Thermoelectric generators (TEG) are re-emerging technology that can be used to recover heat waste from commercial and industrial processes to generate electricity, enhancing fuel utilization and lowering greenhouse gas emissions. TEG modules are solid-state heat engines that produce no noise or vibration during operation. Notably, TEG modules are also able to operate at low-temperature differences, which makes them ideal for a wide range of heat waste recovery applications. Annular thermoelectric generator (ATEG) modules are optimal in applications where either the heat source or sink are round in shape. Bi2Te3 solution-based compounds are of significant interest in the application of thermoelectric materials (TE) used in low-temperature cooling and power generation applications. The main objective of the current work is to design a mechanically reliable ring-shaped ATEG module with a predictable performance using spark plasma sintered Bi2Te3 TE material for low temperature waste heat recovery applications. In terms of structure, this work is divided into two parts. The first part investigates how the use of a powder pre-treatment technique affects the mechanical and thermoelectric properties of P- and N-type Bi2Te3. In addition, part one also presents the measurements of these materials’ mechanical and thermoelectric properties, which serve as inputs for the finite element models used to design thermoelectric modules with parallel and perpendicular configurations vis-a-vis the sintering pressing direction. The second part evaluates the thermoelectric performance and thermal stresses of a ring-shaped ATEG couple that has been integrated between hot-side and cold-side heat exchangers. To this end, two configurations are compared with respect to their heat/electrical current flow paths: one that allows for radial flow (radial configuration), and one that allows for axial flow (axial configuration). The P- and N-type Bi2Te3 powder was treated using a mechanically agitated fluidized powder reduction facility that was built in-house. The characteristic uniaxial tensile strength of the P-type Bi0.4Sb1.6Te3 increased from 13.9 MPa to 26.3 MPa parallel to the sintering pressure, and from 16.3 MPa to 30.6 MPa perpendicular to the sintering pressure following oxide reduction using 5% H2 ˗ 95% Ar at 380 ℃ for 24 h. The figure of merit, ZT, increased from 0.35 to 0.80 and from 0.42 to 1.13 at room temperature (25 ℃) in the parallel and the perpendicular directions, respectively, after the surface oxide reduction treatment. On the other hand, the annealing effects of the oxide reduction pr-treatment of the N-type (Bi0.95 Sb0.05)2(Se0.05 Te0.95)3 using 5% H2 ˗ 95% Ar at 380 ℃ for 24 h were found to be responsible for the majority of the mechanical properties and ZT enhancement. Additionally, the characteristic uniaxial tensile strengths for this material increased from 30.4 to 34.1 MPa and from 30.8 to 38 MPa in the parallel and the perpendicular directions, respectively. The ZTmax (150 ℃) increased from 0.54 to 0.63 in both the parallel and perpendicular directions due to oxide reduction, while annealing led to an increase to 0.58 and 0.62 in the parallel and the perpendicular directions, respectively. An analytical model was constructed to compare the thermoelectric performance of the two configurations under three different hot-side thermal resistances, and a 3D coupled finite element ANSYS model was constructed to study and compare the thermal stresses of the two configurations at different dimensions. The two models were then used to create 2D maps in order to investigate the effects of ATEG couple configuration and dimensions, as well as the hot-side thermal resistance, with the goal of identifying the optimum design. The optimization of module geometry requires a trade-off between performance and mechanical reliability. The results of these investigations showed that increases in the temperature difference across the ATEG couple (ΔT) led to increases in both power and thermal stresses in both configurations. When both configurations were generating the same power at ΔT = 105 ℃, the thermal stresses in the radial configuration were as much as 67 MPa higher than those in the axial configuration due to the formation of additional tensile hoop stresses. The lowest thermal stress obtained for the axial couple configuration was 67.8 MPa, which was achieved when the couple had an outer diameter of 16 mm, an axial thickness of 1 mm, a ΔT of 14.8 ℃, and power generation of 10.4 mW per couple. The maximum thermal stress values were located at the corners of the interface between the solder and the TE rings due to the mismatched coefficient of thermal expansion. This thesis makes a novel contribution to the state-of-the-art literature in ring-shaped ATEG modules, as it details a well-characterised spark plasma sintered Bi2Te3 TE material and a methodology for designing a ring-shaped ATEG module with reliable, robust, and predictable thermoelectric and mechanical performance. The details of the contribution made by this work have been disseminated in the form of three journal publications, which have been integrated into this sandwich Ph.D. thesis. / Thesis / Doctor of Science (PhD)

