In the U.S., clean energy goals and the move towards a clean energy economy are causing the electric power sector to add emerging and innovative renewable energy resources into their generation mix. Electric utilities (EU) face a monumental challenge to create, deliver, and capture value from emerging and disruptive technologies. This study seeks to address the impact of solar photovoltaics on the EU market by investigating the role of business model changes within the domain of urban and rural U.S. electric utility organizations. By integrating the evolving EU business model with the Competing Values Framework (CVF), a new lens is created to assess the changing and evolving business behavior within the EU industry. Furthermore, a predictive and prescriptive tool emerges associated with organizational ambidexterity (OA). Finally, four lessons are presented that will help EU leaders become more anticipatory, adaptable, and responsive in this changing renewable environment.

Residential building sector accounts for significant share of primary energy demand in Sweden. Worldwide, generation from photovoltaic (PV) distributed energy resources is increasing, yet their potential in Sweden has been underdeveloped, in particular due to high system costs. Recent drop in module prices could however trigger more interest in such systems. In this thesis, the financial performance of residential PV plant utilizing the most recent data is carried out. The specific aim is to determine whether private investment into a PV system can be cost-effective. In the analysis, a grid-connected PV microgenerator with nominal power of 5.5 kWp, 34 m2 of arrays and 6 kW inverter is assessed. Expected lifetime of the system is 25 years, where 80% of the electricity output is self-consumed and 20% fed back to the main grid. Discount and escalation rates are utilized to calculate simple payback period, net present value, benefit-cost ratio, cost of conserved energy and internal rate of return (IRR) of the investment. Further, a scenario analysis is worked out to determine the change in the microgenerator’s performance outside of baseline set of parameters. The results are presented both under the default market conditions and with the inclusion of government support mechanisms. The PV plant did not financially perform well under the default conditions. State rebates and tax credit significantly enhanced the results and contributed to the cost-effectiveness of the investment. In the baseline scenario with government support, significant positive results in all the metrics used in the financial appraisal were yielded. The IRR also indicated that loans at various interest rates could be obtained to finance the PV system. The study emphasized the necessity of government support if a faster uptake of distributed PV systems is desired in Sweden. The results of this thesis can be utilized by potential investors (consumers) in their decision-making process, especially when they face an opportunity cost of investment. / COMPLEX - Knowledge Based Climate Mitigation Systems for a Low Carbon Economy, a EU FP7 project (2012-2016)

Nanostructured composites are attracting intense interest for electronic and optoelectronic device applications, specifically as active elements in thin film photovoltaic (PV) device architectures. These systems implement fundamentally different concepts of enhancing energy conversion efficiencies compared to those seen in current commercial devices. This is possible through considerable flexibility in the manipulation of device-relevant properties through control of the interplay between the nanostructure and the optoelectronic response. In the present work, inorganic nanocomposites of semiconductor Ge embedded in transparent conductive indium tin oxide (ITO) as well as Ge in zinc oxide (ZnO) were produced by a single step RF-magnetron sputter deposition process.It is shown that, by controlling the design of the nanocomposites as well as heat treatment conditions, decreases in the physical dimensions of Ge nanophase size provided an effective tuning of the optical absorption and charge transport properties. This effect of changes in the optical properties of nanophase semiconductors with respect to size is known as the quantum confinement effect. Variation in the embedding matrix material between ITO and ZnO with corresponding characterization of optoelectronic properties exhibit notable differences in the presence and evolution of an interfacial oxide within these composites. Further studies of interfacial structures were performed using depth-profiling XPS and Raman spectroscopy, while study of the corresponding electronic effects were performed using room temperature and temperature-dependent Hall Effect. Optical absorption was noted to shift to higher onset energies upon heat treatment with a decrease in the observed Ge domain size, indicating quantum confinement effects within these systems. This contrasts to previous investigations that have involved the introduction of nanoscale Ge into insulating, amorphous oxides. Comparison of these different matrix chemistries highlights the overarching role of interfacial structures on quantum-size characteristics. The opportunity to tune the spectral response of these PV materials, via control of semiconductor phase assembly in the nanocomposite, directly impacts the potential for the use of these materials as sensitizing elements for enhanced solar cell conversion efficiency.

Selectively-transparent and conducting photonic crystals (STCPCs) made of alternating layers of sputtered indium-tin oxide (ITO) and spin-coated silica (SiO2) nanoparticle films have potential applications in micromorph solar cells and building integrated photovoltaics (BIPVs). In this work, theoretical calculations have been performed to show performance enhancement of the micromorph solar cell upon integration of the STCPC an intermediate reflector. Thin semi-transparent hydrogenated amorphous silicon (a-Si:H) solar cells with STCPC rear contacts are demonstrated in proof-of-concept devices. A 10% efficiency increase in a 135nm thick a-Si:H cell on an STCPC reflector with Bragg peak at 620nm was observed, while the transmitted solar irradiance and illuminance are determined to be 295W/m2 and 3480 lux, respectively. The STCPC with proper Bragg peak positioning can boost the a-Si:H cell performance while transmitting photons that can be used as heat and lighting sources in building integrated photovoltaic applications.

