This study examines personal problems which a selected group of 1970's college freshmen at North Texas State University considered important to them and investigates significant changes in the nature, configuration, and frequency of these problems from those indicated by selected freshmen of the 1960's and 1950's. None of the wide variety of previous approaches over the years in studying problems of students has presented such a broad time span as this study. The students of the 1950's and 1960's were North Texas State University freshmen enrolled in Education 161, "The Psychology of Social and Personal Adjustment." The 1970's population was taken from basic freshman English courses at North Texas State University. All students were administered the Mooney Problem Check List, and the results were prepared for computer analysis. An analysis-of-variance program was used on eight hypotheses, with a .05 level of significance required for the hypotheses to be retained. The Spearman Rank Order Correlation Coefficient was used in answering two hypotheses. There were 2,809 freshmen from the 1950's, 1,440 from the 1960's, and 695 from the 1970's.

Orientador: Celio Pasquini / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química / Made available in DSpace on 2018-08-25T08:12:03Z (GMT). No. of bitstreams: 1 Silva_CarlosJulianoda_M.pdf: 4366426 bytes, checksum: f7c8d6474698d79b5e218e2896eec667 (MD5) Previous issue date: 2014 / Resumo: No presente trabalho foi feita uma comparação entre as técnicas de reflectância difusa convencional e imagem hiperespectral na região do infravermelho próximo para determinação de viscosidade Mooney (VM), plasticidade inicial (Po), plasticidade após envelhecimento acelerado (P30) e Índice de Retenção de Plasticidade (PRI) em amostras de borracha natural pré-vulcanizadas. Os espectros foram adquiridos utilizando dois espectrofotômetros com transformada de Fourier e uma câmera hiperespectral e os valores de referência determinados de acordo com suas respectivas normas ASTM. Foram construídos modelos de regressão PLS e os seus respectivos valores de erro médio quadrático da previsão (RMSEP) avaliados. Como resultados, foi possível observar um ganho na capacidade preditiva dos modelos PLS com o aumento da área medida de cada amostra. Os modelos obtidos por ambos os pré-processamentos (MSC e derivada de segunda ordem) não apresentaram diferenças significativas quanto às suas capacidades preditivas, ao passo que a seleção de variáveis usando o método Jack-Knife possibilitou a obtenção de modelos com menor número de fatores. Os valores de RMSEP dos modelos otimizados foram de 4,6; 2,9; 3,0 e 5,3 para a determinação da VM, Po, P30 e PRI. Embora os resultados para os três instrumentos possam ser considerados equivalentes, o uso da câmera hiperespectral apresenta algumas vantagens, tais como: tempo de aquisição espectral aproximadamente seis vezes menor quando comparada aos equipamentos convencionais e maior robustez para determinação da viscosidade e plasticidade na presença de contaminantes / Abstract: In this work a comparison between conventional diffuse reflectance (FT-NIR) and hyperspectral image (HI-NIR) in the Near-Infrared region for determination of Mooney viscosity (VM), initial Plasticity (Po), plasticity after accelerated aging and plasticity retention index (PRI) in pre-vulcanized rubber samples was made. The spectra were acquired by using two Conventional Fourier Transform Spectrometer and one hyperspectral camera. The reference values of the rheological parameters were determined according to their respective ASTM standards. Partial least squares (PLS) regression models were constructed and their respective root mean square error of prediction (RMSEP) were evaluated. As results, it was possible to observe a gain in the prediction ability of the PLS models with increasing probed area. The models obtained for both pretreatments (MSC and second derivative) showed no significant differences. However, the variables selection using the Jack-Knife method allowed to obtain models with a low number of factors. The RMSEP values of the optimized models were 4.6, 2.9, 3.0 and 5.3 for determination of MV, Po, P30 and PRI, respectively. Though the results for the three instruments can be considered equivalent, the hyperspectral image instrument presents some relevant advantages, being about six times faster than most of conventional bulk spectrometers, and producing robust spectral data by ensuring sample representativeness, and minimizing the degrading effect of the presence of contaminants / Mestrado / Quimica Analitica / Mestre em Química

