Burkina Faso is one of the poorest countries in the world. This landlocked country in the west has an extremely warm climate. Temperatures over 45°C are not uncommon and there is an almost constant need to keep the buildings cool to maintain a temperate indoor climate. Air-conditioning is an option to maintain the temperature but it overloads the power grid and only a few people can afford it. This thesis examines, through laboratory experiments, the thermal and mechanical properties that can be obtained by vibrating clayey soil and mixing it with water, lime or cement and organic fiber (Bissap). The report also examines different building projects utilizing local materials, both of a traditional and more modern nature.Energy required to produce building elements of soil is negligible compared to that of concrete and steel. Soil can be used in constructing houses but it is sensitive to water.The insulation is inadequate for a passive house so an extra layer of insulating material is required.The experiments performed during this project were inconclusive so it is impossible, from the results in this paper, to say if vibration is a good method for forming a building material of soil. The high water content needed, is however a major problem, shrinkage was about 20% and cracks were hard to avoid. Further investigations into the subject is necessary. / Burkina Faso är ett av de fattigaste länderna i världen. Som ett kustlöst land beläget i Västafrika har det ett extremt varmt klimat. Temperaturer över 45°C är inte ovanligt och det är ett nästan konstant behov av att kyla byggnader för att behålla ett behagligt inneklimat.   Idag byggs det två typer av byggnader i Burkina Faso; de traditionella lerhusen och de mer moderna husen med väggar av cementstenar och plåttak. Cementväggarna har ett U-värde på 3W/m2K och tillsammans med plåttaket så bildar det ett undermåligt klimatskal utan möjligheter att skydda mot hettan. Det leder idag till endera ett obehagligt varmt inneklimat eller en hög och kostsam energianvändning av luftkonditionering. Överbelastningen på elnätet på grund av luftkonditionering är påtaglig under den varmaste säsongen med frekventa strömavbrott till följd.   Denna rapport undersöker via laboratorieexperiment vilka termiska och mekaniska egenskaper man kan erhålla genom att vibrera lerjord och blanda med vatten, organiska fibrer samt kalk och/eller cement. Litteraturstudier och fältbesök i Burkina Faso har gjorts för att undersöka och förstå vilka svårigheter som kan uppkomma genom att bygga med lera. Rapporten tar även upp konkreta exempel på byggnader i Burkina Faso gjorda av lokala material, historiska såväl som moderna projekt.   Lerjord behöver extremt lite energitillförsel för att bilda ett byggmaterial och den negativa miljöpåverkan är försumbar jämfört med betong och stål. Det kan användas för att bygga energisnåla hus men det är känsligt mot vatten, vilket måste beaktas noga under projekteringen. Värmeledningsförmågan är för hög för att vara tillräcklig som isolering för att erhålla ett inneklimat enligt dagens standard, utan tillförsel av energi, så någon form av extra isolering krävs.   Experimenten som gjordes gav inte tillräckligt exakta resultat för att visa om vibrering är en bra metod att göra byggmaterial eller inte. Den höga vattenhalten som krävs för vibrering är ett stort problem. Krympningen var ungefär 20 % och sprickor var svåra att undvika. Vidare studier på området rekommenderas.

