[pt] Espectroscopia de ressonância plasmônica de superfície (SPR) é uma técnica óptica amplamente utilizada para monitorizar as alterações físicas ou químicas que ocorrem em uma interface metal - dielétrico. A medição simultânea da espessura e do índice de refração de filmes finos orgânicos, adsorvidos ou depositados sobre a superfície plana de um metal, requer duas medições independentes seguindo uma metodologia designada na literatura como método de duas cores ou método de dois meios. Na primeira, as duas medições são realizadas utilizando diferentes comprimentos de onda da radiação eletromagnética interagindo com a amostra. Na segunda, o índice de refração do meio externo (gás, líquido) é alterado entre as duas medições. Enquanto o primeiro método implica no conhecimento da função de dispersão da fase orgânica, o segundo só produz resultados precisos quando as moléculas orgânicas não interagem quimicamente com o fluido externo. Ambos os métodos apresentam dificuldades quando são aplicados à caracterização de materiais luminescentes orgânicos, os quais são na maior parte do tempo altamente reativos à umidade e ao contato com solventes orgânicos. Neste trabalho foi montado um espectrômetro de SPR automatizado. Primeiramente, ele foi testado na caracterização de amostras feitas no laboratório em termos do valor absoluto, e da homogeneidade das constantes ópticas da deposição metálica que suporta a onda de plasma. Nós demonstramos que medições precisas de constantes ópticas permitem a determinação do índice de refração de filmes finos orgânicos luminescentes, evaporados termicamente utilizando o método de substrato com dois metais. Este método, que até onde sabemos é apenas teorizado na literatura, foi aplicado a uma amostra encapsulada com um filme fino de Alq3 comercial. Além disso, a interface metal/Alq3 foi exposta a ar, e a degradação foi monitorada em tempo real, indicando uma diminuição progressiva do ângulo de ressonância da amostra. / [en] Surface Plasmon Resonance Spectroscopy (SPR) is an optical technique widely used to monitor the physical or chemical changes occurring at a metal-dielectric interface. The simultaneous measurement of the thickness and the index of refraction of organic thin films adsorbed or deposited on the metal flat surface require two independent measurements following a methodology commonly named in literature as Two-Colors Method or Two-Medium Method. In the first one, the two measurements are performed using different wavelength of the electromagnetic radiation interacting with the sample. In the second one the index of refraction of the external medium (gas, liquid) is changed between the two measurements.While the first method implies the knowledge of the dispersion function of the organic layer, the second one gives accurate results only when the organic molecules don t interact chemically with the external fluid. Both of these methods present difficulties when applied to the characterization of luminescent organic materials, most of the time highly reactive to humidity and to the contact with organic solvents. In this work an automated SPR spectrometer was assembled and first tested on the characterization of home-made samples in terms of the absolute value and homogeneity of the optical constants of the metal deposition supporting the plasma wave. We demonstrate that accurate measurements of such optical constants allow the determination of the index of refraction of thermally evaporated luminescent organic thin films using a Two-Metal Substrate Method. This method, to our knowledge only theorized up to now in literature, has been applied to an encapsulated sample containing a thin film of commercial Alq3. Further, the degradation of the metal/Alq3 interface exposed to air has been real time monitored indicating a progressive drop in the angle of resonance of the sample.

Neste trabalho são analisados os quatro modos de plasmon, ligados simétrico (Sb) e assimétrico (ab), fuga pelo núcleo (ln) e fuga pela cobertura (lc), que se propagam em uma fibra óptica fracamente guiada envolta por um filme metálico. No filme metálico é depositada uma camada dielétrica extra e acima desta, uma outra denominada cobertura. A análise será desenvolvida para filmes metálicos de prata, paládio e ouro. Esta estrutura é muito útil na confecção de sensores ópticos. / In this work the four Plasmon modes are analyzed, the symmetrical (Sb) and asymmetrical bounded (ab); the core (ln) and covering leaky modes (lc), that propagate in weakly guided optical fibers with a metallic film around that. In the metallic film a layer extra dielectric is deposited and above this, another layer denominated covering. The analysis will be developed for metallic films of the Silver, Palladium and Gold. This structure is very useful to making optical sensors.