Submitted by Luciana Ferreira (lucgeral@gmail.com) on 2018-05-03T11:57:05Z No. of bitstreams: 2 Dissertação - Pedro Felipe Tavares do Amaral - 2018.pdf: 5863877 bytes, checksum: 084454dc18411f245114eb910cfa2474 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2018-05-03T13:20:55Z (GMT) No. of bitstreams: 2 Dissertação - Pedro Felipe Tavares do Amaral - 2018.pdf: 5863877 bytes, checksum: 084454dc18411f245114eb910cfa2474 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) / Made available in DSpace on 2018-05-03T13:20:55Z (GMT). No. of bitstreams: 2 Dissertação - Pedro Felipe Tavares do Amaral - 2018.pdf: 5863877 bytes, checksum: 084454dc18411f245114eb910cfa2474 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Previous issue date: 2018-02-05 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / In the present work, studies about the nonlinear static and dynamic behavior of a spherical membrane are presented. This membrane is composed by a hyperelastic, incompressible homogeneous and isotropic material, which is defined by either of the two distinct constitutive models: Mooney-Rivlin or the Neo-Hookean model. The equilibrium equations are obtained from the large-strain theory, by utilizing a variational formulation and by subjecting the membrane to an uniformly distributed internal radial pressure differential. From the nonlinear static analysis, internal membrane tensions and strains are obtained. From the dynamic analysis, the frequency-amplitude relation, the linear stability analysis, the time response, bifurcation diagrams, resonance curves and basins of attraction are obtained. As a first step, there is an analysis on a membrane composed by the same experimental material, which is described by the two different constitutive models presented in this work. It is observed that the dynamic responses are considerably distinct, due to the difference between the geometrical nonlinearities that each constitutive model insert on the equilibrium equation. The Neo-Hookean model has a lower pre-stretching limit, and its attraction basins are more eroded and irregular than the Mooney-Rivlin, that is still stable on regions of larger vibration amplitudes. Then, the influence of the Mooney-Rivlin parameter (α) is evaluated, and it is found that this parameter is the main source of the differences between the constitutive models, modifying the stability, nonlinear vibrations and also influencing on the loss or gain of the global rigidity of the membrane. / Neste trabalho são apresentados estudos dos comportamentos não lineares, estático e dinâmico, de uma membrana de geometria esférica composta por um material hiperelástico, incompressível, homogêneo e isotrópico definido por um entre esses dois modelos constitutivos: Mooney-Rivlin ou Neo-Hookeano. As equações de equilíbrio são obtidas a partir da teoria de grandes deformações, utilizando uma formulação variacional e considerando a membrana esférica submetida a uma pressão interna na direção radial uniformemente distribuída. A partir da análise não linear estática, encontram-se as tensões e as extensões radiais da membrana e da análise dinâmica obtêm-se as relações frequência-amplitude, a análise não linear da estabilidade, as respostas no tempo, os diagramas de bifurcação, as curvas de ressonância e as bacias de atração da membrana. Primeiramente, analisa-se a membrana composta por um mesmo material experimental e descrita pelos dois modelos hiperelásticos avaliados nesta dissertação. Observa-se que as respostas dinâmicas são consideravelmente distintas entre si devido à diferença entre as não linearidades geométricas que cada modelo constitutivo insere na equação de equilíbrio, sendo que o modelo Neo-Hookeano apresenta menor limite de pré-carregamento com bacias de atração mais erodidas e menos uniformes quando comparado ao modelo de Mooney-Rivlin, que ainda apresenta estabilidade em regiões de maior amplitude de vibração. Posteriormente, avalia-se a influência do parâmetro do material do tipo Mooney-Rivlin (α), que é a principal fonte das diferenças entre os modelos constitutivos, na estabilidade e nas vibrações não lineares da membrana esférica, observando-se que o parâmetro influência na perda ou no ganho de rigidez global do problema.

