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Yes / This study's objective was to conduct a comparative analysis and characterization of the microstructural evolution within the weld nugget for joints of AA5083-H112 and AA6061-T6 produced by friction stir spot welding (FSSW) and modified friction stir clinching (MFSC) processes. The mechanical performance of the welded joints was assessed in shear using a single lap joint. The microstructural study identified significant variation in joint microstructure and material flow due to the differences in the tool geometry and methodology used for the welding processes. The results show that the use of modified friction clinching process improves the welded joint by eliminating keyholes/hook defects leading to the formation of high-strength joints. Mechanical characterization of the welded joints indicated that the shear strength increased significantly from 78.69 MPa for the conventional FSSW to 131 MPa for the MFSC process.

The kinetics of austenite decomposition were studied in high purity Fe-0.1 C-0.4 Mn-0.3 Si-X (concentrations in weight percent, X represents 3 Ni, 1 Cr, or 0.5 Mo) steels at temperatures between 500 and 675°C. The transformation stasis phenomenon was found in the Fe-C-Mn-Si-Mo and Fe-C-Mn-Si-Ni alloys isothermally transformed at 650°C and 675°C but not in the Fe-C-Mn-Si and Fe-C-Mn-Si-Cr alloys at any of the temperatures investigated. The occurrence of transformation stasis was explained by synergistic interactions among alloying elements. The paraequilibrium model was applied to calculate the metastable fraction of ferrite in each alloy. This fraction was shown to coincide with cessation of transformation in the Mo alloy transformed at 600°C. Transformation stasis was found in both the Ni and the Mo alloys isothermally reacted at 650°C and 675°C. The interactions among Mn, Si, and Mo as well as interactions among Mn, Si, and Ni appear to decrease the threshold concentrations for occurrence of transformation stasis in Fe-C-Mn-Si systems. The segregation of Mn and Mo to the α/γ boundary assisted by Si was suggested to enhance the drag force and led to transformation stasis. In the Ni alloy, lower driving force for ferite formation by addition of Ni could be responsible for occurrence of transformation stasis. / Master of Science

Circular Concrete Filled Tubes are gaining importance in the construction industry due to their advantages insofar as economy and structural efficiency. Due to the recent developments in concrete and steel technology, the usage of high strength materials in these concrete filled tubes is increasing. The governing American specification (AISC 360-16) classifies these composite members as compact, non-compact and slender sections. The allowed section slenderness (ratio of diameter to thickness ratio) in each classification is related to the material properties (ratio of Young's modulus to yield strength ratio). AISC 360-16 is applicable for steels up to 75 ksi and concretes up to 10 ksi. These limits are lower than current available materials and restricts the usage of highly slender sections. As the strength of these tubes is dependent on local buckling, tests on many combinations of high strength steel and concrete are needed to extend these material limits. This preliminary research work focuses on understanding the local buckling behavior of highly slender sections and the effect of concrete infill and its confinement. The research began by compiling a database that highlighted a gap on tests with highly slender sections and high strength materials. To address this issue, a pilot set of experimental tests were conducted on short circular concrete filled members. An analytical evaluation of these experimental results are performed using 3D finite element analysis models. The critical buckling load is determined using J2 deformation theory, which proves to give a good estimate when compared with the experimental results. The main objective of the work is to determine if a simplified test like the one used in this work could be used for the large experimental study that will be necessary to expend the material limits in AISC 360-16. The limited data developed in this study indicates that the test can provide satisfactory results with a few improvements and refinements. / Master of Science

Yes / Background: Chronic infections with Pseudomonas aeruginosa are a leading cause of morbidity in patients with cystic fibrosis (CF). The aim of tobramycin inhalation therapy in CF patients with chronic pulmonary infection is to deliver high amounts of drug directly to the site of infection. TOBI® is a tobramycin nebulizer solution (300 mg/5 ml) approved by FDA for maintenance therapy for patient with CF. The 20% tobramycin sulfate solution was reported as the optimal and maximal concentration. Methods: Nebulization of high strength tobramycin solution (20% tobramycin sulfate) (HSTS) has been assessed in this study by using different selected high performance nebulizer delivery systems: two different designs of jet nebulizers, and three new nebulizers based on vibrating mesh technology. The aerosol particle size distribution and output characteristics were measured for in vitro performance assessment of the nebulizer systems. The methodology was adapted from the current European standard, EN 13544-1:2001E. Results: The particle size distribution characteristic measurements showed that all tested nebulizers may be suitable for inhalation of HSTS. The mean (SD) of highest percentage of fine particles (<5 mm) was 77.64 (2.3) % for Sidestream®, at flow rate 16 L/min. The highest respirable inhaled mass was for Pari LC Plus® combined with PariBoyN® compressor, with mean (SD) 90.85 (8.6) mg. The mean (SD) of highest drug wastage percentage was 63.9 (3.9) % for Sidestream® jet nebulizer combined with compressed air cylinder at flow rate 16 L/min, while the lowest was 2.3 (0.26) % for NE-U22 Omron® (high frequency). Conclusions: The HSTS can be nebulized by all tested nebulisers but the high frequency NE-U22 Omron® and Aeroneb Go® are more efficient. When the HSTS compared to TOBI®, the respirable inhaled dose was increased to more than 73%.