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Das Institut für Kern- und Teilchenphysik (IKTP) der Technischen Universität Dresden (TUD) hat im Forschungszentrum Dresden-Rossendorf (FZD) ein Labor zur Untersuchung von neutroneninduzierten kernphysikalischen Prozessen in Materialien, die für die Fusionsforschung relevant sind, aufgebaut. Das Labor ist ausgestattet mit drei intensiven Neutronenquellen: einer 14 MeV-Neutronenquelle, einer weißen kontinuierlichen Photoneutronen-Quelle, die näher in dieser Arbeit beschrieben wird, und einer gepulsten Photoneutronen-Quelle, die vom FZD inKooperation mit der TUD aufgebaut wurde. Die kontinuierliche Photoneutronen-Quelle basiert auf einem Radiator aus Wolfram (engl. Tungsten Photoneutron Source (TPNS)). TPNS nutzt die im ELBE-Beschleuniger (Elektronen Linearbeschleuniger für Strahlen hoher Brillianz und niedriger Emittanz (ELBE)) beschleunigten Elektronen zur Neutronenerzeugung. Der Prozess läuft über Zwischenschritte ab, indem bei der Abbremsung der Elektronen im Radiator Bremsstrahlungsphotonen entstehen, die anschließend Neutronen durch (γ,xn)-Reaktionen erzeugen. Das Neutronenspektrum der TPNS kann mittels Moderatoren so modifiziert werden, dass es dem in der ersten Wand im Fusionsreaktor entspricht. Dies ermöglicht Untersuchungen mit einem für einen Fusionsreaktor typischen Neutronenspektrum. Die technische Verwirklichung des Projektes, die Inbetriebnahme der Anlage sowie die Durchführung der ersten Experimente zur Neutronenerzeugung ist Inhalt dieser Arbeit. Die Neutronenquelle ist insbesondere für qualitative Untersuchungen in der Fusionsneutronik bestimmt. Der Fusionsreaktor produziert, im Vergleich zu einem Spaltungsreaktor, keine langlebigen Isotope als Abfall. Die wesentliche Aktivität des Reaktors ist in Konstruktionsmaterialien akkumuliert. Durch sorgfältige Auswahl der Materialien kann man die Aktivierung minimieren und damit künftig wesentlich weniger radioaktives Inventar produzieren als in Spaltreaktoren. Ziel der kernphysikalischen Untersuchungen ist, solche Materialien für den Aufbau eines Fusionsreaktors zu erforschen, die niedrigaktivierbar sind, das heißt wenig Aktivität akkumulieren können, und eine Halbwertzeit von einigen Jahren haben. Es ist das Ziel, alle Konstruktionsmaterialien nach 100 Jahren wiederverwenden zu können. Die Neutronenflussdichte einer Photoneutronenquelle ist einige Größenordnungen höher als die, die mittels eines DT-Neutronengenerators mit anschließender Moderation erreicht werden kann. Die gesamte Arbeit ist in drei Teile geteilt. Der erste Teil leitet in die Problematik der Energieversorgung ein und zeigt die Kernfusion als eine vielversprechende Energiequelle der naher Zukunft auf. Das Neutronenlabor der TUD, in dem die TPNS aufgebaut ist, wird ebenfalls kurz vorgestellt. Der zweite Teil befasst sich mit der TPNS selbst, mit ihrem physikalischen Entwurf, der Konstruktion und dem Aufbau bis zu der Inbetriebnahme sowie dem ersten Experiment an der TPNS. Der letzte, dritte Teil ist die Zusammenfassung der vorhandenen Ergebnisse und gibt einen Ausblick auf die zukünftige Vorhaben. / The Institute for Nuclear and Particle Physics at the Technische Universität Dresden (TUD) has build a neutron physics laboratory at Forschungszentrum Dresden-Rossendorf (FZD) to investigate nuclear processes in materials. The experiments are focused on materials relevant to nuclear fusion. The laboratory is equipped with three intensive neutron sources. The first is a 14 MeV monochromatic neutron source based on the DT reaction (owned by TUD); the other two are continuous and pulsed white photoneutron sources based on (γ,xn) reactions. One pulsed photoneutron source is realized by FZD in cooperation with the TUD. The continuous photoneutron source utilises a tungsten radiator (Tungsten Photoneutron Source) to produce neutrons with a wide energy spectra. The TPNS uses the ELBE-accelerator as a source of electrons for neutron production. This process involves an intermediate step, where slowed down electrons produce bremsstrahlung (γ -rays) absorbed by tungsten nuclei. Consecutively, the excited nuclei emit neutrons. The neutron flux of the photoneutron source is five orders of magnitude higher than the flux of the DT neutron sources with appropriate moderation. The neutron spectrum of TPNS can be modified by moderators, in such a way that the spectrum is comparable to that in the first wall of a Tokamak-Reactor. That allows investigations with the typical neutron spectrum of the fusion reactor. The technical solution, initial