In the case of soil chemical analyses, frequency distributions for some elements show a dissymmetrical aspect, with a very marked spread to the right or to the left. A high frequency of extreme values is also observed and a possible mixture of several distributions, due to the presence of various soil types within a single geographical unit, is encountered. Then, for the outliers detection and the establishment of detection limits, an original outliers detection procedure has been developed; it allows estimating extreme quantiles above and under which observations are considered as outliers. The estimation of these detection limits is based on the right and the left of the distribution tails. A first estimation is realised for each elementary geographical unit to determine an appropriate truncation level. Then, a spatial classification allows creating adjoining homogeneous groups of geographical units to estimate robust limit values based on an optimal number of observations. / Dans le cas des analyses chimiques de sols, les distributions de fréquences des résultats présentent, pour certains éléments étudiés, un caractère très dissymétrique avec un étalement très marqué à droite ou à gauche. Une fréquence importante de valeurs extrêmes est également observée et un mélange éventuel de plusieurs distributions au sein dune même entité géographique, lié à la présence de divers types de sols, peut être rencontré. Dès lors, pour la détection des valeurs aberrantes et la fixation des limites de détection, une méthode originale, permettant destimer des quantiles extrêmes au-dessus et en dessous desquelles les observations sont considérées comme aberrantes, a été élaborée. Lestimation des limites de détection est établie de manière distincte à partir des queues des distributions droite et gauche. Une première estimation par entité géographique élémentaire est réalisée afin de déterminer un niveau de troncature adéquat. Une classification spatiale permet ensuite de créer des groupes dentités homogènes contiguës, de manière à estimer des valeurs limites robustes basées sur un nombre dobservations optimal.

No description available.

No description available.

Formaldehyde is a chemical used widely in the manufacture of building materials. A remarkable example is represented by the Lucite two-step Alpha technology for the large scale production of methyl methacrylate (MMA), the essential building block of all acrylic-based products. Esters and ketones are important intermediates in the manufacture of acrylate esters therefore α-hydroxymethylenation of carbonyl compounds using formaldehyde as a one carbon alkylating agent and subsequent dehydration to the corresponding methylenated derivatives has been explored in the current work. We report a novel catalytic approach for the synthesis of methyl methacrylate (MMA) via one-pot α-methylenation of methyl propanoate (a chemical intermediate of the ALPHA process) with formaldehyde, generated in situ by Ru-catalysed dehydrogenation of methanol. Elucidation of the mechanism involved in the catalytic dehydrogenation of methanol along with the collateral alcohol decarbonylation reaction was gained through a combined experimental and DFT study. The development of an alternative process where anhydrous formaldehyde is produced in situ would provide a simplification over the current second step of the ALPHA technology where the formaldehyde is initially produced as formalin, subsequently dehydrated to afford anhydrous formaldehyde in order to ensure high selectivity to MMA. As an alternative approach, ketones, in particular 3-pentanone and 2-butanone, were targeted as potential substrates in order to overcome some of the problems related to competing reactions that occur at the ester group. Hydroxymethylenation, followed by dehydration and Baeyer-Villager oxidation, possibly catalysed by enzymes to reverse the normal selectivity, leads to the formation of acrylate esters. The catalytic reaction is enabled by a gold carbene hydroxide complex in such a way that the substrate undergoes C-H activation and the nascent metal alkyl acts as a nucleophile towards the electrophilic formaldehyde, supplied in the form of alcoform* (solution of paraformaldehyde in methanol).

Made available in DSpace on 2015-03-03T15:15:26Z (GMT). No. of bitstreams: 1 EliangelaPB_DISSERT.pdf: 614353 bytes, checksum: 050737d0ef158e6082d81254619adac0 (MD5) Previous issue date: 2011-09-19 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / Considering a non-relativistic ideal gas, the standard foundations of kinetic theory are investigated in the context of non-gaussian statistical mechanics introduced by Kaniadakis. The new formalism is based on the generalization of the Boltzmann H-theorem and the deduction of Maxwells statistical distribution. The calculated power law distribution is parameterized through a parameter measuring the degree of non-gaussianity. In the limit = 0, the theory of gaussian Maxwell-Boltzmann distribution is recovered. Two physical applications of the non-gaussian effects have been considered. The first one, the -Doppler broadening of spectral lines from an excited gas is obtained from analytical expressions. The second one, a mathematical relationship between the entropic index and the stellar polytropic index is shown by using the thermodynamic formulation for self-gravitational systems / Considerando um g?s ideal n?o relativ?stico, os fundamentos da teoria cin?tica padr?o s?o investigados no contexto da mec?nica estat?stica n?o-gaussiana introduzida por Kaniadakis. O novo formalismo ? baseado na generaliza??o do teorema-H de Boltzmann e na dedu??o de Maxwell da distribui??o estat?stica. A distribui??o lei de pot?ncia calculada ? parametrizada por um par?metro medindo o grau de n?o-gaussianidade do sistema. No limite = 0, a teoria gaussiana de Maxwell-Boltzmann ? recuperada. Duas aplica??es dos efeitos n?o-gaussiano s?o estudados. Na primeira, o -alargamento Doppler das linhas espectrais de um g?s excitado ? obtido a partir das express?es anal?ticas. Na segunda, uma rela??o matem?tica entre o ?ndice entr?pico e o ?ndice politr?pico estelar ? mostrada usando uma formula??o termodin?mica para sistemas autogravitantes