This thesis reports onreview and research work carried out on the numerical analysis of elastomers. The two numerical techniques investigated for this purpose are the finite and boundary element methods. The finite element method is studied so that existing theory is used to develop a finite element code both to review the finite element method as applied to the stress analysis of elastomers and to provide a comparison of results and numerical approach with the boundary element method. The research work supported on in this thesis covers the application of the boundary element method to the stress analysis of elastomers. To this end a simplified regularization approach is discussed for the removal of strong and hypersingularities generated in the system on non-linear boundary integral equations. The necessary programming details for the implementation of the boundary element method are discussed based on the code developed for this research. Both the finite and boundary element codes developed for this research use the Mooney-Rivlin material model as the strain energy based constitutive stress strain function. For validation purposes four test cases are investigated. These are the uni-axial patch test, pressurized thick wall cylinder, centrifugal loading of a rotating disk and the J-Integral evaluation for a centrally cracked plate. For the patch test and pressurized cylinder, both plane stress and strain have been investigated. For the centrifugal loading and centrally cracked plate test cases only plane stress has been investigated. For each test case the equivalent results for an equivalent FEM program mesh have been presented. The test results included in this thesis prove that the FE and BE derivations detailed in this work are correct. Specifically the simplified domain integral singular and hyper-singular regularization approach was shown to lead to accurate results for the test cases detailed. Various algorithm findings specific to the BEM implementation of the theory are also discussed.

The purpose of this study was to identify the major problem areas of freshmen community college students and to determine if significant differences in problems of freshmen students existed as a variable of age, sex, or marital status. The population consisted of 674 community college students enrolled in an Orientation to College program during the fall or spring semester of 1976, 1977, 1978 or 1979. Each student was administered the Mooney Problem Check List (MPCL), College Form (1950) during the first week of enrollment at the community college. he data were analyzed in order to determine if a significant difference existed in the problem areas reported by students according to a Friedman Two-Way Analysis of Variance by Ranks. A significant difference produced by the Friedman ANOVA indicated a need to apply a Wilcoxon Matched-Pairs Signed Ranks Test in order to determine which problem areas differed significantly from one another. A Mann Whitney U Test was employed to statistically compare the problem areas of male students and female students as well as married students and single students. A Kruskal-Wallis one-way analysis of variance by ranks for k independent samples was employed to test differences in the responses of four student age groups: 18 and under, 19 and 20, 20 through 29 and 30 years of age and over.

The master's thesis deals with the determination of macroscopic behavior of a particulate composite with cross-linked polymer matrix under tensile load. The main focus of thesis is estimation of mechanical properties of a composite loaded by tensile loading using numerical methods (especially finite elements method). Investigated composite is composed of matrix in a rubbery state filled by alumina-based particles (Al2O3). Hyperelastic properties of the matrix have been modeled by the Mooney-Rivlin material model. Different compositions of particles, their different shape, orientation and different volume fractions have been considered. For all these characteristics of composite numerical models have been developed. The damage mechanisms of the matrix have also been taken into account. Results of numerical analyses have been compared with experimental data and good agreement between numerical models with damage mechanisms of matrix and experimental data has been found.

Functionally graded structures have material properties that continuously vary in one or more directions. Examples include human teeth, seashells, bamboo stems and human organs, where the varying volume fraction of fibers and their orientations optimize functionality. Deformations of such structures typically involve bending, stretching, and shearing. An everyday example of shearing deformation is the twisting of wet fabrics to extract water. In this study, we analytically examine the large deformations of functionally graded Mooney-Rivlin circular cylinders, focusing on how radial grading of material moduli can be beneficially utilized. We investigate the finite deformations caused by pressures applied to the bounding surfaces and axial loads or twisting moments on the end faces. We also simulate residual stresses in a hollow cylinder either by inverting