Thesis (PhD(Agric) (Horticulture))--University of Stellenbosch, 2011. / Includes bibliography. / ENGLISH ABSTRACT: Plums with good taste, aroma and eating quality lead to repeat purchases and sustained demand. Taste includes non-volatile compounds, e.g. sugars and acids, and has been well researched to meet the consumers’ preferences. Plum aroma, however, has not enjoyed the same attention. Limited literature is available on the aroma of Japanese plums and none could be found on the effects of relatively long cold storage on the profiles. The main aim of this study is to investigate the changes in aroma compounds of Japanese plums throughout maturation and ripening and the effects of commercial cold storage regimes. Near infra-red (NIR) spectroscopy was also evaluated as a non-destructive method to determine plum quality parameters aimed at minimising sample variability. In Paper 1, NIR spectroscopy was used to develop prediction models for total soluble solid (TSS), total acidity (TA), sugar-to-acid ratio, firmness and weight in three cultivars (Pioneer, Laetitia and Angeleno) and a multi-cultivar model. Samples were collected for seven consecutive weeks and repeated over two seasons. TSS results showed excellent predictability (R2 = 0.817-0.955; RMSEP= 0.453-0.610 % Brix) but the TA models did not perform well. The sugar-to-acid ratio models had results comparable to that of TSS. Both the firmness and weight models had acceptable results. The models of ‘Pioneer’ and ‘Laetitia’ had a better predictability capacity than the ‘Angeleno’ model. Although the multi-cultivar models outperformed the single cultivar models on R2 values it had higher prediction errors. The robustness of all the TSS, TA and firmness models is high in terms of seasonality, range and cultivar. Papers 2 and 3, the main focus of the study, are concerned with the aroma profile dynamics of Japanese plums. HS-SPME was used in both papers to extract the aroma compounds followed by GC-TOFMS for separation and identification. In Paper 2, the aroma volatile compounds of three cultivars (Pioneer, Laetitia and Angeleno) were determined for a seven week period including samples from three maturity stages (immature, harvest and tree-ripe). A total of 35 compounds were identified of which ten were generic. Each cultivar had five unique compounds resulting in different aroma profiles for each of the maturity stages and distinct separation patterns using discriminant analysis. The study was extended in Paper 3 where the aroma volatile compounds of six cultivars (Pioneer, Sapphire, Laetitia, Songold, Larry Anne and Angeleno) and one plumcot (Flavor King) were determined at three functional stages (commercial harvest, tree-ripe fruit and cold stored fruit). A total of 62 compounds were identified and classified into three groups (‘unique’ (31), ‘generic’ (11) and ‘frequent’ (20)) based on their frequency of occurrence. The aroma profiles of ‘Larry Anne’ and ‘Flavor King’ are the most affected by cold storage conditions and ‘Pioneer’ appears to be the least affected. All the cultivars have significantly different aroma profiles at all three of the functional stages with ‘Sapphire’, ‘Larry Anne’ and ‘Flavor King’ showing the largest differences. ‘Flavor King’, a plumcot, presented a ripe aroma profile that was much diverged from that of the true plums. / AFRIKAANSE OPSOMMING: Pruime met ‘n goeie smaak, aroma en eetkwaliteit lei tot herhaalde verkope en volhoubare aanvraag. Smaak sluit die nie-vlugtige stowwe (suikers en sure) in en is goed nagevors om die verbruikersvoorkeure te bevredig. Pruim aroma het egter nie dieselfde aandag geniet nie. Daar is beperkte literatuur beskikbaar wat handel oor die aroma van Japanese pruime en geen kon gevind word oor die effekte van lang koelopberging op die aromaprofiele nie. Die hoof doel van hierdie studie is om die veranderinge in die aromatiese komponente van Japanese pruime te ondersoek tydens die volwassewording- en rypwordingsprosesse asook die effekte van kommersiele koelopberging. Naby infrarooi (NIR) spektroskopie is ook geevalueer as ‘n nie-destruktiewe manier om pruim kwaliteitsparameters te bepaal met die doel om monstervariasie te beperk. In Artikel 1 is NIR spektroskopie gebruik om voorspellingsmodelle vir