Submitted by Renata Lopes (renatasil82@gmail.com) on 2017-10-02T19:31:50Z No. of bitstreams: 1 felipedesouzadelgado.pdf: 2621698 bytes, checksum: f2d2c40acc8fdf80a70c9f39aabc0cc9 (MD5) / Approved for entry into archive by Adriana Oliveira (adriana.oliveira@ufjf.edu.br) on 2017-10-09T19:46:37Z (GMT) No. of bitstreams: 1 felipedesouzadelgado.pdf: 2621698 bytes, checksum: f2d2c40acc8fdf80a70c9f39aabc0cc9 (MD5) / Made available in DSpace on 2017-10-09T19:46:37Z (GMT). No. of bitstreams: 1 felipedesouzadelgado.pdf: 2621698 bytes, checksum: f2d2c40acc8fdf80a70c9f39aabc0cc9 (MD5) Previous issue date: 2017-08-24 / CAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Esta dissertação apresenta a produção de redes de período longo em fibras ópticas por descargas de arcos elétricos e o seu uso em aplicações de sensoriamento de corrente em veículos aéreos não tripulados. Os aspectos teóricos fundamentais para o entendimento das redes de período longo são apresentados. Além disso, discutiu-se os diferentes tipos de acoplamentos de energia que podem ocorrer em uma rede de período longo e também, os mecanismos responsáveis pela formação dessas redes produzidas por descargas de arco elétrico. A fabricação de redes de período longo utilizando a técnica de arco elétrico foi descrita e o comportamento da perda dependente da polarização das redes produzidas foi investigado. Além disso, é apresentado um novo método para a produção de redes de período longo com perda dependente da polarização reduzida. Constatou-se que por meio de alterações no ângulo de incidência das descargas elétricas na fibra óptica em relação à um ponto de referência, é possível promediar os efeitos induzidos pontualmente por cada descarga de arco elétrico e assim, reduzir a perda dependente da polarização intrínseca dessas redes. Por fim, é apresentada a aplicação de uma rede produzida por arco elétrico combinada a um ímã de neodímio, compondo um novo dispositivo de sensoriamento para medir a corrente elétrica exigida pelos motores elétricos de um veículo aéreo não tripulado. / This dissertation presents the fabrication of long-period fiber gratings through electric arc discharges and their application in current sensing in unmanned aerial vehicles. The theoretical aspects of long-period gratings are presented. Besides, we discussed the different types of coupling that could occur in a long-period fiber grating, as well as the mechanisms responsible for the formation of the gratings produced by electric arc discharges. The manufacture process of the long-period gratings using the electric arc technique was described and the behavior of the polarization dependent loss of these gratings was investigated. In addition, a new method for the production of long period gratings with reduced polarization dependent loss is introduced. It has been found that by changing the incidence angle of the electric discharges in the optical fiber in relation to a reference point, it is possible to average the effects induced by each electric arc discharge and, therefore, reducing the intrinsic polarization dependent loss of these gratings. Finally, the application of a grating produced by electric arc combined with a neodymium permanent magnet is presented. This combination allows us to measure the electric current required by a motor of an unmanned aerial vehicle.

[pt] Este trabalho apresenta um sistema de interrogação de sensores a rede de Bragg em fibras ópticas, baseado em reflectometria no domínio do tempo e filtros fixos a rede de Bragg. Utilizando uma fonte de luz pulsada, a posição espectral do sensor é relacionada à razão da intensidade dos pulsos, tornando a detecção independente de variações de intensidade. São abordados aspectos teóricos e experimentais referentes aos princípios de funcionamento desta técnica. Uma vez que a filtragem é feita com redes de Bragg, apenas um circuito de fotodetecção é utilizado e um número reduzido de acopladores/circuladores ópticos é necessário, o sistema possibilita reduzir consideravelmente o custo para a interrogação de um conjunto de sensores. A utilização de apenas um circuito de fotodetecção apresenta a vantagem de manter as mesmas características para todos os pulsos, minimizando influências externas neste circuito como, por exemplo, variações da temperatura ambiente. Foi montada uma bancada de testes para a interrogação de seis sensores. Comparações entre os resultados experimentais e simulados mostram boa concordância. Extrapolações indicam que seria possível interrogar sensores com uma variação espectral de 2 nanômetros, com incertezas menores que 10 picometros, o que é adequado para sensores de temperatura. Análises de interferência entre dois canais adjacentes mostram pouca influência entre eles e são apresentadas opções para diminuir essa interferência. / [en] This work presents a system for the interrogation of fiber- optic Bragg grating sensors based on time domain reflectometry and Bragg grating fixed filters. Using a pulsed light source, the spectral position of the sensor is related to the ratio of two pulses intensities, making detection independent of intensity variations. Theoretical and experimental aspects regarding the working principles of this technique are discussed. Since filtering is accomplished with Bragg grating so that only one photodetection circuit is used and a reduced number of optic couplers/circulators are needed, the system provides a considerable reduction in the cost of interrogation for a set of sensors. Using only one photodetection circuit also has the advantage of maintaining the same characteristics for all pulses, thus minimizing external influences in this circuit, such as variations in the environment temperature. A test stand was assembled for the interrogation of six sensors. Comparisons between experimental and simulated results show a good agreement. Extrapolations indicate that it would be possible to interrogate sensors with a spectral variation of 2 nanometers, with uncertainties lower than 10 pm, which is adequate for temperature sensors. Cross talk analyses between two adjacent channels show small influence between them, and approaches to reduce this interference are presented.

