[pt] O desenvolvimento da indústria de Gás Natural pelo mundo resultou em um processo de integração entre os setores de gás natural e eletricidade em diversos países. Entretanto, em alguns casos, como o Brasil, apesar de a demanda de gás para uso convencional (industrial, comercial, residencial, GNV) ter crescido a taxas relativamente altas, ela sozinha ainda não justifica novos grandes investimentos na produção e no transporte de gás. Verifica-se que, neste caso, o setor de energia desempenha um papel indispensável por se tratar do maior mercado potencial de gás natural, com a escala suficiente para ser a âncora de demanda que viabiliza os investimentos em produção e transporte do gás. Todavia, devido à predominância hidrológica no sistema elétrico Brasileiro, o despacho das térmicas é bastante volátil e, por conseqüência, o consumo de gás das térmicas é bastante variável. Assim, o produtor de gás está sujeito a um fluxo de caixa muito volátil e incerto e cláusulas de compra compulsória de gás (takeor-pay) e de remuneração do custo da infra-estrutura (ship-or-pay) são observadas. Enquanto estas cláusulas trazem certeza necessária para viabilizar a produção, elas oneram excessivamente os custos das Usinas Térmicas, que se vêem obrigadas a pagar pelo combustível e, portanto, gerar, mesmo quando o preço da energia esteja inferior ao seu custo marginal de produção. Tendo em vista este cenário, foi recentemente discutida no âmbito do Governo Federal a criação de um mercado flexível de gás natural, onde contratos interruptiveis de gás (lastreados no take-or-pay das térmicas) seriam fornecidos a consumidores industriais. Nestes contratos, o fornecimento seria interrompido se a Usina Térmica fosse despachada. O objetivo desta tese é analisar a criação deste mercado sob a ótica dos consumidores. Será verificada a disposição a pagar por um contrato interruptível de gás levando em consideração a incerteza associada ao suprimento (que depende da prioridade de uso do gás pelas térmicas) e o perfil de risco destes consumidores. / [en] With the development of the gas industry worldwide, a process of strengthening the integration between the natural gas and the electricity sectors is underway in several countries. However, although gas demand has been growing at relatively high rates, this demand growth solely is unlikely to justify new large investments in gas production and transportation. This means that the power sector ends up being the largest potential market for natural gas, with the needed scale to provide the necessary anchor demand to spur these production and infrastructure investments. The hydro predominance in the country creates volatility on the dispatch of the gas-fired plants, which ends up creating an undesirable (from the gas-sector point of view) volatility in the natural gas consumption. Since the gas-market is still incipient, gas contracts are typically of long-term with high take or pay and ship or pay clauses to ensure financing of the production- transportation infrastructure. From the power sector point of view, these clauses are undesirable: due to the uncertainty of dispatch gas-based generators want to negotiate a higher flexibility. As such, the aim of this work is to determine the impacts due to the creation of a flexible (secondary) gas market from the costumers´ point of view. It will be also developed the costumers´ willto- contract curve, which will take into account the uncertainty of thermoelectric dispatch (that rules the gas availability over this new proposed market) and the risk-profile of costumers.

<p>The awareness of the effect emissions have on the environment and climate has risen in the last decades. This has caused strict regulations of greenhouse gas emissions. Greenhouse gases cause global warming which may have devastating environmental effects. Most of the fuels commercially available today are fossil fuels. There are two major effects of using fuels with fossil origin; the source will eventually drain and the usage results in an increase of greenhouse gases in the atmosphere. Fuels that are created from a renewable feedstock are often referred to as alternative fuels and under ideal conditions they are greenhouse gas neutral, meaning that the same amount of greenhouse gases is released during combustion as the source of the fuel have absorbed during its growth period. This evaluation method is known as a well-to-wheel analysis which besides emissions also evaluates energy efficiencies during both the production and the combustion phases.</p><p>By evaluating results of well-to-wheel analyses along with fuel properties and engine concept characteristics, this report presents which driving scenario that is suitable for different powertrain configurations. For example, vehicles operating in high populated areas, as cities, have a driving scenario that includes low velocities and multiple stops while vehicles in low populated areas often travel long distances in higher speeds. This implies that different powertrains are suitable in different regions. By matching favorable properties of a certain powertrain to the properties important to the actual driving scenario this report evolves a fuel infrastructure that is suitable in Sweden.</p>

Thesis (M.Eng. (Development and Management Engineering)--North-West University, Potchefstroom Campus, 2008.