totale oplosbare suikers (TOS), totale suur (TS), suiker-tot-suur verhouding, fermheid en gewig te bepaal in drie kultivars (Pioneer, Laetitia en Angeleno) asook ‘n multi-kultivar model. Monsters is vir sewe opeenvolgende weke versamel en herhaal oor twee seisoene. TOS resultate toon uitstekende voorspelbaarheid (R2 = 0.817-0.955; RMSEP= 0.453-0.610 % Brix) maar TS modelle het egter nie so goed gevaar nie. Die suiker-tot-suur verhoudingsmodelle se resultate was vergelykbaar met die van TOS. Beide die fermheid- en gewigsmodelle het aanvaarbare resultate opgelewer. Die modelle vir ‘Pioneer’ en ‘Laetitia’ het ‘n beter voorspelbaarheidskapasiteit getoon as die van ‘Angeleno’. Alhoewel die multi-kultivar model beter presteer het as die enkel kultivar modelle op die R2-waardes was daar meer voorspellingsfoute. Hoe robuustheid is gevind i.t.v. seisoene, datagrense en kultivar vir al die TOS, TA en fermheidsmodelle. Artikels 2 en 3, die fokuspunt van die studie, handel oor die dinamika van die aromaprofiel van Japanese pruime. HS-SPME is in beide artikels gebruik on die aromatiese verbindings te ekstraeer gevolg deur GCTOFMS vir skeiding en identifikasie. In Artikel 2 is die aromatiese stowwe van drie kultivars (Pioneer, Laetitia en Angeleno) bepaal vir sewe opeenvolgende weke en sluit monsters van drie volwassenheidsstadiums in (onvolwasse, oes en boom-rypgemaakte pruime). ‘n Totaal van 35 verbindings is geidentifiseer waarvan tien as generies beskou kan word. Elke kultivar het vyf unieke komponente gehad en het gelei tot verskillende aromaprofiele vir elk van die volwassenheidsstadiums en diverse skeidingspatrone tydens die gebruik van diskriminant analise. Die studie is uitgebrei in Artikel 3 waartydens die aromatiese vlugtige stowwe van ses kultivars (Pioneer, Sapphire, Laetitia, Songold, Larry Anne en Angeleno) en een plumcot (Flavor King) bepaal is tydens drie funksionele stadiums (oes, boom-rypgemaak en koelopgebergde pruime). ‘n Totaal van 62 verbindings is geidentifiseer en in drie groepe geklassifiseer (‘uniek’ (31), ‘generies’(11) en ‘gereeld’ (20)) gebaseer op voorkomsfrekwensie. Die aromaprofiele van ‘Larry Anne’ en ‘Flavor King’ is die meeste deur die koelopberging geaffekteer en ‘Pioneer’ die minste. Al die kultivars het kenmerkend verskil t.o.v. hul aromaprofiele in al drie die funksionele groepe en ‘Sapphire’, ‘Larry Anne’ en ‘Flavor King’ het die grootste verskille getoon. ‘Flavor King’, die plumcot, het ook ‘n ryp aromaprofiel gehad wat baie van die van die egte pruime verskil het.

Vid användning av audio-perceptuell röstanalys för framtagning av referensröster är begreppet reliabilitet av central betydelse. Syftet med denna uppsats var att undersöka reliabiliteten mellan erfarna röstlogopeders perceptuella röstanalys av ett antal utvalda röstexempel. Förhoppningen var att utifrån detta kunna sammanställa en början till ett referensröstmaterial bestående av manliga och kvinnliga referensröster representativa för olika parametrar i SVEA-protokollet. De specifika frågeställningarna var: Hur samstämmiga i perceptuell röstanalys är bedömarna kring de valda röstexemplens olika parametrar? Är någon eller några av de parametrar som bedömarna är överens om extra framträdande i någon röst så att denna röst kan användas som referensröst? Utifrån en databas med 65 röstinspelningar valdes 15 röstexempel ut av författarna att skattas av sju erfarna logopeder med SVEA-protokollet. En andra bedömningsomgång genomfördes med tre röstexempel slumpvis utvalda från de 15 röstexemplen i den första bedömningsomgången. Statistiska analyser av logopedernas inter- och intrabedömarreliabilitet gjordes både på alla röstexempel och på samtliga kvalitetsparametrar. Bedömarnas skattningar uppvisade mycket stor spridning i flera röstexempel, vilket inverkade på korrelationernas utfall och kan vid en första anblick ge ett missvisande resultat. En djupare analys av bedömarnas skattningar av enskilda röstparametrar visade på betydligt högre samstämmighet. Utifrån detta resultat tog författarna fram tre potentiella referensröster. Flera av de övriga 12 röstexemplen hade relativt hög interbedömarreliabilitet men då skattningsvärdena var så pass låga för dessa röster valdes de inte ut som referensröster. Trots låga skattningsvärden skulle