Rapid development in CMOS technology has resulted in its suitability for the implementation of readout front-end systems in terms of high integration density, and low power consumption yet at the same time posing many challenges for analog circuits design like readout front-end. One of the significant challenges is the low noise design for high speed front-end systems, while at the same time minimizing the power consumption as much as possible. A high speed, low noise, low power, and programmable readout front-end system is designed and implemented for an X-ray detector in CMOS 0.18 m technology in this thesis work. The front-end system has a peaking time of 10 ns, which is the highest speed ever reported in the published work. The front-end system is designed to achieve low noise in terms of ENC, and a low power consumption of 2.9 mW. The detector capacitance is the most dominating parameter to low noise, which in turn is directly related to the power consumption. In this thesis work an ENC of 435 electrons is achieved for a detector capacitance of 5 pF and an ENC of 320 electrons for a detector capacitance of 3 pF. Based on the comparison to related published work, a performance improvement of at least two times is achieved taking peaking time, power, ENC, and detector capacitance all into consideration. The output pulse after amplification has peak amplitude of 300 mV for a maximum injected charge of 40000 electrons from the detector. The readout front-end system noise performance is strongly dependent on the input MOSFET type, size, and biasing. In this work a PMOS has been selected and optimized as the input device due to its smaller 1/f noise and high gain as compare to NMOS when biased at same currents. The architecture designed in this work consists of a folded cascode CSA with extra cascode in first stage, a pole-zero cancellation circuit to eliminate undershoot, a shaper amplifier, and integrators using Gm-C filter technique. All of these components are optimized for low power while meeting the noise requirements. The whole front-end system is programmed for peaking times of 10, 20, and 40 ns. The programmability is achieved by switching different capacitors and resistors values for all the poles and zeros in the front-end, and by switching parallel transconductance in the Gm-C filters. Finally fine tuning of all the capacitance, resistance, and transconductance values is done to achieve required performance.

In this research, the homogenization relations for elastic properties in isotropic and anisotropic materials are studied by applying two-point statistical functions to composite and polycrystalline materials. The validity of the results is investigated by direct comparison with experimental results. In todays technology, where advanced processing methods can provide materials with a variety of morphologies and features in different scales, a methodology to link property to microstructure is necessary to develop a framework for material design. Statistical distribution functions are commonly used for the representation of microstructures and also for homogenization of materials properties. The use of two-point statistics allows the materials designer to consider morphology and distribution in addition to properties of individual phases and components in the design space. This work is focused on studying the effect of anisotropy on the homogenization technique based on two-point statistics. The contribution of one-point and two-point statistics in the calculation of elastic properties of isotropic and anisotropic composites and textured polycrystalline materials will be investigated. For this purpose, an isotropic and anisotropic composite is simulated and an empirical form of the two-point probability functions are used which allows the construction of a composite Hull. The homogenization technique is also applied to two samples of Al-SiC composite that were fabricated through extrusion with two different particle size ratios (PSR). To validate the applied methodology, the elastic properties of the composites are measured by Ultrasonic methods. This methodology is then extended to completely random and textured polycrystalline materials with hexagonal crystal symmetry and the effect of cold rolling on the annealing texture of near- Titanium alloy are presented.

The turbine blade platform can be protected from hot mainstream gases by injecting cooler air through the gap between stator and rotor. The effectiveness of this film cooling method depends on the geometry of the slot, the quantity of injected air, and the secondary flows near the platform. The purpose of this study was to measure the effect of the upstream vane or stator on this type of platform cooling, as well as the effect of changes in the width of the gap. Film cooling effectiveness distributions were obtained on a turbine blade platform within a linear cascade with upstream slot injection. The width of the slot was varied as well as the mass flow rate of the injected coolant. Obstacles were placed upstream to model the effect of the upstream vane. The coolant was injected through an advanced labyrinth seal to simulate purge flow through a stator-rotor seal. The width of the opening of this seal was varied to simulate the effect of misalignment. Stationary rods were placed upstream of the cascade in four phase locations to model the unsteady wake formed at the trailing edge of the upstream vane. Delta wings were also placed in four positions to create a vortex similar to the passage vortex at the exit of the vane. The film cooling effectiveness distributions were measured using pressure-sensitive paint (PSP). Reducing the width of the slot was found to decrease the area of coolant coverage, although the film cooling effectiveness close to the slot was slightly increased. The unsteady wake was found to have a trivial effect on platform cooling, while the passage vortex from the upstream vane may significantly reduce the film cooling effectiveness.

