Slurry transport is a key material handling technology in a number of industries. In oilsands ore transport, slurry pipelining also promotes conditioning to release and aerate bitumen prior to separation. Reliability of slurry transport pipelines is a major ongoing problem for operating companies due to unexpected piping failures, even when conservative maintenance strategies are employed. To date, no accurate model has been developed to predict wear rates in slurry transport pipelines, although previous studies have shown that important variables include flow rate, slurry density, and particle size distribution. This work investigates erosion wear mechanisms causing inner pipe wall wear due to sand slurry flow in a horizontal section of pipe under steady state conditions. A corresponding lumped-parameter erosion wear model is presented based on simplification of the physics of oilsands slurry flow. An apparatus was designed and developed to measure the forces acting on the pipe inner wall to monitor forces related to erosion in a laboratory-scale sand slurry loop, and preliminary results are presented with recommendations for future work. / Engineering Management

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The aim of this study was to investigate the reaction behaviors of nanoscale Fe3O4 and H1/10-[Fe3O4]MgO slurry injection coupled with the electrokinectic (EK) process for remediation of NO3− and Cr6+ in saturated soil. To assure the above-mentioned nanomaterials were capable of reductively adsorbing inorganic pollutants (e.g., NO3− and Cr6+) in the acidic environment in the anode reservoir of the ek remediation system, an investigation on transformation of the concerned nanomaterials in different aqueous solutions (de-ionized water and simulated groundwater ) of different initial pHs (2 and 3.5) was conducted. Due to a high dose of nanoscale Fe3O4 and a resulting serious agglomeration while adsorbing NO3− and Cr6+, the characteristic peaks of the X-ray diffraction (XRD) analysis for nanoscale Fe3O4 remained the same after adsorption experiments. But the situations were quite different in the case of nanoscale H1/10-[Fe3O4]MgO, the characteristic peaks of £\-Fe2O3 in the XRD pattern were detected, confirming that this nanomaterial could reductively adsorb NO3− and Cr6+ in the acidic environment. The effectiveness of using polyacrylic acid (PAA) and soluble starch (SS) to stabilize nanoscale Fe3O4 and H1/10-[Fe3O4]MgO in different aqueous solutions containing humic acid was compared. It was found the former yielded a better stability. Therefore, PAA was chosen to prepare the slurries of target nanomaterials. Then slurry injection coupled with the EK process was tested for remediation of NO3- and Cr6+ in saturated soil. The results showed that the removal efficiency of NO3− was more than 90%, and the NO3− concentration in the anode reservoir was below Taiwan¡¦s Pollution Control Standards of type¢¹Groundwater for NO3−-N. Under the same test conditions, however, the removal efficiency of Cr6+ was unsatisfactory. This might be ascribed to acidification of soil near the anode resulting in high adsorption of Cr2O72− by soil. Thus, a solution to solve this problem has to seeked. The solution lies in how to enhance the contact of the above-mentioned nanomaterials with Cr6+ in the anode reservoir. One possibility is to use the nature of SS would hydrolyze in the acidic environment. Therefore, SS-stabilized nanomaterials in the acidic environment would hydrolyze resulting in the exposure of the soil nanomaterials therein. To this end, SS was used to replace PAA for nanomaterial slurry preparation for remediation of Cr6+. In addition, polarity reversal was practiced in the EK system to maintain a neutral ph of soil and increase the mobility of Cr6+ in soil. Finally, the result showed that nanoscale Fe3O4 and H1/10-[Fe3O4]MgO slurry injection coupled with the polarity reversal electrokinetic system could really enhance the removal efficiency of Cr6+ in the saturated soil. In summary, nanoscale Fe3O4 and H1/10-[Fe3O4]MgO slurry injection coupled with the EK process has been proven to be capable of remedying NO3− and Cr6+ in saturated soil. Meanwhile, the concept of reductive adsorption was realized in this work as well.