operation and the first experiment are described in this work. The neutron source is, in particular, dedicated to quantitative investigations in fusion neutronics. A fusion reactor produces radioactive isotopes as a nuclear waste. The main activity is accumulated in the structural materials. Carefully selected structural materials can significantly minimize the activity and thereby the amount of nuclear waste. The purpose of this project is to find constructional materials with half-lives shorter than several years, which can be recycled after about 100 years. The work is divided into three parts. The first part is dedicated to the energy supply problem and nuclear fusion is addressed as a promising solution of the near future. The neutron laboratory housing the TPNS is also briefly described. The second part deals with the tungsten photoneutron source, the design, construction, operation and the first experiments for neutron production. The third part summarises results and presents an outlook for future experiments with the TPNS.

Every day, billions of mobile network log data (commonly defined as Call Detailed Records, or CDRs) are generated by cell phones operators. These data provide inspiring insights about human actions and behaviors, which are essentials in the development of context aware appli- cations and services. This potential demand has fostered major research activities in a variety of domains such as social and economic development, urban planning, and health prevention. The major challenge of this thesis is to interpret CDR for human activity recognition, in the light of background knowledge of the CDR data context. Indeed each entry of the CDR is as- sociated with a context, which describes the temporal and spatial location of the user when a particular network data has been generated by his/her mobile devices. Knowing, by leveraging available Web 2.0 data sources, (e.g., Openstreetmap) this research thesis proposes to develop a novel model from combination of logical and statistical reasoning standpoints for enabling human activity inference in qualitative terms. The results aimed at compiling human behavior predictions into sets of classification tasks in the CDRs. Our research results show that Point of Interest (POI)s are a good proxy for predicting the content of human activities in an area. So the model is proven to be effective for predicting the context of human activity, when its total level could be efficiently observed from cell phone data records.

Smart energy city (SEC) development is a component of the urban development initiative smart city, which has been a popular response to the global energy challenge in Europe during the past two decades. SEC development aims to increase the sustainability of urban energy systems and services. Since 2011, SEC development has been supported by the European Commission as part of the Strategic Energy Technology plan (SET-Plan) and through the European Union Programmes for Research and Technological Development (specifically FP7 and Horizon 2020). This, along with the promising vision of SEC development and considerable financial support by the private sector, has encouraged numerous European cities to initiate SEC projects. Successful implementation of these projects at the urban scale is crucial to achievement of urban energy objectives and sustainability of future urban development. The here presented thesis aims to support urban decision-makers towards successful implementation of urban scale smart energy city development in Europe. The study includes three stages. The first stage is dedicated to conceptual analysis. Within this stage, I conceptualized smart city through a keyword analysis of existing literature on the concept. Then, within the context of the smart city concept, I defined SEC development through literature review and expert knowledge elicitation. The second stage is dedicated to empirical investigation. Using the definition of SEC development, I distinguished and investigated 43 previously implemented SEC projects to identify common barriers that hinder successful implementation of SEC development. In addition, I proposed a new multi-dimensional methodology that allows a simultaneous prioritization of barriers against their probability, the level of impact, scale, origin, and relationship with other barriers. The third stage of the thesis is dedicated to learning methodologies that allow efficient transfer of knowledge from the past SEC experiences to the new SEC developments. I introduced the application of two learning methodologies that support decision-makers to predict barriers to the implementation of a new SEC project: case-based learning and decision tree learning. The former predicts barriers based on internal similarities between the new SEC project and the past projects. The latter uses the past projects and creates a predictive model