In der vorliegenden Arbeit wurde mit Hilfe von Gefäßversuchen der Transfer von ausgewählten organischen (m-Kresol, Simazin, Lindan, Anthracen, Galaxolid) und anorganischen Umweltschadstoffen (As, Cd, Pb, Cr, Zn, Ni) aus dotiertem Substrat in Nutzpflanzen (Tomaten, Paprika) untersucht. Zum besseren Verständnis des Schadstofftransfers der organischen Verbindungen und als Möglichkeit einer kosten- und zeitsparenden Alternative zu den herkömmlichen Untersuchungsverfahren, wurden ergänzend in vivo – Experimente durchgeführt. Weitere Schwerpunkte der Arbeit waren Untersuchungen zur Schadstoffaufnahme durch Pflanzen in Abhängigkeit von der Substratkonzentration sowie der Vegetationsdauer. Ein weiterer Schwerpunkt der Arbeiten waren Studien über mögliche Einflüsse eines neuartigen Bodenverbesserungsmaterials auf die Schadstoffmobilität und Bioverfügbarkeit der oben genannten potentiellen Schadstoffe sowie die damit verbundene mögliche Aufnahme durch die Untersuchungspflanzen.

This thesis describes novel reaction protocols for the synthesis of diaryliodonium salts and also provides an insight to the mechanism of α-arylation of carbonyl compounds with diaryliodonium salts.  The first chapter gives a general introduction to the field of hypervalent iodine chemistry, mainly focusing on recent developments and applications of diaryliodonium salts. Chapter two describes the synthesis of electron-rich to electron-poor diaryliodonium triflates, in moderate to excellent yields from a range of arenes and iodoarenes. In chapter three, it is described that molecular iodine can be used together with arenes in a direct one-pot, three-step synthesis of symmetric diaryliodonium triflates. A large scale synthesis of bis(4-tert-butylphenyl)iodonium triflate is also described, controlled and verified by an external research group, further demonstrating the reliability of this methodology. The fourth chapter describes the development of a sequential one-pot synthesis of diaryliodonium salts from aryl iodides and boronic acids, furnishing symmetric and unsymmetric, electron-rich to electron-poor diaryliodonium tetrafluoroborates in moderate to excellent yields. This method was developed to overcome the regiochemical limitations imposed by the reaction mechanism in the protocols described in the preceding chapters. Chapter five describes a one-pot synthesis of heteroaromatic iodonium salts under similar conditions described in chapter two. The final chapter describes the reaction of enolates with chiral diaryliodonium salts or together with a phase transfer catalyst yielding racemic products. DFT calculations were performed, which revealed a low lying energy transition state (TS) between intermediates, which is believed to be responsible for the lack of selectivity observed in the experimental work. It is also proposed that a [2,3] rearrangement is preferred over a [1,2] rearrangement in the α-arylation of carbonyl compounds. The synthetic methodology described in this thesis is the most generally applicable, efficient and high-yielding to date for the synthesis of diaryliodonium salts, making these reagents readily available for various applications in synthesis.

