Aços inoxidáveis duplex (AID) são materiais amplamente utilizados para uma grande variedade de aplicações desde a indústria química, de alimentos, petroquímica, naval, farmacêutica, energia nuclear e em muitos outros campos devido à combinação de suas excelentes propriedades mecânicas e de resistência à corrosão. Particularmente na indústria petroquímica, os aços AID’s são muito utilizados como materiais estruturais para a construção de gasodutos que transportam altos volumes de CO2 e na confecção das camadas internas dos tubos flexíveis (oleodutos offshore), utilizadas na produção de óleo. A soldagem a arco dos AID’s pode acarretar, dependendo das taxas de resfriamento envolvidas, a formação de precipitados de segunda fase que degradam suas propriedades mecânicas. Um processo alternativo para evitar o problema de precipitação de fases indesejáveis é a utilização do processo de soldagem/reparo por fricção com pino consumível (SFPC). O objetivo do presente trabalho é a caracterização metalúrgica e mecânica de juntas de solda de aço inoxidável duplex UNS S31803 obtidas através dos processos SFPC e de soldagem de costura por fricção (SCF). Na soldagem SCF, o objetivo do estudo foi a verificação da influência do passo de soldagem na formação e alteração das estruturas e nas propriedades mecânicas. Os resultados dos ensaios foram comparados com as propriedades obtidas do material base (MB) “como recebido”. A partir das juntas soldadas obtidas por fricção, foram extraídos corpos de prova para ensaios de microtração e Charpy para avaliação da resistência mecânica e da resistência ao impacto. Análises da microestrutura em microscopia ótica (MO) e perfis de microdurezas ao longo da região de solda também foram realizadas. Verificou-se que os processos de soldagem SFPC e SCF provocam um intenso refinamento de grão na zona de mistura (região da interface entre material do pino e da base), modificando a estrutura lamelar de grãos alongados da matriz ferrítica/austenítica, ocasionado por uma ação conjunta de aquecimento e deformação plástica oriunda do processo de solda por fricção. Os resultados dos ensaios de microtração indicam que as juntas soldadas aumentaram sua resistência mecânica com relação ao material base, fato que se deve ao aumento da quantidade da ferrita na zona termomecanicamente afetada (ZTMA), à formação de nitretos de cromo no centro dos grãos ferríticos e ao refino de grão. O aumento da quantidade de ferrita na ZTMA ocorre devido às altas taxas de resfriamento envolvidas no processo de soldagem e verificados por análise térmica. As elevadas taxas de resfriamento dificultam a difusão do nitrogênio que tem um importante papel no equilíbrio de fases da estrutura duplex (ferrita-austenita), na soldagem. O nitrogênio aprisionado no interior do grão ferrítico produz nitretos de cromo deixando de agir como elemento gamagênico aumentando a quantidade da fase ferrita. As juntas soldadas verificadas apresentaram tenacidade aceitável de acordo com o exigido pela norma ASTM A923. / Duplex stainless steels (DSS) are materials widely used for a variety of applications from the chemical, food, petrochemical, marine, pharmaceutical, nuclear industry and other fields due to the combination of their excellent mechanical properties and corrosion resistance. Particularly in the petrochemical industry, the DSS’s steels are extensively used as structural materials for the construction of gas pipelines that carry high volumes of CO2 and making the inner layers of flexible pipes (pipelines offshore) used in offshore oil production. The arc welding of DSS's can lead, depending on cooling rates involved, the formation of second phase precipitates which degrade their mechanical properties. An alternative method to avoid the problem of precipitation of unwanted phase is to use the welding process Friction Hydro Pillar Processing (FHPP). The aim of this work is the metallurgical and mechanical characterization of joints welds of UNS S31803 duplex stainless steel obtained through FHPP processes and Friction Taper Stitch Welding (FTSW). In FTSW welding, the objective of the study was to verify the influence of the welding step on the formation and alteration of structures and mechanical properties. The test results were compared with the properties of the obtained base material "as received". From the welds joints obtained by friction welding, specimens for microtensile testing and charpy were extracted to evaluate the mechanical strength and toughness. Microstructural analysis in optical microscopy (OM) and scanning electron microscopy (SEM) and microhardness profiles along the weld region were also performed. It was found that the welding process FHPP and FTSW causes an intense grain refinement in bonding zone, modifying the lamellar structure of elongate grains of matrix ferritic/austenitic, caused by action of heating and plastic deformation arising from the welding process by friction. The results of the microtensile tests indicate that the welded joints increased their mechanical resistance with respect to the base material, due to the increase in the amount of the ferrite in the thermomechanically affected zone (ZTMA), the formation of chromium nitrides in the center of ferritic grains and grain refining. The increase in the amount of ferrite in the ZTMA occurs due to the high cooling rates involved in the welding process and verified by thermal analysis. The high cooling rates difficult the nitrogen diffusion, which plays an important role in the phase equilibrium of the duplex structure (ferrite-austenite) in welding. The nitrogen trapped inside the ferritic grain produces chromium nitrides ceasing to act as gamogenic element by increasing the amount of the ferrite phase. The welds joints verified also had acceptable ductility and toughness according required by standard ASTM A923.

