Various occupational stressors like the physical environment, noise, lighting, temperature. aspects of the job, role conflict, workload, lack of career path, poor relationships with peers. and lack of participation arc likely to lead to various stress outcomes, namely behavioural; proneness to accidents, cognitive, inability to make sound decisions, physiological: increased blood pressure, physical and mental health, and organisational: lower productivity, and high turnover rate. These outcomes could however be influenced by moderator variables like age and gender, physiological experience and affective behaviours (type 'A' behaviour, life change, and social support). Studies have also found instances where some workers, exposed 10 the same unbearable work environments, did suffer from neither stress nor burnout. These findings have therefore led to the study of work engagement, which is considered the opposite of burnout. The study of stress, burnout and work engagement has therefore become vehicles through which employees' effectiveness and efficiency can be facilitated. It has become necessary to jointly study stress with burnout and work engagement in a holistic model so as to how a better understanding of work wellness. Burnout and work engagement therefore represent the two aspects of wellness namely, the energy dimension and the identification with work dimension. Studies have identified two underlying dimensions of work wellness in which they identified activation as ranging from exhaustion to vigour, arid identification as ranging from mental distance to dedication. Thus burnout according to them is characterised by a combination of exhaustion (low activation) and mental distance (low identification), while engagement is represented by vigour (high activation) and dedication (high identification). Extreme exhaustion may render employees emotionally and physically drained which may lead them to distance themselves emotionally and cognitively from their work and clients, while an engaged worker develops high levels of energy, and derives a sense of significance, attachment and dedication to work. However, to measure burnout, work engagement, stress, commitment and ill health requires valid and reliable instruments. In South Africa there aren't many systematic studies that have investigated stress, burnout, work engagement, commitment and ill health among civil servants. It is this dearth of well-designed studies in the area that makes this study very important. The objectives of this study were to assess the reliability and validity of the MBI-GS, the UWES, the ASSET, the Job Demands-Resource Scale, Commitment and Ill Health subscales Tor civil servants, determine the occupational stressors that they experience and whether the biographic variables by any way increase or moderate the effects of the stressors, and to finally test a structural model of work wellness consisting of burnout, work engagement, job demands-job resources, ill health, and commitment. The research method for each of the three articles consists of a brief literature review and an empirical study. A cross-sectional survey design was used. An accidental sample (N = 500) for research articles 1, 2 and 3 were targeted from the civil servants in the Mafikeng area of the North West Province of South Africa. The measuring instruments used in this study are; the Maslach Burnout Inventory-General Survey (MBI-GS), Utrecht Work Engagement Scale (UWES), Job Demands and Job Resources Scale (JDRS), Health subscales. Organizational Commitment subscales, the ASSET questionnaire and a biographical questionnaire. Structural equation modelling was used to test the factor structures of the Maslach Burnout Inventory-General Sunley (MBI-GS), and the Utrecht Work Engagement Scale (UWES) respectively. namely exhaustion, cynicism, cognitive weariness, and professional efficacy, and vigour, dedication and absorption. In respect of the MBI-GS, a four-factor model of burnout. consisting of exhaustion (physically drained), cynicism (distancing oneself from colleagues and clients), professional efficacy (feeling of accomplishment) and cognitive weariness (lack of focus on one's work), was found to fit the sample data best in comparison to the three-factor, two-factor and one-factor models. Thus the study established burnout as a bur-dimensional construct. In the case of the UWES a two-factor model of work engagement, consisting of vigour and dedication fined the data best as compared to a three-factor or one-factor model. This means that the UWES is a two-dimensional construct and not a three-factor nor a one-factor dimensional construct. The scales of the MBI-GS, UWES, and the ASSET subscales of work relationships, work life balance, overload, job security, control, resources/communication. aspects of the job, and the stress outcomes of organisational commitment, individual commitment physical health and psychological (un)well-being showed acceptable internal consistencies. There existed no statistically significant differences between burnout, work engagement. the stress dimensions, commitment and ill health respectively and any of the biographical variables. The study found that psychological (un)well-being, is a major stress outcome for the civil servants followed by physical (un)health, respectively. It was discovered that the civil servants generally have low levels of stress, and security was the lowest stressor. Employee commitment was also found to be high. Stress, due to lack of resources, predicted physical ill health and explained 21% of the variance of ill health among the sample of civil servants. Stress relating to aspects of the job and security, predicted psychological ill health and explained 31% of the variance in psychological ill health. Issues relating to control on the job and security predicted organisational and individual commitment respectively and further explained 28% and 20% of organisational commitment and individual commitment. Stress due to lack of job resources, security and aspects of [he job seem to be the most important stressors. Another objective of the study was to find out if energy and identification with work could be predicted from job demands and job resources respectively. It was found that job demands and lack of job resources lead to ill health through burnout, and job resources could lead to commitment via engagement. The implications are that employees who experience excessive workload are likely to experience burnout, which in turn leads to health related problems. Continuous availability of job resources would lead to work engagement, which in turn leads to organisational commitment, while lack of it would lead to burnout. Recommendations for further research were accordingly made. / Thesis (Ph.D. (Industrial Psychology))--North-West University, Potchefstroom Campus, 2007