dessa röstexempel kunna användas som referensröster för att exemplifiera lägre grader av avvikelser. Slutsatsen är att det finns skillnader i hur bedömarna skattat röstexemplen i denna studie och reliabiliteten mellan bedömarna skiftar. Författarna drar även slutsatsen att det är motiverat att fortsätta leta och analysera röstexempel för att få en heltäckande uppsättning referensröster. Metodvalet i denna studie anses vara en framkomlig väg för att fortsätta forma detta referensröstmaterial. / Interrater and intrarater reliability are of great importance in the selection of reference voice examples. The purpose of this study is to investigate the reliability of experienced speech and language pathologists’ evaluations of selected voice samples. The aim is to begin a collection of male and female reference voice examples which represent different voice quality parameters according to the Stockholm Voice Evaluation Approach (SVEA). The specific questions are: How well do speech and language pathologists agree when rating voices along different voice quality parameters? Are any of the voice quality parameters in the speech samples prominent enough to be qualified as reference voice examples? The authors selected 15 voice samples out of a database consisting of 65 voice samples. The voices were evaluated by seven experienced speech and language pathologists using the SVEA protocol. The results were statistically analyzed to study interrater reliability. In order to investigate intrarater reliability a second evaluation session was carried out in which the speech and language pathologists evaluated three voice samples randomly selected from the 15 samples used in the first evaluation session. The results showed a wide range in the raters’ evaluations, which had an impact on the correlations. However, a closer look at separate parameters indicated considerably higher similarity in the ratings. Based on these results three reference voice examples were selected. Even though high correlation values were found in several of the other twelve voice samples, the ratings in these were not high enough to qualify them as reference voice examples in this study. Nevertheless, these voices can still be used to exemplify various degrees of deviation. The conclusions are that there is a great variation regarding reliability between and within raters and also regarding how the different speech and language pathologists rate the voices. The authors also conclude that the search for clear reference voice examples is highly motivated and ought to be continued, preferably with the method used in this study.

No description available.

Au Liban, 65% de la population résident à Beyrouth et au Mont Liban particulièrement dans la zone côtière et dans une bande étroite du flanc ouest du Mont Liban. Cette occupation engendre une forte pression anthropique sur les ressources hydriques. En effet environ 330 Mm3 d'eaux usées par an sont rejetés dans la Méditerranée par 53 émissaires distribués sur les villes côtières. Ces eaux, rejetées en grande majorité sans traitement, représentent le vecteur principal de pollution du milieu récepteur que représente la Mer Méditerranée (MOE/UNDP/ECODIT, 2011).Cette étude avait pour objectif principal de déterminer la qualité des eaux usées au Liban et d'établir une comparaison entre les contextes Libanais (en s'appuyant sur Beyrouth) et Français (cas de l'agglomération parisienne). Un suivi ponctuel des eaux usées provenant de 4 sites de prélèvement représentatifs de la région de Beyrouth et ses banlieues (sites d'Al Ghadir, Fleuve Beyrouth, Antelias et Jounieh) a été conduit. Deux sites ont été sélectionnés pour un suivi en continu de l'évolution des eaux usées aux échelles journalière et hebdomadaire : Jounieh et Al Ghadir. En France, une série de campagnes ont été réalisées sur les principaux émissaires des stations d'épuration de Marne Aval, Seine Amont, Seine Centre et Seine Aval, au sein de la STEP Seine Centre (au niveau des traitements primaire et secondaire), et en Seine. Ensuite les résultats à Beyrouth et Paris ont été confrontés pour déterminer l'impact sur l'environnement qu'aurait la mise en place de traitements adaptés aux effluents libanais. Les niveaux de contamination pour les paramètres