L’hygiène des mains (HDM) est déterminante dans la prévention du risque infectieux associé aux soins. Les pratiques actuelles privilégient l’utilisation de produits hydro-alcooliques (PHA), généralement formulés avec de l’éthanol, de l’isopropanol et/ou du n-propanol, en présence de co-formulants pour une meilleure acceptabilité cutanée. L’efficacité antimicrobienne sur un temps court, nécessaire en raison des situations fréquentes de pratique d’HDM, est atteinte par des teneurs élevées en alcools pouvant excéder 80 % p/p. Cela soulève la question de la toxicité cutanée et respiratoire associée à l’utilisation des PHA. L’évaluation de la toxicité cutanée basée sur les données publiées et des essais in vitro d’irritation cutanée (OCDE 439) et de phototoxicité (OCDE 432) conclut à l’absence d’irritation cutanée aiguë et de phototoxicité en relation avec l’exposition cutanée à ces alcools, y compris en présence de co-formulants, tels que fournis dans les PHA. Il est ressorti de nos essais le possible manque de spécificité, déjà décrit dans la littérature, des modèles d’épidermes humains reconstitués (RhE) vis-à-vis de certaines substances, qu’il convient de garder à l’esprit dans le cadre de l’évaluation de l’irritation cutanée in vitro. Des investigations complémentaires et une évaluation par l’approche Weight of Evidence peuvent être utiles avant de conclure aux propriétés irritantes d’un item d’essai. En termes de génotoxicité, une différence entre les alcools ressort de la revue bibliographique, avec des propriétés génotoxiques décrites uniquement pour l’éthanol. Dans une certaine mesure, nos essais ont confirmé une différence de profil. L’isopropanol et le n-propanol testés dans une batterie de tests in vitro permettant d’appréhender les différents mécanismes génotoxiques (test d’Ames et test du micronoyau (MN) sur cellules humaines p53 compétentes : cellules lymphoblastoïdes TK6 et cellules pulmonaires NCI H292) ont donné des résultats négatifs, y compris lorsqu’ils étaient formulés avec des co-formulants, ou administrés sous forme de vapeurs sur les cellules NCI H292 cultivées en interface air-liquide (IAL). Pour l’éthanol, la réalisation de la même batterie de tests a conduit à des résultats équivoques uniquement dans le test du MN sur cellules TK6 avec l’éthanol seul. Un test du MN supplémentaire sur cellules TK6 en co-culture avec un RhE mimant la barrière cutanée a donné des résultats négatifs. Par ailleurs, aucune exposition systémique significative aux alcools induite par les pratiques d’HDM ne ressort des études publiées chez l’homme, avec des taux indiscernables des valeurs endogènes existantes pour l’éthanol et l’isopropanol. L’ensemble de ces données est en faveur de l’absence de risque génotoxique systémique consécutif à l’utilisation des PHA, et de l’absence de génotoxicité pulmonaire locale liée à l’exposition aux vapeurs d’alcools. En conclusion, en situation d’utilisation des PHA pour l’HDM, aucun risque pour la santé humaine en termes d’irritation cutanée aiguë, de phototoxicité et de génotoxicité ne ressort de ce travail de recherche. / Hand hygiene (HH) is a key factor in preventing healthcare-associated infections. Current practices favor the use of alcohol-based hand rubs (AbHR), generally formulated with ethanol, propan-2-ol and/or propan-1-ol, in the presence of co-formulants for a better skin acceptability. The antimicrobial efficiency within a short time, essential because of the frequent situations of HH practice, is achieved by high levels of alcohols which can exceed 80% w/w. This raises the question of dermal and respiratory toxicity associated with the use of AbHR. The assessment of dermal toxicity based on published data and in vitro skin irritation (OECD 439) and phototoxicity tests (OECD 432) conclude to non acute dermal irritation and phototoxicity risk linked to dermal exposure to these alcohols, even in the presence of co-formulants, as provided in the AbHR. We encountered in our trials the possible lack of specificity, already described in the literature, of the reconstructed human epidermis (RhE) models for some substances, which should be kept in mind in the context of the evaluation of skin irritation in vitro. Additional investigations and an assessment using the Weight of Evidence approach may be useful before concluding the irritant properties of a test item. In terms of genotoxicity, a difference between the alcohols emerges from the bibliographic review, with genotoxic properties described only for ethanol. To a certain extent, our tests confirmed a difference in profile. Propan-2-ol and propan-1-ol tested in a battery of in vitro tests to explore the various genotoxic mechanisms (Ames test and micronucleus test (MN) on p53 competent human cells: lymphoblastoid cells TK6 and pulmonary cells NCI H292) gave negative results, even in the presence of co-formulants, or administered as vapors on air-liquid interface (ALI) NCI H292 cells. For ethanol, the same battery of tests gave equivocal results only in the MN test on TK6 cells with ethanol alone. An additional MN test on TK6 cells co-cultured with a RhE mimicking the existing skin barrier gave negative results. In addition, no significant systemic exposure to alcohols induced by HH practices is apparent from published studies in humans, with indiscernible levels of existing endogenous values for ethanol and isopropanol. All of these data support the absence of an increased systemic genotoxic risk resulting from the use of AbHR and the absence of local pulmonary genotoxicity due to exposure to alcohol vapors. In conclusion, during AbHR use for HH, no risk to human health in terms of acute skin irritation, phototoxicity and genotoxicity is apparent from this research.

