Les matériaux architecturés font émerger de nouvelles possibilités en termes de propriétés structurales et fonctionnelles, repoussant ainsi les limites des cartes d'Ashby. Le terme "matériaux architecturés" inclus toute microstructure conçue de façon astucieuse, de sorte que certaines de ses propriétés soient optimisées. Les exemples sont nombreux : composites fibreux et particulaires, matériaux cellulaires, structures sandwiches, matériaux tissés, structures treillis, etc. Un enjeu de taille pour l'emploi de tels matériaux est la prédiction de leurs propriétés effectives. Dans ce travail, deux types de microstructures sont considérées : des structures auxétiques périodiques et des milieux fibreux aléatoires. Les auxétiques sont des matériaux apparus au milieu des années 1980, présentant un coefficient de Poisson négatif. On attend des auxétiques qu'ils présentent des propriétés mécaniques améliorées, comme le module de cisaillement ou la résistance à l'indentation. Les milieux fibreux aléatoires considérés dans ce travail sont constitués de fibres 3D infinies interpénétrantes aléatoirement distribuées et orientées. Ce type de structure aléatoire est très défavorable à la détermination d'une taille de volume élémentaire statistiquement représentatif. Pour les deux types de matériaux, l'homogénéisation numérique à l'aide de la méthode des éléments finis est implémentée dans le but d'estimer les propriétés thermiques et mécaniques effectives. / Architectured materials bring new possibilities in terms of structural and functional properties, filling gaps and pushing the boundaries of Ashby's materials maps. The term "architectured materials" encompasses any microstructure designed in a thoughtful fashion, so that some of its materials properties have been improved. There are many examples: particulate and fibrous composites, foams, sandwich structures, woven materials, lattice structures, etc. One engineering challenge is to predict the effective properties of such materials. In this work, two types of microstructures are considered: periodic auxetic lattices and stochastic fibrous networks. Auxetics are materials with negative Poisson's ratio that have been engineered since the mid-1980s. Such materials have been expected to present enhanced mechanical properties such as shear modulus or indentation resistance. The stochastic fibrous networks considered in this work is made of 3D infinite interpenetrating fibres that are randomly distributed and oriented. This case of random structure is challenging regarding the determination of a volume element size that is statistically representative. For both materials, computational homogenization using finite element analysis is implemented in order to estimate the effective thermal and mechanical properties.

It has become popular for political scientists to discuss the transformation from government to governance and the networks’ greater influence on public policymaking. However, this debate lacks methodological, empirical and theoretical research about the relationship between governance networks and representative democracy. The main objective of this essay is to understand the relationship between governance networks and representative democracy through a case study of the governance network Leader Linné. The theoretical framework includes four analysis models about the relationship between governance networks and representative democracy that are analysed by five factors connected to representative democracy. Each model has a specific approach to the public policymaking in networks e. g. were the power lies, how the general interest is understood and the role of politicians. The essay is designed as a case study combined with interviews of participants from the network’s national, regional and local level. The result of the essay is that the relationship between the governance network and representative democracy is complemental, meaning that representative democracy makes the central decisions in society where secondary decisions are made through a combination of representative- and participate democracy introduced by Leader. In Leader Linné the general interest is formed at EU level and politicians have a managerial role.