This thesis presents a comprehensive example framework on how current multiple model state estimation algorithms for jump Markov linear systems can be improved. The possible improvements are categorized as: -Design of multiple model state estimation algorithms using new criteria. -Improvements obtained using existing multiple model state estimation algorithms. In the first category, risk-sensitive estimation is proposed for jump Markov linear systems. Two types of cost functions namely, the instantaneous and cumulative cost functions related with risk-sensitive estimation are examined and for each one, the corresponding multiple model estate estimation algorithm is derived. For the cumulative cost function, the derivation involves the reference probability method where one defines and uses a new probability measure under which the involved processes has independence properties. The performance of the proposed risk-sensitive filters are illustrated and compared with conventional algorithms using simulations. The thesis addresses the second category of improvements by proposing -Two new online transition probability estimation schemes for jump Markov linear systems. -A mixed multiple model state estimation scheme which combines desirable properties of two different multiple model state estimation methods. The two online transition probability estimators proposed use the recursive Kullback-Leibler (RKL) procedure and the maximum likelihood (ML) criteria to derive the corresponding identification schemes. When used in state estimation, these methods result in an average error decrease in the root mean square (RMS) state estimation errors, which is proved using simulation studies. The mixed multiple model estimation procedure which utilizes the analysis of the single Gaussian approximation of Gaussian mixtures in Bayesian filtering, combines IMM (Interacting Multiple Model) filter and GPB2 (2nd Order Generalized Pseudo Bayesian) filter efficiently. The resulting algorithm reaches the performance of GPB2 with less Kalman filters.

Resolver, due to its reliability and durability, has been used for the aim of shaft position sensing of military rotary systems such as tank turrets and gun stabilization platforms for decades. Ready-to-use resolver-to-digital converter integrated circuits which convert the resolver signals into position and speed measurements are utilized in servo systems most commonly. However, the ready-to-use integrated circuits increase the dependency of the servo system to hardware components which in turn decrease the efficiency and flexibility of the servo system for changing system structures such as for changing resolver carrier frequency or changing position and speed sensors. The proposed solution to increase the efficiency and flexibility of the servo system is a software-based resolver-to-digital converter which does not require aforesaid special hardware components and presents a complete software-based solution for the conversion. The proposed software-based resolver-to-digital converter makes use of common programmable hardware v components, that is, FPGA and DSP which form the heart of the servo controller technology in recent years. The proposed structure for the conversion has three components. The first component is the signal conditioner which minimizes the disturbances coming from the resolver signals as harmonic distortions and noise. The second component, the phase-sensitive demodulator, as the name implies, is responsible for phase-sensitive demodulation of resolver signals. The third component is the estimator filter. In order to determine the optimal estimator filter, five different estimator filters with the aforesaid two components are implemented in ASELSAN&rsquo / s stabilized gun system STAMP and they are compared in terms of both estimation performance and computational complexity. The implemented filters include nonlinear observer type filter which is already proposed in the literature for resolver conversion, tracking differentiator adapted to resolver conversion and kalman filters adapted to resolver conversion in different forms such as linear kalman filter, extended kalman filter and unscented kalman filter. At the end of the study, stability and sensitivity analyses are also performed for the proposed system.