it inside out or by closing a longitudinal wedge opening parallel to the cylinder axis through axisymmetric deformation before other loads are applied. It is observed that the maximum shear stress in an initially stress-free Mooney-Rivlin cylinder can occur at an interior point. In the absence of axial forces on the end faces, the cylinder elongates when twisted, with the degree of elongation depending on the grading of the material moduli. These findings should aid numerical analysts in verifying their algorithms for simulating large deformations of rubber-like materials modeled by the Mooney-Rivlin relation. / Master of Science / Functionally graded materials (FGMs) are composites whose properties vary in one or more directions to exploit the functionality of the individual components. An example would be a sheet of material that is fully metallic on one side and fully ceramic on the other, with properties changing gradually through the thickness. The Mooney-Rivlin model is used to capture the stress-strain response of rubber-like materials. Therefore, functionally graded Mooney-Rivlin cylinders are rubber-like composite cylinders whose properties change throughout their thickness. Functionally graded cylinders have a wide array of applications, including in pressure vessels, vibration damping systems and tires. Therefore, having a thorough understanding of the stresses induced in these cylinders when subjected to loads is essential for safe and reliable designs. This research aims to investigate the effects of material inhomogeneity on the stresses induced in functionally graded cylinders subjected to torsion, radial expansion, eversion, and various combinations of these. Furthermore, realizing that stresses induced during the fabrication process cannot be easily quantified, we study a problem in which these induced stresses can be determined and analyze their effect on subsequent deformations of the cylinder when subjected to torsion and radial expansion. To achieve this aim, we use a member of Ericksen's third family of universal deformations, which mathematically describes torsion, inflation, and eversion, along with the Mooney-Rivlin model to determine the stress state resulting from deformation. The results show that for cylinders of the same geometry in the stress-free undeformed state subjected to identical surface tractions, material inhomogeneities greatly influence the stresses in the cylinder. It was also found that the magnitude of the normal and shear stresses, axial stretch, and the geometry of the cylinder after deformation depend on the type of deformation and functional grading. Additionally, the results indicate that the normal stresses induced in an initially stressed cylinder are much greater than those in a cylinder that is initially stress-free when subjected to the same boundary conditions.

In vielen industriellen Anwendungen sind Dichtungen im Einsatz. Vergleicht man den Preis mit dem eines Gesamtsystems, in denen Dichtungen verwendet werden, so sind Dichtungen verhältnismäßig günstig. Jedoch führt ein Versagen von Dichtungen meist zu schwerwiegenden Konsequenzen. Dichtungen sind komplexe Subsysteme und ihre Auslegung erfordert umfangreiche Kenntnisse im Bereich Materialmodellierung, Belastung und Versagenskriterien. Die heutige Simulationstechnologie ermöglicht einen parametrischen Workflow für die Berechnung des Verhaltens von Dichtungen mit den auftretenden Effekten wie nichtlinearem Materialverhalten, wechselnden Kontaktbedingungen und Flüssigkeitsunterwanderung bei Druck. Als ein führendes Simulationswerkzeug für diese physikalische Fragestellung wird ANSYS Mechanical für die Auslegung herangezogen. Desweiteren kann das Verständnis für das Produkt erhöht werden, was zu einer Verbesserung der Funktionalität und der Zuverlässigkeit führt. Versuchsdaten können als Spannungs-Dehnungskurven in ANSYS importiert werden, welche das Materialverhalten des hyperelastischen Werkstoffs mit traditionellen Materialmodellen wie Mooney Rivlin, Ogden and Yeoh oder einer neueren Formulierung, der Antwortfunktionsmethode, widerspiegeln. Robuste Kontakttechnologien beschleunigen die Simulation und Entwicklungszeit-Berechnungszeiten und gewährleisten ein genaues Verhalten des Simulationsmodells. Insbesondere bei Dichtungen ist die druckbeaufschlagte Fläche in 2D und 3D Anwendungen von Bedeutung. ANSYS berechnet diese automatisch in Abhängigkeit des aktuellen Kontaktzustandes. Diese benutzerfreundliche Unterstützung führt zu einer höheren Genauigkeit des Simulationsergebnisses, da ein manuelles Schätzen der Druckflächen entfällt. Mit einem parametrischen und durchgängigen Ansatz innerhalb von ANSYS Workbench, beginnend bei der CAD-Geometrie, über die Vernetzung, Material- und Randbedingungsdefinition und Lösung. können eine Reihe von Varianten in kurzer Zeit berechnet werden. Neben einem besseren Verständnis für das Produkt hilft dies dem Ingenieur Änderungen vorzunehmen, was zu exakten und aussagekräftigen Ergebnissen führt. Desweiteren kann der Einfluss von Unsicherheiten berücksichtigt werden, sodass der Berechnungsingenieur fernab von idealen Bedingungen robuste und zuverlässige Dichtungen entwickeln kann.