Cette thèse s’inscrit dans le champ de recherche en ergonomie qui porte sur les acteurs de la prévention. Elle défend l’idée que l’activité des représentants du personnel est un travail et qu’il est possible de contribuer au développement de leur activité à travers des interventions ergonomiques.Elle a été conduite auprès de sept CHSCT de métiers différents de la SNCF et fait suite à une demande sociale formulée par l’Observatoire de la Qualité de Vie au Travail de cette entreprise. Les membres de cet Observatoire souhaitaient avoir un éclairage scientifique pour comprendre les difficultés de fonctionnement de ces instances et les possibilités d’y améliorer la prise en compte du travail pour contribuer à la prévention de la pénibilité.Par l’Analyse Ergonomique du Travail, il a été possible de comprendre les spécificités de cette activité. Plusieurs interventions ergonomiques ont été mises en place au sein de sept CHSCT pour mettre à l’épreuve les diagnostics locaux réalisés. Il a ainsi été possible de contribuer au développement de l’activité des représentants du personnel.Cette thèse démontre que les représentants du personnel sont des praticiens qui contribuent par leur activité à résoudre les problèmes de l’entreprise. Pour autant, le cadre réglementaire ne leur permet pas de prendre en charge le caractère dynamique des situations de travail des salariés et les possibilités d’action de leur propre activité. Cela les amène à définir des modes d’action qui soient en adéquation avec l’environnement dynamique dans lequel ils agissent.Il leur est de fait nécessaire de construire un référentiel commun permettant d’articuler une nécessité d’agir ensemble tout en tenant des points de vue individuels. La conflictualité et la coopération sont par conséquent inhérentes au mode de fonctionnement des CHSCT. Toutefois, ce cadre commun doit s’appuyer sur d’autres éléments que la réglementation et il est nécessaire de donner une place aux salariés dans la construction des problèmes et des solutions.Il apparaît également qu’il est difficile pour eux de pouvoir débattre des difficultés individuelles et collectives qu’ils rencontrent. Cela contribue au développement de défenses collectives amenant à un traitement des problèmes en vase clos au sein de l’instance.Dès lors, l’intervention ergonomique doit faciliter une activité collective par la mise en débat des pratiques et des difficultés individuelles et collectives. Toute la difficulté pour l’intervenant étant qu’il ne s’appuie pas sur un collectif de travail qui pour autant doit développer un travail collectif. Il s’agit ainsi de contribuer à ce que le dénominateur commun entre les membres permette d’y intégrer la complexité du travail et les salariés. En cela, la conflictualité et la coopération doivent s’articuler autour des situations de travail des salariés et non uniquement de l’application de la réglementation. / This dissertation falls within a field of research in ergonomics focused on health and safety staff. It defends the idea that the activity of staff representatives is to be considered as work and that it is possible to contribute to the development of their activity thanks to ergonomic interventions.This research was carried out by studying seven CHSCTs (Occupational Health and Safety Committee) of different professions at the SNCF (French National Rail Company), and was ordered by their Observatoire de la Qualité de Vie au Travail (Monitoring Agency for Quality of Life in the Workplace). The members of the Observatoire wanted a scientific study to help them understand the functional difficulties encountered by the CHSCTs, and the possibilities for improving work analysis, in turn improving their prevention work.Thanks to an Ergonomic Work Analysis, we were able to understand the specificities of this activity. Several ergonomic interventions were organized in order to test previous local diagnostics. We were thus able to contribute to the development of the activity of staff representatives.This dissertation shows that staff representatives are practicians who, through their activity, contribute to problem solving in the company. The current regulations framework does not permit them to take into account the dynamic nature of employees' work situations, nor the possibilities for action in their own work. This has lead them to defining modes of action that are in line with the dynamic environment in which they are called upon to intervene.It is therefore necessary for them to build a common frame of reference in order to act together, while still retaining individual points of view. Inevitably, conflictuality and cooperation are inherent to the functioning of CHSCTs. This common framework however must be based upon other elements besides regulations, and it is necessary to give employees a say in the formation of both problems and solutions.It also appears to be difficult for them to discuss the individual and collective difficulties that they encounter. This contributes to the development of collective defenses, leading to a closed, in-house treatment of the workers situational problems.As such, ergonomic interventions must facilitate collective activity by questioning both individual and collective pratices and difficulties. The challenge for the ergonomist is that he cannot base his intervention upon a work collective, which must none-the-less produce a collective work. Therefore the contribution must work towards a common denominator between the members, allowing for the integration of both the complexity of work and the employees. In that, conflictuality and cooperation must be articulated around employees' work situations, and not only the application of regulations.

Cohabitation is becoming more prevalent in western society so that up to 7.5 million cohabiting couples were reported in the USA for the year 2010. The present study investigated whether the cohabitants’ attachment style might be one of the reasons for cohabitation gaining such popularity. Attachment styles as well as socio-demographic variables were compared in regard to the partnership status. A sample of 1,002 participants aged 18 to 60 were used as a representative sample (M = 43.5, SD = 10.9), of which 54% were female and 82% were married. The cohabitants were younger, more highly educated, and less frequently affiliated with a church. The cohabitants were more anxious-attached, especially those of a younger age. A one-point increase in value on the AAS anxiety scale almost doubled the possibility of cohabitation. Most of the variance can be explained by socio-demographic variables. However, based on these representative data, and after controlling for socio-demographic variables, attachment anxiety is still connected to cohabitation. The diverse results in the literature may be explained by differences in the socio-demographic characteristics of the sample.