Made available in DSpace on 2014-12-17T14:07:18Z (GMT). No. of bitstreams: 1 GuillermoVEC_TESE.pdf: 6213025 bytes, checksum: d3b714c7e267456f45d8fb37e52fccfd (MD5) Previous issue date: 2013-04-19 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / Brazil has vast amounts of hydric resources, whose quality has been deteriorating due to pollutant dumping. Household waste disposal is one of the main sources of water pollution, stimulating bacteria proliferation and introducing microorganisms, including those from fecal matter. Conventional water disinfection methods are a solution, but on the downside, they lead to the formation byproducts hazardous to human health. In this study, aiming to develop bactericidal filters for the disinfection of drinking water; silver nanoparticles were deposited on alumina foams through three routes: sputtering DC, dip coating and in situ chemical reduction of silver nitrate. The depositions were characterized through X-ray diffraction, scanning electron microscopy and EDS element mapping. The influence of the depositions on permeability and mechanical properties of the ceramic foams was assessed and, in sequence, a preliminary antibacterial efficiency analysis was carried out. Characterization results indicate that the chemical reduction routes were efficient in depositing homogeneously distributed silver particles and that the concentration of the metallic precursor salt affects size and morphology of the particles. The antibacterial efficiency analysis indicates that the chemical reduction filters have potential for water disinfection / O Brasil apresenta vastos recursos h?dricos cuja qualidade tem deteriorado como consequ?ncia do despejo de poluentes. A descarga de res?duos domiciliares ? uma das principais fontes de polui??o dos mananciais, estimulando a prolifera??o de bact?rias e inserindo outros microrganismos, incluindo aqueles oriundos de mat?ria fecal. O tratamento ou purifica??o da ?gua residencial se apresenta como solu??o, entretanto os m?todos tradicionais de desinfec??o da ?gua t?m sido contestados por conduzirem ? forma??o de subst?ncias prejudiciais ? sa?de humana. No presente estudo, com o intuito de desenvolver filtros com a??o bactericida para desinfec??o de ?gua para consumo humano, nanopart?culas de prata foram depositadas em s?lidos celulares cer?micos de alumina atrav?s de tr?s rotas distintas: sputtering DC, dip coating e redu??o qu?mica in loco de nitrato de prata. As deposi??es foram caracterizadas por difra??o de raios-X (DRX), microscopia eletr?nica de varredura (MEV) e mapeamento por espectrometria por dispers?o de energia de raios-X (EDS). A influ?ncia da deposi??o sobre as propriedades mec?nicas e de permeabilidade do s?lido celular cer?mico foi avaliada, sendo posteriormente executada uma an?lise preliminar de efici?ncia antibacteriana. Os resultados da caracteriza??o indicam que as rotas via redu??o qu?mica in loco de nitrato de prata foram eficientes na deposi??o de part?culas homogeneamente distribu?das e que a concentra??o do precursor met?lico afeta o tamanho e a morfologia das part?culas. A an?lise de efici?ncia antibacteriana indica que os filtros confeccionados por redu??o qu?mica apresentam potencial para a desinfec??o de ?gua para consumo humano

Made available in DSpace on 2014-12-17T14:09:13Z (GMT). No. of bitstreams: 1 AlvaroBN_TESE.pdf: 1929903 bytes, checksum: 92f40cf4d3b6ab5536ad5ad3d2aa192a (MD5) Previous issue date: 2012-02-29 / The present study provides a methodology that gives a predictive character the computer simulations based on detailed models of the geometry of a porous medium. We using the software FLUENT to investigate the flow of a viscous Newtonian fluid through a random fractal medium which simplifies a two-dimensional disordered porous medium representing a petroleum reservoir. This fractal model is formed by obstacles of various sizes, whose size distribution function follows a power law where exponent is defined as the fractal dimension of fractionation Dff of the model characterizing the process of fragmentation these obstacles. They are randomly disposed in a rectangular channel. The modeling process incorporates modern concepts, scaling laws, to analyze the influence of heterogeneity found in the fields of the porosity and of the permeability