Accounting for blast hazards has become one of the major concerns for civil engineers when analysing and designing structures. Recent terrorist attacks and accidental explosions have demonstrated the importance of mitigating blast effects on buildings to ensure safety, preserve life and ensure structural integrity. Innovative materials such as high-strength concrete, steel fibers, and high-strength steel offer a potential solution to increase resistance against extreme dynamic loading and improve the blast resilience of buildings. This thesis presents the results of an experimental and analytical study examining the effect of high-strength concrete, high-strength reinforcement and steel fibers on the blast behaviour of reinforced concrete columns. As part of the study, a total of seventeen reinforced concrete columns with different design combinations of concrete, steel fibers, and steel reinforcement were designed, constructed, and tested under gradually increasing blast loads using the University of Ottawa shock-tube facility. Criteria used to assess the blast performance of the columns and the effect of the test variables included overall blast capacity, mid-span displacements, cracking patterns, secondary fragmentation, and failure modes. The effect of concrete strength was found to only have a moderate effect on the blast performance of the columns. However, the results showed that benefits are associated with the combined use of high-strength concrete with steel fibers and high-strength reinforcement in columns tested under blast loads. In addition to the experimental program, a dynamic inelastic single-degree-of-freedom analysis was performed to predict the displacement response of the test columns. A sensitivity analysis was also conducted to examine the effect of various modelling parameters such as materials models, DIFs, and accumulated damage on the analytical predictions.

High performance concrete (HPC) provides a long lasting, durable concrete that is typically used in bridge decks due to its low permeability, high abrasion resistance, freeze-thaw resistance and strength. However, this type of concrete is highly susceptible to the deleterious effects of both autogenous and drying shrinkage. Both types of shrinkage occur when water leaves small pores , (< 50 nm) in the paste matrix to aid in hydration or is lost to the surrounding environment. Autogenous deformation (self-desiccation) occurs as the internal relative humidity decreases due to hydration of the cementitious material. Drying (and subsequent shrinkage) occurs when water is lost to the environment and continues until the internal relative humidity is equivalent to the ambient relative humidity. Typically, the magnitude of autogenous shrinkage is less than that of drying shrinkage. These two types of shrinkage do not act independently, and the total shrinkage is the aggregation of the two shrinkage mechanisms. It is imperative to minimize the amount of shrinkage in restrained members, such as bridge decks, to reduce the cracking potential. Various methods have been researched to minimize both types of shrinkage. Two methods to that have been reported to reduce shrinkage were selected for further research; internal curing using pre-soaked lightweight fine aggregate (LWFA) and shrinkage reducing admixtures (SRAs). The purpose of this study was to determine the long-term drying shrinkage performance of these two methods while reducing the external curing duration of 14 days for new bridge deck construction as specified by the Oregon Department of Transportation. In addition to monitoring drying shrinkage, durability testing was performed on concrete specimens to ensure these shrinkage mitigation methods performed at levels similar to concrete with the current mixture design. Freeze-thaw testing, permeability testing and restrained drying shrinkage testing were conducted. It was concluded that the combination of SRAs and pre-soaked LWFA was the most effective method to reduce longterm drying shrinkage for all curing durations (1, 7, and 14 day). Additionally, for durability testing, it was found that the use of SRAs performed the best in freeze-thaw testing, chloride permeability and restrained shrinkage. / Graduation date: 2012

Abstract not available

Secondary hardening ultra-high strength (SHUHS) steels possess a unique combination of strength, fracture toughness and stress corrosion cracking resistance, which makes them candidate materials for aircraft landing gear and armour applications. There is a sustained drive to develop stronger and tougher materials for such applications. The objectives of this thesis are two-fold: first, to develop a new SHUHS alloy that is stronger than the existing SHUHS steel developed at Defence Metallurgical Research Laboratory (DMRL), Hyderabad and second, to establish processing-structure-property correlations for the new alloy. Empirical design and development of these complex steels involves enormous effort, cost, time and materials resources. To avoid this, a semi-empirical approach was espoused in this thesis wherein thermodynamic calculations using ThermoCalc were conducted to computationally design a series of alloys with varying levels of Cr and Mo. The design space was constrained by two objectives related to M2C carbides which are the primary cause of secondary hardening in these alloys. The first objective was to increase the amount of M2C to increase the peak strength, while the second objective was to lower the Cr/Mo ratio of the M2C to control its over-ageing behavior. Two new alloys C23 (with 2Cr-3Mo, wt. %) and C55 (with 5Cr-5Mo, wt. %) and a base alloy akin to the DMRL SHUHS steel, C21 were selected for experimental validation. These alloys were melted, rolled and subjected to a battery of heat treatments. Austenitization studies revealed that the new alloys required higher austenitization temperatures to dissolve primary carbides. However such a treatment also resulted in an austenite composition that was not conducive for obtaining a fully martensitic microstructure on quenching. Based on these studies, the design space was modified to include additional criteria related to the Ms and precipitate dissolution temperatures. C55 failed to clear either criteria, while C23 cleared both, and so tempering studies were limited to C23. Isochronal tempering studies revealed that C23 in the peak aged condition was >10% stronger than C21 indicating that the alloy design objective of strength enhancement was achieved successfully. Microstructural characterization revealed that the strength enhancement was due to the higher number density and volume fraction of the M2C-like solute clusters in C23, which resist shearing in the under-aged condition and strengthen by Orowan mechanism in the over-aged condition. This thesis has successfully demonstrated that the design paradigm of enhancing strength by increasing the amount of M2C is justified and that ThermoCalc can be used to as an objective-oriented alloy design tool in this class of the steels.