This thesis describes the results of new analysis of gravity studies over West Antarctica. Set on the Siple Coast, an airborne geophysical survey was flown between 1994 and 1997 that covered the trunk of Bindschadler Ice Stream and the up-stream areas, including Whitmore Accommodation Zone and Byrd Subglacial Basin. The new gravity reduction methodology removed vertical and horizontal accelerations, the Eötvös effect, and the theoretical gravity; unlike previous analyses, this reduction did not level individual lines, preserving the high frequency data and avoiding introduction of new errors. This reduction provided the free-air gravity disturbance over the area, which was then leveled and registered by the more regional extensive GOCE satellite gravity. The processing and reduction of the data improved the high frequency signal over previous work on the data, giving better definition of small scale, short wavelength features, which works well with satellite gravity data that emphasizes the large scale, long wavelength features. The leveled free-air gravity was then processed with a FORTRAN 90 program that calculates the Bouguer disturbance based on the free-air gravity and the topography. The topography was gathered concurrently with the gravity with ice penetrating radar during the airborne survey. The Bouguer disturbances provide a crustal model of the area. The final Bouguer disturbance was also corrected for the ice above sea level, which was calculated with a simple Bouguer slab correction. Finally, a power spectrum analysis was run on a profile in the Bouguer gravity disturbance in order to complete a spectral analysis. The spectral analysis provides crustal density boundaries for a density anomaly near the surface, a mid-crustal anomaly, and the Moho boundary. The improved the high frequency content of the data allows spectral analysis down to 4 km. The differing crustal thickness from spectral analysis also shows the character and extent of the West Antarctic Rift System, the northern flank of which extends out from Marie Byrd Land and into the survey area. Bindschadler Ice Stream is located on the WARS rift floor and MacAyeal Ice Stream sits on the rift flank. / text

The modern insular shelf and slope of western Puerto Rico is characterized by reef carbonate and siliciclastic sedimentary environments controlled by the complex interplay of tectonic arching and faulting, vigorous erosion of the elevated island of Puerto Rico, fluvial incision and sedimentation pulses, reef growth, and rapid late Quaternary eustatic sea-level changes. For this study, I interpret 725 km of high-resolution, single-channel seismic lines that were collected over the western insular shelf and slope by the RV Isla Magueyes in 2000 to better understand tectonic, erosional, and eustatic controls on late Quaternary history. The seafloor geology of the western shelf and slope area of Puerto Rico has been well studied and mapped mainly from grab and short cores collected by geoscientists at the U.S. Geological Survey and at the University of Puerto Rico at Mayagü̈ez. Because of low tectonic uplift rates from the western coast of Puerto Rico, the onland late Quaternary sedimentary history is not recorded in Quaternary coastal outcrops. The results of my seismic interpretation and correlation with multi-channel seismic data collected in 1972, reveal four main units defined by characteristic stratal reflection terminations and seismic facies. These units include: Unit 1 (basement) - a gently folded and faulted basal section correlated to the Oligocene-early Pleistocene carbonate shelf of Puerto Rico; deeper penetration, industry multi-channel seismic lines show that these rocks are deformed in a broad east-west-trending arch; Unit 2 (lowstand systems tract, LST) - chaotic channel fill deposits filling deep (~ 30 meter) incisions formed during the Last Glacial Maximum about 20 ka; Unit 3 (transgressive system tract, TST) - poorly stratified deposits truncating the top of Unit 2 and deposited during early Holocene transgression of the shelf margin; Unit 4 (highstand system tract, HST) - late Holocene, highly stratified deposits related to aggradation as the Holocene transgression began to slow. The base of unit 4 is a downlap surface interpreted as a maximum flooding surface likely formed about 8 ka. East-northeast-striking faults are observed that offset the late Quaternary units in three separate zones off the west coast of Puerto Rico. Because of a lack of wells and long cores from the shelf and slope area, age estimates for the four units are based on correlations with sea-level curves derived from dated coral samples in the Caribbean and western Atlantic region. All four units are deformed by faulting that should be considered active and possibly hazardous for the rapidly developing west coast of Puerto Rico. In one area, a large, late Holocene-slump (~ 0.016 km³) is mapped using seismic, sidescan sonar and bathymetric data. Onland continuations of these faults are likely, but have not been identified due to cultural overprint of natural scarps on late Quaternary floodplains. / text

No description available.

