More and more, advanced polymer and composite materials are being applied in engineering situations where a high resistance to loading at high rates of strain, such as by impact or blast deformation, are a vital requirement. Specific examples exist in the fields of defence and sport research and development for personal, and in the case of the former, vehicular, protection. There are obvious advantages to the use of polymer materials for these applications in augmenting the more widely used metals and ceramics, most notably the evident reduction in weight, and it is believed that with suitable nano-reinforcement these materials may exhibit improved combat survivability. The current study concerns the effect that nano-reinforcements in the form of Carbon Black, Titanium Dioxide, Exfoliated Hectorite Nanoclay and Carbon Nanotubes; have upon the high strain rate mechanical properties of structural variants of Polyethylene (Linear Low Density Polyethylene, LLDPE; High Density Polyethylene, HDPE; Ultra-High Molecular Weight Polyethylene, UHMWPE) and blends of UHMWPE and HDPE. The testing samples were manufactured using a novel process developed in the Loughborough University Materials Department, which has produced well-dispersed specimens. The formed nanocomposite samples were studied using an in-house four-bar Split Hopkinson Pressure Bar (SHPB) system for high strain rate performance, instrumented dropweight for intermediate strain rates and a conventional commercial Hounsfield H50KM universal testing machine for quasi-static strain rate compressive tests. The experimental results recorded for un-reinforced materials are used as a reference to allow comparative analysis of any effect the nano-reinforcements or the blending process have upon the structure, performance and properties of the composite material. From the mechanical testing, it was seen that the stress-strain behaviour of Polyethylene is highly strain-rate-dependent, as plots of the average representative yield stress as a function of strain rate show a bilinear relationship when plotted on a logarithmic strain rate scale, with the gradient of the curve rising sharply at around 103s-1. Concerning the addition of the nanofiller materials, it was seen that there was an increase in the flow and yield stresses and the energy absorption characteristics of the resulting composite with the magnitude dependent upon whether it was a pure or blended polymer that was reinforced. Of the aforementioned fillers it was seen that the addition of Carbon Nanotubes in the small concentrations studied resulted in the greatest increase in properties compared to the pure polymers, closely followed by the Carbon Black fillers. Also of note, the un-reinforced blended samples showed significant increases in flow stress, yield stress and energy absorption when compared to the constituent UHMWPE and HDPE polymers. Additionally, a complete set of Differential Scanning Calorimetry and density measurements were made before testing to assess any changes in the properties after reinforcement or blending, and to help in the interpretation of the results from the different mechanical tests.

For microelectronics used in the low-temperature applications, the understanding of their reliability and performance has become an important research subject characterised as electronics to serve under the severe or extreme service conditions. Along with the impact from the increased miniaturization of devices, the various properties and the relevant thermo-mechanical response of the interconnection materials to temperature excursion at micro-scale become a critical factor which can affect the reliable performance of microelectronics in various applications. Pure indium as an excellent interconnection material has been used in pixellated detector systems, which are required to be functional at cryogenic temperatures. This thesis presents an extensive investigation into the thermo-mechanical properties of indium joints as a function of microstructure, strain (loading histories-dependent) and temperature (service condition-sensitive), specifically in the areas as follows: (i) the interfacial reactions and evolution between indium and substrate during the reflow process (liquid-solid) and thermal aging (solid-solid) stages by taking low-temperature cycling into account; (ii) determination of the effects of joint thickness and the types of substrate (e.g. Cu or Ni) on the mechanical properties of indium joints, and the stress- and temperature-dependent creep behaviour of indium joints; (iii) the establishment of a constitutive relationship for indium interconnects under a wide range of homologous temperature changes that was subsequently implemented into an FE model to allow the analysis of the evolution of thermally-induced stresses and strains associated with a hybrid pixel detector.

Carbon Capture and Storage (CCS) is recognised as having a significant role to play in tackling climate change and reducing carbon dioxide (CO2) emissions. In CCS schemes, CO2 is captured from anthropogenic sources, and transported to suitable sites either for EOR (Enhanced Oil Recovery) or storage. The transport of such huge amount of CO2 causes new challenges. The main concern is in the difference between natural gas and CO2 transportation pipelines. CO2 phase behaviour during decompression, existence of different impurities and very high operating pressure are some of the new challenges for pipeline designer and operators. This PhD study has taken a systematic approach to understand the mechanics involved in the fracture of pipes containing high pressure flue-gas CO2. The work involved the development of a novel weight function stress intensity factor solution that can be used with complex stress fields induced by residual and/or thermal stresses in addition to applied pressure. In addition, the thesis reports a substantial experimented test programme which involved low temperature fracture toughness tests linked to a detailed finite element based stress analysis. Overall, the thesis presents an integrated engineering criticality means to assess the suitability or otherwise of a pipeline system to transport high pressure flue-gas CO2.