The current research has considered the characterization of the high strain rate constitutive response of three steels: a drawing quality steel (DDQ), a high strength low alloy steel (HSLA350), and a dual phase steel (DP600). The stress-strain response of these steels were measured at seven strain rates between 0. 003 s^-1 and 1500 s^-1 (0. 003, 0. 1, 30, 100, 500, 1000, and 1500 s^-1) and temperatures of 21, 150, and 300 ??C. In addition, the steels were tested in both the undeformed sheet condition and the as-formed tube condition, so that tube forming effects could be identified. After the experiments were performed, the parameters of the Johnson-Cook and Zerilli-Armstrong constitutive models were fit to the results. <br /><br /> In order to determine the response of the steels at strain rates of 30 and 100 s^-1, an intermediate rate tensile experiment was developed as part of this research using an instrumented falling weight impact facility (IFWI). An Instron tensile apparatus was used to perform the experiments at lower strain rates and a tensile split-Hopkinson bar was used to perform the experiments at strain rates above 500 s^-1 <br /><br /> A positive strain rate sensitivity was observed for each of the steels. It was found that, as the nominal strength of the steel increased, the strain rate sensitivity decreased. For an increase in strain rate from 0. 003 to 100 s^-1, the corresponding increase in strength at 10% strain was found to be approximately 170, 130, and 110 MPa for DDQ, HSLA350, and DP600, respectively. <br /><br /> The thermal sensitivity was obtained for each steel as well, however no correlation was seen between strength and thermal sensitivity. For a rise in temperature from 21 to 300 ??C, the loss in strength at 10% strain was found to be 200, 225, and 195 MPa for DDQ, HSLA350, and DP600, respectively for the 6 o?clock tube specimens. <br /><br /> For all of the alloys, a difference in the stress ? strain behaviour was seen between the sheet and tube specimens due to the plastic work that was imparted during forming of the tube. For the DP600, the plastic work only affected the work-hardening response. <br /><br /> It was found that both the HSLA350 and DDQ sheet specimens exhibited an upper/lower yield stress that was amplified as the strain rate increased. Consequently the actual strength at 30 and 100 s^-1 was obscured and the data at strain rates above 500 s^-1 to be unusable for constitutive modeling. This effect was not observed in any of the tube specimens or the DP600 sheet specimens <br /><br /> For each of the steels, both the Johnson-Cook and Zerilli-Armstrong models fit the experimental data well; however, the Zerilli-Armstrong fit was slightly more accurate. Numerical models of the IFWI and the TSHB tests were created to assess whether the experimental results could be reproduced using the constitutive fits. Both numerical models confirmed that the constitutive fits were applied correctly.