in such a way as to characterize the medium in terms of their fractal properties. This procedure allows numerically analyze the measurements of permeability k and the drag coefficient Cd proposed relationships, like power law, for these properties on various modeling schemes. The purpose of this research is to study the variability provided by these heterogeneities where the velocity field and other details of viscous fluid dynamics are obtained by solving numerically the continuity and Navier-Stokes equations at pore level and observe how the fractal dimension of fractionation of the model can affect their hydrodynamic properties. This study were considered two classes of models, models with constant porosity, MPC, and models with varying porosity, MPV. The results have allowed us to find numerical relationship between the permeability, drag coefficient and the fractal dimension of fractionation of the medium. Based on these numerical results we have proposed scaling relations and algebraic expressions involving the relevant parameters of the phenomenon. In this study analytical equations were determined for Dff depending on the geometrical parameters of the models. We also found a relation between the permeability and the drag coefficient which is inversely proportional to one another. As for the difference in behavior it is most striking in the classes of models MPV. That is, the fact that the porosity vary in these models is an additional factor that plays a significant role in flow analysis. Finally, the results proved satisfactory and consistent, which demonstrates the effectiveness of the referred methodology for all applications analyzed in this study. / O presente trabalho proporciona uma metodologia que d? um car?ter preditivo ?s simula??es computacionais baseadas em modelos detalhados da geometria porosa de um meio. N?s utilizando o software FLUENT para investigar o escoamento de um fluido newtoniano viscoso atrav?s de um meio fractal aleat?rio que simplifica um meio poroso desordenado bidimensional representando um reservat?rio de petr?leo. Este modelo fractal ? formado por obst?culos de diversos tamanhos, cuja fun??o de distribui??o segue uma lei de pot?ncia, onde o expoente ? definido como sendo a dimens?o fractal de fracionamento Dff do modelo e caracteriza o processo de fragmenta??o desses obst?culos. Eles s?o aleatoriamente dispostos em um canal retangular. O processo de modelagem incorpora conceitos modernos, leis de escala, para analisar a influ?ncia das heterogeneidades encontradas nos campos da porosidade e da permeabilidade de tal maneira que se possa caracterizar o meio em fun??o de suas propriedades fractais. Este procedimento permite analisar numericamente as medidas da permeabilidade k e do coeficiente de arrasto Cd propondo rela??es, tipo lei de pot?ncia, para essas propriedades sobre v?rios esquemas de modelagem. O prop?sito desta pesquisa ? estudar a variabilidade proporcionada por estas heterogeneidades onde o campo de velocidade e outros detalhes da din?mica dos fluidos viscosos s?o obtidos resolvendo numericamente as equa??es da continuidade e de Navier-Stokes no n?vel de poros e observar como a dimens?o fractal de fracionamento do modelo pode afetar as suas propriedades hidrodin?micas. Neste estudo foram consideradas duas classes de modelos, modelos com porosidade constante, MPC, e modelos com porosidade vari?vel, MPV. Os resultados permitiram-nos encontrar rela??es num?ricas entre a permeabilidade, coeficiente de arrasto e os par?metros geom?tricos do modelo. Com base nestes resultados num?ricos propusemos rela??es de escala envolvendo os par?metros relevantes do fen?meno. Nesta pesquisa foram determinadas equa??es anal?ticas para Dff em fun??o dos par?metros geom?tricos dos modelos. Constatamos tamb?m uma rela??o entre a permeabilidade e o coeficiente de arrasto onde uma ? inversamente proporcional ? outra. Quanto ? diferen?a de comportamento ela ? mais marcante nas classes de modelos MPV. Isto ?, o fato da porosidade variar nestes modelos constitui um fator adicional que desempenha um papel significativo na an?lise de fluxo. Finalmente, os resultados encontrados se mostraram consistentes e satisfat?rios, o que demonstra a efic?cia da referida metodologia para todas as aplica??es analisadas nesta pesquisa.