The consumption of fresh-cut fruits has been increasing in recent years due to their health benefits. Fresh-cut cantaloupe (Cucumis melo L.) represents a great snack alternative due to its low caloric content, freshness, and basic component of a healthy diet. One of the latest alternatives to reduce the decay of quality brought by minimal processing of fruits is the development of edible coatings. Acting as a barrier to moisture and gases, the coatings are expected to extend the shelf-life of fresh-cut products, thus the main objective of this research was to determine the effectiveness of an antimicrobial edible coating on the shelf-life of fresh cut cantaloupe (stored at 4 degrees C for 15 days) while maintaining its quality attributes. The effect of different coating compositions and their concentrations on a product's chemical properties and quality attributes was studied. A set of solutions containing chitosan, beta-cyclodextrin, trans-cinnamaldehyde, pectin and calcium chloride were used as coating systems for the fruit using the layer-by-layer method. Quality was measured in terms of texture, color, weight loss, moisture, acidity, and pH. In addition, a consumer sensory test was carried out to support the findings from the objective quality data. Microbiological tests were carried out to determine the effectiveness of trans-cinnamaldehyde as antimicrobial agent within the coating. Uncoated fresh-cut cantaloupe samples stored at 4 degrees C served as controls. In terms of microbiological and physicochemical quality attributes, the antimicrobial coating improved the shelf-life of fresh-cut cantaloupe (up to 12 days), compared to the controls (only 6 days). The coating composed of 2% antimicrobial, 2% chitosan and 1% pectin was the most effective in terms of consumer's acceptance (P<0.05) and shelf-life extension. The results indicated that different ratios between solutions present a variation for each specific quality attribute. The thicker the coating, the firmer the fruit and different thicknesses resulted in different amounts of antimicrobial compound in the coating, thus critically affecting the shelf-life of the product. This study demonstrates the feasibility of a new generation of edible coating for fresh-cut cantaloupe, the coating consists of using a system specially designed to allow the incorporation of natural antimicrobial agents by means of the application of microencapsulation and the layer-by-layer assembly.

Of the maritime boundaries yet to be delimited between Canada and the United States, the Beaufort Sea might be the more pressing one, considering its strategic location in a rapidly developing Arctic region and its vast economic potential. In accordance with the Law of the Sea Convention (UNCLOS), maritime boundaries are to be delimited by agreement on the basis of international law as referred to in Article 38 of the Statute of the International Court of Justice, in order to reach an equitable solution. When an agreement cannot be reached, parties can resort to third-party arbitration. While jurisprudence has determined that international law does not mandate a particular method of delimitation, it requires the consideration of equitable principles, also called special circumstances or factors. The notion of equity is therefore the foundation of boundary determination. But, what is equity and how is it applied? This thesis examines the various forms of equity, their origins in legal philosophy and domestic law and how they have been incorporated in international law. The main focus, however, is to analyse the differences between how international tribunals or courts have interpreted and applied equity in boundary determination and how States have applied it in negotiated agreements. While tribunals have tended to consider equitable principles as equivalent to geographical proportionality, States have considered those principles more in keeping with the notion of distributive justice and, more and more, are taking a globalised approach to boundary determination. On the basis of this analysis, this thesis evaluates the potential outcome of a third-party arbitration of the Beaufort Sea boundary dispute between Canada and the United States as well as the options for settlement negotiations between the Parties. In the Beaufort Sea area where hydrocarbon development is intrinsically linked not only to the development of the local population but also to the entire Arctic region, be it on issues related to the environment, navigation or security, the thesis concludes that a third-party adjudication would not serve the interests of the States. As delimiting boundaries nowadays is only one aspect of the management of oceans related issues, interests are best served when delimitation is understood as part of this global approach.