Made available in DSpace on 2008-10-20T20:22:55Z (GMT). No. of bitstreams: 1 CPDOC2006ClaudiaSantiago.pdf: 1174020 bytes, checksum: 8abc7401b180c8ea81aacc2fb66251d3 (MD5) Previous issue date: 2006-03-10T00:00:00Z / This essay reports the use of information in the decisive process that took place in the basin of Paraíba do Sul River when charging for the use of untreated water was implemented, determined by National Policy of Hydro Resources, in the year of 1997. This hydrographic basin is of great importance to the national scenery of Brazil (since it is located between the two largest cities of the country). It was choosen as the focus of this study because it was a pioneer experience in implementing a Management System of Hydro Resources in rivers of Union domain, having as background the complexity of Brazilian federalism and the lack of tradition in participative processes of making decisions in this field. This study shows how the fact of charging for the use of water was an agglutinative factor for all the actors in the basin, how the accumulative social capital was fundamental for the negotiation process, and finally how the use of technical information, contrary to what was expected, led to significant advances in methodology and criteria proposed for implementation of this important instrument of water management. / Esta dissertação relata o uso da informação no processo decisório havido na bacia do rio Paraíba do Sul em torno da implementação da cobrança pelo uso da água bruta,instituída pela Política Nacional de Recursos Hídricos. De grande importância no cenárionacional essa bacia hidrográfica foi escolhida como foco de estudo por se tratar de umaexperiência pioneira de implementação de um Sistema de Gestão de Recursos Hídricosem rios de domínio da União, tendo como pano de fundo a complexidade do federalismobrasileiro e a falta de tradição em processos participativos para tomada de decisão nestecampo. O estudo mostra, ainda, como a cobrança pelo uso da água foi um fator deaglutinação dos atores da bacia, como o capital social acumulado foi fundamental para oprocesso de negociação, e finalmente, como o uso da informação técnica, ao contráriodo que se imaginava, proporcionou avanços significativos na metodologia e critériospropostos para implementação desse importante instrumento de gestão das águas.

Les matériaux soumis à de grandes déformations présentes pour la plupart l’apparition de déformations inélastiques. Ce phénomène est souvent accompagné d’une localisation des déformations dans une zone étroite, précurseur de la rupture. Un cas particulier, mais très fréquent, est les bandes de cisaillement qui apparaissent pour beaucoup de géomatériaux. Ces bandes peuvent être rencontrées à des échelles allant de l’échelle kilométrique pour les zones de subduction à l’échelle micrométrique à l’intérieur des zones de faille. Etudier et modéliser la création de ces zones d’instabilité est fondamental pour décrire la rupture des géomatériaux et des phénomènes associés comme les glissements sismiques dans les zones de faille mature de la lithosphère. Les conditions de pression, de température, l’interaction de l’eau interstitielle avec un matériau finement fracturé conduisent à l’apparition de multiples processus physiques impliqués dans les glissements sismiques. Dans ce travail, nous nous attachons à modéliser la création de bandes de cisaillement à l’intérieur des gouges de faille en prenant en compte l’effet de la microstructure par l’intermédiaire des milieux continus de Cosserat, ainsi que les couplages thermo-hydro-mécanique. L’utilisation de la théorie de Cosserat permet non seulement de régulariser le problème de localisation des déformations par l’introduction d’une longueur interne dans les lois constitutives, mais en même temps de prendre en compte l’effet de la microstructure. Deux approches sont employées pour étudier le système d’équations couplées aux dérivées partielles non linéaires : L’analyse de stabilité linéaire et la méthode des éléments finis. L’analyse de stabilité linéaire permet d’examiner les conditions d’apparitions d’instabilités pour un système mécanique avec des couplages multi-physiques. Par ailleurs, des considérations sur les perturbations appliquées au système permettent aussi de déterminer l’épaisseur de la zone de cisaillement, un paramètre clé pour la compréhension du mécanisme mécanique des failles. Ces estimations sont confirmées par l’intégration numérique pour des déformations restant dans une gamme donnée. Elles sont confrontées aux observations expérimentales et in situ et présentent une bonne corrélation. D’autre part, les simulations numériques permettent d’obtenir la réponse mécanique de la gouge de faille et de donner des informations sur l’influence des différents couplages dans le budget énergétique d’un tremblement de terre / When materials are subjected to large deformations, most of them experience inelastic deformations. It is often accompanied by a localization of these deformations into a narrow zone leading to failure. One particular case of strain localization is the formation of shear bands which are the most common patterns observed in geomaterials. In geological structures, they appear at very different scales, from kilometer scale for subduction zones, to micrometric scale inside fault cores. Studying their occurrence and evolution is of key importance to describe the failure of geomaterials and model seismic