This thesis follows the process of introducing natural gas in Sweden and the construction of a Northern European gas grid from 1967 to 1991. Natural gas is a relatively unnoticed fuel in Sweden today, but this relative anonymity stands in contrast to an extensive historical activity that has taken place behind the scenes of Swedish energy policy. The single pipeline constructed between Denmark and Sweden in the early 1980s was both preceded and followed by many other attempts to construct a larger natural gas pipeline in the region made in the last 50 years. Åberg traces these attempts while discussing the complex and messy process of constructing and managing a transnational energy infrastructure.Åberg follows actors in Sweden and other countries in their attempts to negotiate and construct a natural gas infrastructure, and puts this process into a national as well as transnational context. The perceived risks and opportunities surrounding natural gas are examined, together with factors that have influenced the development of natural gas in a broader sense. By seeing the changing and messy natural gas projects as arenas where different actors construct and negotiate risks and opportunities, as well as contexualize the projects, Åberg shows how the natural gas sector in Sweden has evolved and taken shape.The study shows that natural gas in Sweden has suffered from unstable actor coalitions on different levels, a difficult market situation, and a changeful political context, especially with regard to energy policy. The import status of the fuel and the consequential transnationality of the natural gas infrastructure have also made the process of constructing a pipeline more complex. However, natural gas was introduced in Sweden, showing that when a strong enough actor coalition agreed that there was enough reason to warrant a natural gas introduction and was ready to join this endeavor, a connection could be achieved. This puts into question to what degree general explanations in terms of finance and policy drive energy decisions, and makes a case for showing how these explanations are adapted into their social and historical contexts in sometimes surprising ways. / <p>QC 20130507</p> / The integration of energy markets across system and nation boundaries

In this work, a source term model for estimating the rate of spreading and vaporization of LNG on land and sea is introduced. The model takes into account the composition changes of the boiling mixture, the varying thermodynamic properties due to preferential boiling within the mixture and the effect of boiling on conductive heat transfer. The heat, mass and momentum balance equations are derived for continuous and instantaneous spills and mixture thermodynamic effects are incorporated. A parameter sensitivity analysis was conducted to determine the effect of boiling heat transfer regimes, friction, thermal contact/roughness correction parameter and VLE/mixture thermodynamics on the pool spreading behavior. The aim was to provide a better understanding of these governing phenomena and their relative importance throughout the pool lifetime. The spread model was validated against available experimental data for pool spreading on concrete and sea. The model is solved using Matlab for two continuous and instantaneous spill scenarios and is validated against experimental data on cryogenic pool spreading found in literature.

An exercise in applied Christian ecotheology, this thesis focuses on a community of Lutheran church bodies (ELCA) in North Central Pennsylvania as they grappled with natural gas hydraulic fracturing in the summer of 2012. In the paper, I employ a combination of theological, environmental, historical, and ethnographic research methodologies to ground my analysis of how this synod of Lutherans to date has approached the fracking boom. My primary research question is: How might the Upper Susquehanna Synod of the ELCA--as a representative body of 131 Lutheran churches that are steeped in tradition--use its history, community involvement, theology, and church structure to address an ecological quandary like fracking? I answer this question in four sections, with each chapter focusing on a different thematic sub-question. Though I borrow techniques from the social sciences, I have written this thesis as a narrative, in order to draw the reader into this fascinating community. Instead of separating my literature review from my ethnographic data, I blend the two together in each chapter, weaving together quotes from synod members with secondary source material. Embedded throughout the report are also maps that I have produced using a Geographic Information Systems (GIS) technique to give the story a spatial dimension. Additionally, I use photographs of the synod counties to enhance the reader’s understanding of the region’s ecological and cultural landscapes.