In this research, nanoscale zero-valent iron (NZVI) was synthesized using the chemical reduction method. Experimental results have revealed that nanoiron synthesized by the reagent-grade chemicals had a size range of 50-80 nm, as determined by FE SEM. BET specific surface area of thus synthesized nanoparticles was 66.34 m2/g. NZVI prepared by the industrial-grade chemicals had a broader particle size distribution (30-80 nm) and its BET specific surface area was 61.50 m2/g. Results of XRD showed that both types of NZVI were composed of iron with a poor crystallinity. Additional test results further showed that both types of NZVI had similar characteristics. NZVI prepared by the chemical reduction method tends to aggregate resulting in a significant loss in reactivity. To overcome this disadvantage, four water-soluble dispersants were used in different stages of the NZVI preparation process. Of these, Dispersant A (an anionic surfactant) has shown its superior stabilizing capability to others. An addition of 0.5 vol % Dispersant A during the nanoiron preparation process would result in a good stability of NZVI slurry (NZVIS). Degradation of trichloroethylene (TCE) by NZVIS under different atmospheres was carried out in batch experiments. Experimental results have shown that the TCE dechlorination rate increased markedly when the reaction proceeded under hydrogen gas atmosphere as compared with that of air. Methane was the primary end product with a trace amount of ethane and ethylene when the reaction was conducted under the atmosphere of H2. It was suggested that an addition of H2 to the reaction system could promote the hydrogenolysis reaction for better degradation. On the other hand, ethane was the main product when the reaction system consisted of nanoscale palladized iron and H2 atmosphere. It demonstrated that Pd-catalyzed TCE dechlorination has resulted in a direct conversion of TCE to ethane in the study. The greatest dechlorination rate was obtained when 2 g/L nanoscale palladized iron and 50 mL H2 was employed in the reaction system. Under the circumstances, the TCE (10 mg/L) removal efficiency was up to 99 % in 3 minutes. Experimental results have demonstrated that the reaction system with both nanoscale palladized iron and H2 atmosphere would promote TCE degradation rate. The culture of microorganism in soil showed minor changes to microbial community structures between the pre- and post-injection conditions. The number of microorganism colony was found to be increased after adding 1 mL NZVIS to 1 g soil. Experimental results revealed that NZVIS would not cause the inhibition or reduction of microorganism activity. Surface modification of NZVI slurry by Dispersant A could enhance its transport in saturated porous media. Sticking coefficients were determined to be 0.56 and 0.11, respectively, for bare and Dispersant A-modified NZVIS transporting in quartz sand columns. The sticking coefficient for modified NZVIS transport in soil (loamy sand) column was determined to be 0.0061. Apparently, NZVIS modified by Dispersant A would enhance the transport of NZVI in saturated porous media. The results of combining electrokinetic technology and NZVIS injection tests in horizontal soil column illustrated that the sticking coefficient was 0.00034 and the total content of iron reduced 10 wt. %. Experimental results revealed that the transport distance of NZVIS in saturated horizontal soil column would be greatly increased under electronkinetic conditions.

There exist various applications of transportation of slurries through pipelines all over the world. In the present study, the problem is formulated as a &quot / transportation problem&quot / to determine the pipe diameters and amounts of slurry to be transported from the demand (production) points to the processing (factory) points. The minimization of the cost consisting of the pipe and energy cost terms is considered as the objective function to determine the stated decision variables. Pipe cost is given as the function of pipe diameters and the energy cost is defined as function of pipe diameters and slurry amounts. Energy cost is obtained by using the relation that is previously determined after the experimental studies made for the magnetite ore. The optimization method used in the study is genetic algorithm method. A commercially available software written in C language is used and modified for the present study The proposed methodology to solve this nonlinear programming problem is applied to a transportation system and it is seen that the methodology made the complex, labor intensive equation solution process very convenient for the users.

<p>This thesis summarises the work performed within the project known as ICE-COOL at the Royal Institute of Technology (KTH) on low tem-perature applications of ice slurry. The ICE-COOL project is a Euro-pean Community funded project within the 5th Framework Program. The task given to KTH was to find and characterize the best possible aqueous solution with a freezing point of -25 °C applicable for ice slurry with an operating temperature of -35 °C. The circumstances differ for low temperature ice slurry from medium temperature as a result of for example the change in thermo-physical properties due to increased addi-tive concentration and the lower temperature.</p><p>Ice slurry is a mixture of fine ice crystals, water and freezing point de-pressant additives. The typical ice crystal size ranges between 0.1 to 1 mm in diameter. The main purpose of using ice slurries is to take advan-tage of the latent heat. More than a few requirements are to be fulfilled by an ideal ice slurry fluid. It should have good thermo-physical proper-ties, high heat transport and transfer abilities, as well as low pressure drop to facilitate small pumping power. The ice content of ice slurry af-fects all the mentioned abilities. Apart from the mentioned factors of the fluid, there are other aspects that have to be taken into consideration such as environmental pollution and toxicity, flammability, material compatibility, corrosion, handling security and cost.</p><p>This thesis reports on the experiences accomplished and the initial ex-periments performed on low temperature ice slurry. The thesis also gives the background and fundamentals necessary for a discussion and com-parison of different aqueous fluids suitable for ice slurry in general and for low temperature in particular. In addition to the low temperature ap-plication, the thesis also reports on an initial energy consumption com-parison between using ice slurry and single-phase fluid in supermarkets by means of the simulation program CyberMart developed by Jaime Arias at the Department of Energy Technology at KTH.</p>

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Today the use of anaerobic digestion technique emerges as an alternative to the conventional treatment method of pig slurry to the pig producers in Brazil because of the energy demanding intensive pig production and the negative environmental impact that arises during storage and use. The end products of AD technique are biogas as an energy source and digestate that can be used as a fertilizer. The study took place at two pig producers in southern Brazil in order to evaluate the biogas production in the area, its applications and environmental impact. The visited pig producers run a confined animal production system where the slurry that is used in the anaerobic digesters is diluted. The studied digesters are covered with an air tight flexible plastic membrane that takes the shape of a balloon where each digester has the volume of 620 m3. Sedimentation occurs inside each reactor where the temperature also fluctuates. The produced biogas is conveyed to a torch where the biogas is combusted. The results of this study show that the digesters are working properly but there is a need for mixing and constant temperature in order to optimize the process. Biogas is primarily suited for heat production and the digestate can be used as a fertilizer. Biogas production is considered to have a positive environmental impact if the biogas is used or combusted in a torch. There is also a need to apply a cover over the digestate during the storage time to avoid ammonia emissions. The approximated biogas potential for Rio Grande do Sul is nearly 100 GWh/year. For an approximated biogas potential of more consideration it is found that further studies of the housing systems in Rio Grande do Sul are needed. This is due to a greatly varying amount of degradable materials in the pig slurry from one ranch to another.

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