globaux sont comparables pour le prélèvement ponctuel entre les bassins versants d'Al Ghadir et de Jounieh. Cependant les niveaux relevés à Al Ghadir et Jounieh sont plus élevés que ceux d'Antelias et Fleuve Beyrouth. Par ailleurs, le suivi en continu a permis de mettre en évidence que les niveaux en MES, MVS, DCOT et DBO5 sont généralement comparables sur les deux sites Al Ghadir et Jounieh. La comparaison avec les émissaires parisiens montre des différences significatives pour les MES, MVS et DBO5, ces paramètres sont significativement plus élevés sur les sites libanais. Pour la DCOT, les concentrations sont comparables entre les deux pays. En comparant les ETM totaux (Cr, Zn, Cu, Cd et Pb), on trouve que la concentration en cuivre des émissaires parisiens est plus élevée que celle du Liban pour les bassins versants d'Al Ghadir et Jounieh. Pour le plomb et le zinc, les concentrations sont comparables entre les deux pays. Enfin les concentrations en cadmium et chrome sont beaucoup plus élevées à Beyrouth qu'à Paris. Les flux en ETM au Liban exportés vers la Mer Méditerranée pour le site d'Al Ghadir sont 20,7; 20,8; 2,42; 0,6; et 1,5 kg/jour respectivement pour le CrT, ZnT, CuT, CdT et PbT et pour l'émissaire de Jounieh 0,66; 3,7; 0,38; 0,045 et 0,33 kg/jour. En s'appuyant sur l'efficacité des STEP parisiennes, les niveaux rejetés diminueraient de 90 à 98% pour les MES, de 84 à 95% pour la DCOT et de 63 à 97 % suivant l'ETM concerné / In Lebanon, 65 % of the population lives in Beirut and Mount Lebanon particularly along the coastal area and a narrow band of the western side of the Lebanon Mount. This occupation generates a strong anthropic pressure on the water resources. Indeed approximately 330 mm3 of waste waters a year are rejected into the Mediterranean by 53 trunks distributed along the coastal towns. In fact, these wastewaters are released to natural media without any significant treatment and These effluents, released in great majority without treatment, are considered as the primary vector of the Mediterranean Sea pollution (MOE/UNDP/ECODIT, 2011).This study aimed at determining the quality of wastewaters in Lebanon and at establishing a comparison between the Lebanese (with respect to Beirut) and French (case of the urban area of Paris) contexts. A specific monitoring of wastewaters was led on 4 representative sampling sites of the area of Beirut and its suburbs (Al Ghadir sites, Beirut River, Antelias and Jounieh). Two sites were selected to follow the evolution of the wastewater quality both at the daily and weekly scale: Jounieh and Al Ghadir. In France, a series of campaigns were carried out on the main trunks of several wastewater treatment plants, e.g., Marne Aval, Seine Amont, Seine Aval and Seine Centre, in the Seine Centre WWTP (within the primary and secondary treatments), and in the Seine River. Then the results in Beirut and Paris were confronted to determine the environmental impact of the installation of treatments adapted to the Lebanese effluents.Contamination levels for the water quality parameters were comparable for the punctual sampling between the Al Ghadir and Jounieh watersheds. However, the levels found in Al Ghadir and Jounieh were higher than those of Antelias and Beirut River. In addition, continuous monitoring helped to highlight the levels of TSS, VSS, BOD5 and CODT were generally comparable at both sites: Al Ghadir and Jounieh. The comparison with the Parisian trunks showed significant differences for TSS, BOD5 and VSS, these parameters were significantly higher on Lebanese sites. For CODT, concentrations were comparable between the two countries. By comparing the total ETM (Cr, Zn, Cu, Cd and Pb), we found that Cu concentrations in Parisian trunks were higher than those of Lebanese Al Ghadir and Jounieh watersheds. For lead and zinc concentrations were comparable between the two countries. Finally, the concentrations of cadmium and chromium were much higher in Beirut than in Paris. Trace metal flows to the Mediterranean Sea from the Al Ghadir site were of 20,7; 20,8; 2,42; 0,6; and 1,5 kg/day for CrT, ZnT, CuT, CdT and PbT respectively, and for Jounieh they were of 0,66; 3,7; 0,38; 0,045 and 0,33 kg/day, respectively. Based on the effectiveness of the Parisian WWTPs, released levels would decrease by 90-98 % for TSS, 84-95 % for CODt and 63-97 % depending on the ETM concerned

