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Le but général de ce travail fut de quantifier la silice biogène (BSiO2) dans les sédiments du continuum de l'Escaut (estuaire – zone côtière), ainsi que son taux de recyclage - rétention. Le coefficient de diffusion moléculaire de la DSi a été déterminé pour différentes valeurs de température et deux salinités et une relation empirique reliant le coefficient de diffusion à la température et à la viscosité de la solution a été établie. La distribution longitudinale de la BSiO2 dans les sédiments de surface, ainsi que les profils verticaux de BSiO2 et de silice dissoute ont été déterminés durant différentes saisons en 2004 et 2005. Les flux de DSi ont été également estimés via des expériences d’incubations et par modélisation des profiles verticaux de DSi. Des expériences de dissolution des sédiments ont permis de déterminer (via modélisation) les constantes cinétiques de vitesse de la BSiO2 et une première évaluation du taux de recyclage de la BSiO2 (5 – 70%). Sur base des calculs à partir des profiles de DSi dans l’eau interstitielle, le taux de recyclage de la BSiO2 varie entre 8 et 92% dans l’estuaire, ce qui correspond à une rétention moyenne de la BSiO2 supérieure à 60%, et souligne ainsi l'efficacité du filtre estuarien par rapport à la silice. En revanche, le recyclage de BSiO2 dans la zone côtière apparaît comme très intensif, avec des valeurs souvent supérieures à 40%. Ces résultats montrent l'importance d'inclure les estuaires dans le calcul des budgets globaux de Si. / The general objective of this study was to quantify the BSiO2 in the sediments of the Scheldt continuum, together with its recycling and retention in this area. First an empirical relation linking the diffusion coefficient of DSi to temperature and salinity was determined, via diffusion experiments. The longitudinal BSiO2 distribution in surface sediments and the vertical BSiO2 and DSi profiles in sediment cores where then measured during 2 years and different seasons, together with other parameters characterizing pore waters, such as alkalinity, pH, sulphate… DSi fluxes were also estimated either directly through whole core incubations measurements or via modelling of interstitial water profiles. BSiO2 dissolution experiments allowed the evaluation of the kinetic rate constants also through modelling of the results, and gave preliminary information over the BSiO2 recycling rates (5 – 70%). The recycling rate as obtained from pore water profiles vary between 8 and 92%, with an average value of about 32%, which highlights the importance of the estuarine filter for silica. Recycling is much more intense in the coastal area, with values up to 40%, which we explain by higher salinity and higher sediment permeability. The different experiments and results also indicated that secondary mineral precipitation might be and important process affecting BSiO2 in the Scheldt sediments.

The Environmental Protection Administration of Executive Yuan has been promoting the environmental protection policy for years, hoping to achieve the goal of ¡§zero waste¡¨ and meet the international environmental standard by executing source minimization and resource recycling. The study aims to investigate the causality between the disbursement incurred from waste management and the effectiveness of control measures of the 22 Taiwan¡¦s administrative regions from 2001 to 2010; variables of the examination are, disbursement incurred from waste management , disposal or treatment rate of municipal waste, and recycling rate of enforcement authority. After the gathering of data, the Granger test is conducted to determine the causality. Given that the data of disbursement incurred from waste management is hard to gather and the details of the actual disbursement of the evaluation indices are impossible to separate, the study postulates that, with consideration of the consistency and continuity of the budgeting process and the massive accident, all the disbursement incurred from waste management is used for the said purpose. The result of the empirical research indicates that disposal or treatment rate of municipal waste and disbursement incurred from waste management are not causally related. In the Granger test, the correlation between disbursement incurred from waste management and recycling rate of enforcement authority are significant at the 0.01 level; the correlation between recycling rate of enforcement authority and disbursement incurred from waste management are significant at the 0.1 level. Therefore, the ¡§Zero Waste¡¨ and ¡§source minimization and resource recycling¡¨ policy promoted by the Administration is effective in reducing the disbursement incurred from waste management. If we adhere to the environmental policy, we can not only improve the environmental health and life quality, but also be able to reduce the expense of waste management and invest the resource on other departments to achieve the effect of protecting the environment while maintaining economic growth.