The main topic of this thesis is the development of a chemical microsystem based on integration of a silicon-based resonant microsensor and a CMOS ASIC for portable sensing applications. Cantilever and disk-shape microresonators have been used as mass-sensitive sensors. Based on the characteristics of the microresonators, CMOS integrated interface and control electronics have been implemented. The CMOS ASIC utilizes the self-oscillation method, which incorporates the microresonator in an amplifying feedback loop as the frequency determining element. In this manner, the ASIC includes a main feedback loop to sustain oscillation at or close to the fundamental resonance frequency of the microresonator. For stable oscillation, an automatic gain control loop regulates the oscillation amplitude by controlling the gain of the main feedback loop. In addition, an automatic phase control loop has been included to adjust the phase of the main feedback loop to ensure an operating point as close as possible to the resonance frequency, resulting in improved frequency stability. The CMOS chip has been interfaced to cantilever and disk-shape microresonators and short-term frequency stabilities as low as 3.4×10-8 in air have been obtained with a 1 sec gate time. The performance of the implemented microsystem as a chemical sensor has been evaluated experimentally with microresonators coated with chemically sensitive polymer films. With a gas-phase chemical measurement setup constructed in this work, chemical measurements have been performed and different concentrations of VOCs, such as benzene, toluene and m-xylene have been detected with limits of detection of 5.3 ppm, 1.2 ppm and 0.35 ppm, respectively. To improve the long-term stability in monitoring applications with slowly changing analyte signatures, a method to compensate for frequency drift caused by environmental disturbances has been implemented on the CMOS chip. This method uses a controlled stiffness modulation generated by a frequency drift compensation circuit to track the changes in the resonator's Q-factor in response to variations in the environmental conditions. The measured Q-factor is then used to compensate for the frequency drift using an initial calibration step. The feasibility of the proposed method has been verified experimentally by compensating for temperature-induced frequency drift during gas-phase chemical measurements.

Ziel dieser Arbeit ist die Darstellung funktioneller Materialien, die ein multi-sensitives Ansprechverhalten aufweisen. Die Charakterisierung des Quellverhaltens der Gele stellt die Voraussetzung dar, die phasenseparierten Polymerfilme als multi-sensitive Sensorschichten mit verbessertem Ansprechverhalten einzusetzen. Die Aufgabe dieser Arbeit besteht in der Synthese von AB-Blockcopolymeren, die im wässrigen Medium auf die Temperatur oder auf die Temperatur und den pH-Wert ansprechen. Unter Verwendung der Makroinitiator-Technik werden Blockcopolymere synthetisiert. Zunächst werden temperatur-sensitive Polymere mit einem wasserlöslichen Polyethylenglykol-Block (PEG) und N-Isopropylacrylamid (NIPAAm) mittels "Atom Transfer Radical Polymerization" (ATRP) hergestellt. Die Umsetzung der durch "Nitroxide Mediated Radical Polymerization" (NMRP) hergestellten pH-sensitiven Poly(2-vinylpyridin)-Blöcke (P2VP) mit NIPAAm führt zu multi-sensitiven Blockcopolymeren. Da die Polymere auf ihre Quelleigenschaften in dünnen Filmen hin untersucht werden sollen, ist die Verwendung eines Chromophors, der in den NIPAAm-Block einpolymerisiert wird, nötig. Die Vernetzung der Polymerfilme erfolgt photochemisch. Das Quellverhalten der Polymerschichten wurde mit der Methode der "Surface Plasmon Resonance"-Spektroskopie (SPR) charakterisiert. Im Rahmen dieser Arbeit ist es gelungen, multi-sensitive Polymere darzustellen und deren Sensitivität in dünnen Polymerfilmen nachzuweisen. Bei den synthetisierten Polymeren handelt es sich um neuartige und funktionelle Materialien.