This PhD thesis introduces basic concepts of smart chemical sensors design, which are afterwards applied to a particular application: the analysis of natural gas. The thesis addresses thus two sets of objective, a first set of objectives related to the conceptual design of a smart chemical sensor using smart sensor standards: - The design of an optimal smart chemical sensor architecture - The novel combination in a working prototype of the highly complementary smart sensor standards IEEE-1451 and BS-7986 A second set of objectives is directly related to the selected application. Natural gas quality control. Natural gas is an energy source of major importance in the world energy supply, its quality control is increasingly important due to its origin-dependent properties and the progressive liberalization of the energy market. The objectives related to this application are: - To solve the natural gas quality analysis problem by using a lower cost approach taking advantage of MEMS technology, smart sensor features, and embedded intelligent signal processing. - To select suitable sensing technologies and associated signal processing. An overall goal addressed by the PhD Thesis is in the end the reporting of a working smart sensor prototype implementing all the smart sensor features, MEMS based natural gas analysis and advanced signal processing as a demonstration of a novel low-cost and high speed natural gas analyzer. The thesis covers this research along 7 chapters, introducing the concepts and application in chapters 1 and 2, the objectives in chapter 3, the simulation of a proposed MEMS sensor approach in chapter 4, the description of the advanced signal processing approach adopted in chapter 5, the description of the electronics and engineering of the smart natural gas analyzer prototype in chapter 6, and finally the conclusions of the work in chapter 7. / La tesis introduce conceptos básicos sobre el diseño de sensores químicos inteligentes, en particular presenta los estándares propuestos IEEE-1451 y BS-7986, y elabora una propuesta para el diseño óptimo de dichos sensores químicos inteligentes. Se implementa la propuesta de diseño para una aplicación concreta, el análisis de gas natural. Además de la aplicación de los conceptos sobre sensores químicos inteligentes se pretende además diseñar un analizador compacto, rápido y de bajo coste, para ello se estudia el uso de un microsensor termoeéctrico como sensor principal del analizador. Una vez probada su viabilidad se implementan ambos conceptos (sensores inteligentes y microsensor termoeléctrico) en un prototipo funcional validado en laboratorio. Como resultado se obtiene una propuesta para el diseño de sensores químicos inteligentes basada en estándares, y por otro lado se presenta un nuevo analizador de gas natural, más rápido y compacto que los existentes. Los resultados obtenidos originan diversas publicaciones en revistas así como dos patentes de método y sistema.

Membrane-based acid gas (e.g., CO2) separation, gas dehydration and humidification, as well as solvent dehydration are important to the energy and process industries. Fixed carrier facilitated transport membranes can enhance the permeation without compromising the selectivity. The development of suitable fixed carrier membranes for CO2 and water permeation, and understanding of the transport mechanism were the main objectives of this thesis. Poly(N,N-dimethylaminoethyl methacrylate) (PDMAEMA) composite membranes were developed using microporous polysulfone (PSF) or polyacrylonitrile (PAN) substrates. The PDMAEMA layer was crosslinked with p-xylylene dichloride via quaternization reaction. Fourier transform infrared, scanning electron microscopy, adsorption tests, and contact angle measurements were conducted to analyze the chemical and morphological structure of the membrane. It was shown that the polymer could be formed into thin dense layer on the substrates, while the quaternary and tertiary amino groups in the side chains of PDMAEMA offered a high polarity and hydrophilicity. The solid-liquid interfacial crosslinking of PDMAEMA led to an asymmetric crosslinked network structure, which helped minimize the resistance of the membrane to the mass transport. The interfacially formed membranes were applied to CO2/N2 separation, dehydration of CH4, gas humidification and ethylene glycol dehydration. The membranes showed good permselectivity to CO2 and water. For example, a CO2 permeance of 85 GPU and a CO2/N2 ideal separation factor of 50 were obtained with a PDMAEMA/PSF membrane at 23oC and 0.41 MPa of CO2 feed pressure. At 25oC, the permeance of water vapor through a PDMAEMA/PAN membrane was 5350 GPU and the water vapor/methane selectivity was 4735 when methane was completely saturated with water vapor. On the other hand, the relative humidity of outlet gas was up to 100 % when the membrane was used as a hydrator at 45oC and at a carrier gas flow rate of 1000 sccm. For used for dehydration of ethylene glycol at 30oC, the PDMAEMA/PSF membrane showed a permeation flux of ~1 mol/(m2.h) and a permeate concentration of 99.7 mol% water at 1 mol% water in feed. This work shows that the quaternary and tertiary amino groups can be used as carriers for CO2 transport through the membrane based on the weak acid-base interaction. In the presence of water, water molecules in the membrane tend to form a water "path" or water "bridge" which also help contribute to the mass transport though the membrane. In addition, CO2 molecules can be hydrated to HCO3-, which reaction can be catalyzed by the amino groups, the hydrated CO2 molecules can transport through the water path as well as the amino groups in the membrane. On the other hand, for processes involving water (either vapor or liquid) permeation, the amino groups in the membrane are also helpful because of the hydrogen bonding effects.