for each barrier based on internal and external project characteristics. These models are later used to predict barriers to a new SEC project. Both methodologies were tested in a new SEC project, named SINFONIA. The conceptual analysis revealed that application of information and communication technologies, the collaboration of multiple stakeholders, integration of multiple urban domains, and sustainability evaluation are the constant characteristics (i.e. principles) of smart city and SEC development. It resulted in, to the best of my knowledge, the first multi-dimensional and comprehensive definition of SEC development, revealing its principles, objectives, domains of intervention, stakeholders, time and spatial dimensions. Furthermore, a list of smart energy solutions in each SEC domain of intervention was provided. The empirical investigation of the past SEC projects resulted in the identification of 35 common barriers to the implementation of SEC development, categorized in policy, administrative, legal, financial, market, environmental, technical, social, and information and awareness dimensions. The barrier prioritization showed that barriers related to collaborative planning, external funding of the project, providing skilled personnel, and fragmented ownership should be the key action priorities for SEC project coordinators. Application of case-based learning methodology resulted in identifying five past SEC projects that were the most similar to the SINFONIA project in terms of project internal characteristics. Investigating the barriers to the similar projects revealed that fragmented ownership is the most probable barrier to implementation of SINFONIA project. Application of the decision trees methodology resulted in generation of 20 barrier models, four of which showed a very good performance in prediction of barriers: lack of values and interest in energy optimization measures, time-consuming requirements by European Commission concerning reporting and accountancy, economic crisis, and local unfavorable regulations for innovative technologies. None of these four barriers were predicted to occur in the SINFONIA project. The application of this method in the SINFONIA showed a higher predicting power when a barrier was absent. The findings of the here presented thesis contribute to successful implementation of SEC development by supporting decision-makers in different phases of SEC projects. The results of the conceptual analysis contribute to a common understanding and foster the dialogue on the concept among various SEC stakeholders, particularly decision-makers and urban planners. The results of the empirical investigation lead to a better comprehension and evaluation of the barriers to the implementation of SEC projects in order to efficiently allocate resources to mitigate barriers. The proposed learning methodologies proved to be promising in helping decision-makers to identify similar projects to a new SEC development and to predict barriers to the implementation of new SEC projects. The thesis concludes that SEC is an outstanding urban development that can make a valuable contribution to the sustainability of urban energy systems. The specific characteristics of SEC development pose new challenges to the future smart and sustainable urban planning. Nevertheless, SEC development brings about unprecedented opportunities for integration and application of advanced quantitative techniques with current urban planning methods. This allows efficient knowledge transfer in not only intra-urban but also inter-urban levels in order to provide a collaborative, integrated and constructive movement towards successful implementation of SEC projects and sustainability of future urban development.

La Vie des Pères, raccolta di racconti esemplari dell’inizio del XIII secolo, aspira alla formazione religiosa cristiana proponendo nella narrazione e nei para-sermoni dell’autore (i prologhi e gli epiloghi ai racconti) un insegnamento teologico. In una prospettiva critica letteraria e storica, questa ricerca analizza la genesi e la ricezione del testo. Le intenzioni poetiche dell’autore determinano l’aggiornamento di una materia narrativa preesistente ai temi spirituali dominanti intorno al 1215 (la confessione, l’eucarestia, il celibato dei chierici). Il pubblico medievale (XIII-XV secolo) ha interpretato il testo a partire dai supporti fisici che lo hanno trasmesso. La tradizione manoscritta è così studiata come un insieme di testimoni di presentazione del testo, più o meno modificato e adattato a diversi contesti (altre opere religiose, testi profani, testi non narrativi) e per diverse comunità interpretative: i possessori dei manoscritti, i lettori che hanno annotato i margini, i copisti che hanno strutturato l’opera con le rubriche. Ne emerge una sostanziale coerenza dell’opera tra la funzione esemplare e l’utilizzo effettivo.

