selected to be representative of typical hard and conventional anodizing processes. SEM was employed to observe the film morphology, which was then correlated with the voltage-time responses. The anodic film composition was investigated by TEM/EDX and SEM/EDX to determine the effect of alloy element enrichment and cell diameter on the distribution of copper species in the film. A real-time gravimetric method was developed to measure the rate of oxygen evolution during anodizing and its influence on the anodizing voltage and film morphology. Results showed that hard anodic films on AA 2024-T3 alloy formed at relatively high voltages have linear pores and cells, contrasting with sponge-like porosity under conventional anodizing. The linear porosity is shown to depend on the voltage, with a morphological transition occurring in the range 25 to 30 V, with linear cells promoted by a high current density and/or low electrolyte temperature. As the film thickens with time, pore blockage by oxygen bubbles, impedes oxidation of the alloy leading to current re-distribution and hence localized increases in the current density producing a rise of the anodizing voltage as anodizing proceeds. The rise of the anodizing voltage, which leads to an increasing call diameter and barrier layer thickness, has a minor influence on the rate of oxygen evolution, which typically consumes about 20 % of the applied current density. In contrast, the voltage rise in the presence of sponge-like films is comparatively negligible, which is suggested to be due to easier escape of oxygen from the film. The films comprising linear cells contain more copper than the sponge-like films, with copper being enriched at the cell boundaries. Moreover, a model is proposed to explain the enrichment of copper, suggesting that above a critical cell diameter, an alloy enrichment sufficient for oxidation of the alloying element can be maintained across the alloy/film interface. Below this diameter, the enrichment is less than that necessary for oxidation, and the alloying element is then incorporated into the film at the cell boundaries.