Hybrid renewable energy systems (HRES) have proven to be a more stable and feasible source of energy than heir single source counterparts. The benefit of HRES is their ability to balance the stochastic behavior of wind and solar production. As result of this, they have been used as stand-alone systems with great success. Optimization studies in the field have shown optimum sizing of the components in the system to be a key element in order to increase feasibility. This paper focuses on the HRES impact on internal grid design and cost. The goal of the thesis is to create a mathematical function and graph on the internal grid design/cost relation for a virtual site with varying wind speed and solar irradiation. A secondary goal is to analyze how much Photovoltaics (PV) in Megawatt (MW) that can be connected to the internal grid post realization of the wind farm and to performed this analyze on the two specific case projects, Site A (17.25 MW) in Sweden and Site B (51.75 MW) in Italy. By utilizing a case study methodology, a mathematical model was created based on two case projects, both with potential to be a combined Wind-PV hybrid plants provided by the wind developer OX2. Identifiers for the two cases studied in this thesis where removed with respect to OX2’s ongoing projects. Hybrid renewable energy systems is a method of increasing the utilization of a regions RES, the system has an increase in overall power output compared to the single RES alternative. However, the internal grid cost was shown to be 3.85 % more expensive Site A and 5.3 % in Site B. This stood in direct correlation to the HRES in Site A using 8.6 % more cable for its internal grid and 29.7 % more in Site B, this is highly depending (depending on the location of the PV array). Furthermore, the case projects showed that the maximum PV to be connected post realization of the farm without major curtailment would be 11.5% of the wind farms rated power in the case of site A and 67.6 % in the case of Site B. Variations in wind speed and solar irradiation were shown to have some impact on grid cost. However, the results pointed out that grid cost in HRES is to a higher degree affected by total cable length in the internal grid than fluctuation in available energy sources. The extent of increase in cable length, the total grid investment cost rises up to 53.4 % for the two case projects.

The global market for photovoltaics (PV) has increased rapidly: during 2014, 44 times more was installed than in 2004, partly due to a price reduction of 60-70% during the same time period. Economic support schemes that were needed to make PV competitive on the electricity market have gradually decreased and self-consumption of PV electricity is becoming more interesting internationally from an economic perspective. This licentiate thesis investigates self-consumption of residential PV electricity and how more PV power can be allowed in and injected into a distribution grid. A model was developed for PV panels in various orientations and showed a better relative load matching with east-west-oriented compared to south-oriented PV panels. However, the yearly electricity production for the east-west-system decreased, which resulted in less self-consumed electricity. Alternatives for self-consumption of PV electricity and reduced feed-in power in a community of detached houses were investigated. The self-consumption increased more with shared batteries than with individual batteries with identical total storage capacity. A 50% reduction in feed-in power leads to losses below 10% due to PV power curtailment. Methodologies for overvoltage prevention in a distribution grid with a high share of PV power production were developed. Simulations with a case with 42% of the yearly electricity demand from PV showed promising results for preventing overvoltage using centralized battery storage and PV power curtailment. These results show potential for increasing the self-consumption of residential PV electricity with storage and to reduce stress on a distribution grid with storage and power curtailment. Increased self-consumption with storage is however not profitable in Sweden today, and 42% of the electricity from PV is far more than the actual contribution of 0.06% to the total electricity production in Sweden in 2014.

This thesis studies the application of silver nanowire transparent conductors in PbS quantum dot photovoltaics. Silver nanowires were synthesized using a colloidal method and characterized using scanning electron microscopy. Nanowires were deposited on glass substrates by a stamp transfer process to generate a low density continuous network of conductive nanowires. This resulted in a highly conductive and transparent film appropriate for optoelectronic applications. Nanowire synthesis, deposition, and processing were optimised to produce transparent conductors suitable for thin film photovoltaics. These nanowire films were used to fabricate lead sulphide (PbS) colloidal quantum dot solar cells. In this structure, p-type PbS quantum dots form a junction with a n-type ZnO nanoparticle layer. A variety of fabrication and processing treatments were developed in order to reduce short-circuiting of devices and to enhance cell performance. Moderate nanowire density, improved ZnO adherence, slight device aging, and increased PbS film thickness proved to result in the highest quality devices. The champion device developed in this thesis achieved a power conversion efficiency of 2.2%.