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La spectroscopie du proton issu de la décroissance du neutron donne un accès complémentaire à lambda (rapport des constantes de couplage faibles gA/gV) et permet la recherche de physique au-delà du Modèle Standard. Au sein des expériences, les protons de basse-énergie (E<751.4 eV) sont guidés et sélectionnés grâce à des champs électromagnétiques. La connaissance précise du potentiel électrostatique est primordiale car celui-ci peut biaiser la sélection des protons. Il faut une précision de quelques mV dans les expériences de spectroscopie du proton aSPECT et PERC pour leur permettre d’atteindre la précision de mesure désirée. Comme les conditions expérimentales impactent le champ (effets de température sur la position des électrodes et leur fonction de travail, condition de surface, pièges qui se chargent etc.), il est nécessaire de pouvoir effectuer la mesure du champ électrostatique in-situ. D’autres effets systématiques sont reliés à la détection de protons: résolution du détecteur, homogénéité, probabilité de rétrodiffusion etc. in-situ.Les objectifs de ce projet sont de créer des sources de calibration pour des mesures électrostatiques in-situ et la caractérisation de détecteurs de protons et de construire une chambre d’essai dédiée à la caractérisation et l’optimisation des sources.Pour les mesures électrostatiques, la modération des positrons a été identifiée comme prometteuse. Ce processus crée un faisceau de particules chargées positivement avec une largeur spectrale très faible (FWHM de quelques dizaines de meV) et avec une distribution angulaire bien définie. Un tel faisceau pourrait permettre de comparer, au sein du spectromètre, les différences de potentiels entre des électrodes.Pour la caractérisation des détecteurs, les sources de protons disponibles sur le marché sont difficiles à coupler aux forts champs magnétiques et induisent souvent une détérioration de la qualité du vide dans les expériences, rendant ardue l’utilisation d’un détecteur sous haute tension (entre -15 et -30 kV). La Désorption Stimulée par Electrons (ESD) de l’hydrogène adsorbé sur la surface d’un cristal s’avère posséder les qualités requises: une distribution en énergie piquée et bien définie et une compatibilité avec l’ultravide.Le spectromètre aSPECTino a été créé en tant que système de test. C’est un filtre MAC-E qui utilise des champs EM pour guider et sélectionner les particules chargées de basse énergie avant de les détecter à l’aide d’un détecteur sous haute tension pour accélérer les particules sélectionnées. Dans le spectromètre règne un champ magnétique entre 3.5 et 16 mT qui est suffisant pour confiner les positrons de basse-énergie. Les protons de basse-énergie avec un faible moment radial peuvent aussi être guidés vers le détecteur.CALIPSO, qui signifie CALIbration Positron/proton SOurce, est une source de calibration deux en un : elle peut fournir indépendamment des positrons et des protons et est basée autour d’un cristal de tungstène (110). Pour la source de positrons ce cristal est couplé à une source de positron 22Na. Il sert alors de modérateur et réémet une fraction des positrons primaires issus de la source 22Na avec une faible énergie et une distribution angulaire et spectrale étroite. Dans la configuration proton le même cristal est utilisé en tant que substrat pour l’adsortion d’hydrogène. L’ESD est induit par les électrons émis par une source thermoionique et frappants le cristal de tungstène.Cette thèse présente les processus physiques utilisés pour créer les faisceaux de positrons et de protons de basse-énergie de CALIPSO ainsi que la conception et le développement du spectromètre aSPECTino et de la source CALIPSO. Elle présente les premiers résultats expérimentaux de la caractérisation préliminaire d’aSPECTino et de CALIPSO. Les performances attendues de CALIPSO pour ses deux configurations et pour la sensibilité de comparaison des potentiels d’électrodes sont dérivés et démontrés à l’aide de simulations. / Proton spectroscopy in neutron beta decay gives a complementary access to $lambda$ (ratio of the weak coupling constants gA/gV and enables new searches for physics beyond the Standard Model. In experiment, low-energy protons (E< 751.4 eV) are usually guided and selected using electromagnetic fields. Precise knowledge of the electrostatic potentials is mandatory as it can drastically bias proton selection. For instance, electrostatic potentials have to be known with an accuracy of a few mV in the proton spectroscopy instruments aSPECT and PERC in order to reach their aspired precision. As experimental conditions can directly impact the field (temperature effects on electrode position and work function, surface conditions, charging traps, etc.), it is mandatory that electrostatic measurements are performed in-situ. Further systematic effects are related to proton detection. In addition to prior off-line detector characterization, it is important to verify detector resolution, homogeneity, backscattering probability etc. in-situ. The protons from neutron decay itself are not suitable for this purpose because of their broad energy distribution and insufficient localization.The goals of this project were to create calibration sources for in-situ electrostatic measurements and proton detector characterizations and to build a dedicated test setup to characterize and optimize the sources.For electrostatic measurements, the process of positron moderation was identified as most promising. Positron moderation creates a beam of positively charged particles