Made available in DSpace on 2014-12-17T14:17:54Z (GMT). No. of bitstreams: 1 MirellaCSA_DISSERT.pdf: 648930 bytes, checksum: 06627ea14cbf2543775d82cecd4ee6ec (MD5) Previous issue date: 2014-03-21 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / Mimosa caesalpiniaefolia Benth. is a forest species of the Mimosaceae family, recommended for recovery of degraded areas. The evaluation of vigor by biochemical tests have been an important tool in the control of seed quality programs, and the electrical conductivity and potassium leaching the most efficient in the verifying the physiological potential. The objective, therefore, to adjust the methodology of the electrical conductivity test for seeds of M. caesalpiniaefolia, for then compare the efficiency of this test with the potassium in the evaluation of seed vigor of different lots of seeds M. caesalpiniaefolia. To test the adequacy of the electrical conductivity were used different combinations of temperatures , 25 ?C and 30 ?C, number of seeds , 25 and 50, periods of imbibition , 4 , 8 , 12 , 16 and 24 hours , and volumes deionized water, 50 mL and 75mL. For potassium leaching test, which was conducted from the results achieved by the methodology of the adequacy of the electrical conductivity test, to compare the efficiency of both tests , in the classification of seeds at different levels of vigor, and the period 4 hours also evaluated because the potassium leaching test can be more efficient in the shortest time . The best combination obtained in experiment of electrical conductivity is 25 seeds soaked in 50 mL deionized or distilled water for 8 hours at a temperature of 30 ? C. Data were subjected to analysis of variance, the means were compared with each other by F tests and Tukey at 5 % probability, and when necessary polynomial regression analysis was performed. The electrical conductivity test performed at period eight hour proved to be more efficient in the separation of seed lots M. caesalpiniaefolia at different levels of vigor compared to the potassium test / Mimosa caesalpiniaefolia Benth. ? uma esp?cie florestal pertencente ? fam?lia Mimosaceae, recomendada para recomposi??o de ?reas degradadas. A avalia??o do vigor por meio de testes bioqu?micos tem sido importante ferramenta dentro de programas de controle de qualidade de sementes, sendo os testes de condutividade el?trica e lixivia??o de pot?ssio um dos mais utilizados na verifica??o do potencial fisiol?gico. Objetivou-se, portanto, adequar a metodologia do teste de condutividade el?trica para sementes de M. caesalpiniaefolia, para ent?o comparar a efici?ncia deste teste com o de lixivia??o de pot?ssio na avalia??o de vigor das sementes dos diferentes lotes de M. caesalpiniaefolia. Para o teste de adequa??o da condutividade el?trica foram utilizadas diferentes combina??es de temperaturas, 25 e 30 ?C, de n?mero de sementes, 25 e 50, de per?odos de tempo de embebi??o, 4, 8, 12, 16 e 24 horas, e de volumes de ?gua deionizada, 50 e 75 mL. Para o teste de lixivia??o de pot?ssio, que foi realizado a partir dos resultados alcan?ados pela metodologia da adequa??o do teste de condutividade el?trica, p?de-se comparar a efici?ncia de ambos os testes, na classifica??o dos lotes das sementes em diferentes n?veis de vigor, sendo o per?odo de 4 horas tamb?m avaliado devido o teste de lixivia??o de pot?ssio poder ser mais eficiente em menor espa?o de tempo. A melhor combina??o obtida no experimento de adequa??o da condutividade el?trica ? a combina??o de 25 sementes embebidas em 50 mL de ?gua deionizada durante 8 horas a uma temperatura de 30 ?C. Os dados foram submetidos ? an?lise de vari?ncia, as m?dias comparadas entre si pelos testes F e de Tukey a 5% de probabilidade, e quando necess?rio foi realizada an?lise de regress?o polinomial. O teste de condutividade el?trica realizado no per?odo de oito horas mostra ser mais eficiente na separa??o de lotes de sementes de M. caesalpiniaefolia em diferentes n?veis de vigor comparativamente ao teste de lixivia??o de pot?ssio