Submitted by Rosivalda Pereira (mrs.pereira@ufma.br) on 2017-09-04T17:47:07Z No. of bitstreams: 1 MarcusLopes.pdf: 2085041 bytes, checksum: 14f6f9bbe0d5b050a23103874af8c783 (MD5) / Made available in DSpace on 2017-09-04T17:47:07Z (GMT). No. of bitstreams: 1 MarcusLopes.pdf: 2085041 bytes, checksum: 14f6f9bbe0d5b050a23103874af8c783 (MD5) Previous issue date: 2017-07-26 / The growing demand for energy and the limitations of oil reserves have led to the search for renewable and sustainable energy sources to replace, even partially, fossil fuels. Biodiesel has become in last decades the main alternative to petroleum diesel. Its quality is evaluated by given parameters and specifications which vary according to country or region like, for example, in Europe (EN 14214), US (ASTM D6751) and Brazil (RANP 45/2014), among others. Some of these parameters are intrinsically related to the composition of fatty acid methyl esters (FAMEs) of biodiesel, such as viscosity, density, oxidative stability and iodine value, which allows to relate the behavior of these properties with the size of the carbon chain and the presence of unsaturation in the molecules. In the present work four methods for direct classification (support vector machine, K-nearest neighbors, decision tree classifier and artificial neural networks) were optimized and compared to classify biodiesel samples according to their compliance to viscosity, density, oxidative stability and iodine value, having as input the composition of fatty acid methyl esters, since those parameters are intrinsically related to composition of biodiesel. The classifi- cations were carried out under the specifications of standards EN 14214, ASTM D6751 and RANP 45/2014. A comparison between these methods of direct classification and empirical equations (indirect classification) distinguished positively the direct classification methods in the problem addressed, especially when the biodiesel samples have properties values very close to the limits of the considered specifications. / A demanda crescente por fontes de energia renováveis e como alternativa aos combustíveis fósseis tornam o biodiesel como uma das principais alternativas para substituição dos derivados do petróleo. O controle da qualidade do biodiesel durante processo de produção e distribuição é extremamente importante para garantir um combustível com qualidade confiável e com desempenho satisfatório para o usuário final. O biodiesel é caracterizado pela medição de determinadas propriedades de acordo com normas internacionais. A utilização de métodos de aprendizagem de máquina para a caracterização do biodiesel permite economia de tempo e dinheiro. Neste trabalho é mostrado que para a determinação da conformidade de um biodiesel os classificadores SVM, KNN e Árvore de decisões apresentam melhores resultados que os métodos de predição de trabalhos anteriores. Para as propriedades de viscosidade densidade, índice de iodo e estabilidade oxidativa (RANP 45/2014, EN14214:2014 e ASTM D6751-15) os classificadores KNN e Árvore de decisões apresentaram-se como melhores opções. Estes resultados mostram que os classificadores podem ser aplicados de forma prática visando economia de tempo, recursos financeiros e humanos.

While modeling electronic service systems application quality parameters are always relevant. Future system must be reliable in operating, flexible enough in different situations and to have good efficiency. Price is important for system builder. Integrated quality parameter is defined for measuring and evaluation of all other quality parameters. In this work Petri nets architecture is picked as projecting methodology. electronic service information system - E-Government, is created and modeled theoretically. While studying information security methods in every projecting and modeling step we try to valuate these parameters: a) flexibility b) reliability c) performance d) price. While analyzing Petri nets it is required to make and describe information system theoretically. It is analyzed how to find the best way to reach optimal information security features. Application quality parameters are used for that.