slip for mature crustal faults. The pressure and temperature conditions in these faults and the interaction with the pore water inside a highly fractured materials highlight the importance of different physical processes involved in the nucleation of earthquakes. In this thesis, we study the occurrence and evolution of shear bands inside fault gouges taking into account the material microstructure by resorting to elastoplastic Cosserat continua and also the effect of thermo-hydro mechanical couplings. The use of Cosserat theory introduces information about the gouge microstructure, namely the grain size, and permits to regularize the mathematical problem of in the post-localization regime by introducing an internal length into the constitutive equations. Two approaches are used to study the coupled non-linear partial differential set of equations: linear stability analysis and finite element simulations. Linear stability analysis allows to study the occurrence of localized deformation in a mechanical system with multi-physical couplings. Considerations on the dominant wave length of the perturbations permit also to determine the width of the localized zone. This shear band thickness is confirmed by numerical integration in the post-localization regime for a certain range of deformation. The obtained widths of the localized zone are key parameters for understanding fault behavior, are in agreement with experimental and field observations. Moreover, numerical finite element computations enable to model the mechanical response of a fault gouge during seismic slip and give insights into the influence of various physical couplings on the energy budget

A corrosão acarreta riscos ambientais, perdas de vidas e elevados gastos financeiros. Logo, a prevenção e o controle tornam-se mandatórios para a operação segura e rentável de estruturas metálicas. O combate à corrosão depende essencialmente de uma maior compreensão dos fenômenos envolvidos e de investimentos em novas tecnologias. A indústria do petróleo recorre frequentemente à aplicação do aço inoxidável UNS S31803 em suas estruturas, devido a sua boa resistência mecânica e à corrosão. Apesar de ser considerada uma liga de boa soldabilidade, ainda é possível que existam heterogeneidades, defeitos e a formação de fases indesejadas após a soldagem, os quais podem deteriorar a resistência à corrosão da junta. A técnica de soldagem com pino consumível (FHPP) mostra-se como uma recente alternativa para o setor industrial offshore devido as suas qualidades inerentes. Deste modo, a finalidade desse trabalho é avaliar separadamente a resistência à corrosão das principais regiões da junta soldada por FHPP (material base do pino e do substrato e a zona termomecanicamente afetada) de aço inoxidável dúplex UNS S31803, frente a um meio de água do mar sintética na condição naturalmente aerada. De tal modo, é possível identificar eventual comprometimento da resistência à corrosão de uniões desta natureza. Para isso foi desenvolvida uma célula eletroquímica de três eletrodos com dimensões reduzidas (microcélula). Assim, as regiões principais da junta soldada foram analisadas separadamente através de polarizações potenciodinâmicas cíclicas. Foi possível obter os potenciais de corrosão (Ecor), de quebra de passividade (Eq) e de proteção (Eprot1 e Eprot2), junto com os coeficientes de Tafel (ba e bc) e as densidades de corrente de corrosão (icor) e de quebra de passividade (iq). Com base nestas observações, acredita-se que a junta soldada apresenta comportamento eletroquímico em todas suas regiões. / Corrosion impacts annually in environmental risks, loss of human life and high financial costs. Thus, the prevention and the control became mandatory for safe and profitable operation of metal structures. Therefore, the maintenance of acceptable levels of corrosion depends essentially on a greater understanding of the corrosion phenomena and investments in new technologies. The petroleum industry often relies on the UNS S31803 stainless steel in their structures, due to the good mechanical and corrosion resistance of this material. Even though it is considered to be an alloy of good weldability, it is still possible to have heterogeneities, defects and formation of deleterious phases after the welding, which may result in the weakening of the corrosion resistance of the joint. Friction hydro pillar process, arise as a good and recent alternative to the offshore industry, due to its inherent qualities. Therefore, the aim of this study is to individually evaluate the corrosion resistance of the main regions (base materials from the pin and from the subtract and the thermo-mechanically affected zone) of the duplex stainless steel UNS S31803 joint welded by FHPP, against synthetic seawater in the naturally aerated condition, in order to identify potential impairment of the corrosion resistance of these joints. For this, it was developed a three electrode electrochemical cell with reduced dimensions (microcell). This way, the main regions of the welded joint could be analyzed separately with cyclic potenciodinâmica polarizations. It was obtained the corrosion (Ecor), pitting (Eq) and protective (Eprot1 and Eprot2) potentials, along with the Tafel slopes (ba and bc) and corrosion (icor) and passivity breakdown (iq) current densities. Based on these observations, it is believed that the welded joint present good electrochemical behavior in all its regions.