The results from this study show that it is possible to obtain data series on the steel scrap collection based on mass balance model on the crude steel production figures by steelmaking reactor type and additional knowledge on process metallurgy as well as information on inputs and outputs into the reactors with an area correlation coefficient of 0,91 compared to data obtained from trade statistics. Furthermore, the study shows that based on a new method it is possible to calculate the time duration of mass flows on a continuous basis. Furthermore, two complementary statistical dynamic material flow models that can be used to calculate the societal recycling rates of steel was constructed. These statistical models contribute to a standardized way of obtaining consistent results. The new models are able to segregate the non-recirculated amounts of steel into the hibernating steel stock available for future collection from the amounts of losses based on statistics. The results show that it is possible to calculate the amounts of steel scrap available for steelmaking at a given point in time. In addition, based on the new models it is possible to calculate recycling trends in society. Also, the models are able to calculate robust forecasts on the long-term availability of steel scrap, and test if forecast demand of steel scrap exceeds a full recovery. This due to that the steel scrap generation is a function of the collection rate of steel scrap. Also, a method for obtaining representative samplings on the alloy content in steel scrap called random sampling analysis (RSA) was developed. The results from the RSA show that it is possible to optimize the recovery of valuable elements in the production process of steelmaking based on the information on the composition of steel scrap. / <p>QC 20151020</p>

One of the main polluting industries in the world with high environmental impact is the construction industry which also generates a huge amount of waste. To overcome the seburdens, we need to reduce the impacts through new solutions, technologies and by injecting circular economy concept into the industry. Construction and building material industry are responsible for nearly 11% of all GHG emissions and the usage of residential/commercial buildings is contributing to 28% of all GHG emissions globally. the construction industry is also responsible for 35% of the total wastes in the European Union. Both linear economy and emissions of the construction sector are becoming more important in recent years that led to the development of many standards, frameworks and innovations. Reporting environmental burdens of the construction elements, products and construction works or construction projects is one of the ways for emissions accounting. Therefore, a report on environmental impacts of goods or services is called environmental product claims which can be based on a single criterion (like CO2 emission or % of recycled content) or based on a complete LCA study with multiple impacts. These reports have been classified by ISO 14020 series in three types, Type I (third-party certified label), Type II (self-declared claims) and Type III (the third party verified declaration based on LCA study). The third type is known as Environmental Product Declaration (EPD). To make the LCA results in EPD:s comparable, Product Category Rules (PCR) are developed. The regulations for the construction materials are defined in EN 15804 so the declarations of the building materials and construction works according to these regulations are compliant with EN 15804. Another framework for environmental declarations called, Product Environmental Footprint (PEF) is developed in Europe. Besides Business to Business declarations that are the target group for EN 15804, PEF also includes environmental labelling (type I) with consumers as the target group. The PCR:s from the updated version of EN15804:2012+A2:2019 can be regarded as the parallel methodology specification for the construction materials in the PEF system. Other product groups' rules and specifications are based on the PEF guidance document. The overall aims of this study are to compare the EN 15804 and PEF formulas concentrating on credits at the end of life and after the end of life stage and to reduce the subjectivity of two variables, energy margin, and recycling rate in the assessment of recycling alternatives after the end-of-life stage. Calculated credits can be included differently in the environmental declarations depending on the methodological approach. PEF includes the End-of-Life (EoL) credits into the Life Cycle Assessment (LCA) study and adds them to the product's performance results, while EN 15804 mandates to report the credits from recycling/recovery separately as supplementary information to the products environmental performance. To compare the credits that are