Master’s thesis deals with implementation of a European standard DATEX II. This standard specifies the data format for information transmission in road transport. The road traffic is flowing streams of current information. For the work was selected network of meteorological stations, which will publish the measured data, ie weather conditions of road transport. Measured data will be available to consumers in the format DATEX II. Implementation will be operational in its entirety meteorological station from design to the actual web service that will produce data information for consumers.

L'élaboration de composites à matrice céramique denses et à fibres continues multidirectionnelles par de nouveaux procédés hybrides a été étudiée. Les procédés développés reposent sur le dépôt d'interphases autour des fibres par Infiltration Chimique en phase Vapeur (CVI) puis sur l'introduction de poudres céramiques au sein de préformes fibreuses par infusion de suspensions aqueuses colloïdales concentrées et stables, et enfin sur la consolidation des préformes soit par frittage flash, soit par imprégnation réactive de métaux liquides.La consolidation des composites par frittage flash est très rapide (palier de maintien en température inférieure à 5 minutes) et permet d'obtenir des composites denses. Durant le frittage, la dégradation des fibres de carbone a pu être évitée en adaptant le cycle de pression afin de limiter l'évolution des gaz au sein du système.La densification totale des composites par imprégnation de métaux liquides a été obtenue en contrôlant attentivement les paramètres d'imprégnation afin d'éviter de piéger des espèces gazeuses au sein des préformes fibreuses.Les composites à fibres de carbone consolidés par frittage flash ou par imprégnation réactive de métaux liquide possèdent un comportement mécanique de type élastique endommageable ainsi qu'une contrainte à rupture en flexion voisine de 300 MPa. Ces composites ont montré leur capacité à s'autocicatriser dans des conditions oxydantes. Comparés aux composites à matrice céramiques élaborés par CVI, les composites densifiés par imprégnation de métaux liquide sont eux parfaitement denses et ont un comportement mécanique en traction à température ambiante similaire avec notamment une contrainte à rupture en traction de 220 MPa. / The fabrication of multidirectional continuous carbon fibers reinforced dense self healing Ceramic Matrix Composites by new short time hybrid processes was studied. The processes developed are based, first, on the deposition of fiber interphase and coating by chemical vapor infiltration, next, on the introduction of ceramic powders into the fibrous preform by Slurry Impregnation and, finally, on the densification of the composite by liquid-phase Spark Plasma Sintering (SPS) or by Reactive Melt Infiltration of silicon (RMI).The homogeneous introduction of the ceramic particles into the multidirectional fiber preforms was realized by slurry impregnation from highly concentrated (> 32 %vol.) and well dispersed aqueous colloid suspensions. The densification of the composites by spark plasma sintering was possible with a short (< 5 minutes) dwelling period in temperature. The chemical degradation of the carbon fibers during the fabrication was prevented by adapting the sintering pressure cycle to inhibit gas evolution inside the system. The composites elaborated are dense. The fully densification of the composites by RMI was realised by carefully controlling the impregnation parameters to avoid to entrap some gaseous species inside the fiber preforms. Our carbon fiber reinforced ceramic matrix composites processed by Spark Plasma Sintering or Reactive Melt Infiltration have a damageable mechanical behaviour with a room temperature bending stress at failure around 300 MPa and have shown their ability to self-healing in oxidizing conditions. Compared to the CMC processed by CVI, the composites processed with a final consolidation step by RMI are fully dense and have a similar room temperature tensile test behaviour with an ultimate tensile stress around 220 MPa.