<p>The purpose of this study is to develop a flexible computer tool to predict the power produced by a photovoltaic (PV) panel. The performance of the PV panel is dependent on the incident solar radiation and the cell temperature. The computer tool predicts voltage-current curves, power-voltage curves, and maximum power point values. Five different models are implemented to predict the temperature of the panel, and comparison between the different thermal models is good. A thermal capacitance approach that uses a simple relationship for the forced convection heat transfer coefficient is used to predict the cell temperature. Both the electrical and temperature models are verified through comparisons using PVWatts and validated by comparisons to measured values. The model is flexible in the sense that it can be applied to PV arrays of any size, at any location, and of different cell types. After being verified and validated, the model is used to investigate the effects of cooling on the photovoltaic panel to improve the panel efficiency and increase its power output. Typical results show that for every degree Celsius rise in temperature, the efficiency of the solar panel is reduced by 0.5%. The effect of cooling and the resulting increase in energy production in two different climatic zones are studied and discussed. </p>

<div>In this paper various applications of axial tensile load, bending load, and rolling loading has been applied to a Copper Indium Gallium Diselenide (CIGS) Solar Cell to lean how it would affect the solar cell parameters of: Open circuit voltage (Voc), Short circuit current, (Isc), Maximum power (Pmax), and Efficiency (EFF), and Fill Factor (FF). These Relationships were found for with three different experiments. The first experiment the applies axial tensile stress is to a CIGS solar cell ranging from 0 to 200 psi with various strain rates: 0.0001, 0.001, 0.01, and 0.1 in/sec as well as various relaxation time: 1min, 5min, and 10 min while the performance of solar cell is measured. The results of this gave several trends couple pertaining the Voc . The first is that open circuit voltage increases slightly with increasing stress. The second is the rate of increase (the slope) increases with longer relaxation times. The second set of trend pertains to the Isc. The first is that short circuit current generally is larger with larger stress. The second is there seems to be a general increase in the Isc up to a given threshold of stress. After that threshold the Isc seems to decrease. The threshold stress varies depending on strain rate and relaxation time. The second set of experiments consisted of holding a CIGS solar cell in a fixed curved position while it was in operational use. The radii of the curved cells were: 0.41, 0.20, 0.16, 0.13, 0.11, 0.094, and 0.082 m. The radii were performed for both concave and convex cell curvature. The trends for this show a slight decrease in all cell parameters with decreasing radii, the exception being Voc which is not effecting, the convex curvature causing a slightly faster decrease than the concave. This set of experiments were also processed to find the trends of the single diode model parameters of series resistance (Rs), shunt resistance (Rsh), dark current (I0), and saturation current (IL), which agreed with the experimental results. The second experiment consisted of rolling a CIGS solar cell in tensile (cells towards dowel.) and compression (cells away from dowel) around a dowel to create internal damage. The diameter of the dowels decreased. The dowel diameters were: 2. 1.75, 1.25, 1, 0.75, 0.5, and 0.25 inches. This experiment showed similar trends as the bending one but also had a critical diameter of 1.75 in where beyond that damage much greater. Finally a parametric study was done in COMSOL Multiphysics® to examine how changes in the CIGS material properties of electron mobility (EM), electron life time, (EL), hole mobility 15 (HM), and Hole life time (HL) effect the cell parameters. The trends are of an exponential manner that converges to a given value as the material properties increase. When EL, EM, HL are very small, on the order of 10-4 times smaller than their accepted values, a transient like responses occurs.<br></div>