Made available in DSpace on 2014-12-17T14:55:43Z (GMT). No. of bitstreams: 1 EricoCB_DISSERT.pdf: 1960043 bytes, checksum: 7c0ebefa8d09683721a890c3c7d00bbb (MD5) Previous issue date: 2010-03-26 / The Methods for compensation of harmonic currents and voltages have been widely used since these methods allow to reduce to acceptable levels the harmonic distortion in the voltages or currents in a power system, and also compensate reactive. The reduction of harmonics and reactive contributes to the reduction of losses in transmission lines and electrical machinery, increasing the power factor, reduce the occurrence of overvoltage and overcurrent. The active power filter is the most efficient method for compensation of harmonic currents and voltages. The active power filter is necessary to use current and voltage controllers loop. Conventionally, the current and voltage control loop of active filter has been done by proportional controllers integrative. This work, investigated the use of a robust adaptive control technique on the shunt active power filter current and voltage control loop to increase robustness and improve the performance of active filter to compensate for harmonics. The proposed control scheme is based on a combination of techniques for adaptive control pole placement and variable structure. The advantages of the proposed method over conventional ones are: lower total harmonic distortion, more flexibility, adaptability and robustness to the system. Moreover, the proposed control scheme improves the performance and improves the transient of active filter. The validation of the proposed technique was verified initially by a simulation program implemented in C++ language and then experimental results were obtained using a prototype three-phase active filter of 1 kVA / Os m?todos para compensa??o de correntes e tens?es harm?nicas v?m sendo bastante utilizados, visto que esses m?todos permitem reduzir a n?veis aceit?veis as distor??es harm?nicas nas tens?es ou correntes em um sistema el?trico de pot?ncia, e ainda, compensar reativos. A redu??o de harm?nicas e reativos contribuem para: a diminui??o das perdas nas linhas de transmiss?o e nas m?quinas el?tricas, o aumento do fator de pot?ncia e a redu??o de ocorr?ncias de sobretens?es e sobrecorrentes. O filtro ativo de pot?ncia ? o m?todo mais eficiente para compensa??o de correntes e tens?es harm?nicas. No filtro ativo de pot?ncia ? necess?ria a utiliza??o de controladores para as malhas de corrente e tens?o. Convencionalmente, o controle dessas malhas tem sido feito por controladores proporcionais integrativos. Neste trabalho, ? investigado o uso de uma t?cnica de controle adaptativo robusto nas malha de corrente e tens?o, do filtro ativo de pot?ncia em paralelo trif?sico, para aumentar a robustez e melhorar o desempenho desse filtro ativo na compensa??o de harm?nicos. A t?cnica de controle proposta ? baseada na combina??o das t?cnicas de controle adaptativo por posicionamento de p?los e de estrutura vari?vel. As vantagens do m?todo proposto sobre os convencionais s?o: menor taxa de distor??o harm?nica, maior flexibilidade, capacidade de adapta??o e robustez para o sistema. Al?m disso, a t?cnica de controle proposta aumenta o desempenho e melhora o transit?rio do filtro ativo. A valida??o da t?cnica proposta foi verificada inicialmente atrav?s de um programa de simula??o implementado em linguagem C ++ e em seguida foram obtidos resultados experimentais usando um prot?tipo de um filtro ativo trif?sico de 1 kVA

Made available in DSpace on 2014-12-17T14:55:52Z (GMT). No. of bitstreams: 1 BezalielASP_DISSERT.pdf: 2307069 bytes, checksum: aa5ddc5e2ae2722d27d66e85a1e511f1 (MD5) Previous issue date: 2011-08-03 / This work develops a methodology for defining the maximum active power being injected into predefined nodes in the studied distribution networks, considering the possibility of multiple accesses of generating units. The definition of these maximum values is obtained from an optimization study, in which further losses should not exceed those of the base case, i.e., without the presence of distributed generation. The restrictions on the loading of the branches and voltages of the system are respected. To face the problem it is proposed an algorithm, which is based on the numerical method called particle swarm optimization, applied to the study of AC conventional load flow and optimal load flow for maximizing the penetration of distributed generation. Alternatively, the Newton-Raphson method was incorporated to resolution of the load flow. The computer program is performed with the SCILAB software. The proposed algorithm is tested with the data from the IEEE network with 14 nodes and from another network, this one from the Rio Grande do Norte State, at a high voltage (69 kV), with 25 nodes. The algorithm defines allowed values of nominal active power of distributed generation, in percentage terms relative to the demand of the network, from reference values / Neste trabalho, prop?e-se uma metodologia para defini??o dos valores m?ximos de pot?ncia ativa a serem injetados em barras pr?