with a very narrow energy spread (FWHM of a few tens of meV) and with a well-defined emission angular distribution. Such a beam would allow to directly compare, inside the spectrometer, potential differences between different electrodes.For detector characterization, available commercial proton sources are difficult to couple to high magnetic fields and often induce a deterioration of the vacuum quality in experiments, making it complicated to use detection systems at high voltage (-15 to -30 kV). Electron Stimulated Desorption (ESD) of hydrogen adsorbed on a crystal surface was found to provide the desired properties: a sharp and well-defined energy distribution of the created proton beam and compatibility with ultrahigh vacuum.The aSPECTino spectrometer was built as test setup. It is a MAC-E filter which uses electro-magnetic fields to guide and select low-energy charged particles before detecting them in a solid-state detector. The detector is set at high voltage to post-accelerate the selected particles. The resistive coils of the spectrometer produce a magnetic field between 3.5 and 16 mT which is sufficient to confine low-energy positrons. Low-energy protons with a small radial momentum component can also be effectively guided onto the detector.CALIPSO, which stands for CALIbration Positron/proton SOurce, is a two-in-one calibration source: one apparatus is designed to provide, not at the same time, both positrons and protons. Its core is a tungsten (110) crystal. In the case of positrons the tungsten crystal is coupled to a 22Na positron source. The crystal serves as positron moderator and re-emits a fraction of the primary positrons from the Na source, with low energy and a small angular and energy spread. In the proton configuration the same crystal is used as substrate for adsorbed hydrogen. ESD is induced by electrons emitted from a hot cathode and hitting the tungsten crystal.This thesis introduces the physical processes used to create the low-energy positron and proton beams of CALIPSO as well as the design and the development of both the aSPECTino spectrometer and the CALIPSO source. It presents first experimental results of the preliminary characterizations of aSPECTino and CALIPSO. The expected performances of CALIPSO in both configurations and the sensitivity for comparisons of electrode potentials are derived and demonstrated by simulations.

L’espace est un milieu hostile pour les équipements embarqués à bord des satellites. Les importants flux d’électrons qui les bombardent continuellement peuvent pénétrer à l’intérieur de leurs composants électroniques et engendrer des dysfonctionnements. Leur prise en compte nécessite des outils numériques 3D très performants, tels que des codes de transport d’électrons utilisant la méthode statistique de Monte-Carlo, valides jusqu’à quelques eV. Dans ce contexte, l’ONERA a développé, en partenariat avec le CNES, le code OSMOSEE pour l’aluminium. De son côté, le CEA a développé, pour le silicium, le module basse énergie MicroElec dans le code GEANT4. L’objectif de cette thèse, dans un effort commun entre l’ONERA, le CNES et le CEA, est d’étendre ces codes à différents matériaux. Pour ce faire, nous avons choisi d’utiliser le modèle des fonctions diélectriques, qui permet de modéliser le transport des électrons à basse énergie dans les métaux, les semi-conducteurs et les isolants. La validation des codes par des mesures du dispositif DEESSE de l’ONERA, pour l’aluminium, l’argent et le silicium, nous a permis d’obtenir une meilleure compréhension du transport des électrons à basse énergie, et par la suite, d’étudier l’effet de la rugosité de la surface. La rugosité, qui peut avoir un impact important sur le nombre d’électrons émis par les matériaux, n’est habituellement pas prise en compte dans les codes de transport, qui ne simulent que des matériaux idéalement plats. En ce sens, les résultats de ces travaux de thèse offrent des perspectives intéressantes pour les applications spatiales. / Space is a hostile environment for embedded electronic devices on board satellites. The high fluxes of energetic electrons that impact these satellites may continuously penetrate inside their electronic components and cause malfunctions. Taking into account the effects of these particles requires high-performant 3D numerical tools, such as codes dedicated to electrons transport using the Monte Carlo statistical method, valid down to a few eV. In this context, ONERA has developed, in collaboration with CNES, the code OSMOSEE for aluminum. For its part, CEA has developed for silicon the low-energy electron module MicroElec for the code GEANT4. The aim of this thesis, in a collaborative effort between ONERA, CNES and CEA, is to extend those two codes to different materials. To describe the interactions between electrons, we chose to use the dielectric function formalism that enables to overcome of the disparity of electronic band structures in solids, which play a preponderant role at low energy. From the validation of the codes, for aluminum, silver and silicon, by comparison with measurements from the experimental set-up DEESSE at ONERA, we obtained a better understanding of the transport of low energy electrons in solids. This result enables us to study the effect of the surface roughness. This parameter, which may have a significant impact on the electron emission yield, is not usually taken into account in Monte Carlo transport codes, which only simulate ideally flat materials. In this sense, the results of this thesis offer interesting perspectives for space applications.