Fibre reinforced polymer (FRP) composites have been used for strengthening concrete structures since early 1990s. More recently, FRP has been used for retrofitting concrete structures for high energy events such as impact and blast. Debonding at the FRP-to-concrete interface is one of the predominant failure modes for both static and dynamic loading. Although extensive research has been conducted on the static bond behaviour, the bond-slip mechanics under high strain rates is not well understood yet. This thesis is mainly concerned with the FRP-to-concrete bond behaviour under dynamic loading. Because debonding mostly occurs in the concrete adjacent to the FRP, the behaviour of concrete is of crucial importance for the FRP-to-concrete bond behaviour. The early emphasis of this thesis is thus on the meso-scale concrete modelling of concrete with appropriate consideration of static and dynamic properties. Issues related to FE modelling of tensile and compressive localization of concrete are first investigated in detail under static condition using the K&C concrete damage model in LS-DYNA. It is discovered for the first time that dilation of concrete plays an important role in the FRP-to-concrete bond behaviour. This has led to the development of a model relating the shear dilation factor to the concrete strength based on the modelling of a large number of static FRP-to-concrete shear tests, forming the basis for dynamic modelling. Concrete dynamic increasing factor (DIF) has been a subject of extensive investigation and debate for many years, but it is for the first time discovered in this study that mesh objectivity cannot be achieved in meso-scale modelling of concrete under high strain rate deformation. This has led to the development of a mesh and strain rate dependent concrete tension DIF model. This DIF model shall have wide applications in meso-scale modelling of concrete, not limited to the topic in this thesis. Based on a detailed numerical investigation of the FRP-to-concrete bond shear test under different loading rates, taking on the above issues into careful consideration, a slip rate dependent FRP-to-concrete dynamic bond-slip model is finally proposed for the first time. The FE predictions deploring this proposed bond-slip model are compaed with test results of a set of FRP-to-concrete bonded specimens under impact loading, and a FRP plated slab under blast loading, validating the model.

Approved for public release, distribution is unlimited / In this thesis, SiN films grown on Si substrates were characterized using Fourier Transform Infrared (FTIR) spectroscopy. The stress in SiN films can be used to enhance of mobility of electrons and holes which increases the performance of metal-oxide-semiconductor (MOS) transistors. The samples used in this study were prepared by Applied Materials using chemical vapor deposition (CVD) technique with different growth parameters. The stress of the samples varied from 1.3 GPa compressive to 1 GPa tensile depending on the growth conditions employed. The FTIR measurement showed three distinct absorption peaks associated with Si-N, Si-H and N-H vibrational modes. The hydrogen was unintentionally incorporated into the SiN film during the CVD process due to its use as the carrier gas for the precursors. It was found from the FTIR data that the area under Si-H and N-H peaks (amount of bonds) varies in opposite directions when the film stress changes from compressive to tensile. In addition, the peak position of the Si-H absorption shifted to higher energy while the opposite was true for N-H as the stress changes from compressive to tensile. The strength and the position of the Si-N absorption peak were found to be relatively insensitive to the stress of the film. This indicates that the amount of Si-H and N-H bonds in the film is responsible for controlling the stress of the film. The use of quantum calculation of SiN molecules with different amount of Si-H and N-H bonds was used toward understanding the experimental absorption spectra. / Lieutenant, Mexican Navy

Intensive training is associated with hemodynamic changes that typically induce an enlargement of cardiac chamber. Despite LA dilatation in athletes has been interpreted as a benign adaptation, little evidence is available. The aim of this thesis is to demonstrate that LA size changes in response to alterations in loading conditions and to analyse atrial myocardial function in athletes through the application of novel echocardiographic techniques. We found that top-level athletes exhibit a dynamic morphological and functional LA remodelling, induced by training, with an increase in reservoir and conduit volumes, but stable active volume. Training causes an increase in biatrial volumes which is accompanied by normal filling pressures and stiffness. These changes in atrial morphology are not associated with respective electrical changes. Extending the evidence from adult athletes to children, we found that training-induced atrial remodelling can occur in the early phases of the sports career and is associated with a preserved biatrial function. Finally, in a meta-analysis study of the available evidence we demonstrated that atrial function and size are not affected by aging. In conclusions, athlete’s heart is characterized by a physiological biatrial enlargement. This adaptation occurs in close association with LV cavity enlargement, is dynamic and reversible. This increase in biatrial size is not intrinsically an expression of atrial dysfunction. Indeed, in athletes the atria are characterized by a preserved reservoir function, normal myocardial stiffness, and dynamic changes in response to different loading conditions.

New insight into the temperature dependent evolution of internal strain in the austenite phase during the martensitic phase transformation in NiTi shape memory alloys is provided via classical molecular dynamics simulations that employ well-established interatomic potentials for NiTi. It is shown, for the first time, that the developed strain tensor in the austenite phase is tetragonal in nature, with exponential temperature-dependence. Equally importantly, it is found that the developed internal strain (parallel to the habit plane) in the austenite varies linearly with the evolving martensite phase fraction. Interestingly, the Richard’s equation is found to describe the temperature dependence of the martensite phase fraction as well as the internal strain components parallel to the habit plane in the austenite phase. An analysis of the temperature dependent phonon dispersion of strained austenite revealed the competition between phonon softening of the TA2 branch and internal strain that leads to stabilization of the austenite phase in the two phase regime.