-definidas das redes de distribui??o estudadas, considerando a possibilidade de m?ltiplos acessos de unidades geradoras. A defini??o desses valores m?ximos se obt?m a partir de um estudo de otimiza??o, no qual as novas perdas n?o superam as do caso base, ou seja, sem a presen?a da gera??o distribu?da. No estudo atendem-se as restri??es de carregamentos nos ramos e tens?es do sistema. Para tratar o problema, prop?e-se um algoritmo baseado no m?todo num?rico de otimiza??o nuvem de part?culas, ou particle swarm optimization PSO, aplicado ao estudo de fluxo de carga convencional CA e ao fluxo de carga ?timo para maximiza??o da penetra??o da gera??o distribu?da. Tamb?m se incorporou o m?todo de Newton-Raphson, como alternativa, para a resolu??o do fluxo de carga. Realiza-se a programa??o computacional no software SCILAB. Testa-se o algoritmo proposto com os dados da rede IEEE-14 barras e de uma rede de distribui??o em alta tens?o (69 kV) do Estado do Rio Grande do Norte, com 25 barras. O algoritmo determina valores permitidos de pot?ncia ativa nominal de gera??o distribu?da, em termos percentuais relativos ? demanda da rede, a partir de valores de refer?ncia

Made available in DSpace on 2014-12-17T14:56:12Z (GMT). No. of bitstreams: 1 SuelioFC_DISSERT.pdf: 1266723 bytes, checksum: 8001a23164a7a48663a60001950fc3e0 (MD5) Previous issue date: 2013-02-01 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / The stability of synchronous generators connected to power grid has been the object of study and research for years. The interest in this matter is justified by the fact that much of the electricity produced worldwide is obtained with the use of synchronous generators. In this respect, studies have been proposed using conventional and unconventional control techniques such as fuzzy logic, neural networks, and adaptive controllers to increase the stabilitymargin of the systemduring sudden failures and transient disturbances. Thismaster thesis presents a robust unconventional control strategy for maintaining the stability of power systems and regulation of output voltage of synchronous generators connected to the grid. The proposed control strategy comprises the integration of a sliding surface with a linear controller. This control structure is designed to prevent the power system losing synchronism after a sudden failure and regulation of the terminal voltage of the generator after the fault. The feasibility of the proposed control strategy was experimentally tested in a salient pole synchronous generator of 5 kVA in a laboratory structure / A estabilidade de geradores s?ncronos conectados a rede el?trica tem sido objeto de estudo e investiga??es durante anos. O interesse por este assunto ? justificado pelo fato de grande parte da energia el?trica produzida no mundo ser obtida com a utiliza??o de geradores s?ncronos. Nesse aspecto, muitos trabalhos t?m sido propostos utilizando t?cnicas de controle convencional e n?o convencional como l?gica fuzzy, redes neurais e controladores adaptativos visando aumentar a margem de estabilidade do sistema quando ele est? sujeito a falhas s?bitas e dist?rbios transit?rios. Este trabalho apresenta uma estrat?gia de controle robusta n?o-convencional para a manuten??o da estabilidade dos sistemas de pot?ncia e regula??o da tens?o de sa?da de geradores s?ncronos conectados ? rede el?trica. A estrat?gia de controle utilizada ? composta pela integra??o de uma superf?cie deslizante com um controlador linear. Esta estrutura de controle contribui para a preven??o dos sistemas de pot?ncia de perder o sincronismo ap?s uma falha s?bita e regula??o da tens?o terminal do gerador ap?s a falta. A viabilidade da estrat?gia de controle proposta foi testada experimentalmente em um gerador s?ncrono de p?los salientes de 5 kVA em uma estrutura de laborat?rio