The purpose of this thesis was to investigate the feasibility of a wireless architectural approach for intra-vehicle communications. The current wired architecture was compared to a wireless approach based on three prominent wireless protocols, namely Bluetooth Low-Energy, Ultra Wide-Band, and 60 GHz Millimeter wave technology. The evaluation was focused on their potential use within the intra-vehicle domain, and judged by characterizing properties such as frequency, bandwidth utilization, and power efficiency. A theoretical study targeting the propagating behavior of electromagnetic waves was also involved. In particular, wireless behavior has been investigated both in general aspects as well as specifically aimed towards the intra-vehicle application. The theoretical study was then concluded and presented with a course of action regarding wireless connectivity. Beneficial design considerations, potentials and challenges were highlighted together with a discussion on the feasibility of a wireless architectural approach. Suggestions for future work and research have been given, which include further expansion of targeted protocols, alleviating the restricted security aspects, and extend the physical aspects onto more software based approaches.

Les propriétés physiques intriguantes présentées dans certains oxydes complexes de métaux de transition sont attractives non seulement pour la recherche fondamentale, mais pour les applications, par exemple, la supraconductivité, la magnétorésistance colossale, la multiferroïcité. La forte corrélation électronique est à l'origine de ces comportements.La thèse contribue à la fois à l'effort expérimental de détermination de la structure électronique des systèmes fortement corrélés et à l'analyse critique des modèles théoriques les décrivant. Expérimentalement, le travail a porté sur la diffusion inélastique résonante des rayons X pour déterminer les excitations électroniques de basse énergie de l'état fondamental (excitations d-d, transfert de charge, etc.). Les expériences ont été effectuées sur la ligne de lumière SEXTANTS du synchrotron SOLEIL (France), en utilisant le spectromètre AERHA avec un haut pouvoir résolvant. L'analyse des résulats a été focalisée sur la détermination du champ cristallin des métaux de transition en jeu en utilisant la théorie des multiplets avec champ cristallin.Deux systèmes ont été étudiés: les composés multiferroïques RMnO3 (R = Tb, Dy) et un isolant de Mott ferromagnétique Lu2V2O7. / The intriguing physical properties presented in some complex oxides of transition metals draw attention not only in fundamental research but also in applications, for instance, superconductivity, colossal magnetoresistance, multiferroicity. The strong electronic correlation is at the origin of these behaviours. The thesis is a contribution to both the experimental effort to determine the electronic structure of strongly correlated systems and the critical assesment of the theoretical models describing them. Experimentally, the work of is devoted to the investigations of the low-energy excitations (d-d excitations, charge transfer, …) of the ground state by resonant inelastic x-ray scattering. The experiments have been performed on the SEXTANTS beamline of SOLEIL synchrotron (France) using the high resolving power AERHA spectrometer. The analysis of the data has been focused on the determination of the the crystal field of the transition metal involved using the crystal field multiplets theory.Two systems have been investigated: the multiferroics RMnO3 (R = Tb, Dy) and the ferromagnetic Mott insulator Lu2V2O7.