Tem crescido a demanda por energia em todo o mundo. No Brasil, com o aquecimento da economia aumentam ainda mais as pressões. O parque gerador Brasileiro é fortemente baseado na geração hidrelétrica, que representa aproximadamente 77,6% da oferta de geração de eletricidade. Entre os impactos ambientais gerados pela construção de barragens e reservatórios de aproveitamentos hidrelétricos está a mudança do regime fluvial de jusante, a chamada vazão remanescente. Entre outros, esta vazão deve garantir as condições adequadas à sobrevivência e continuação das espécies e dos ecossistemas, associando as necessidades humanas, ambientais e as características de cada região. Tomou-se como objeto de análise dois estudos de caso, a pequena central hidrelétrica (PCH) Santa Gabriela, localizada no rio Correntes, na divisa entre os estados de Mato Grosso e Mato Grosso do Sul e a usina hidrelétrica (UHE) Batalha, situada no rio São Marcos, na divisa entre os estados de Minas Gerais e Goiás. Embora o assunto seja discutido amplamente pela comunidade técnica e acadêmica, não há ainda nos marcos legais Brasileiros associados, uma definição explícita de critérios ou limites para estabelecimento da vazão remanescente. Em geral, as legislações estaduais estabelecem valores máximos outorgáveis determinados a partir de percentuais da curva de permanência (Q90, Q95) ou da vazão mínima anual de sete dias de duração e tempo de recorrência de 10 anos Q7,10, garantindo consequentemente as vazões mínimas remanescentes. Essas metodologias implicam num único valor fixo para a vazão ao longo do ano, o que não condiz com a realidade do regime hidrológico natural. Estudos atuais apontam para um hidrograma ecológico, que represente a variação das vazões entre os meses de estiagem e cheia. Assim, a metodologia envolveu a comparação entre critérios de outorga utilizados em alguns estados Q90, Q95 e Q7,10 e métodos citados na literatura para estudo da vazão ecológica (Tennant, Texas, Vazão Base e Perímetro Molhado) e as Resoluções referentes à Declaração de Reserva de Disponibilidade Hídrica (DRDH) das usinas, que especificam a vazão remanescente nas fases de enchimento e operação, emitidas pela Agência Nacional de Águas (ANA). Observaram-se valores de vazões substancialmente diferenciados entre os seis métodos empregados. Cabe destacar, que representa um avanço a publicação do Manual de Estudos de Disponibilidade Hídrica para Aproveitamentos Hidrelétricos (ANA, 2009), que visa à padronização dos documentos para fins obtenção da DRDH e da outorga do uso do potencial de energia hidráulica em corpo de água de domínio da União. Assim, o empreendedor poderá propor e negociar a demanda hídrica para as necessidades ambientais com as autoridades competentes, o que deverá ser discutido em reunião técnica inicial que deverá contar com a participação da Agência Nacional de Energia Elétrica (ANEEL), ANA, órgão ambiental, empreendedor e a empresa responsável pelos estudos ambientais. / Worldwide, the demand for energy has been increasing. In Brazil, with the economy warming up in the last years, the demand for energy supply further increased. The Brazilian power generating facilities are heavily based on hydroelectric generation, which represents 77,6% of the total generated electricity. Among the environmental impacts caused by the construction of dams and reservoirs are the changes on downstream discharges, known as the remaining discharge. This discharge should ensure the appropriate conditions to the survival and perpetuation of ecosystems, linking human and wild life needs of each region. In this respect, two case studies are taken as object of analysis: (1) a small hydroelectric power plant Santa Gabriela, located in Correntes river, in the limits of Mato Grosso and Mato Grosso do Sul States; (2) the hydropower plant Batalha, in São Marcos river, in the limits of Minas Gerais and Goiás States. Although its been observed that this issue is widely discussed by technical and academic communities, no legal framework or an explicit definition, or criteria, or limit values has been identified for the establishment of the remaining discharge in hydroelectric power plant projects. Generally, values have been defined based on criteria adopted in states water use rights acts that define minimum discharge parameters based on time series frequency analysis such as Q90%, Q95% or Q7, 10. These methodologies imply on a single value discharge throughout the year, which does not reflect the variability of natural hydrological regime. Current studies lead to an, so called, ecological hydrogram, which would represent discharges variability during drought and flood periods. The methodology of analysis in which the discussion presented in this master dissertation was based, involved the comparison of values obtained by different water use rights criteria adopted in some states like Q90%, Q95% and Q7, 10 and, methods quoted in the literature to define the ecological discharge (Tennant, Texas, Base Flow and Wetted Perimeter), as well as National Water Agencys (ANA) declarations related to the Water Availability Reserve Statement (WARS) which specifies remaining dischargesflow for the reservoir filling and operating phases. It was observed that the application of the different methods in the two case studies resulted in significantly different values for the definition of the remaining discharge. However, its worth to note that the publication of the Guidelines for Water Availability Study for Hydroelectric Power Plants (ANA, 2009) that aims the standardization of documents to obtain WARS and granting the use of water for energy generation purposes in federal jurisdiction represents an advance in these matters. By that, the developer may propose and negotiate water demands for wild life needs with the involved authorities, which should be discussed in the initial technical meeting that will count on the National Electrical Energy Agency (ANEEL), ANA, the related environmental agency, the developer and the organization/agency responsible for the environmental studies.