Submitted by Cláudia Bueno (claudiamoura18@gmail.com) on 2015-10-27T18:16:56Z No. of bitstreams: 2 Dissertação - Renato de Sousa e Silva - 2015.pdf: 7212801 bytes, checksum: 41d5a93b0ae749a6418b871cd4fea683 (MD5) license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) / Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2015-10-28T14:29:10Z (GMT) No. of bitstreams: 2 Dissertação - Renato de Sousa e Silva - 2015.pdf: 7212801 bytes, checksum: 41d5a93b0ae749a6418b871cd4fea683 (MD5) license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) / Made available in DSpace on 2015-10-28T14:29:10Z (GMT). No. of bitstreams: 2 Dissertação - Renato de Sousa e Silva - 2015.pdf: 7212801 bytes, checksum: 41d5a93b0ae749a6418b871cd4fea683 (MD5) license_rdf: 23148 bytes, checksum: 9da0b6dfac957114c6a7714714b86306 (MD5) Previous issue date: 2015-06-12 / Fundação de Amparo à Pesquisa do Estado de Goiás - FAPEG / Structural elements with large deformation capacity as hyperelastic membranes are gaining prominence in several engineering branches and have applications in biomechanics, thus the study of the dynamic behavior of hyperelastic structures is very important to minimize effects as the loss of the stability and undesirable vibrations. In this paper the elasticity theory for large deformations in the development of membrane theory, in order to investigate the linear and nonlinear dynamic behavior of hyperelastic membrane is used. A rectangular membrane composed of an elastomeric material, isotropic, homogeneous, incompressible and consisting of neo-Hookeano, Mooney-Rivlin and Yeoh models is considered. To model the membrane, the energy and work of external forces are used together with the application of the Hamilton on the Lagrange function. The Galerkin method is applied to obtain a discretized system of nonlinear Partial Differential Equations (PDE) and the Runge-Kutta method of 4th order is used to obtain its time response. Finally, the Brute Force and Continuation methods are applied to investigate the nonlinear dynamic behavior of the membrane. A parametric analysis is carried out looking to evaluate the influence of the material, geometry and initial tensions on the natural frequencies of the membrane. It is noted that increasing the size of a tensioned membrane, it is also increased the natural frequency for a given amplitude, and increasing the strength of a pre-tensioned membrane, the smaller the value of the frequency in relation to a range. Small differences are perceived in the behavior of the membrane for the three constitutive models of material, which are calibrated to represent the same material. Moreover, the main bifurcations of the analyzed membranes are of cyclic bending type, known as saddle-node bifurcation. / Elementos estruturais com grande capacidade de deformação como membranas hiperelásticas vêm ganhando destaque em diversas áreas da engenharia e têm várias aplicações na biomecânica, assim, o estudo do comportamento dinâmico de estruturas hiperelásticas é de grande importância visando minimizar os efeitos, como à perda de estabilidade e vibrações indesejáveis. No presente trabalho é utilizada a teoria da elasticidade para grandes deformações no desenvolvimento da teoria de membranas com o objetivo de investigar o comportamento dinâmico linear e não linear de membranas hiperelásticas. Considera-se a membrana retangular composta por um material elastomérico, isotrópico, homogêneo, incompressível e descrito pelos modelos constitutivos de neo-Hookeano, Mooney-Rivlin e Yeoh. Para obter as equações de equilíbrio estático e dinâmico da estrutura são utilizadas as energias e trabalhos atuantes, bem como o princípio de Hamilton aplicado na função de Lagrange. O Método de Galerkin é utilizado para discretizar as Equações Diferenciais Parciais (EDP) em um sistema de Equações Diferenciais Ordinárias (EDO). Para resolver esse sistema, utiliza-se o Método de Runge-Kutta de quarta ordem e utiliza-se o Método da Força Bruta e o Método da Continuação para investigar o comportamento dinâmico da membrana. É realizada uma análise paramétrica visando avaliar a influência do material e da geometria da membrana nas frequências naturais e nas tensões inicias. Constata-se que as bifurcações das membranas analisadas são do tipo Dobra Cíclica, conhecida como Nó-Sela. Além de verificar que quanto menor o nível de tração, maior será a não linearidade da curva de frequênciaamplitude da membrana e que há leves divergências no comportamento da membrana em relação aos três modelos constitutivos do material adotados.