Made available in DSpace on 2014-12-17T14:56:13Z (GMT). No. of bitstreams: 1 CecilioMSN_DISSERT.pdf: 1132732 bytes, checksum: 95ce32ef2cdf325116d25b76e2b1858a (MD5) Previous issue date: 2013-07-05 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / The power system stabilizers are used to suppress low-frequency electromechanical oscillations and improve the synchronous generator stability limits. This master thesis proposes a wavelet-based power system stabilizer, composed of a new methodology for extraction and compensation of electromechanical oscillations in electrical power systems based on the scaling coefficient energy of the maximal overlap discrete wavelet transform in order to reduce the effects of delay and attenuation of conventional power system stabilizers. Moreover, the wavelet coefficient energy is used for electric oscillation detection and triggering the power system stabilizer only in fault situations. The performance of the proposed power system stabilizer was assessed with experimental results and comparison with the conventional power system stabilizer. Furthermore, the effects of the mother wavelet were also evaluated in this work / Os estabilizadores de sistemas de pot?ncia s?o empregados para suprimir oscila??es eletromec?nicas, de baixa frequ?ncia, e estender os limites de estabilidade de geradores s?ncronos. Prop?e-se nesta disserta??o de mestrado um estabilizador de sistema de pot?ncia baseado nas wavelets, composta por uma novametodologia para extra??o e compensa??o de oscila??es eletromec?nicas em sistemas el?tricos de pot?ncia baseada nas energias dos coeficientes de aproxima??o da transformada wavelet discreta redundante, com o objetivo de reduzir os efeitos de atraso e atenua??es dos estabilizadores de sistemas de pot?ncia convencionais. Por outro lado, as energias dos coeficientes wavelet s?o utilizadas para detec??o das oscila??es el?tricas e habilita??o do estabilizador de sistema de pot?ncia proposto apenas nas situa??es de falta. A efic?cia do desempenho do estabilizador de sistema de pot?ncia proposto foi comprovada por meio de resultados experimentais, cujo desempenho foi comparado com o desempenho do estabilizador de sistema de pot?ncia convencional. Al?m disso, os efeitos das wavelets m?es tamb?m foram avaliados

Made available in DSpace on 2014-12-17T15:03:26Z (GMT). No. of bitstreams: 1 SelmaTBS_DISSERT.pdf: 3810080 bytes, checksum: 8b739c6a2157b745d52a0808728726c9 (MD5) Previous issue date: 2011-06-27 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / The detention and infiltration ponds of urban drainage system has function to protect the population from undesirable effects of floods. In general these ponds are not completly used and it potential is wasted. As it are disseminated at different places at cities it can reduce costs with water transport and permit water preservation of best quality. Some it utilities includes use in green areas irrigation, industrial among than cooling towers and boiler, soil compaction, cleaning urban road, pisciculture and fire fighting system. The quality these water is influenced by anauthorized sewage in the drainage system. This study was performed in six detention and infiltration ponds at drainage system of Natal, which aim was to verify the non-portable use these ponds on urban environment. As indirect aim would to incentive the water utilization these ponds as a water source to another uses in urban environment. These ponds represents the characteristics of detention and infiltration of Natal city and consequently of Brazil. As the water quality, the ponds presents following characteristics: three has apparently good quality, other showed intermediate condition and two had water polluted. Were performed twenty sample in each ponds and the following parameters assessed: pH, temperature, dissolved oxygen, turbidity, electrical conductivity, coliform thermotolerant, ammonia, organic nitrogen, TKN, nitrate, total phosphorus and alkalinity, bicarbonate, chloride, total hardness, calcium and magnesium hardness, total solids, TSS, TDS, COD and SAR?. To utilization on pisciculture we recommend use in ponds which presents the best quality. Only one pond presented higher pollutants and it not being appropriated