Made available in DSpace on 2014-12-17T14:54:54Z (GMT). No. of bitstreams: 1 ClovisBMO_TESE_1_a_75.pdf: 2549651 bytes, checksum: d03d835bba88763c08a8cb99eac15cd8 (MD5) Previous issue date: 2010-03-12 / Universidade Federal do Rio Grande do Norte / This study presents a description of the development model of a representation of simplified grid applied in hybrid load flow for calculation of the voltage variations in a steady-state caused by the wind farm on power system. Also, it proposes an optimal load-flow able to control power factor on connection bar and to minimize the loss. The analysis process on system, led by the wind producer, it has as base given technician supplied by the grid. So, the propose model to the simplification of the grid that allows the necessity of some knowledge only about the data referring the internal network, that is, the part of the network that interests in the analysis. In this way, it is intended to supply forms for the auxiliary in the systematization of the relations between the sector agents. The model for simplified network proposed identifies the internal network, external network and the buses of boulders from a study of vulnerability of the network, attributing them floating liquid powers attributing slack models. It was opted to apply the presented model in Newton-Raphson and a hybrid load flow, composed by The Gauss-Seidel method Zbarra and Summation Power. Finally, presents the results obtained to a developed computational environment of SCILAB and FORTRAN, with their respective analysis and conclusion, comparing them with the ANAREDE / Este trabalho apresenta uma descri??o do desenvolvimento de modelo para representa??o de rede simplificada aplicado em fluxo de carga h?brido para c?lculo das varia??es de tens?o em regime permanente provocadas pela conex?o de aerogeradores na rede el?trica. Al?m disso, se apresenta um fluxo de carga ?timo capaz de controlar remotamente o fator de pot?ncia na barra de conex?o e minimizar perdas. O princ?pio do processo de an?lise do sistema, conduzido pelo acessante, tem como base dados t?cnicos fornecidos pela rede acessada. Assim, se prop?e um modelo para simplifica??o de redes que permita a necessidade do conhecimento apenas dos dados referente a rede interna, ou seja, a parcela da rede de interesse para an?lise. Dessa forma, pretende-se fornecer meios para auxiliar na sistematiza??o das rela??es entre concession?ria e acessante. O modelo para simplifica??o de rede proposto identifica a rede interna, rede externa e as barras de fronteira a partir de dados provenientes de um estudo de vulnerabilidade da rede, atribuindo-as pot?ncias l?quidas flutuantes, ou seja, modelando-as como barras slack. Aplica-se o referido modelo no fluxo de carga Newton-Raphson e em um fluxo de carga h?brido, composto pelos m?todos de Gauss Seidel Zbarra e Soma de Pot?ncias. Ao final, apresentam-se os resultados obtidos por um ambiente computacional desenvolvido do SCILAB e FORTRAN, com suas respectivas an?lises e conclus?es, comparando-os com o ANAREDE

Kyoto University (京都大学) / 0048 / 新制・論文博士 / 博士(工学) / 乙第12423号 / 論工博第4033号 / 新制||工||1480(附属図書館) / 27519 / (主査)教授 寶 馨, 教授 岡田 憲夫, 教授 角 哲也 / 学位規則第4条第2項該当

This thesis describes properties of windings of electric rotating machines and their insulation systems. There are winding and insulation low voltage machines tests listed with their procedures and criteria. Further it deals with coordination methodology and the last part contains execution and results assessment of tests conducted on stator samples.

This diploma thesis deals with the development of constructive technology project od local road in Žďár nad Sázavou. Specifically, there is a solution prestressed reinforced concrete construction of the bridge over the Sázava river according to the extent of the diploma work.