Este trabalho apresenta o primeiro estudo dos estados aniônicos de baixa energia da para-Benzoquinona (p-BQ) por meio de cálculos de espalhamento elástico de elétrons pela molécula neutra. Foi utilizado o método multicanal de Schwinger implementado com pseudopotenciais de Bachelet, Hamann e Schlüter, na aproximação de núcleos fixos, e nas aproximações estático-troca e estático-troca mais polarização. As seções de choque integrais foram calculadas em duas geometrias do alvo, otimizadas para o estado fundamental da molécula neutra e do ânion. Os estados aniônicos encontrados foram aracterizados e comparados com resultados experimentais, realizados com a técnica de espectroscopia de transferência eletrônica (ETS). Três estados * foram observados, sendo um ligado e dois metaestáveis, em acordo com os experimentos. Uma ressonância de Feshbach foi encontrada nos cálculos, tal qual é observada experimentalmente e sugerida em diversos estudos teóricos de estado ligado. Acredita-se que a aproximação utilizada para descrever estados excitados do alvo poderá ser reconsiderada, em que é sugerida uma proximação mais sofisticada, a ser utilizada em cálculos futuros. Com este estudo, é possível uma melhor compreensão dos resultados experimentais ETS, assim como é permitida uma interpretação de estudos teóricos sobre os estados aniônicos da p-BQ. Ademais, este trabalho possibilita próximos estudos de espalhamento envolvendo quinonas mais complexas. / This work present the first study of low-energy anionic states in para-benzoquinone (p-BQ) by electron scattering calculations. The elastic scattering calculations were done in the fixed-nuclei approximation, with the Schwinger multichannel method implemented with pseudopotentials of Bachelet, Hamann and Schlüter, in the static-exchange and in the static-exchange plus polarization approximations. The integral cross sections were performed in two target geometries optimized for the neutral and anion ground states. The anionic states found were characterized and compared with experimental results obtained by electron transfer spectroscopy (ETS). Three * states were observed, a bound state and two metastable, in good agreement with experimental results. A Feshbach resonance was found in calculations, also it is observed experimentally and it was suggested in several theoretical studies of bound state. It is believed that the approach used to describe the target excited states can be reconsidered, as it is suggested a more sophisticated approach to be used in future calculations. With this study, a better understanding of experimental results ETS is possible, as it allowed an interpretation of theoretical studies of the anionic states of p-BQ. Moreover, this work enables further scattering studies involving more complex quinones.

Orientador: Richard Landers / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Fisica Gleb Wataghin / Made available in DSpace on 2018-08-09T10:50:19Z (GMT). No. of bitstreams: 1 Pancotti_Alexandre_M.pdf: 2977317 bytes, checksum: 914d690fda86677fcc9c894c6f408409 (MD5) Previous issue date: 2005 / Resumo: Nesse trabalho nos propomos a estudar a estrutura eletrônica e geométrica de ligas de superfície à partir de filmes ultra finos, da ordem de monocamada atômica , crescidos por MBE sobre substratos monocristalinos. Os filmes finos foram crescidos in situ e analizados por XPS (X-Ray Photoelectron Spectroscopy), PED (Photoelectron Diffraction), LEED (Low Energy Electron Diffraction) e UPS (Ultra Violet Photoelectron Spectroscopy). As ligas de superfície estudas foram InPd, SnPd e SbPd sempre sobre um substrato de Pd(111). Os resultados das medidas PED dos sistemas InPd e SnPd foram interpretadas usando programas tipo MSCD[1]. Foi mostrado que Sn e In em baixa cobertura formam uma estrutura (raiz2 3 x raiz2 3) R 30o ( e o In mostrou uma estrutura (1x1) para filmes com mais de 2 monocamadas, provavelmente na forma de ilhas sobre a superfície do Pd. Estudos anteriores mostraram que Sb sobre Pd(111) também apresenta a fase (raiz2 3 x raiz2 3)R 30o para baixas coberturas[2]. Os modelos que melhor se adequaram aos dados sugerem fortemente que os metais sp(In, Sn,e Sb) não difundem além da segunda monocamada. Durante estes estudos foi observado que a intensidade do satélite de shake-up do Pd tendia a zero para os átomos em contato direto com os metais s / Abstract: The purpose of this report is to present a study of the electronic and geometric structure of surface alloys grown by MBE (Molecular Beam Epitaxy) on single crystal substrates in the sub monolayer regime. The films were grown "in-situ" in the analysis chamber and analyzed by XPS (X-Ray Photoelectron Spectroscopy), PED (Photoelectron Diffraction), LEED (Low Energy Electron Diffraction) and UPS (Ultra Violet Photoelectron Spectroscopy). The alloys studied were InPd, SnPd e SbPd, all grown on the (111) face of a Pd crystal. The PED measurements for InPd and SnPd were analyzed using the MSCD code[3]. It was possible to show that for low coverages both metals formed a (raiz2 3 x raiz2 3) R 30o ( reconstruction and the first inter-planar distances were determined. For films with over two monolayers the In grew with a (1x1) structure probably in the form of islands separated by clean Pd. Previous studies showed that Sb[4] at low coverage also forms a (raiz2 3 x raiz2 3) R 30o ( structure. Our simulations suggest that In, Sn and Sb for the coverages studied do not diffuse beyond the second atomic layer. We also observed that the intensity of the Pd shake up satellite tends to zero for the Pd atoms in contact with these sp metals / Mestrado / Física da Matéria Condensada / Mestre em Física