Mushrooms are one of the protein rich foods, however they have a short pro-harvest life (2 to 3 days) compared to most vegetables. The aim of this study was to evaluate whether applying an anti-browning solution using vacuum impregnation and then electron beam irradiation can be used to extend the shelf life of fresh-cut mushrooms (Agaricus bisporus). Solutions made with (a) 2% ascorbic acid + 1% calcium lactate, (b) 2% citric acid + 1% calcium lactate, (c) 1% chitosan + 1% calcium lactate, and (d) 1% calcium lactate were used to impregnate mushroom slices at different vacuum pressures, vacuum pressure times, and atmospheric restoration times. Mushrooms were also irradiated at a dose of 1 kGy using a 1.35 MeV e-beam accelerator and their quality was evaluated in terms of color, texture, and microbial growth during 15 days storage at 4 degrees C. The best vacuum impregnation treatment was the 2% ascorbic acid and 1% calcium lactate solution using a vacuum pressure of 50 mmHg for 5 minutes and an atmospheric restoration time of 5 minutes. The control (not treated) and impregnated samples lost their structure (softening) during storage. The irradiated samples lost their firmness by day 4 of storage. The addition of calcium lactate to the samples during the treatment helped to keep the product’s texture during the 15 days storage time. Color of the mushrooms changed during storage for all the control and impregnated samples and only the irradiated samples showed an acceptable color by the end of day 15. Aerobics and psychrotrophics counts were significantly reduced by irradiation; while yeast and molds population increased by day 9 and were not completely inactivated with a dose of 1 kGy. Sensory panelists preferred the treated samples over the controls. The best treatment was the combination of vacuum impregnation with irradiation according to the consumer studies.

The validation and potential use of mathematical models to estimate the shelf-life of refrigerated food exposed to temperature abuse and basing such estimations on microbial growth was analyzed. Combined heat transfer, microbial growth models, and non-parametric statistical procedures formed a computer-based predictive tool to assess shelf-life and estimate the accuracy of the prediction. Experiments were carried out to assess the precision of the combined model parameters. The different situations analyzed considered stepwise fluctuations in environmental temperature and a change in package characteristic (size and packaging material). Computer simulations showed that even when the temperature abuse period constitutes a small fraction of the total exposure time (2%-3%), shelf-life can be highly affected (20%-30%). To analyze the precision of the combined model response, two sources of variation were considered, microbial growth and heat transfer parameters. First order, pseudo-zero order kinetics and Arrhenius model formed the basis for the microbial model. The accuracy of lag and exponential phase of microbial growth for a mixture of three microorganisms (P. fluorescens, S. aureus, and A. Iwoffi) was assessed using a nonparametric statistical procedure based on the bootstrap method. The activation energy (E [subscript a]) and the logarithm of the frequency factor (InK₀) were found to be 109±3.4 J/mole and 48.3±1.5 for the exponential phase of this microbial mixture. The values for the exponential phase were 152±4 J/mole and 64.0±1.7, respectively. These parameters together with experimental values for the overall heat transfer coefficient were used to analyze the precision of the model response. This precision was not affected by a change in environmental temperature and packaging characteristics and remained constant at ±1 day. Two different temperature abuse situations yield estimated shelf-life of 4.8±1 and 8.9±1 day, respectively. This result can not be generalized as it depends on the particular examples analyzed. / Graduation date: 1993

In this thesis three independent studies of tidal dynamics have been pesented. The first is an analytical study of continental shelf tides forced at the ocean boundary. Earlier studies have shown that the response for a sloping shelf and a flat shelf differ and that the response for a flat shelf changes when tides are incident at an angle. Other studies considered a sloping shelf but they did not take into account a possible non-zero depth at a coastal wall. This study shows that the effects of a sloping shelf, a coastal wall and obliquely incident tides an all significantly modify the response on the shelf. The modification increases with the width of the shelf, and in a wide shelf scenario, near resonance, it greatly modifies the response. Secondly, the Princeton Ocean Model in barotropic mode along with a tracer transport module has been used to study the tides of Sydney Harbour. The tidally induced residual circulation due to the semi-diurnal tide consists of a series of recirculating gyres which are due to the interaction of flow with topography. This study shows that in the harbour it is the Lagrangian residual velocity not the Eulerian residual velocity which determines the net transport of material over a tidal cycle. In addition, the flushing time of the harbour varies significantly in space, and the tidal mixing is restricted in the vicinity of the entrance. The third is a theoretical study of forced oscillations in a rotating, flat-bottomed, circular basin. This study shows that the direction of propagation of waves in a basin depends on the ratio of its radius to depth. At each latitude there is a critical value of this ratio and this value decreases with increase in latitude. Beyond this value, waves start to propagate around the basin in the opposite direction to the earth ???s rotation (clockwise in the northern hemisphere and anti-clockwise in the southern hemisphere).The presence of friction increases this critical value which shows that friction plays an important role in determining the response.