Perseguendo politiche comuni per gli Stati membri, l'Unione Europea si è trasformata da unione puramente economica ad unione politica. Tuttavia, per quanto riguarda quest'ultimo aspetto, è stato fatto poco. Lo scetticismo è venuto a caratterizzare il clima politico dell'Unione Europea e l’elevata eterogeneità nei termini degli Stati membri hanno causato difficoltà nel processo decisionale. Questa tesi si concentra sulle politiche europee da tre aspetti: la legittimità, che si riferisce al sostegno politico dei cittadini, il comportamento di voto e di partecipazione dei cittadini. Una delle questioni principali della ricerca riguarda l’esistenza delle basi per la genesi di veri e propri partiti politici europei, come via d’uscita dalla crisi di legittimità dell'Unione Europea. Ci si chiede poi quali sono i principali fattori che influenzano la partecipazione alle elezioni del Parlamento Europeo, dal momento che esso è l'unica fonte diretta di legittimità. Infine, si studiano le cause del gap in affluenza per le elezioni europee e nazionali, guardando la quota di voto del partito. L'argomento principale per l’esistenza dei partiti pan-europei è quello di difendere gli stessi interessi e valori su scala europea. I risultati empirici sottolineano che la polarizzazione di classe sociale, è già presente nei primi 12 Stati membri dell'UE, e anche nei nuovi Stati membri, mentre nelle elezioni del Parlamento europeo gli elettori votano sinceramente. In conclusione: l'Europa soddisfa la base per la creazione di partiti pan-Europei che difendino vere e proprie politiche europee, mirate ai gruppi sociali che rappresentano, come una possibile soluzione per la crisi di legittimità. / By pursuing common policies for its Member States, the European Union moved from being a purely economic union, to being a political one as well. However, little has been done to tackle the latter aspect. Skepticism has come to characterize the political climate of the European Union and high heterogeneity in terms of Member States has induced difficulties in the decision-making process. This thesis focuses on the European Politics from three aspects: legitimacy, which refers to citizens’ political support, voting behavior and turnout. One of the main research questions we address is whether or not the basis for the existence of true European party politics exists, as a way out of the European Union legitimacy crisis. Then, we ask what are the main factors that influence electoral participation in the European Parliament elections since it is the only source of direct legitimacy. Lastly, we investigate what are the causes for the turnout gap across European and National elections, looking at the party vote share. The main argument for pan-European to exist is to defend the same values and interests European-wide. Empirical results point out that social class's polarization already exists in the initial 12 EU Member States, as well as later entries, while in the European Parliament elections voters cast their vote sincerely. We conclude that Europe fulfils the base requirement for the creation of true European politics, party politics and social groups' targeted-policies being a possible solution for the legitimacy crisis.

La tesi si concentra sul Partito Nazionalista Cinese negli anni Venti come punto privilegiato di osservazione del cambiamento politico della Cina dopo la Prima guerra mondiale. Questo decennio rappresentò un momento di definizione identitaria sia per i comunisti sia per i nazionalisti. La storiografia ne ha sottolineato numerosi aspetti, ma si è finora occupata del periodo 1919-1928 come una preistoria degli anni Trenta piuttosto che come un autonomo segmento di storia cinese. Studi recenti hanno superato implicitamente questo approccio criticando due date periodizzanti fondamentali per il Novecento cinese: la nascita della Repubblica nazionalista (1911) e la nascita della Repubblica Popolare (1949). A metà tra queste due date, gli anni Venti sono emersi come snodo decisivo nel passaggio da impero a Stato nazionale, durante cui si definì un nuovo spazio di discussione politica. Questo processo, pur interno, subì l’influsso delle strategie internazionali di sovietici e statunitensi dando vita a una nuova visione non soltanto della rivoluzione ma anche dello Stato post-rivoluzionario. Le classi dirigenti nazionalista e comunista, durante la collaborazione, si rivelarono dinamiche e tale “competizione” si trasferì anche all’interno di ciascun movimento diventando un fattore determinante per il successo o il fallimento del partito inteso come moderna formazione politica. / The thesis focuses on the Chinese Nationalist Party in the 1920s as a special standpoint to analyze the political changes in China after the World War I. That decade was crucial for shaping the identity of nationalists and communists. Many works have already examined some aspects, but they mostly considered the years 1919-1928 as a pre-history of the Thirties rather than an autonomous part of Chinese history. Recent studies have overcome this approach by criticizing two of the main periodization in the Chinese twentieth century: the birth of the nationalist Republic (1911) and the birth of the People’s Republic (1949). Halfway, the 1920s stood out as a critical juncture in the transition from empire to nation-state. A new space of political discussion was defined. The process, albeit internal, was under the influence of the USSR and US international strategies and gave birth not only to a new vision of the revolution, but also to a vision of the post-revolutionary state. Also, the nationalist and communist leaderships turned out to be dynamic. That "competition" may be seen also within the two political movements and became a shaping factor for the success or failure of the party as a modern political formation.