The characterization of the material’s deformation is nowadays common in transmission electron microscopy. The ability to resolve the crystalline lattice enables the strain to be linked with the deformation of the crystal unit cells. Imaging the crystal unit cells imposes the sampling scheme to oversample the resolved crystal periodicities and, thus, limits the field of view (FOV) of the micrograph. Therefore, alternative methods were developed (electron diffraction and holography) to overcome the FOV limitation. The method presented in this thesis is part of the large FOV challenge. Its principle is based on the coherent interference of the sampling grid with the crystalline lattices of the material in scanning transmission electron microscopy (STEM). The interference results to a set of Moiré fringes embedding the structural properties of the material such as a strain field. The STEM Moiré hologram (SMH) formation can be elegantly described using the concept of Moiré sampling in STEM imaging. The STEM Moiré fringes reveals to be undersampling artefacts commonly known as aliasing artefacts. The SMH is, therefore, violating the sampling theorem and is not a proper representation of the crystal unit cells. However, an oversampled representation can be recovered from the SMH using a set of prior knowledge. The SMH becomes suitable to characterize the 2D strain field giving birth to a new dedicated method, called STEM Moiré GPA (SMG), that is using the Geometric Phase Analysis method on the SMH directly. After detailing the theory of SMG, the technique is validated experimentally by comparing it to other strain characterization methods and to Finite Element Method simulations. The characteristics of SMG (resolution, precision and accuracy) and its limits are then detailed. Finally, the SMG method is applied on semiconductor devices to highlight the typical capabilities of the technique. / Thesis / Doctor of Philosophy (PhD)

The main aim of the presented diploma thesis was to record objective and subjective changes after therapy with DNS concept in a group of 13 people with LBP. Moiré projection topography was used to record postural changes after 5.5 week therapeutic intervention. It was not clear, whether DNS exercise would help them to achieve visible postural changes and whether this technique is able to record these changes, which would mean that it is a suitable option for objectivisation of therapies focusing on correction of stabilisation and postural functions. Pedoscan was used for further objectivisation of the effect of DNS concept. The chosen correlate of the mentioned objective evaluation was Oswestry disability index, evaluating limitations of common everyday activities resulting from pain in the lower back, and the Numeric pain scale. Patients underwent 5 hour-long physiotherapeutic lessons, the recommended frequency of exercises in the household environment was 3-4 times per day. The probands exercised with the use of DNS concept according to the individual examination findings, especially in the area of the integrated spine stabilisation system. The data were statistically elaborated by Wilcoxon Signed-Rand test, which a non-parametric variant of the pair T-test. It is obvious from the results that...

The graphene moiré superstructure formed on Ru(0001) (g/Ru(0001)) has shown the potential as a template to self-assemble super-lattices of metal nanoparticles as model catalysts. To explore the possibility of rational catalyst design on g/Ru(0001), detailed density functional theory (DFT) calculations have been performed to investigate the adsorption and diffusion of Rh and Au adatoms on g/Ru(0001). The consequences of different hopping rates for cluster nucleation have been explored by performing Monte Carlo-based statistical analysis, which suggests that diffusing species other than adatoms need to be taken into account to develop an accurate description of cluster nucleation and growth on this surface. DFT calculations have also been carried out to investigate the adsorption and diffusion of 18 4d (Y-Ag) and 5d (La-Au) transition metal adatoms on g/Ru(0001). Given the necessity to study larger diffusing species than adatoms, DFT calculations have been performed to study the adsorption and diffusion of Rh and Au dimers and trimers on g/Ru(0001). It was shown that the mobility of Rh clusters decreases with the increase of cluster size, while for Au, dimers diffuse faster than monomers and trimers on the moiré surface. We then used a genetic algorithm combined with DFT calculations to predict the lowest energy structure of a Au8 cluster on g/Ru(0001). Our prediction leads us to propose that Au clusters aggregates through Oswald ripening with Au dimer being the major diffusing species. Finally, we examined the morphology of a Cu19 cluster on g/Cu(111) using MD simulations with COMB3 potential. We also studied the mobility of Cu clusters on g/Cu(111) at elevated temperatures. The analysis suggests that g/Cu(111) may not be a suitable substrate for the formation and growth of isolated Cu clusters. All these calculation results have provided us a better understanding and useful insights into the nucleation and growth mechanism of metal clusters on graphene moiré.