This thesis studies quaternary chalcogenide nanocrystals and their photovoltaic applications. A temperature-dependent phase change between two distinct crystallographic phases of stoichiometric Cu₂ZnSnS₄ is investigated through the development of a one pot synthesis method. Characterisation of the Cu₂ZnSnS₄ nanocrystals was performed using absorption spectroscopy, transmission electron microscopy (TEM) and powder X-ray diffraction (XRD). An investigation was conducted into the effects of using hexamethyldisilathiane (a volatile sulphur precursor) in the nucleation of small (<7nm), mono-dispersed and solution-stable quaternary Cu₂ZnSnS₄ nanocrystals. A strategy to synthesize high quality thermodynamically stable kesterite Cu₂ZnSnS₄ nanocrystals is established, which subsequently enabled the systematic study of Cu₂ZnSnS₄ nanocrystal formation mechanisms, using optical characterization, XRD, TEM and Raman spectroscopy. Further studies employed scanning transmission electron microscopy (STEM) energy dispersive x-ray (EDX) mapping to examine the elemental spatial distributions of Cu₂ZnSnS₄ nanocrystals, in order to analyse their compositional uniformity. In addition, the stability of nanocrystals synthesised using alternative ligands is investigated using Fourier transform infrared spectroscopy, without solution based ligand substitution protocol is used to replace aliphatic reaction ligands with short, aromatic pyridine ligands in order to further improve Cu₂ZnSnS₄ colloid stability. A layer-by-layer spin coating method is developed to fabricate a semiconductor heterojunction, using CdS as an n-type window, which is utilised to investigate the photovoltaic properties of Cu₂ZnSnS₄ nanocrystals. Finally, three novel passivation techniques are investigated, in order to optimise the optoelectronic properties of the solar cells to the point where a power conversion efficiency (PCE) of 1.00±0.04% is achieved. Although seemingly modest when compared to the performance of leading devices (PCE>12%) this represents one of the highest obtained for a Cu₂ZnSnS₄ nanocrystal solar cell, fabricated completely under ambient conditions at low temperatures.

Title: Legislation of renewable energy sources and their use Abstract The presented thesis deals with issues of legal regulation of renewable energy sources with target on legal regulation of system of support in the Czech Republic. The thesis contains the overview of documents and instruments from international enviroment. As a result of the Czech Republic membership in the European Union the thesis presents instruments of union legislation which due to integration of EU member states legislation and due to marking out obligatory goals aims to opened unified and liberal energy market. The thesis describes historical development of this phenomenon from partial legislation to complex and sophisticated legislation and artificially formed systems of support including and puts them into context with social economic aspects of pursued period of time. Due to comparative method the thesis brings not only comparation of legislation in the course of time in Czech and European background but also evaluate them and try to estimate progress and find possible solution. One of the thesis targets is to provide the comprehensive view on legislation of renewable energy sources from businessmen points of view and put this relationship into context with institute of environment protection.

La production d’électricité photovoltaïque a connu une forte croissance ces dernières années, mais présente encore des coûts de production élevés comparés aux autres sources d’énergie. Le silicium monocristallin est fréquemment utilisé comme couche active dans les cellules photovoltaïques, et la matière première silicium représente une part importante du prix final de la cellule. La couche de silicium est classiquement obtenue par sciage d’un lingot, entraînant une perte de matière première de l’épaisseur du trait de scie. Une technique innovante de détachement des films minces de silicium consiste à implanter de l’hydrogène à haute énergie dans le silicium puis à appliquer un traitement thermique pour détacher la couche de silicium implantée. Les pertes dues au trait de scie sont ainsi éliminées. Ce type de procédé est couramment utilisé en microélectronique avec des énergies de quelques centaines de keV pour le report de couches minces d’un substrat à un autre. Ce travail de thèse est l’un des premiers à étudier l’extension de ce procédé à des énergies comprises entre 1 et 3 MeV pour le détachement de films de 15 à 100 μm d’épaisseur. L’efficacité du détachement dépend fortement de l’orientation du silicium utilisé. Les caractérisations réalisées après implantation et à différents stades du traitement thermique permettent de mieux comprendre le mécanisme du détachement et de proposer un modèle théorique expliquant les différences d’efficacité du détachement constatées en fonction de l’orientation du silicium. Des essais exploratoires suggèrent plusieurs pistes pour l’optimisation des conditions d’implantation et de fracture, dans le but d’améliorer l’efficacité du détachement. / Photovoltaic power generation strongly increased in the last decades, but the cost of PV-generated electricity must be further reduced to be competitive. Monocrystalline silicon is widely used as the active layer, and silicon raw materials account for a large percentage of the price of PV-cells. Ingot sawing is commonly used to separate silicon layer, resulting in significant kerf-loss. An innovative kerf-free technique to separate a thin silicon layer consists of high energy implantation of hydrogen in silicon and subsequent annealing. Such a process is commonly used in the field of microelectronics to transfer thin layers from a substrate to another and involves low implantation energy from a few ten to few hundred of keV. In this work, we propose to extend this process to higher energy in the range 1-3 MeV, in order to separate free-standing layer with thickness in the range 15-100μm. Separation efficiency strongly depends on silicon orientation. Characterizations of implanted silicon were performed after implantation and at several stages of the heat treatment to investigate the separation mechanisms. A theoretical model was proposed to explain the effect of silicon orientation on the separation efficiency. Optimizations of implantation conditions and heat treatment parameters are also suggested in order to improve the yield of the separation process.