More and more, advanced polymer and composite materials are being applied in engineering situations where a high resistance to loading at high rates of strain, such as by impact or blast deformation, are a vital requirement. Specific examples exist in the fields of defence and sport research and development for personal, and in the case of the former, vehicular, protection. There are obvious advantages to the use of polymer materials for these applications in augmenting the more widely used metals and ceramics, most notably the evident reduction in weight, and it is believed that with suitable nano-reinforcement these materials may exhibit improved combat survivability. The current study concerns the effect that nano-reinforcements in the form of Carbon Black, Titanium Dioxide, Exfoliated Hectorite Nanoclay and Carbon Nanotubes; have upon the high strain rate mechanical properties of structural variants of Polyethylene (Linear Low Density Polyethylene, LLDPE; High Density Polyethylene, HDPE; Ultra-High Molecular Weight Polyethylene, UHMWPE) and blends of UHMWPE and HDPE. The testing samples were manufactured using a novel process developed in the Loughborough University Materials Department, which has produced well-dispersed specimens. The formed nanocomposite samples were studied using an in-house four-bar Split Hopkinson Pressure Bar (SHPB) system for high strain rate performance, instrumented dropweight for intermediate strain rates and a conventional commercial Hounsfield H50KM universal testing machine for quasi-static strain rate compressive tests. The experimental results recorded for un-reinforced materials are used as a reference to allow comparative analysis of any effect the nano-reinforcements or the blending process have upon the structure, performance and properties of the composite material. From the mechanical testing, it was seen that the stress-strain behaviour of Polyethylene is highly strain-rate-dependent, as plots of the average representative yield stress as a function of strain rate show a bilinear relationship when plotted on a logarithmic strain rate scale, with the gradient of the curve rising sharply at around 103s-1. Concerning the addition of the nanofiller materials, it was seen that there was an increase in the flow and yield stresses and the energy absorption characteristics of the resulting composite with the magnitude dependent upon whether it was a pure or blended polymer that was reinforced. Of the aforementioned fillers it was seen that the addition of Carbon Nanotubes in the small concentrations studied resulted in the greatest increase in properties compared to the pure polymers, closely followed by the Carbon Black fillers. Also of note, the un-reinforced blended samples showed significant increases in flow stress, yield stress and energy absorption when compared to the constituent UHMWPE and HDPE polymers. Additionally, a complete set of Differential Scanning Calorimetry and density measurements were made before testing to assess any changes in the properties after reinforcement or blending, and to help in the interpretation of the results from the different mechanical tests.

For microelectronics used in the low-temperature applications, the understanding of their reliability and performance has become an important research subject characterised as electronics to serve under the severe or extreme service conditions. Along with the impact from the increased miniaturization of devices, the various properties and the relevant thermo-mechanical response of the interconnection materials to temperature excursion at micro-scale become a critical factor which can affect the reliable performance of microelectronics in various applications. Pure indium as an excellent interconnection material has been used in pixellated detector systems, which are required to be functional at cryogenic temperatures. This thesis presents an extensive investigation into the thermo-mechanical properties of indium joints as a function of microstructure, strain (loading histories-dependent) and temperature (service condition-sensitive), specifically in the areas as follows: (i) the interfacial reactions and evolution between indium and substrate during the reflow process (liquid-solid) and thermal aging (solid-solid) stages by taking low-temperature cycling into account; (ii) determination of the effects of joint thickness and the types of substrate (e.g. Cu or Ni) on the mechanical properties of indium joints, and the stress- and temperature-dependent creep behaviour of indium joints; (iii) the establishment of a constitutive relationship for indium interconnects under a wide range of homologous temperature changes that was subsequently implemented into an FE model to allow the analysis of the evolution of thermally-induced stresses and strains associated with a hybrid pixel detector.