Jusqu'à récemment, la plupart des applications des arcs électriques mettaient en oeuvre les propriétés du coeur de la colonne, un effort particulier a donc été effectué pour développer des méthodes de caractérisation de ces zones dont la température moyenne est de l'ordre de 10000 K. Avec le développement de la plasma-chimie, le diagnostic des zones périphériques d'arcs et des décharges hors équilibre est devenu un enjeu primordial. Les méthodes de mesure classiques sont mal adaptées pour cette tâche ; le but du travail présenté dans cette thèse se résume donc au développement et à la validation de techniques de diagnostic adaptées à ces zones, dont la température cinétique n'excède pas 8000 K. Deux méthodes innovantes basées sur l'indice de réfraction, l'ombroscopie quantitative et la déflectométrie moirée, ont été étudiées en détails. Les résultats théoriques ainsi que le traitement des données obtenues ont été validés sur un jet de plasma laminaire d'argon, un modèle parfait de zone périphérique. Pour sonder les décharges hors équilibre, l'utilisation du spectre UV de OH a été aussi envisagée. À cette occasion, un programme de simulation de spectre moléculaire a été développé. L'étude des spectres synthétiques obtenus a permis de mettre au point des méthodes de mesure simples de la température rotationnelle et vibrationnelle pour une large gamme de résolution. Une des méthodes développées a été mise en œuvre sur une décharge à faible intensité de courant. On montre que les résultats obtenus par spectroscopie moléculaire sur le radical OH sont très proches de ceux obtenus à l'aide d'une simulation.

京都大学 / 新制・課程博士 / 博士(エネルギー科学) / 甲第24116号 / エネ博第449号 / 新制||エネ||84(附属図書館) / 京都大学大学院エネルギー科学研究科エネルギー応用科学専攻 / (主査)教授 大垣 英明, 教授 松田 一成, 教授 宮内 雄平 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM

Title from PDF of title page. / Document formatted into pages; contains 87 pages. / Thesis (M.S.M.E.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: As technology progresses towards smaller electronic packages, thermo-mechanical considerations pose a challenge to package designers. One area of difficulty is the ability to predict the fatigue life of the solder connections. To do this one must be able to accurately model the thermo-mechanical performance of the electronic package. As the solder ball size decreases, it becomes difficult to determine the performance of the package with traditional methods such as the use of strain gages. This is due to the fact that strain gages become limited in size and resolution and lack the ability to measure discreet strain fields as the solder ball size decreases. A solution to the limitations exhibited in strain gages is the use of Moiré interferometry. Moiré interferometry utilizes optical interferometry to measure small, in-plane relative displacements and strains with high sensitivity. / ABSTRACT: Moiré interferometry is a full field technique over the application area, whereas a strain gage gives an average strain for the area encompassed by the gage. This ability to measure full field strains is useful in the analysis of electronic package interconnections; especially when used to measure strains in the solder ball corners, where failure is known to originate. While the improved resolution of the data yielded by the method of Moiré interferometry results in the ability to develop more accurate models, that is not to say the process is simple and without difficulties of it's own. Moiré interferometry is inherently susceptible to error due to experimental and environmental effects; therefore, it is vital to generate a reliable experimental procedure that provides repeatable results. This was achieved in this study by emulating and modifying established procedures to meet our specific application. / ABSTRACT: The developed procedure includes the preparation of the specimen, the replication and transfer of the grids, the use of the PEMI, interpretation of results, and validation of data by finite element analysis using ANSYS software. The data obtained maintained uniformity to the extent required by the scope of this study, and potential sources of error have been identified and should be the subject of further research. / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.

This research aims to understand the reliability of Sn-Ag-Cu solder interconnects used in plastic ball grid array (PBGA) packages using microstructure evolution, laser moiré interferometry and finite-element modeling. A particle coarsening based microstructure evolution of the solder joint material during thermal excursions was studied for extended periods of time lasting for several months. The microstructure evolution and particle coarsening was quantified, and acceleration factors were determined between benign field-use conditions and accelerated thermal cycling (ATC) conditions for PBGA packages with different form factors and for two different lead-free solder alloys. A new technique using laser moiré interferometry was developed to assess the deformation behavior of Sn-Ag-Cu based solder joints during thermal excursions. This technique can used to estimate the fatigue life of solder joints quickly in a matter of few days instead of months and can be extended to cover a wide range of temperature regimes. Finite-element analysis (FEA) in conjunction with experimental data from the ATC for different lead-free PBGA packages was used to develop a fatigue life model that can be used to predict solder joint fatigue life for any PBGA package. The proposed model will be able to predict the mean number of cycles required for crack initiation and crack growth rate in a solder joint.