Le sujet de thèse concerne l’analyse et la prédiction de la corrosion des renforts métalliques exposés dans des environnements représentatifs. Dans cette étude, le système va se complexifier en commençant à partir du renfort métallique délaitonné (acier perlitique) en passant par le renfort métallique laitonné (couche de laiton) pour finir avec le renfort métallique sulfuré (couche de sulfures). Cette approche permet de comprendre pas à pas les phénomènes de corrosion ainsi que l’interaction entre les différentes couches. Les matériaux de l’étude sont caractérisés au départ par des techniques de microscopies (MEB-EBSD, MET) et d’analyses de surface (XPS, Auger). Ces informations microstructurales et de composition chimique sont essentielles pour l’interprétation des essais de corrosion. Les essais électrochimiques sont ensuite réalisés dans 0,1M NaCl pour observer et quantifier le comportement en corrosion des trois types de renforts de l’étude. La quantification est un élément important pour établir des modèles prédictifs de corrosion. Deux types de techniques électrochimiques sont utilisés, les mesures à l’échelle globale (Voltampérométrie, Impédance électrochimique, couplage galvanique…) et les mesures à l’échelle locale (microcellule). Les essais à l’échelle locale sont directement reliés aux cartographies EBSD grâce à la microcellule. Un lien direct microstructure-corrosion est donc établi. A partir des essais électrochimiques, des analyses de solutions (SAA, ICP…) ainsi que des mesures de pH localisées sont réalisés pour quantifier les espèces passant en solution. Ces résultats sont des données d’entrée pour définir un milieu représentatif. De nouveaux essais électrochimiques sont enfin effectués dans le milieu représentatif pour étudier l’impact de ce nouveau milieu sur la corrosion des renforts métalliques. / This work deals with analysis and corrosion prediction of steel cords exposed in representative environments. In this study, the system will become more and more complex starting from “délaitonné” metal reinforcement (perlitic) via the brass metal reinforcement (brass layer) to finish with the metal reinforcement sulfide (sulfide layer). This approach allows you to understand step by step corrosion phenomena and the interaction between different layers. Materials of the study are first characterized by microscopy techniques (SEM-EBSD, TEM) and surface analysis (XPS, Auger). These microstructural informations and chemical composition are essential for interpretation of corrosion tests. Electrochemical tests are worked out in 0,1M NaCl to observe and quantify corrosion behavior of the three kind of steel cords. Quantification is a significant element to establish predictive corrosion models. Two electrochemical techniques are used, measurements at global scale (voltammetry, electrochemical impedance, galvanic coupling ...) and locally measurements (microcell). Measurements at the local scale are directly linked to EBSD maps thanks to the microcell. A direct link microstructure-corrosion is established. From electrochemical tests, solutions analysis (AAS, ICP ...) and local pH measurements are performed to quantify species passing into solution. These results are input data to define a representative environment.New electrochemical tests are then performed in this representative solution to study the impact of this medium on the steel cords corrosion.

Magister Administrationis - MAdmin / The call centre industry has been one of the fastest growing industries in South Africa. Call centres have for most companies become a basic business requirement for servicing customers. Zapf, Isic, Bechtoldt and Blau (2003: 311) argue that there are high levels of stress amongst employees in call centres, which they believe to be the result of both the work tasks and the interactions with customers. The aim of this study was to establish whether call centre work design and structure contributed to role stress amongst client service representatives (CSRs). It was also the aim of this study to establish whether role stress affected the CSRs' levels of job satisfaction and their intentions to quit from their jobs. / South Africa