Carbon Capture and Storage (CCS) is recognised as having a significant role to play in tackling climate change and reducing carbon dioxide (CO2) emissions. In CCS schemes, CO2 is captured from anthropogenic sources, and transported to suitable sites either for EOR (Enhanced Oil Recovery) or storage. The transport of such huge amount of CO2 causes new challenges. The main concern is in the difference between natural gas and CO2 transportation pipelines. CO2 phase behaviour during decompression, existence of different impurities and very high operating pressure are some of the new challenges for pipeline designer and operators. This PhD study has taken a systematic approach to understand the mechanics involved in the fracture of pipes containing high pressure flue-gas CO2. The work involved the development of a novel weight function stress intensity factor solution that can be used with complex stress fields induced by residual and/or thermal stresses in addition to applied pressure. In addition, the thesis reports a substantial experimented test programme which involved low temperature fracture toughness tests linked to a detailed finite element based stress analysis. Overall, the thesis presents an integrated engineering criticality means to assess the suitability or otherwise of a pipeline system to transport high pressure flue-gas CO2.

Fibre reinforced polymer (FRP) composites have been used for strengthening concrete structures since early 1990s. More recently, FRP has been used for retrofitting concrete structures for high energy events such as impact and blast. Debonding at the FRP-to-concrete interface is one of the predominant failure modes for both static and dynamic loading. Although extensive research has been conducted on the static bond behaviour, the bond-slip mechanics under high strain rates is not well understood yet. This thesis is mainly concerned with the FRP-to-concrete bond behaviour under dynamic loading. Because debonding mostly occurs in the concrete adjacent to the FRP, the behaviour of concrete is of crucial importance for the FRP-to-concrete bond behaviour. The early emphasis of this thesis is thus on the meso-scale concrete modelling of concrete with appropriate consideration of static and dynamic properties. Issues related to FE modelling of tensile and compressive localization of concrete are first investigated in detail under static condition using the K&C concrete damage model in LS-DYNA. It is discovered for the first time that dilation of concrete plays an important role in the FRP-to-concrete bond behaviour. This has led to the development of a model relating the shear dilation factor to the concrete strength based on the modelling of a large number of static FRP-to-concrete shear tests, forming the basis for dynamic modelling. Concrete dynamic increasing factor (DIF) has been a subject of extensive investigation and debate for many years, but it is for the first time discovered in this study that mesh objectivity cannot be achieved in meso-scale modelling of concrete under high strain rate deformation. This has led to the development of a mesh and strain rate dependent concrete tension DIF model. This DIF model shall have wide applications in meso-scale modelling of concrete, not limited to the topic in this thesis. Based on a detailed numerical investigation of the FRP-to-concrete bond shear test under different loading rates, taking on the above issues into careful consideration, a slip rate dependent FRP-to-concrete dynamic bond-slip model is finally proposed for the first time. The FE predictions deploring this proposed bond-slip model are compaed with test results of a set of FRP-to-concrete bonded specimens under impact loading, and a FRP plated slab under blast loading, validating the model.

Approved for public release, distribution is unlimited / In this thesis, SiN films grown on Si substrates were characterized using Fourier Transform Infrared (FTIR) spectroscopy. The stress in SiN films can be used to enhance of mobility of electrons and holes which increases the performance of metal-oxide-semiconductor (MOS) transistors. The samples used in this study were prepared by Applied Materials using chemical vapor deposition (CVD) technique with different growth parameters. The stress of the samples varied from 1.3 GPa compressive to 1 GPa tensile depending on the growth conditions employed. The FTIR measurement showed three distinct absorption peaks associated with Si-N, Si-H and N-H vibrational modes. The hydrogen was unintentionally incorporated into the SiN film during the CVD process due to its use as the carrier gas for the precursors. It was found from the FTIR data that the area under Si-H and N-H peaks (amount of bonds) varies in opposite directions when the film stress changes from compressive to tensile. In addition, the peak position of the Si-H absorption shifted to higher energy while the opposite was true for N-H as the stress changes from compressive to tensile. The strength and the position of the Si-N absorption peak were found to be relatively insensitive to the stress of the film. This indicates that the amount of Si-H and N-H bonds in the film is responsible for controlling the stress of the film. The use of quantum calculation of SiN molecules with different amount of Si-H and N-H bonds was used toward understanding the experimental absorption spectra. / Lieutenant, Mexican Navy