One of the main concerns of the power utilities is secure, continuously supplying electric power to customers, thus meeting so satisfy these as to regulatory requirements. Thus, the proposed paper presents a method of restoring the electric power supply applying the concepts of automatic reconfiguration of the aggregate distribution networks the possibility of islanded operation of small hydro (SHP), since the use of PCH so islanded in certain circumstances, or becomes only, or the best solution to be adopted in a contingency situation in order to reduce the impact of unwanted interruptions. Since the intrinsic decision making process of reconfiguration of distribution networks involves multiple objectives and constraints, the proposed methodology uses the Analytic Hierarchy Process (AHP) method, which is a very useful tool for issues involving multicriteria decision taken. Additionally, case studies for analysis and validation of the proposed methodology are presented. / Uma das principais preocupações das empresas distribuidoras de energia elétrica é garantir, de forma contínua, o fornecimento de energia elétrica aos seus clientes, atendendo assim tanto a satisfação desses quanto às exigências regulatórias. Sendo assim, o trabalho proposto visa apresentar uma metodologia de restabelecimento do fornecimento de energia elétrica aplicando os conceitos de reconfiguração automática das redes de distribuição agregados a possibilidade de operação ilhada de pequenas centrais hidroelétricas (PCHs), uma vez que a utilização de PCH de forma ilhada, em determinadas circunstâncias, torna-se ou a única, ou a melhor solução a ser adotada em uma situação de contingência com o objetivo de reduzir o impacto causado por interrupções indesejadas. Visto que a tomada de decisão intrínseca ao processo de reconfiguração das redes de distribuição envolve vários objetivos e restrições, a metodologia proposta utiliza o método Analytic Hierarchy Process (AHP) que representa uma ferramenta muito útil para questões envolvendo tomadas de decisão multicriteriais. Adicionalmente, são apresentados estudos de caso para análises e validações da metodologia proposta.

L'Agence nationale pour la gestion des déchets radioactifs (Andra) a commencé en 2000 la construction du Laboratoire Souterrain de Meuse / Haute-Marne (LS-M/HM) avec l'objectif principal de démontrer la faisabilité d’un stockage géologique dans l’argilite du Callovo-Oxfordien. Un réseau de galeries expérimentales a été excavé, principalement en suivant les directions des contraintes horizontales (majeure et mineure), avec des variations sur : la méthode d'excavation, la géométrie de la structure et le soutènement. Chaque galerie a été instrumentée en différentes sections pour suivre le comportement hydromécanique de la roche face à l’excavation. Le suivi de la zone autour des galeries excavées au niveau principal (-490 m) a révélé le développement d'une zone fracturée (fractures en extension et en cisaillement) induite par l'excavation. La distribution de la zone fracturée dépend à la fois de l'orientation de la galerie et du champ de contraintes in-situ et a une influence importante sur la déformation des galeries. En effet, les mesures de convergence ont montré une fermeture anisotrope de la section de la galerie. De plus, il a été observé un champ de distribution anisotrope de la pression de pores ainsi que des surpressions autour des galeries.Afin d’analyser la réponse anisotrope du massif pendant l’excavation et après celle-ci, les travaux effectués dans le cadre de la thèse sont axés principalement sur une étude directe des mesures de convergence in-situ. Cette analyse s’effectue à l’aide de la loi semi-empirique proposée par Sulem et al. (1987) [Int J Rock Mech Min Sci Geomech Abstr 24: 145–154]. A cet égard, différentes galeries excavées dans le LS-M/HM ont été étudiées. Ces galeries présentent certaines différences dans leurs orientations et l’état initial des contraintes, dans la méthode et la vitesse d’excavation ainsi que dans les diamètres de la section et les types de soutènements installées. Cette analyse permet d’obtenir des prédictions fiables de la convergence à long-terme, ce qui peut servir pour le dimensionnement et la prévision de la performance du soutènement à long-terme.En outre, nous avons étudié la réponse anisotrope du champ de pression interstitielle observée in-situ. Cette analyse est basée sur une approche poroélastique anisotrope. L’objectif principal est de reproduire qualitativement l’évolution de la pression des pores autour des galeries avec une approche simple qui prend en compte l’anisotropie intrinsèque du matériau. Enfin, une analyse de l’apparition de la rupture montre le rôle clé que joue le couplage hydromécanique dans l’extension de la zone fracturée / The French National Radioactive Waste Management Agency (Andra) began in 2000 the construction of an Underground Research Laboratory (URL) with the main goal of demonstrating the feasibility of a geological repository in Callovo-Oxfordian claystone. Several research programs have taken place to improve the knowledge of the rock properties and its response to the excavation progress. A network of experimental drifts has been constructed with variations on: excavation method, structure geometry, supports system and