Recent advances in atomically thin two-dimensional materials have led to various promising technologies such as nanoelectronics, sensing, energy storage, and optoelectronics applications. Graphene with sp2-bonded carbon atoms densely packed in a honeycomb crystal lattice has attracted tremendous interest with excellent electrical, optical, mechanical, and chemical properties. In this work, graphene’s mechanical properties, chemical properties, and piezoelectric properties are explored as graphene is implemented in the automotive electrical distribution system. Graphene is useful in friction reduction, corrosion protection, and piezoelectric energy harvesting cell improvement. Besides graphene, transition metal dichalcogenides (TMDs), which are the metal atoms sandwiched between two chalcogen atoms, have also attracted much attention. Unlike graphene, many TMDs are semiconductors in nature and possess enormous potential to be used as a potential channel material in ultra-scaled field-effect transistors (FETs). In this work, chemical doping strategies are explored for the tunnel FETs applications using different metal phthalocyanines and polyethyleneimines as dopants. TMDs FETs can also be used as a selective NO₂ gas sensor with a polydimethylsiloxane filter and a highly sensitive photo-interfacial gated photodetector application.

Spectrally-based fiber optic sensors are a rapidly maturing technology capable of sensing several environmental parameters in environments that are unfitting to electrical sensors. However, the sensor interrogation systems for this type of sensors are not yet fit to replace conventional sensor systems. They lack the speed, compact size, and usability necessary to move into mainstream test and measurement. The Fiber Sensor Integrated Monitor (FSIM) technology leverages rapid optical components and parallel hardware architecture to move these sensors across the research threshold into greater mainstream use. By dramatically increasing speed, shrinking size, and targeting an interface that can be used in large-scale industrial interrogation systems, spectrally-based fiber optic sensors can now find more widespread use in both research labs and industrial applications. The technology developed in this thesis was demonstrated by producing two advanced interrogators: one that was one half the size of commercially available systems, and one that accelerated live spectral capture by one thousand times – both of which were operated by non-developers with little training.