Le pourcentage élevé de blessures dues à des traumatismes abdominaux survenant lors d’accidents de la route mais également la nécessité de détecter des maladies (l'hépatite virale, la cirrhose, le cancer etc.), ont conduits plusieurs chercheurs à étudier les propriétés mécaniques des organes abdominaux à la fois in vivo et in vitro. Dans tous les MEF de corps humain actuellement disponibles, les organes abdominaux sont caractérisés par des lois élastiques linéaires ou viscoélastiques linéaires, alors que ces matériaux montrent un comportement non linéaire hyper élastique. L’objectif de ce travail de thèse est de développer des modèles par éléments finis (MEF) robustes des différents organes de l’abdomen tels que le foie, le rein et la rate. Pour ce faire des tests expérimentaux sur chacun des constituants de ces organes ont été réalisés dans le but de caractériser le comportement mécanique de ceux-ci et de déterminer les propriétés mécaniques inhérentes à ces constituants. Pour caractériser mécaniquement ces différents constituants, des tests statiques ont donc été réalisés pour chacun des constituants du foie et du rein porcin à savoir, des tests de traction de la capsule de Glisson et de la capsule rénale ainsi que des veines hépatiques, des tests de compression et de cisaillement pour le parenchyme hépatique et le cortex rénale. Finalement la rate a été testée en compression statique. Les résultats expérimentaux obtenus ont été utilisés afin de caractériser les tissus par des lois de comportement de type hyper élastique, viscoélastique et hyper viscoélastique sous la forme de modèles d'Ogden, Mooney Rivlin et Maxwell et implémentés dans les MEF porcin et humain développés dans le cadre de cette thèse. Ces MEF ont ensuite été validés en regards de tests expérimentaux dynamiques in vivo réalisés sur modèle porcin et vis-à-vis de la littérature pour les MEF d’organes humains. Ainsi, les MEF développés dans cette étude sont les premiers modèles détaillés et validés et peuvent désormais être utilisés dans le cadre de reconstructions d’accidents mais également pour des applications biomédicales dans le but de développer des environnements virtuels de chirurgie, de planifier les actes chirurgicaux et d’aider les chirurgiens à l’apprentissage de gestes. / The objective of this study is to develop robust finite element models of abdominal organs (viz. liver, kidney and spleen), by performing experiments on each organ’s constituents to extract the material properties. Understanding the mechanical properties of the organs of the human body is the most critical aspect of numerical modeling for medical applications and impact biomechanics. Many researchers work on identifying mechanical properties of these organs both in vivo and in vitro considering the high injury percentage of abdominal trauma in vehicle accidents and for easy detection of diseases such as viral hepatitis, cirrhosis, cancer etc. In all the current available finite element human body models the abdominal organs are characterized as linear elastic or linear visco-elastic material, where as the materials actually show a non linear hyper elastic behavior. In this study the organs are modeled for first time as hyper visco-elastic materials and with individual constituents of each (viz. the capsule and veins). To characterize the tissue, static experiments are performed on individual parts of the abdominal organs, like incase of liver, Glisson’s capsule and hepatic veins are tested under static tension where as liver parenchyma is tested under static compression and under shear at low frequency. In case of kidneys, renal capsule is tested under static tension and renal cortex is tested under static compression, where as spleen tissue is tested under static compression. The results of the these experiments are used to characterize the tissues as hyper elastic, visco elastic and hyper visco elastic materials in the form of Ogden, Mooney Rivlin and Maxwell materials. These material models are further used to develop the finite element model of organs for human and pigs. The developed models are validated by performing in vivo dynamic tests on pigs, whereas using dynamic tests data from the literature on human liver and reproducing the same with the numerical approach in the LS Dyna explicit solver. The developed models are observed to be robust and can be used for accident reconstruction as well for biomedical applications viz., to develop virtual surgical environments & to plan surgeries or train surgeons.