orientations with respect to principal stresses’ directions. In each drift different sections have been instrumented to monitor the hydro-mechanical behavior of the rock mass formation. Continuous monitoring of the excavated zone around the drifts in the main level (-490 m) revealed the development of a fractured zone (extensional and shear fractures) induced by the excavation. The extent of this fractured zone depends on the drift orientation regarding the in-situ stress field. Accordingly, the convergence measurements showed an anisotropic closure which depends also on the drifts’ orientations. Moreover, marked overpressures and an anisotropic pore pressure field around the drifts have been also observed.The approach proposed in this work is mainly based on a direct analysis of the convergence measurements, for studying the anisotropic response of the rock formation during and after excavation. The convergence evolution is analyzed on the basis of the semi-empirical law proposed by Sulem et al. (1987) [Int J Rock Mech Min Sci Geomech Abstr 24: 145–154]. The monitoring and analysis of convergence data can provide a reliable approach of the interaction between rock mass and support. Therefore, the anisotropy and the variability of the closure are analyzed taking into account different field cases: drifts excavated in two different orientations (i.e. influence of the initial stress state), different methods, sizes and rates of excavation and different supports systems with different conditions of installation. This broad range of cases permits to refine the analysis for reliable predictions of the convergence evolution in the long term. This approach can thus be used for the design of various types of support and the evaluation of its performance in the long term.On the other hand, the pore pressure evolution induced by excavation of drifts as recorded in situ has been analyzed. The anisotropic response observed in-situ suggests that the intrinsic anisotropy of the material plays a key role in the response of the rock formation. To understand these phenomena, an anisotropic poroelastic analysis of the pore pressure evolution induced by the drift excavation is performed. The main goal is to simulate the main trends of the pore pressure evolution with a simple model taking into account the inherent anisotropy of the material. Finally, an analysis of the onset of failure shows the key role of the hydro-mechanical coupling on the extension of the failed zone around the drifts

Ce travail s'intéresse aux altérations des systèmes fluviaux et à leur modélisation à une échelle de temps intermédiaire, de l'ordre de quelques décennies, et à l'échelle spatiale de bassins versants étendus et complexes. Une revue de la littérature montre que cette question reste principale chez les géomorphologues. Elle permet de dégager les constantes des différents modèles conceptuels qui ont été développés et en particulier i) la dépendance aux conditions hydrologiques et aux conditions d'alimentation solide, ii) la réaction du système pour s'adapter en cas d'altération de ces conditions, et iii) la propagation de ces perturbations avec une atténuation progressive vers l'aval du bassin versant. Nous avons choisi d'étudier plus particulièrement les perturbations introduites par les aménagements hydroélectriques à l'échelle du bassin versant en développant un modèle conceptuel, basée sur une description volontairement limitée des altérations hydrologiques et d'alimentation solide, et sur la connaissance experte pour la prédiction de l'évolution de la morphologie des rivières alluviales. L'objectif est la détermination des trajectoires d'évolution de variables représentatives de la morphologie de la rivière qui les font évoluer d'un état d'équilibre dynamique à un autre. Nous avons testé ce modèle sur une représentation du bassin versant de l'Isère à l'amont de Grenoble (5818 km2) en intégrant une description du schéma complexe d'aménagements hydroélectriques construits dans la deuxième moitié du XXème siècle. La modélisation donne des résultats cohérents avec les observations du système mais qui sont limitées par les hypothèses fortes d'un équilibre initial du système fluvial et de l'unicité de l'origine des perturbations. En dernière partie, nous ébauché le développement d'un modèle numérique simplifié destiné à prendre en compte la période de transition entre les états d'équilibre dynamique. Ce modèle permet d'évaluer la durée de la période transitoire d'un tronçon de rivière et de valider l'utilisation du concept de débit morphogène qui est fait dans le modèle conceptuel des équilibres dynamiques. Ce modèle permet de simuler la superposition d'altérations mais, dans l'état actuel, il ne permet pas de modéliser la cinétique de la propagation des altérations amont vers l'aval du bassin versant. Mots-clés : morphologie fluviale, bassin versant, régime hydrologique, apports sédimentaires, aménagements hydroélectriques, trajectoires de ajustements, cinétique de évolution du lit. / Abstract This work focuses on the geomorphological dynamics of a river system and the modelling of these changes over a medium time scale (the order of a few decades) and a large watersheds spatial scale (the order of 5000 km2). A literature review shows that this subject is one of the