Structural health monitoring (SHM) is an emerging field in civil engineering in recent years. The main objectives of the SHM are to identify structural integrity issues at early stage and improve the structural safety through measuring and analyzing structural behaviors. Sensing systems for SHM can be used to identify applied vehicle loads for bridge structures. Bridge weigh-in-motion (BWIM) is one type of such vehicle load identification. As a tool to monitor the vehicle weight moving on the bridges, BWIM uses the structural responses induced by moving vehicle on the bridge to back-calculate vehicle information. In this thesis, optimized BWIM systems using multimetric measurements will be investigated. In Chapter 1, the concept and background of BWIM systems will be introduced. The objective of this research will be also demonstrated in this chapter. Chapter 2 is the literature review section. In Chapter 3, the finite element bridge model adopted for this study will be described. In this section, the moving-load time history analysis, sectional properties for bridge members, and other structural parameters of bridge model will be introduced. The methodology of BWIM systems used in this study will be demonstrated in Chapter 4. In Chapter 5, optimized sensor locations for BWIM using normal and shear strain measurements and acceleration measurement will be discussed for the case without measurement noise. In Chapter 6, sensor location optimization for the case considering measurement noises will be investigated. A new acceleration-based BWIM method is proposed in this section. Non-drift displacement reconstruction technique using acceleration measurement and FIR filtering is applied for BWIM. Finally, Chapter 7 is the conclusion part of this thesis.

In this thesis, first-principles calculations based on density functional theory have been employed to investigate metal hydrogen interaction in transition, p-block and rare earth metals. Furthermore, the accuracy of the stochastic quenching method was tested in describing the structure of amorphous Fe(1-x)Zrx. The investigated systems of transition metal hydrides are V-H and ScZr(CoNi)2-H. For V-H, the main focus of the studies is the effect that strain has on the potential energy landscape which governs the metal hydrogen interactions. The investigation has focused on how the properties of hydrogen occupancy in the interstitial sites changes with strain and also how the hydrogen atoms themselves exert strain on the vanadium structure to lower the energy. Results on diffusion, induced strain and zero-point energy are presented which all reveal the considerable difference between tetrahedral and octahedral site occupancy. Diffusion was studied by employing ab initio molecular dynamics simulations to obtain diffusion coefficients and to map the movement of the hydrogen atom. A description of hydrogen in vanadium is provided from a fundamental basis that is expected to be applicable to any lattice gas system. For ScZr(CoNi)2-H, the difference of hydrogen occupancy in various interstitial sites and the hydrogen-induced strain was also investigated through calculations of the change in total volume as a function of hydrogen concentration. The fundamental properties of metal hydrogen bonding were investigated by studying the Zintl phase hydrides that are constituted of the electropositive metal of Nd or Gd and the electronegative metal Ga. Mixing metals of very different electronegativity gives rise to an intricate potential energy landscape in which the incorporation of hydrogen will have a big effect on both the electronic and atomic structure. From the theoretical side of the investigation, structural parameters are presented along with the density of states and Bader charge analysis to describe the hydrogen induced changes to the atomic and electronic structures. Finally, the accuracy of the stochastic quenching method in describing amorphous Fe(1-x)Zrx was evaluated by comparing simulated and measured EXAFS spectra. Once the structural agreement had been established the simulated structures were characterized through radial distribution functions and an analysis of the short-range order from Voronoi tessellation. The structural changes with respect to the composition parameter x were also evaluated.

Previous research has provided a helpful, albeit narrow, understanding of task interruptions as related to outcomes such as wellness and performance (e.g., Eyrolle & Cellier, 2000). Building on this foundation by viewing interruptions through the broader theoretical context of the theory of mental workload, this study sought to explain the cognitive processes underlying the negative performance effects often associated with interruptions and to apply an intervention aimed at mitigating these effects. Specifically, mindfulness has emerged as a promising method for reducing the cognitive burden of interruptions. This study examined the effects of intrusions (a type of interruption) on psychological strain and performance through perceived mental workload. Although perceived mental workload did predict strain outcomes, the overall mediation models failed to reach significance. Results also failed to support the hypothesized effect of state mindfulness as a potential moderator. A set of post hoc analyses, however, found that intrusion perceptions acted as a mediator between intrusion condition and psychological strain outcomes. Further, this mediation was moderated by state mindfulness, which in turn was moderated by the intrusion time. Specifically, the indirect effect of intrusion condition on strain outcomes was such that individuals experienced more strain if they received an intrusion compared to those who were not given an intrusion, unless they completed the form quickly and were also low on state mindfulness, in which case there was no difference in strain outcomes based on whether they experienced an intrusion. Together, these results suggest that intrusion perceptions play key roles in strain outcomes, and that moderators of these relationships should be further explored.