Intensive training is associated with hemodynamic changes that typically induce an enlargement of cardiac chamber. Despite LA dilatation in athletes has been interpreted as a benign adaptation, little evidence is available. The aim of this thesis is to demonstrate that LA size changes in response to alterations in loading conditions and to analyse atrial myocardial function in athletes through the application of novel echocardiographic techniques. We found that top-level athletes exhibit a dynamic morphological and functional LA remodelling, induced by training, with an increase in reservoir and conduit volumes, but stable active volume. Training causes an increase in biatrial volumes which is accompanied by normal filling pressures and stiffness. These changes in atrial morphology are not associated with respective electrical changes. Extending the evidence from adult athletes to children, we found that training-induced atrial remodelling can occur in the early phases of the sports career and is associated with a preserved biatrial function. Finally, in a meta-analysis study of the available evidence we demonstrated that atrial function and size are not affected by aging. In conclusions, athlete’s heart is characterized by a physiological biatrial enlargement. This adaptation occurs in close association with LV cavity enlargement, is dynamic and reversible. This increase in biatrial size is not intrinsically an expression of atrial dysfunction. Indeed, in athletes the atria are characterized by a preserved reservoir function, normal myocardial stiffness, and dynamic changes in response to different loading conditions.

New insight into the temperature dependent evolution of internal strain in the austenite phase during the martensitic phase transformation in NiTi shape memory alloys is provided via classical molecular dynamics simulations that employ well-established interatomic potentials for NiTi. It is shown, for the first time, that the developed strain tensor in the austenite phase is tetragonal in nature, with exponential temperature-dependence. Equally importantly, it is found that the developed internal strain (parallel to the habit plane) in the austenite varies linearly with the evolving martensite phase fraction. Interestingly, the Richard’s equation is found to describe the temperature dependence of the martensite phase fraction as well as the internal strain components parallel to the habit plane in the austenite phase. An analysis of the temperature dependent phonon dispersion of strained austenite revealed the competition between phonon softening of the TA2 branch and internal strain that leads to stabilization of the austenite phase in the two phase regime.

Structural health monitoring (SHM) is an emerging field in civil engineering in recent years. The main objectives of the SHM are to identify structural integrity issues at early stage and improve the structural safety through measuring and analyzing structural behaviors. Sensing systems for SHM can be used to identify applied vehicle loads for bridge structures. Bridge weigh-in-motion (BWIM) is one type of such vehicle load identification. As a tool to monitor the vehicle weight moving on the bridges, BWIM uses the structural responses induced by moving vehicle on the bridge to back-calculate vehicle information. In this thesis, optimized BWIM systems using multimetric measurements will be investigated. In Chapter 1, the concept and background of BWIM systems will be introduced. The objective of this research will be also demonstrated in this chapter. Chapter 2 is the literature review section. In Chapter 3, the finite element bridge model adopted for this study will be described. In this section, the moving-load time history analysis, sectional properties for bridge members, and other structural parameters of bridge model will be introduced. The methodology of BWIM systems used in this study will be demonstrated in Chapter 4. In Chapter 5, optimized sensor locations for BWIM using normal and shear strain measurements and acceleration measurement will be discussed for the case without measurement noise. In Chapter 6, sensor location optimization for the case considering measurement noises will be investigated. A new acceleration-based BWIM method is proposed in this section. Non-drift displacement reconstruction technique using acceleration measurement and FIR filtering is applied for BWIM. Finally, Chapter 7 is the conclusion part of this thesis.