Inom Machine Vision är det av stor vikt att kameran har möjlighet att detektera de detaljer som eftersöks. Aliasing är ett problem inom all digital fotografering och beror på att kamerans upplösning är för låg i förhållande till de detaljer den försöker fånga. Det här arbetet analyserar kamerans begränsningar och orsaken till dessa. En enkel kamerarigg som används till försök inom Machine Vision konstrueras om från grunden för bättre kontroll och upplösning och en ny styrning skapas till denna efter beställarens specifikationer. Ett testmönster för ISO 12233:2000 fotograferas därefter i denna rigg. Resultatet analyseras och jämförs mot Nyquists samplingsteorem med avseende på digital fotografering. Resultatet visar hur kamerans konstruktion och sätt att registrera färger genom ett filter framför bildsensorn och algoritmer för att beräkna färgen för varje enskild bildpunkt höjer sampelstorleken med en faktor 3 jämfört med det ursprungliga teoremet om dubbla samplingsfrekven-sen. / Within Machine Vision, it is very important that the camera can detect the details requested. Aliasing is a problem in all digital photography, and is because the camera's resolution is too low relative to the details it tries to capture. This work analyzes the camera's limitations and the cause of these. A simple camera rig used for Machine Vision tests is re-designed for better control and resolution, and a new control-system is created to this according to the client's specifications. A test pattern for ISO 12233: 2000 is then photographed in this rig. The result is analyzed and compared to Nyquist sampling theorem regarding digital photography. The result shows how the camera's design and way of registering colors through a filter in front of the image sensor and algorithms to calculate the color for each individual pixel increases the sample size by a factor of 3 compared with the original theorem with double sampling frequency.

Diese Dissertation konzentriert sich auf die Untersuchung der Schwingungs- und exzitonischen Eigenschaften von zweidimensionalen Übergangsmetall-Dichalkogeniden (TMDCs) unter Verwendung von mikro- und nanooptischer Spektroskopie. Im ersten Teil der Arbeit wird Mikro-Raman-Spektroskopie verwendet, um die Schwingungseigenschaften von 2D-TMDC-Homo- und Heterostrukturen zu untersuchen, mit dem Ziel, die Hochfrequenz-Raman-Signatur für die Wechselwirkung zwischen den Schichten und die Gitterdynamik zu erforschen. Basierend auf einer systematischen Raman-Studie, unterstützt durch Photolumineszenz- (PL) und Topographie-Untersuchungen an nicht gekoppelten und gekoppelten TMDC-Doppellagen, wird die aus der Ebene herausragende $B_{2g}$-Schwingungsmode experimentell als ein charakteristischer Raman-Fingerabdruck zur Einschätzung der Wechselwirkung zwischen den Schichten in 2D-TMDC-Systemen erklärt. Darüber hinaus wird anhand eines Beispiels mit verdrehter Doppellage (tB) von WSe$_2$ als typisches TMDC gezeigt, dass das Raman-Intensitätsverhältnis der beiden Peaks $I_{B_{2g}}/I_{{E_{2g}}/{A_{1g}}}$ mit der Entwicklung der Moiré-Periode korreliert. Mit einer Reihe temperaturabhängiger Raman- und Photolumineszenz-Messungen sowie \textit{ab initio}-Berechnungen wird das Intensitätsverhältnis $I_{B_{2g}}/I_{{E_{2g}}/{A_{1g}}}$ als Signatur der Gitterdynamik in tB-WSe$_2$-Moiré-Übergittern erklärt. Durch die weitere Untersuchung verschiedener Materialkombinationen von verdrehten Hetero-Doppellagen werden die Ergebnisse auf alle Arten von Mo- und W-basierten TMDCs erweitert. Im zweiten Teil der Dissertation wird die spitzenverstärkte Photolumineszenz-Spektroskopie (TEPL) eingesetzt, um die konventionelle optische Auflösungsgrenze zu überwinden und die konkurrierenden Mechanismen der lokalen Photolumineszenz-Dämpfung und -Verstärkung an 2D-TMDC/hBN/Plasmonik-Grenzflächen zu verstehen. Durch den Vergleich verschiedener Nahfeldemissions-Eigenschaften und TEPL-Spektren in Abhängigkeit von der Spitzen-Proben-Entfernung an einer komplexen Monolagen-MoSe$_2$/hBN/NT/SiO$_2$-Probe werden die lokalisierte Oberflächenplasmonenresonanz (LSPR), die Elektronen-Dotierung und der Tunneltransport sowie hochlokalisierte Belastung als dominierende Faktoren für die lokale PL-Dämpfung und -Verstärkung identifiziert.

Cette étude porte sur l'application des techniques de mesure optiques pour la caractérisation mécanique des organes biologiques. Deux voies ont été explorées : la réalisation de maillages en éléments finis et la mesure de déformations planes. Les maillages en éléments finis peuvent être réalisés à partir du relief des organes. Nous avons alors développé une technique de projection de réseaux de traits. Afin d'améliorer l'exactitude, l'analyse des réseaux s'effectue par des techniques de décalages de phases. Une procédure de calibrage du montage a été spécialement développée. La mesure des déformations sur de la peau a été effectuée par une extension de la technique de suivi de marqueurs. Afin de voir l'ensemble des phénomènes mécaniques qui régissent ce tissu, nous avons réalisé des essais de traction simple, de relaxation, de traction à accélération constante et de traction biaxiale. Le caractère viscoplastique de la peau et l'orthotropie de sa structure ont été ainsi mis en évidence.