Masters in Public Administration - MPA / Municipal councils are vested with the legal authority to promote financial accountability in their respective municipalities. To accomplish this responsibility, municipal council establishes committees to enable a structured and coordinated mechanism through which it can promote financial accountability effectively. However and despite the available legal and institutional mechanisms established to enable council committees to promote financial accountability, the lack of effective financial accountability in municipalities has persisted. This study focused on the role of council committees in ensuring financial accountability. It was guided by the following research questions: What are the major factors that contribute to financial accountability at local level, what is the role of council committees in promoting financial accountability and how can council committees be strengthened to play an effective role in Stellenbosch municipality’s municipal financial accountability. Stellenbosch Local Municipality was used as a case study for this research. The data was collected from primary and secondary sources. Primary data was sourced from members of relevant council committees through structured and unstructured interviews. Secondary data was obtained from relevant municipal reports, internet sources, government department publications, journals and Auditor - General’s reports which contributed to the reliability, validity and objectivity of the findings. The findings showed that political instability, a lack of a culture of accountability, lack of clearly defined authority for accountability, lack of relevant capacity and willingness are some of the major factors that have impacted negatively on council committees from promoting effective financial accountability. The study opens up the possibility of future research to include a wider number of municipalities. / South Africa

As recent immigrants seek a productive and dignified life in “new immigrant destinations” that have little historical experience with immigration, public education systems serve a key function in immigrant integration efforts. In a federal system increasingly focused on accountability, a crucial sub-set of education policy and local responsiveness to immigration is English language instruction and services for Limited English Proficient (LEP) students and parents. In such contexts, the role that local bureaucrats play, and whether they actively represent the interests of the newfound diversity of community members, are crucial questions if strongly held American ideals of social equity and equal opportunity are to be upheld. This research asks broad questions at the intersection of bureaucratic power, representative bureaucracy and educational policy toward English language learners at the local level. Variations in how school systems in the political bellwether of Virginia responded to a recent policy shock - federal guidance released in January 2015 that reiterated local school system responsibility for providing equal educational access to LEP students and parents – form a unique window into local policy-making. Using a concurrent triangulation mixed methodology that consists of a state-wide survey and interviews with a sub-set of the Title III coordinators who supervise programs for English Language Learners, this research shows Title III coordinators to be unrepresentative in passive terms of the foreign born population but nevertheless to have a strong sense of advocating for English Language Learners. Findings suggest that public service motivation is the key explanatory factor in driving a sense of role advocacy and this in turn drives a greater range of action taking by the coordinator to benefit ELLs. Despite this link between role advocacy and coordinator action, role advocacy is not found to be significant in driving the likelihood or range of system level responsiveness to the letter. Instead, political and demographic factors increase the likelihood of system action but, counter to existing literature, more conservative localities are found to be more likely to have responded to the Dear Colleague Letter. This suggests that a previous reluctance to act in these places may have been dislodged by the letter and points to the importance of change over time in conceptualizing local responsiveness to immigrants.

Please read the abstract in the dissertation Copyright / Dissertation (MSW)--University of Pretoria, 2010. / Social Work and Criminology / unrestricted

Composite materials show heterogeneity at different length scales. hence concurrent multiscale analysis is the only reliable method to analyze them. But unfortunately there is no concurrent multi-scale strategy that is efficient, and accurate while addressing all kinds of problems. This lack of reliability is partly because there is no micro-mechanical model which inherently keeps all relevent global information with it. This thesis tries to fill this gap. The presented micro-mechanical model not only homogenizes the micro-structure but also keeps the global information with it. Most of the micro-mechanical models in the literature extract the Representative Volume Element (RVE) from the continuum for analysis which results in loss of information and accuracy. In the present approach also, the RVE has been extracted from the continuum but with the major difference that all the macro/meso-scopic parameters are accounted for. Five macro/meso-scopic one dimensional parameters have been defined which completely define the effect of continuum. 11 for one dimensional stretch, _1 for torsion, __ (_ = 2, 3) for bending and _33 for uniform pressurization due to the presence of the continuum. Further, the above macro/meso-scopic parameters are proven, by the asymptotic, theory to be constant at a cross section but vary, in general, over the length of the fiber. Hence, the analysis is valid for any location and is not restricted to any local domain. Three major problems have been addressed: • Homogenization and analysis of RVE without any defects • Homogenization and analysis of RVE with fiber-matrix de-bonding • Homogenization and analysis of RVE with radial matrix cracking. Variational Asymptotic Method (VAM) has been used to solve the above mentioned problems analytically. The results have been compared against standard results in the literature and against 3D FEA. At the end, results for “Radial deformation due to torsion” problem will be presented which was solved “accidentally.”