calculated according to PEF and EN 15804, a separate indicator is virtually defined for PEF in order to calculate all the credits separately and compare the results with EN 15804 Module Dresults to give the reader an overview of the most beneficial uses of the construction waste according to PEF and EN 15804. Reducing subjectivity of choosing recycling rate has been addressed by developing more transparent and less subjective tool by integrating and using DGNB (German Sustainable Building Council) and BRE (center for building research in the UK) methods. For energy margin, this has been done by integrating energy margin calculation tool by CDM (Clean Development Mechanism, United Nations) and find the contribution of different materials to the environmental benefits in and after the end of life stage of the building lifecycle. However, the DGNB and BRE methods require further development, since they are not originally developed for LCA studies and just used as the only current options available in order to make recyclability assessment methods compatible with LCA studies. Other methods, specifically for LCA, can also be developed in the future. Based on an inventory of the components and materials used in a real building, the most environmental benefits (credits) from downstream recycling/recovery considering all materials are generated for the wooden products when using the EN 15804 formula, while aluminium is in the second place. On the other hand, aluminium is in the first place and wood is second using the PEF formula. Aluminium has by far the most benefits (credits) considering the credits per kg of each material, due to the huge recycling potential that aluminium has and will replace primary aluminium in the future. Unlike PEF, EN 15804 reports all credits separately outside of the LCA system boundary. This is very beneficial since the correct verified LCA will not beaffected by the credits that are given based on current technologies when the end of life of the building components are between 40 to 120 years away from today. / En av de industrier i världen med högst miljöpåverkan är byggbranschen som också genererar en enorm mängd avfall. För att hantera detta måste vi minska effekterna genom nya lösningar, teknologier och genom att använda konceptet cirkulär ekonomi i byggbranschen. Bygg- och byggnadsmaterialindustrin är ansvarig för nästan 11% av alla växthusgasutsläpp och användningen av bostäder / kommersiella byggnader bidrar till 28% av allaväxthusgasutsläpp globalt. Byggbranschen ansvarar också för 35% av det totala avfallet i EU. Både linjär ekonomi och utsläpp från byggsektorn har blivit viktigare under de senaste åren vilket har lett till utveckling av många standarder, ramverk och innovationer. Att rapportera miljöbelastningar för byggelement, produkter och bygg- och anläggningsarbeten är ett av sätten för utsläppsredovisning. Därför kallas en rapport om miljöpåverkan av varor eller tjänster Miljömärkning som kan baseras på ett enda kriterium (som CO2-utsläpp eller procent av återvunnet innehåll) eller baserat på en fullständig LCAstudie med flera effekter. Dessa rapporter har klassificerats enligt ISO 14020-serien i tre typer, typ I (tredjepartscertifierad märkning), typ II (självdeklarerade påståenden) och typ III (tredjepart verifierad deklaration baserad på LCA-studie). Den tredje typen är känd som Miljövarudeklaration/Environmental Product Declaration (EPD). För att göra LCA-resultat i EPD:er jämförbara, utvecklas Product Category Rules (PCR) (Produktkategoriregler). Regler för byggnadsmaterialen definieras i EN 15804, så deklarationerna om byggnadsmaterial och byggnadsarbeten enligt dessa regler överensstämmer med EN 15804. Ett annat ramverk för miljödeklaration är ProductEnvironmental Footprint (PEF) som är utvecklad inom EU. Förutom Business to Businessdeklarationer som är målgruppen för EN 15804 inkluderar PEF också miljömärkning (typ I) med konsumenter som målgrupp. PCR:erna från den uppdaterade versionen av EN 15804:2012 + A2: 2019 kan betraktas som den parallella metodspecifikationen för byggmaterialen i PEF-systemet. Andra produktgruppers regler och specifikationer är baserade på PEFs vägledningsdokument. De övergripande syftena med denna studie är att jämföra formlerna EN 15804 och PEF som koncentrerar sig på krediter i slutet av livscykeln och att minska subjektiviteten för två variabler, energimarginal och återvinningsgrad vid bedömningen av återvinningsalternativ i slutet av livscykeln. Beräknade krediter kan inkluderas olika i miljödeklarationerna beroende på den valda metoden. PEF inkluderar slutet av livscykeln (EoL)-krediter i livscykelanalys (LCA) -studien och lägger dem till produktens resultat, medan EN 15804 kräver att krediterna från återvinning rapporteras separat som kompletterande information till produkternas miljöprestanda. För att jämföra krediter som beräknas