EUs direktiv för energiprestanda innebär att alla nya byggnader från och med 2021 ska vara nära-nollenergibyggnader. De stundande kraven innebär att beställare måste skärpa sina energikrav vid upphandling av flerbostadshus. Vidare spelar lågenergibyggnader som koncept en viktig roll för att nå hållbar utveckling och det är av högsta vikt att kommande byggprojekt blir effektiva både i byggprocess och vidare i driftskedet.  Nybyggnation av lågenergibyggnader har visat sig problematisk i många aspekter, där den uppmätta energianvändningen i många fall visat sig väsentligt högre än vad som projekterats. I och med den ny byggpraxis med bättre isolation, lufttäthet och ventilation med återvinning blir tappvarmvatten och hushållsel de största energiposterna i en byggnads energibalans.  Syftet med arbetet är att konkretisera problemen som finns för nyproducerade flerbostadshus med energikrav för lågenergibyggnader. Utifrån det har fokus lagts på två byggnader som AB Bostäder låtit bygga – båda projekterade för att uppnå lågenergikrav.  Likt befarat visar Examensarbetet att det är svårt att härleda problemet till specifika poster. Byggprocessen i sig kan vara en bidragande faktor, där tidsbrist, bristfällig kommunikation och okunskap kring ny byggpraxis är förekommande i en bransch som har svårt att hinna med den efterfrågade volymen av nybyggnation. Vad gäller specifika felkällor till försämrad energiprestanda stödjer vår rapport tidigare publicerade rapporter i ämnet där bristfällig indata vid energiberäkningar, byggprocessens inverkan, oaktsamhet av VVC-förluster och betydelsen av brukare har belysts. / The energy performance of buildings directive means that all new buildings must be nearly zero energy buildings by 31 December 2020. The current requirements mean that constructor companies must tighten their energy requirements when procuring multi-family houses. Lowenergy buildings as concepts play an important role in achieving sustainable development, and it is of the utmost importance that future construction projects become effective both in the construction process and on further operation.  New construction of low-energy buildings has proved to be quite problematic in many aspects, where the measured energy performance in many cases proved to be significantly higher than projected. With the new building practice with better insulation, air tightness and ventilation with recycling – hot water supply and household appliances become the largest energy posts in a building's energy balance.  The purpose of this master thesis is to concretize the problems that exist for newly produced multi-family houses with energy requirements for low-energy buildings. Based on this, focus has been on two building that AB Bostäder Borås recently has built – both built to achieve low energy requirements.  As expected, this master thesis shows the difficulty to deduce the problem to specific aspects. The construction process itself may be the source of error, where time shortages, inadequate communication and lack of knowledge concerning low energy buildings are present in an industry with difficulties catching up with the demanded volume of new construction. Regarding specific sources of vulnerability to energy performance, our report supports previously published reports where the lack of input data for energy calculations, the impact of the construction process, negligence of losses due to recirculation of hot water and the importance of user behaviour have been highlighted.

Mobile technology is developing quickly and becomming a part of daily life and communication. Bluetooth Low Energy is presented as a new way of mobile interaction. However there are not enough studies in this field on the interaction between mobile devices and the physical world. In order to understand user needs, and to encourage users to interact, we simulated an interaction process through designing and testing a prototype in a specific indoor environment. Prototype effectiveness and main characteristics for future mobile application was evaluated through a qualitative user study with 20 participants who interacted with our prototype. / Den mobila tekniken växer snabbt och blir en del av våra liv och vår kommunikation. BLE presenteras på ett nytt sätt inom mobilinteraktion. Det förekommer inte tillräckligt med studier inom området för interaktionen mellan mobila enheter och den fysiska världen. För att förstå användarbehov och få användare att interagera har vi simulerat en interaktiv process genom att designa och testa en prototyp i en specifik inomhusmiljö. Utvärdering av prototypens effektivitet och heuristiken har evaluerats genom en kvalitativ studie med 20 användare som har deltagit i interaktionen med vår prototyp.