for use in cooling tower. The content of solids suspension restricted the water use in all ponds in boilers. As water use in soil compaction, cleaning urban road and fire fighting system the water from these ponds are not appropriated. However, the recommended limits from literature are to domestic sewage, due to this, the parameters are restrictive to diminish the sanitary risk that could be offered with it utilization. The infiltration velocity of water these assessed ponds restrict a moderato use, however the effects are potentiated only in soil less sandy, which not occur in Natal. It is recommend the unrestricted irrigation utilization in ponds with best quality of water, and a restricted irrigation to ponds with worst quality of water. As load of pollutants, it is recommended a complementary treatment in those ponds whit higher load to diminish sanitary risks. In only one pond was found one helminth eggs and due to the convention formula of results, it was found for all ponds less than 1 helminth/liter eggs. / As lagoas de deten??o e infiltra??o do sistema de drenagem urbana geralmente possuem a fun??o de proteger a popula??o contra os efeitos indesej?veis de enchentes. Geralmente as ?guas de tais lagoas n?o s?o utilizadas e o seu potencial ? desperdi?ado. Por estarem disseminadas nas cidades pode-se reduzir os custos com transporte de ?gua, al?m de permitir a preserva??o de ?guas de melhor qualidade. Alguns dos poss?veis usos s?o irriga??o de ?reas verdes, uso em caldeiras, torres de resfriamento, e outros usos industriais, na compacta??o do solo, limpeza de vias p?blicas, na piscicultura, em sistemas de combate a inc?ndio, etc. A qualidade destas ?guas sofre influ?ncia de lan?amentos indevidos de esgotos sanit?rios na rede de drenagem. O estudo foi realizado em seis lagoas de deten??o e infiltra??o do sistema de drenagem de Natal, com o objetivo de verificar as condi??es de uso n?o pot?vel de suas ?guas no meio urbano. Indiretamente tamb?m objetiva incentivar a utiliza??o das ?guas destas lagoas como uma fonte de ?gua com potenciais de outros usos no meio urbano. As lagoas s?o representativas das caracter?sticas de lagoas de deten??o e infiltra??o que est?o disseminadas em Natal, assim como no Brasil. As lagoas apresentaram as seguintes similaridades: tr?s delas apresentaram aparentemente boa qualidade de suas ?guas, outra lagoa apresentou uma condi??o de qualidade intermedi?ria, e outras duas lagoas apresentam ?guas polu?das. Foram realizadas vinte coletas em cada lagoa de deten??o e infiltra??o. Os par?metros analisados foram: pH, temperatura, oxig?nio dissolvido, turbidez, condutividade el?trica, coliformes termotolerantes, nitrog?nio amoniacal, nitrog?nio org?nico, NTK, nitrato, f?sforo total, alcalinidade total, bicarbonatos, cloretos, dureza total, dureza de c?lcio, dureza de magn?sio, s?lidos totais, SST, SDT, DQO e RAS?. Para a utiliza??o em piscicultura recomenda-se o uso das ?guas das lagoas que apresentaram as melhores qualidades. Em torres de resfriamento apenas a ?gua de uma das lagoas, a que apresentou a maior carga de poluentes, n?o ? adequada. O teor de s?lidos em suspens?o restringiu o uso das ?guas de todas as lagoas em caldeiras. Para uso das ?guas das lagoas em compacta??o do solo, limpeza de vias p?blicas, e em sistemas de prote??o contra inc?ndio as ?guas das lagoas n?o s?o adequadas. Entretanto, os limites recomendados nas refer?ncias pesquisadas s?o para esgotos dom?sticos, e em fun??o disto, os par?metros s?o restritivos para que se diminuam os riscos sanit?rios que podem ser oferecidos com a utiliza??o. A velocidade de infiltra??o das ?guas das lagoas analisadas imp?s uma condi??o de uso moderado, mas os efeitos s?o potencializados apenas em solos pouco arenosos, que n?o ocorre em Natal. Recomenda-se a utiliza??o em irriga??o irrestrita para as ?guas da lagoa que possui a melhor qualidade, e, exceto para a de pior qualidade, a recomenda??o ? para uso em irriga??o restrita. Para as ?guas da lagoa com maior carga de poluentes recomenda-se tratamento complementar para que riscos sanit?rios sejam eliminados. Em uma ?nica lagoa foi encontrado apenas um ovo de helminto, e em fun??o das f?rmulas para convers?o dos resultados, foi encontrado para todas as lagoas a concentra??o de menos de 1 ovo de helminto/litro.