Les micelles complexes de polyions, ou « micelles PIC », formées par interaction électrostatique entre un copolymère à blocs double hydrophile neutre-ionique (DHBC) et un homopolyélectrolyte de charge opposée au DHBC possèdent des propriétés particulièrement intéressantes : solubilité des polyélectrolytes dans l'eau, stabilité des micelles, contrôle de l'association/dissociation micellaire par divers stimuli (pH, force ionique, irradiation lumineuse…). Dans cette thèse, les propriétés physico-chimiques des micelles PIC de type DHBC neutre-cationique/homopolymère anionique et DHBC neutre-anionique/homopolyélectrolyte cationique ont été étudiées en solution aqueuse en vue de leur utilisation comme agent structurant des matériaux siliciques organisés à l'échelle nanométrique. La gamme de pH de formation des micelles PIC, la concentration micellaire critique et le nombre d'agrégation des micelles ont été déterminés pour chacun des systèmes étudiés. Nous avons montré que la formation des micelles suit un mécanisme coopératif qui dépend de la taille de l'homopolymère. Par ailleurs, nous avons proposé une voie originale de formation des micelles PIC photoinduite, basée sur une modification du pH suite à l'irradiation d'une molécule photochrome. Les études concernant l'utilisation des micelles PIC comme agent structurant des matériaux nous ont permis de montrer que la morphologie (nanoparticulaire, massif) et la structure des matériaux (lamellaire, vermiculaire) peuvent être contrôlés par divers paramètres, tels que la concentration en masse du système DHBC/homopolyélectrolyte/précurseur de silice, la teneur en précurseur de silice et le rapport entre les fonctions cationique et anionique des polyélectrolytes. Le lavage des matériaux sous des conditions douces (à l'eau) permet de récupérer l'agent structurant. / Polyion complex micelles, or "PIC micelles", formed by electrostatic interaction between a neutral-ionic double hydrophilic block copolymer (DHBC) and an oppositely charged homopolyelectrolyte possess interesting properties: solubility of the polyelectrolytes in water, stability of micelles, control of the micellar association / dissociation by various stimuli (pH, ionic strength, light irradiation ...). In this thesis, the physico-chemical properties of PIC micelles of neutral-cationic DHBC/ anionic homopolymer and neutral-anionic DHBC/cationic homopolymer were studied in aqueous solution for use as structuring agents of silica-based organized nanomaterials. The pH range of PIC micelle formation, the critical micelle concentration and aggregation number of micelles were determined for each studied system. We have shown that the formation of micelles follows a cooperative mechanism which depends on the size of the homopolymer. Furthermore, we proposed an original way of photoinduced PIC micelle formation, based on a pH change after irradiation of a photochromic molecule. The studies on the PIC micelles as structuring agents of materials have shown that the morphology (nanoparticular, bulk) and the material structure (lamellar, vermicular) can be controlled by various parameters, such as the mass concentration of the DHBC / homopolyelectrolyte / silica precursor system, the content of the silica precursor and the ratio between the functions of the cationic and anionic polyelectrolytes. Finally, the template was removed by washing the hybrid materials under soft conditions in water.

This research was inspired by a need to discover more refined technologies for imaging growing joints to facilitate research in childhood arthritis, which is among the most common chronic conditions of childhood. The objective of this project was to develop and test a new technology for imaging growing joints using diffraction enhanced imaging (DEI) combined with computed tomography (CT) using a synchrotron radiation source. DEI is a modality that derives contrast from x-ray refraction, extinction (an extreme form of scatter rejection), and absorption (as in conventional radiography). The ability to add to an image’s contrast from the refraction of x-rays, rather than that solely from absorption, generates more detailed visualization of soft tissue and of interfaces between tissues. Additionally, refraction-based imaging allows reduction of absorbed radiation dose by the sample tissue. For this research, stifle joints from four-week piglet joints were imaged by DEI-CT using the BioMedical Imaging and Therapy (BMIT) beamline at the Canadian Light Source (CLS) synchrotron facility. This new modality for imaging growing joints incorporated a novel feedback control to maintain precise alignment of the analyzer crystal, which is used to re- diffract the beam that passes through the object, throughout the scanning procedure. Results showed that high-resolution DEI-CT provided three-dimensional images of the bone and soft tissue of growing joints at a resolution on the order of microns. Fine detail within and between all joint structures and tissues, including striking detail of cartilage vasculature, a iii characteristic of growing but not mature joints, was demonstrated. This report documents for the first time that DEI combined with CT and using a synchrotron radiation source can generate more detailed images of intact, growing joints than is currently available from conventional imaging modalities. The development of this high resolution imaging system, which provides excellent contrast for both hard and soft tissues, fills an important gap in the suite of imaging modalities available for joint research, particularly during growth.

No description available.