enligt PEF och EN 15804, definieras en virtuell separat indikator för PEF för att beräkna alla krediter separat och jämföra resultaten med EN 15804 Modul D-resultat för att ge läsaren en översikt över de mest fördelaktiga användning av byggavfall enligt PEF och EN 15804. Olika sätt att minska subjektiviteten i valet av återvinningsgrad behandlas genom att utveckla mer transparenta och mindre subjektiva verktyg med hjälp av metoder från DGNB (German Sustainable Building Council) och BRE (Center for building research, UK). Energimarginal behandlas genom att integrera ett verktyg för energimarginaler från CDM (Clean Development Mechanism, FN) och hitta bidraget från olika material till miljöfördelarna i och efter livscykeln för byggnaden. DGNB och BRE metoderna kräver emellertid ytterligare utveckling, eftersom de inte ursprungligen är utvecklade för LCA-studier och bara används som de enda tillgängliga alternativen för att göra utvärderingsmetoder för återvinningsbarhet kompatibla med LCA-studier. Andra metoder, speciellt för LCA, kan också utvecklas i framtiden. Baserat på en inventering av komponenter och material som används i en riktig byggnad, genereras de största miljömässiga fördelarna (krediter) av nedströms återvinning av träprodukter när man använder EN 15804-formeln, medan aluminium ligger på andra plats. Å andra sidan är kommer aluminium i första hand och trä kommer på andra plats med PEFformeln. Aluminium har överlägset flest fördelar (krediter) per kg av varje material, på grundav den enorma återvinningspotentialen som aluminium har och kommer att ersätta primärt aluminium i framtiden. Till skillnad från PEF rapporterar EN 15804 alla krediter separat utanför LCA-systemgränsen. Detta är mycket fördelaktigt eftersom den korrekta verifierade LCAn inte kommer att påverkas av de krediter som ges baserat på nuvarande teknik när byggnadskomponenternas livslängd är mellan 40 och 120 år från idag.

Le but général de ce travail fut de quantifier la silice biogène (BSiO2) dans les sédiments du continuum de l'Escaut (estuaire – zone côtière), ainsi que son taux de recyclage - rétention. Le coefficient de diffusion moléculaire de la DSi a été déterminé pour différentes valeurs de température et deux salinités et une relation empirique reliant le coefficient de diffusion à la température et à la viscosité de la solution a été établie. La distribution longitudinale de la BSiO2 dans les sédiments de surface, ainsi que les profils verticaux de BSiO2 et de silice dissoute ont été déterminés durant différentes saisons en 2004 et 2005. Les flux de DSi ont été également estimés via des expériences d’incubations et par modélisation des profiles verticaux de DSi. Des expériences de dissolution des sédiments ont permis de déterminer (via modélisation) les constantes cinétiques de vitesse de la BSiO2 et une première évaluation du taux de recyclage de la BSiO2 (5 – 70%). Sur base des calculs à partir des profiles de DSi dans l’eau interstitielle, le taux de recyclage de la BSiO2 varie entre 8 et 92% dans l’estuaire, ce qui correspond à une rétention moyenne de la BSiO2 supérieure à 60%, et souligne ainsi l'efficacité du filtre estuarien par rapport à la silice. En revanche, le recyclage de BSiO2 dans la zone côtière apparaît comme très intensif, avec des valeurs souvent supérieures à 40%. Ces résultats montrent l'importance d'inclure les estuaires dans le calcul des budgets globaux de Si. / The general objective of this study was to quantify the BSiO2 in the sediments of the Scheldt continuum, together with its recycling and retention in this area. First an empirical relation linking the diffusion coefficient of DSi to temperature and salinity was determined, via diffusion experiments. The longitudinal BSiO2 distribution in surface sediments and the vertical BSiO2 and DSi profiles in sediment cores where then measured during 2 years and different seasons, together with other parameters characterizing pore waters, such as alkalinity, pH, sulphate… DSi fluxes were also estimated either directly through whole core incubations measurements or via modelling of interstitial water profiles. BSiO2 dissolution experiments allowed the evaluation of the kinetic rate constants also through modelling of the results, and gave preliminary information over the BSiO2 recycling rates (5 – 70%). The recycling rate as obtained from pore water profiles vary between 8 and 92%, with an average value of about 32%, which highlights the importance of the estuarine filter for silica. Recycling is much more intense in the coastal area, with values up to 40%, which we explain by higher salinity and higher sediment permeability. The different experiments and results also indicated that secondary mineral precipitation might be and important process affecting BSiO2 in the Scheldt sediments.<p> / Doctorat en Sciences / info:eu-repo/semantics/nonPublished