Sverige har som många länder runt om i världen en åldrande infrastruktur och behovet av underhåll stiger. I en artikel i Svenska Dagbladet från 21/9–2018 redovisar analys- och teknikkonsultföretaget WSP en grov uppskattning att 300 miljarder kronor behöver investeras för att rusta upp existerande infrastruktur. Efter upprustningen skulle det krävas ca 25 miljarder kronor årligen för att utföra löpande tillståndsbedömning och underhåll av Sveriges väg- och järnvägsnät. Idag används inspektioner för att bedöma broars tillstånd. Det finns tre olika inspektionstyper; huvudinspektion, allmäninspektion och särskild inspektion. Structural Health Monitoring (SHM) är en teknik som globalt används mer och mer som en metod vid tillståndsbedömning av broar. SHM siktar mot att i realtid utföra automatisk bedömning av hela konstruktionens och de enskilda skadornas tillstånd. SHM använder sig av sensorer placerade på kritiska positioner för att samla in mätdata som jämförs med i förtid definierade gränsvärden. I Sverige används SHM sparsamt idag där kunskapen ligger på akademisk nivå och det råder en osäkerhet om hur SHM ska implementeras i praktiken. Genom att implementera SHM, kan skador upptäckas i ett tidigt skede och minimeras genom att snabbt utföra reparationer på konstruktionen innan skadorna blivit kritiska. Studien syftar till att producera en rapport som kan användas som en guide för hur SHM kan implementeras samt visa på hur SHM-systemen har implementerats på tidigare projekt. Rapporten skall ge läsaren en helhetsbild över hur tillståndsbedömning går till idag, vilka skador som är vanligt förekommande samt hur SHM kan användas som ett verktyg vid tillståndsbedömning. Rapporten syftar också till att ge en övergripande förklaring på svenska av SHM-tekniken och vad som behövs för implementering. Öppna ostrukturerade intervjuer genomfördes med forskare inom SHM och skador på betongkonstruktioner samt sakkunniga inom tillståndsbedömning. Intervjuerna användes som utgångspunkt för vidare studier av vanligt förekommande skador och SHM-tekniker. I litteraturstudien användes olika vetenskapliga databaser såsom Diva och ScienceDirect, samt KTH:s bibliotek för att få fram tidigare material om betongskador på broar, deras skademekanismer och om SHM-tekniken. Vidare hämtades information från ett antal doktorsavhandlingar, artiklar och tidigare examensarbeten. Genom litteraturstudie och intervjuer med sakkunniga kom studien fram till att armeringskorrosion och sprickor i betongen är skador som är vanligt förekommande i betongbroar. Skadornas skademekanismer beskrivs i rapporten. Studien identifierade tre olika system som kan användas för detektering och övervakning av armeringskorrosion och sprickor, de systemen är akustisk emission, SOFO-system (SOFO är en förkortning för Surveillance d'Ouvrage par Fibers Optics) och MuST-system (MuST är ett kommersiellt namn). Rapporten ger exempel på hur systemen kan användas för detektering och övervakning av skadorna genom att presentera fyra fallstudier där systemen har använts. Två av fallstudierna presenterar hur akustisk emission har implementeras och två av fallstudierna presenterar hur SOFO-systemet har implementerats. Studien kunde inte identifiera någon fallstudie för MuST-systemet och hur systemet har implementerats. Slutsatsen av studien är att SHM kan användas som ett komplement vid tillståndsbedömningar men man kan inte utföra automatiserade tillståndsbedömningar idag. / Like many countries around the world, Sweden has an aging infrastructure and the need for maintenance is increasing. In an article in Svenska Dagbladet from 21 / 9–2018, the analysis and engineering consulting company WSP reports a rough estimate that SEK 300 billion needs to be invested to upgrade existing infrastructure. After the upgrade, it would require approximately SEK 25 billion annually to carry out ongoing condition assessment and maintenance of Sweden's road and railway networks. Today, inspections are used to assess the condition of bridges. There are three types of inspection; main inspection, general inspection and special inspection. Structural Health Monitoring (SHM) is a technology that is globally more used as a method for condition assessment of bridges. SHM aims to perform automatic assessment of the state of the entire construction and individual damages in real time. SHM uses sensors placed at critical positions to collect measurement data compared to pre-defined limit values. In Sweden, SHM is used sparingly today, where knowledge is at an academic level and there is uncertainty about how SHM should be implemented in practice. By implementing SHM, damage can be detected at an early stage and minimized by quickly performing repairs on the design before the damage becomes critical. The study aims to produce a report that can be used as a guide on how SHM can be implemented and show how the SHM systems have been implemented on previous projects. The report should give the reader an overall picture of how condition assessment is performed today, which damages are common and how SHM can be used as a tool when assessing the condition. The report also aims to provide an overall explanation in Swedish of the SHM technology and what is needed for implementation. Open unstructured interviews were conducted with researchers within SHM and damages to concrete structures as well as experts in condition assessment. The interviews were used as a starting point for further studies of commonly occurring damages and SHM techniques. In the literature study, various scientific databases were used, such as Diva and ScienceDirect, as well as KTH's library to obtain earlier material on concrete damage to bridges, its damage mechanisms and about SHM technology. Furthermore, information was obtained from a number of doctoral dissertations, articles and previous degree projects. Through literature study and interviews with experts, the study concluded that reinforcement corrosion and cracks in the concrete are damages that are commonly found in concrete bridges. The damage mechanisms are described in the report. The study identified three different systems that can be used for detection and monitoring of reinforcement corrosion and cracks, those systems are acoustic emission, SOFO system (SOFO is an abbreviation for Surveillance d'Ouvrage pair of Fiber's Optics) and MuST system (MuST is a commercial name). The report gives examples of how the systems can be used for the detection and monitoring of the damages by presenting four case studies where the systems have been used. Two of the case studies present how acoustic emission has been implemented and two of the case studies present how the SOFO-system has been implemented. The study could not identify any case study for the MuST-system and how the system was implemented. The conclusion of the study is that SHM can be used as a supplement to condition assessments but cannot for the time being used for performing automated condition assessments today.

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