Pieno ūkis – viena svarbiausių žemės ūkio šakų pasaulyje. Pagal statistiką, Lietuvoje vienam gyventojui tenka 563kg pieno, kas yra vienas didžiausių rodiklių pasaulyje, tad pieno ūkis yra viena svarbiausių žemės ūkio, tuo pačiu ir ekonomikos sričių. Siekiant gerinti pieno kokybę bei mažinti kaštus vis daugiau pieno melžimo įmonių investuoja ir taiko naujas technologijas - melžimo aparatai į liniją ir robotai. Lietuvoje pirmoji robotizuota sistema įdiegta 2007 m. Tiriamajame ūkyje ši sistema įdiegta 2009 m. Tyrimo tikslas buvo palyginti pieno sudėties ir kokybės rodiklius X ūkyje, melžiant karves melžimo aparatais ir robotais. Svarbiausios pieno sudėtinės dalys yra – baltymai, riebalai ir angliavandeniai (laktozė, mineralinės ir biologiškai aktyvios medžiagos, vitaminai, fermentai ir kitos). Melžimas turi didelę reikšmę karvių produktyvumo bei pieno sudėtinių dalių rodikliams, todėl būtina parinkti teisingą melžimo būdą. Buvo ieškota būdų – kaip pilnai pakeisti žmogų melžimo aikštelėse. Siekiant pagerinti karvių pieno kokybę ir padidinti primilžį, modernizuojant pieno ūkius inovatyviomis technologijomis, rekomenduojama robotizuoti karvių melžimą. Nustatyta, kad robotais melžiamų karvių pieningumas padidėja vidutiniškai 15 proc. Pieno gamybą skatina dažnesnis karvių melžimas ir geresnė jų savijauta. Mažuose pieno ūkiuose, kur karvių yra mažai naudojamas įprastas melžimo būdas, t. y. melžimas rankomis. Melžiant karves rankomis yra didesnė tikimybė pieną užteršti bakterijomis... [toliau žr. visą tekstą] / Dairy farming is one of the most important branches in agriculture worldwide. According to statistics in Lithuania there's 563 kg of milk produced per capita. That is one of the highest production rates per capita in the world. Dairy farming is crucial to local economy. In order to achieve higher milk quality and minimize expenditures more dairy farms are investing and adapting new technologies: milking pipelines and fully automated robotic milking. The first fully automated robotic milking line in Lithuania was used implemented in 2007. In the researched farm the system was implemented in 2009. The main goal of research was to compare milk composition and quality in the research farm X by milking cows to pipelines and using fully automated robotic milking. The main nutrients that compose milk are: proteins, fats and carbohydrates(lactose, minerals and biologically active materials, vitamins, enzymes and others). The way that cows are milked has high impact on milk yields and nutrients, so the best milking technology is essential for optimal results. The research on how to eliminate human labor during milking process has been done. In order to increase the quality and yields of cow's milk by modernizing the dairy farms and using the fully automated robotic milking. It was concluded that by using fully automated robotic milking milk yield increases by 15% on average. The milk production is increased by more frequent milking and cattle welfare. In the small dairy farms with... [to full text]

The diploma thesis identifies the attitude of the Czech public on the issue of fresh breads and pastries prepared from frozen semi-finished product based on consumer research. It is focused on the supply side, specifically on analysis of sales of fresh bread and bakery products prepared from frozen semi-finished products within the selected retail units. Further to the survey among Czech producers of bread, and also monitored supply of bread from frozen semi-finished products in selected retail chains.

This study aimed to evaluate commercial biofertiliser quality and awareness amongst smallholder farmers in Gauteng Province, South Africa. Sixty-seven smallholder farmers were interviewed in Gauteng Province by using a survey method, while the physicochemical and microbiological properties of 13 biofertilisers were evaluated using laboratory experiments. The results showed that awareness and use of biofertiliser are very poor, with 96% of the smallholder farmers surveyed not having biofertiliser knowledge. Furthermore, the products lack basic quality parameters: 54% contained no biofertiliser strain while all the products contained microbial contaminants. The pH, moisture content and viable microbial densities were below the acceptable standards for some of the products. Two fungal and 58 bacterial operational taxonomic units were obtained from the 16S rRNA Sanger sequences while 5 791 OTUs were obtained from the Illumina Miseq system. Approximately 40%, 41% and 59% of the isolates were positive for nitrogen-fixation, siderophore production and phosphorous solubilisation. Overall, there is a need to improve awareness amongst farmers and promote good-quality biofertiliser products for increased crop productivity. / Environmental Sciences / M. Sc. (Environmental Science)