main issues in fluvial geomorphology today. It reveals the constants of different conceptual models that have been developed and in particular i) the dependence of geomorphological dynamics on hydrological flow regime and sediment supply conditions, ii) the ability of the system to adapt, in case of alteration in hydrological flow regime and sediment supply, and iii) the spread of these disturbances with the gradual attenuation of the effect of alteration downstream. In particular, we chose to study the effect of disturbances introduced by hydroelectric structures on the river morphology at the watershed scale by developing a conceptual river morphology model. The model outline was based on a, deliberately limited, description of hydrological regime and -sediment supply alterations, and on expert knowledge to predict the morphological evolution in alluvial rivers. The objective of this work was to determine the direction of evolution trajectories of the river morphology, trough representative variables that evolve from one dynamic equilibrium state to another. We tested the model on a representation of the Isère watershed, upstream of Grenoble, France (5818 km2), incorporating a description of the complex pattern of hydropower structures, built during the second half of the XXth century. The modelled changes in river morphology give results that are consistent with the observations. However, the model is limited by two strong assumptions: i) the initial equilibrium of the system and ii) the synchronisation of the disturbances. In the final section, we described the development of a simplified numerical model which aims to take into account the transient period between the dynamic equilibrium states. This model is used to evaluate the duration of the relaxation period for a river reach and validate the use of the channel-forming discharge concept that was used in the conceptual model. The model simulates the overlay of the disturbances, but in the current state it is not capable of modelling the kinetic propagation of the disturbances downstream into the watershed. fluvial morphology, watershed, hydrological flow regime, sediment supply, hydropower structures

[pt] Atrelado aos cenários cada vez mais complexos de extração de energia, o estudo de fenômenos acoplados em meios porosos - notadamente térmicos, hidráulicos, químicos e mecânicos - tem se apresentado como essencial na previsão de comportamento de meios geológicos no que diz respeito à disposição de rejeitos radioativos, armazenamento de dióxido de carbono, engenharia de reservatórios geotérmicos e geomecânica de reservatórios. Assim, este trabalho objetiva desenvolver um esquema de acoplamento termo-hidro-mecânico-químico iterativo visando a simulação do armazenamento geológico de dióxido de carbono, empregando um simulador de fluxo composicional (GEM) e um programa de análise de tensões (ABAQUS ou CHRONOS). A idealização das metodologias de acoplamento foi efetuada através dos processos hidro-mecânico, termo-hidro-mecânico e termo-hidro-mecânico-químico, bem como as validações e aplicações em casos reais. Os casos de validação, realizados empregando modelos simplificados monofásicos, apresentaram resultados satisfatórios quanto ao comportamento hidro-mecânico e termo-hidro-mecânico. Adicionalmente às validações, os esquemas termo-hidro-mecânico e termo-hidro-mecânico-químico foram aplicados em dois casos reais de armazenamento de CO2 apresentados na literatura, projeto In Salah (Argélia) e aquífero Utsira (Noruega), respectivamente. De maneira geral, os resultados encontrados, para ambos os casos estudados, representaram acuradamente as respostas encontradas em campo, fato que evidencia a qualidade, robustez e aplicabilidade dos esquemas de acoplamento propostos neste trabalho. / [en] Considering the increasingly complex scenarios of energy extraction, the study of coupled phenomena in porous media - notably thermal, hydraulic, chemical and mechanical - has been considered as essential in order to predict the behavior of geological media with regard to radioactive waste storage, CO2 geological storage, geomechanics of geothermal reservoirs and reservoir geomechanics. Thus, this work aims to develop a thermo-hydro-mechanical-chemical iterative coupling scheme in order to simulate the geological storage of CO2, employing a compositional flow simulator (GEM) and a stress analysis program (ABAQUS or CHRONOS). The idealization of the coupling methodologies was carried out through the processes hydro-mechanical, thermo-hydro-mechanical and thermo-hydro-mechanical-chemical, as well as the validations and applications in real cases. The validation cases, performed employing simplified single-phase models, presented satisfactory results regarding the hydro-mechanical and thermo-hydro-mechanical behaviors. Additionally to the validations, the thermo-hydro-mechanical and thermo-hydro-mechanical-chemical schemes were applied in two real cases of CO2 geological storage reported by the literature, In Salah project (Algeria) and Utsira aquifer (Norway), respectively. In general, the results found, in both cases studied, accurately represented the behavior observed in the field, which in turn highlights the accuracy, robustness and applicability of the coupling schemes proposed in this work.