In this thesis three independent studies of tidal dynamics have been pesented. The first is an analytical study of continental shelf tides forced at the ocean boundary. Earlier studies have shown that the response for a sloping shelf and a flat shelf differ and that the response for a flat shelf changes when tides are incident at an angle. Other studies considered a sloping shelf but they did not take into account a possible non-zero depth at a coastal wall. This study shows that the effects of a sloping shelf, a coastal wall and obliquely incident tides an all significantly modify the response on the shelf. The modification increases with the width of the shelf, and in a wide shelf scenario, near resonance, it greatly modifies the response. Secondly, the Princeton Ocean Model in barotropic mode along with a tracer transport module has been used to study the tides of Sydney Harbour. The tidally induced residual circulation due to the semi-diurnal tide consists of a series of recirculating gyres which are due to the interaction of flow with topography. This study shows that in the harbour it is the Lagrangian residual velocity not the Eulerian residual velocity which determines the net transport of material over a tidal cycle. In addition, the flushing time of the harbour varies significantly in space, and the tidal mixing is restricted in the vicinity of the entrance. The third is a theoretical study of forced oscillations in a rotating, flat-bottomed, circular basin. This study shows that the direction of propagation of waves in a basin depends on the ratio of its radius to depth. At each latitude there is a critical value of this ratio and this value decreases with increase in latitude. Beyond this value, waves start to propagate around the basin in the opposite direction to the earth ???s rotation (clockwise in the northern hemisphere and anti-clockwise in the southern hemisphere).The presence of friction increases this critical value which shows that friction plays an important role in determining the response.

The aim of this research was to demonstrate the relationship between variations in summertime surface mass balance of the McMurdo Ice Shelf and atmospheric processes. The approach encompassed a broad range of techniques. An existing energy balance mass balance model was adapted to deal with debris-covered ice surfaces and modified to produce distributed output. Point based surface energy and mass balance for two key surfaces of the ice shelf were linked to different synoptic types that were identified using a manual synoptic classification. The distributed model was initialised with distributed parameters derived from satellite remote sensing and forced with data from a regional climate model. Patterns of summertime surface mass balance produced by the distributed model were assessed against stake measurements and with respect to atmospheric processes. During the summers of 2003-2004 and 2004-2005 an automatic weather station (AWS) was operated on bare and debris-covered ice surfaces of the McMurdo Ice shelf, Antarctica. Surface mass balance was calculated using the energy balance model driven by the data from the AWS and additional data from permanent climate stations. Net mass balance for the measurement period was reproduced reasonably well when validated against directly measured turbulent fluxes, stake measurements, and continuously measured surface height at the AWS. For the bare ice surface net radiation provided the major energy input for ablation, whereas sensible heat flux was a second heat source. Ablation was by both melt (70%) and sublimation (30%). At the debris-covered ice site investigated, it is inferred that the debris cover is sufficient to insulate the underlying ice from ablation. Synoptic weather situations were analysed based on AVHRR composite images and surface pressure charts. Three distinct synoptic situations were found to occur during the summers, these were defined as Type A, low pressure system residing in the Ross Sea Embayment; Type B, anticyclonic conditions across region; and Type C, a trough of low pressure extending into the Ross Sea Embayment. A dependence of surface energy fluxes and mass balance on synoptic situation was identified for the bare ice surface. The distributed model was found to produce spatial patterns of mass balance which compared well with stake measurements. Mass balance patterns show that the McMurdo Ice Shelf was generally ablating in the west, and accumulating in the east during summer. Areas of enhanced ablation were found which were likely to be caused by the surface conditions and topographic effects on the wind field. The mean summertime surface mass balance across the entire ice shelf for the 2003-2004 and 2004-2005 summers were –2.5 mm w.e. and –6.7 mm w.e. respectively. The differences between the two summers are inferred to be a result of more frequent type A conditions occurring during the summer of 2004-2005.