Submitted by Lucienne Costa (lucienneferreira@ufcg.edu.br) on 2018-04-13T20:32:36Z No. of bitstreams: 1 THIAGO CABRAL NEPOMUCENO – DISSERTAÇÃO (PPGECA) 2018.pdf: 5961539 bytes, checksum: ea3a80835b67c0d1615b111f56921a4a (MD5) / Made available in DSpace on 2018-04-13T20:32:36Z (GMT). No. of bitstreams: 1 THIAGO CABRAL NEPOMUCENO – DISSERTAÇÃO (PPGECA) 2018.pdf: 5961539 bytes, checksum: ea3a80835b67c0d1615b111f56921a4a (MD5) Previous issue date: 2018-02-27 / Capes / O lançamento de efluentes domésticos em ambientes aquáticos sem o devido tratamento vem comprometendo a qualidade da água de reservatórios e rios. Esta torna-se ainda mais relevante quando, em torno desses corpos hídricos superficiais, existe uma intensa prática agrícola, com aplicação de fertilizantes a base de nitrogênio e fósforo, onde a ocorrência de eventos chuvosos pode gerar escoamento superficial e encaminhar o excesso desses nutrientes presentes no solo para os rios e reservatórios próximos. Portanto, o presente trabalho propôs o desenvolvimento e aplicação de um modelo para simulação de nitrogênio e fósforo em sistemas de recursos hídricos, que permita simular a interação de rios, reservatórios e áreas agrícolas em termos desses parâmetros de qualidade de água. No arranjo estrutural do modelo desenvolvido, duas etapas metodológicas merecem destaque, são elas: modelagem de nitrogênio e fósforo nas áreas agrícolas, considerando os principais fluxos de entrada e saída desses macronutrientes no solo, e definição dos sistemas de equações diferenciais ordinárias que possam representar a dinâmica comportamental de nitrogênio e fósforo nos corpos hídricos, ou seja, rios e reservatórios integrantes de um determinado sistema estudado. Como estudo de caso, foi selecionado um sistema de recursos hídricos localizado na unidade de planejamento hidrológico do Alto Piranhas-PB, compreendendo áreas agrícolas, rios e reservatórios, juntamente com as principais contribuições de nutrientes para o respectivo sistema, além de ser levado em consideração o aporte das águas da transposição do rio São Francisco, proveniente do Eixo Norte da transposição. Para a aplicação do modelo desenvolvido, foram analisados cenários que possibilitassem uma melhor avaliação da resposta do sistema estudado ao lançamento dos efluentes domésticos e agrícolas, além do impacto das águas da transposição. Os resultados das simulações indicaram que os recursos hídricos analisados são sensíveis a ação dos efluentes domésticos e agrícolas, principalmente nos períodos de seca, onde o volume dos reservatórios e vazões nos trechos dos rios são reduzidos. Com o acréscimo das águas da transposição, foram observadas atenuações significativas nos níveis de nitrogênio e fósforo nos corpos hídricos, devido ao maior poderio de diluição dos efluentes proporcionado por esse aporte hídrico, embora foram observados níveis críticos em alguns meses. Desta forma, medidas preventivas e corretivas devem ser adotadas a esse tipo de sistema, de maneira a evitar o comprometimento da biota aquática e dos múltiplos usos as quais as águas estão destinadas. / The release of domestic effluents in aquatic environments without the proper treatment has compromised the water quality of reservoirs and rivers. This becomes even more relevant when, around these surface water bodies, there is an intense agricultural practice, with the use of nitrogen and phosphorus base fertilizers, where the occurrence of rainfall events can generate runoff and return the excess nutrients present in the soil to nearby rivers and reservoirs. Therefore, this work proposed the development and application of a model for simulation of nitrogen and phosphorus in water resources systems, allowing the interaction of rivers, reservoirs and agricultural areas in terms of water quality parameters. In the structural arrangement of the developed model, two methodological steps are worth mentioning: nitrogen and phosphorus modeling in agricultural areas, considering the main input and output flows of these macronutrients in the soil, and definition of the systems of ordinary differential equations that can represent the behavioral dynamics of nitrogen and phosphorus in the water bodies, ie, rivers and reservoirs that are part of a given system studied. As a case study, a water resource system was selected, located in the Alto Piranhas-PB hydrological planning unit, comprising agricultural areas, rivers and reservoirs, together with the main nutrient contributions to the respective system, besides being taken into account the contribution of the waters of the transposition of the São Francisco river, coming from the Eixo Norte of the transposition. For the application of the developed model, scenarios were analyzed to enable a better evaluation of the response of the studied system to the release of domestic and agricultural effluents, besides the impact of the transposition waters. The results of the simulations indicated that the analyzed water resources are sensitive to the action of domestic and agricultural effluents, mainly in periods of drought, where the volume of the reservoirs and flows in the stretches of the rivers are reduced. With the addition of the transposition waters, significant attenuations were observed in the nitrogen and phosphorus levels in the water bodies, due to the higher dilution power of the effluents provided by this water supply, although critical levels were observed in some months. Therefore, preventive and corrective measures should be adopted for this type of system in order to avoid compromising the aquatic biota and the multiple uses to which the waters are destined.