MENVSC / Department of Ecology and Resource Management / South Africa is highly dependent on coal for production of electricity. The combustion of coal for electricity generation produces waste by-products which include fine ash (fly ash) and coarse ash. Fly ash (FA) is produced in large amounts while its utilization is low due to its classification as a hazardous material. Sasol produces about 7 million tons of FA, while Eskom produces about 28 million tons of coal FA annually. FA is a fine by-product from pulverized coal with detrimental effects on plants, soil or land, animals and human beings, and pollutes the air. The present investigation focuses on the examination of the chemical elements bioaccumulation and phytoremediation potential of Indian mustard (Brassica juncea) and Spinach (Spinacia Oleracea L). X-ray fluorescence (XRF) was used to analyze the elemental composition of FA and soil, Scanning Electron Microscope (SEM) to examine the morphology, while X-ray diffraction (XRD) analysis was used to evaluate the mineralogy of FA. The concentrations of metal and non-metal species that are released from FA on contact with water at different conditions were quantified using ICP-MS. Pot culture experiment was conducted to grow Brassica juncea and Spinacia Oleracea L. using FA and soil as growth medium. Leachates from the pots were collected and analysed using ICP-MS. Plant parts from harvested Brassica juncea and Spinacia Oleracea L. were cut separately and analysed using ICP-MS for the concentrations of different metal and non-metal species in plant parts. Plant parts were also used to estimate biomass and chlorophyll content (leaves). To prepare these plant samples for analysis, the powdered plant sample (0.5 g) was digested through aqua regia (HCL:HNO3 = 3:1 (v/v)) to near dryness using hotplate and filled to 100 mL of MilliQ water. The samples were filtered and directly used to determine the chemical elements concentrations. Blanks and internal standards were used for quality assurance during analysis. Chemical elements that are present in FA and sometimes in higher concentrations are associated with detrimental effects in plants, animals and human beings, hence phytoremediation is vital. Bioconcentration factor (BCF) was used to estimate the metal species accumulation ability of the plants from the FA, FA/soil mixtures, while translocation factor (TF) was used to assess the plant species potential for phytoremediation of coal fly ash dumps. Analysis of Varience (ANOVA) was used to statistically test data using Graphpad software package. Relationship between chemical elements in soil, FA and FA+soil growth media and also different plant parts (root, stem and leaf) of B. juncea and S. Oleracea L were calculated using the t - test, ANOVA-Bartlett test, Mann-Whitney Test and Kruskal-Wallis Statistic (KW) depending on each data set. The physicochemical characterization of coal fly ash showed that FA from Grootvlei power station can be classified as class F with an alkaline pH level of 10.62. It showed that particle morphology of this FA had a lower degree of sphericity with irregular agglomerations of many particles while there were dominant spherical particles and smaller sharp needle like particles. It is also an alumino-silicate material as confirmed by the high SiO2 and Al2O3 content, while soil leachates had an average/neutral pH of 7.22 with very high amounts of Si. In both soil and FA, elements that were expected to be readily available to plants included Ca, Si, K, Ba, Mo, Na, Al, Mg, Sr and non-essential elements (Si, Ba, Na, Al, Sr), which, if uptaken by plants’ roots can have negative impacts in plants. Physicochemical analysis of soil, FA and FA+soil leachates showed that the alkalinity of the FA changed over time and there was also a decrease in the EC due to dissolution iv of soluble major oxides, which was promoted by continuous water irrigation. The soil and FA+soil growth media showed similar results. Chemical elements like B, Mn, Fe and Ba were occurring at higher concentrations in leachates for most weeks in the pot culture experiments. However, it was observed that in the eleventh week of leachate collection all these chemical elements decreased to very low concentrations. This suggest that these chemical elements can be reduced over time as plants are being irrigated which is either due to uptake by plants or washed off with water. Statistically, there was a significant difference for different chemical elements of leachates from different growth media for each plant species (B. juncea and S. Olearcea L.). The overall growth rate shows that S. Oleracea L was better than that of B. juncea especially in the FA media over time, while the biomass of the two plant species showed similar results. After all, even though S. Oleracea L had carotenoid content below detection limits, it had higher chlorophyll b than B. juncea for all growth media in general. But, statistically there was no significant difference between the two plant species in terms of growth rate and biomass; even between the plant parts denoting similar growth performance for the two plant species under study. The bioaccumulation potential of the two plant species showed that chemical elements such as Fe, Mn, Ba, Zn and B were highly accumulated by the different parts of the plants. However, the chemical elements such as of Mo, Ni, Cu, and Cr showed the least concentrations. This trend was similar for all growth media and both plant species but this changes over time for different growth media and plant species as increasing and decreasing trends can be noticed. This led to no significant difference between plant species and also growth media, statistically. High BCF values of Fe, Mn, Ba, Zn and B were observed in the different parts of the plants for both plant species. However, Mo, Ni, Cu, and Cr had BCF values less than 1 for most growth media over time. BCF values in plant parts differed with time, growth media and plant species. Translocation of chemical elements shows that the B. juncea plant proved to be an effective phytoremediation plant species since it is effective in translocation of many chemical elements for different growth media to shoots while S. Oleracea L failed to translocate most chemical elements from stem to leaves although it translocated some from root to shoots. Hence, it can be concluded from the study that both species can be used in phytoremediation of coal fly ash dumps but with B. juncea being the most effective accumulator and translocator of many chemical elements. However, it can be recommended that chelating agents like ethylene diamine tetra acetic acid (EDTA) be introduced to solubilize chemical elements from growth media matrix into growth media solution to facilitate the quick transport of chemical elements into xylem, and increase