The awareness of the effect emissions have on the environment and climate has risen in the last decades. This has caused strict regulations of greenhouse gas emissions. Greenhouse gases cause global warming which may have devastating environmental effects. Most of the fuels commercially available today are fossil fuels. There are two major effects of using fuels with fossil origin; the source will eventually drain and the usage results in an increase of greenhouse gases in the atmosphere. Fuels that are created from a renewable feedstock are often referred to as alternative fuels and under ideal conditions they are greenhouse gas neutral, meaning that the same amount of greenhouse gases is released during combustion as the source of the fuel have absorbed during its growth period. This evaluation method is known as a well-to-wheel analysis which besides emissions also evaluates energy efficiencies during both the production and the combustion phases. By evaluating results of well-to-wheel analyses along with fuel properties and engine concept characteristics, this report presents which driving scenario that is suitable for different powertrain configurations. For example, vehicles operating in high populated areas, as cities, have a driving scenario that includes low velocities and multiple stops while vehicles in low populated areas often travel long distances in higher speeds. This implies that different powertrains are suitable in different regions. By matching favorable properties of a certain powertrain to the properties important to the actual driving scenario this report evolves a fuel infrastructure that is suitable in Sweden.

Membrane-based acid gas (e.g., CO2) separation, gas dehydration and humidification, as well as solvent dehydration are important to the energy and process industries. Fixed carrier facilitated transport membranes can enhance the permeation without compromising the selectivity. The development of suitable fixed carrier membranes for CO2 and water permeation, and understanding of the transport mechanism were the main objectives of this thesis. Poly(N,N-dimethylaminoethyl methacrylate) (PDMAEMA) composite membranes were developed using microporous polysulfone (PSF) or polyacrylonitrile (PAN) substrates. The PDMAEMA layer was crosslinked with p-xylylene dichloride via quaternization reaction. Fourier transform infrared, scanning electron microscopy, adsorption tests, and contact angle measurements were conducted to analyze the chemical and morphological structure of the membrane. It was shown that the polymer could be formed into thin dense layer on the substrates, while the quaternary and tertiary amino groups in the side chains of PDMAEMA offered a high polarity and hydrophilicity. The solid-liquid interfacial crosslinking of PDMAEMA led to an asymmetric crosslinked network structure, which helped minimize the resistance of the membrane to the mass transport. The interfacially formed membranes were applied to CO2/N2 separation, dehydration of CH4, gas humidification and ethylene glycol dehydration. The membranes showed good permselectivity to CO2 and water. For example, a CO2 permeance of 85 GPU and a CO2/N2 ideal separation factor of 50 were obtained with a PDMAEMA/PSF membrane at 23oC and 0.41 MPa of CO2 feed pressure. At 25oC, the permeance of water vapor through a PDMAEMA/PAN membrane was 5350 GPU and the water vapor/methane selectivity was 4735 when methane was completely saturated with water vapor. On the other hand, the relative humidity of outlet gas was up to 100 % when the membrane was used as a hydrator at 45oC and at a carrier gas flow rate of 1000 sccm. For used for dehydration of ethylene glycol at 30oC, the PDMAEMA/PSF membrane showed a permeation flux of ~1 mol/(m2.h) and a permeate concentration of 99.7 mol% water at 1 mol% water in feed. This work shows that the quaternary and tertiary amino groups can be used as carriers for CO2 transport through the membrane based on the weak acid-base interaction. In the presence of water, water molecules in the membrane tend to form a water "path" or water "bridge" which also help contribute to the mass transport though the membrane. In addition, CO2 molecules can be hydrated to HCO3-, which reaction can be catalyzed by the amino groups, the hydrated CO2 molecules can transport through the water path as well as the amino groups in the membrane. On the other hand, for processes involving water (either vapor or liquid) permeation, the amino groups in the membrane are also helpful because of the hydrogen bonding effects.