High-tone extensor thrust is common to those with cerebral palsy and those suffering spinal cord injuries. It is a muscle-control phenomenon that causes the body to straighten spastically. One goal of this thesis is to design a dynamic seating system that moves with respect to the wheelchair frame, allowing the seat to move with the user during an extensor thrust and reduce forces. One unique challenge is that the seat needs to remain rigid during normal functional activities and only become dynamic when an involuntary thrust is detected. A second goal of this thesis is to design a control scheme that is able to differentiate between these two types of motion. These design goals are initially investigated with a hinged-seatback system, instrumented with sensors to allow for the detection of thrusts and to actively control seating components. A full seating system is then built to allow for full-body extensor thrusts, involving the seatback, seat bottom, and leg rest of the wheelchair. This system is analyzed for effectiveness of reducing forces on the body during an extensor thrust. Another serious problem for this segment of the population is pressure ulcers. These are caused by prolonged pressure on the skin from weight-bearing bony prominences. Various seating system configurations are known to help with pressure relief. The three standard configurations for a chair are tilt, recline, and standing. The final goal of this thesis is to measure and compare the effectiveness of these three methods for their ability to relieve pressure on the seat bottom. To accomplish this, a powered wheelchair with built-in capabilities for recline and standing is mounted to a tilting mechanism. Test subjects are used to experimentally compare the effectiveness of each method for pressure reduction using pressure mats on all weight-bearing surfaces. A 2D model is also developed and validated with the experimental results.

This study first examined the kinetic changes of fiber carboxyl group content in bulk fiber, polysaccharide, and residual lignin of oxygen delignified pulps during one-stage oxygen delignification of a low kappa (32.5) kraft pulp. The carboxyl group contents determined in different chemical components of oxygen delignified pulps was used to establish the distribution of carboxyl groups in lignin and pulp polysaccharide and decouple the responses from residual lignin and polysaccharide. Following this study, two high kappa (~ 49.0) SW kraft pulps prepared were delignified through two-stage oxygen delignification. Fiber carboxyl group profiles of these pulps were elucidated to investigate the effect of lignin content of incoming unbleached kraft pulps on fiber carboxyl group formation. Due to a limitation to enhance fiber carboxyl groups only by parameter optimization during one- and two- stage oxygen delignification, a catalytic oxidation program was developed to enhance fiber carboxyl groups by 52.2 116.0 % employing 0.10 - 0.18% of a bismuth ruthenium pyrochlore oxide catalyst during oxygen delignification. The mechanism of fiber carboxyl group formation through the catalytic oxidation was proposed. The main factor on carboxyl group formation in pulp carbohydrate was identified to follow the order: NaOH > oxygen pressure> reaction temperature through a 3-factor at 3-level (L933) orthogonal experimental design and the optimal conditions were found at 2.5% NaOH, 85-100 oC, and 800-960 kPa O2 during the catalytic oxidation. ECF bleaching study was also conducted on these pulps with higher amount of fiber carboxyl group enhanced at early pulping and oxygen delignification processes. The bleaching results demonstrated that the early-stage enhanced fiber carboxyl groups were partially retained through ECF bleaching. Additionally, fiber carboxyl groups of fully bleached kraft pulps were ~ 20% different from typical bleaching protocols, depending on bleaching chemicals used and the bleaching sequences such as DEDED, (D+C)EDED, ODEDD, and OQPZP. This study finally demonstrated that an increase of fiber carboxyl groups by 17.4-62.1% through chemical oxidation resulted in reduced fiber curl, increased fiber WRVs, 4.3-25.5 % increase in paper tensile index at comparable pulp viscosity; and 4.4 -30.1% increase in paper dry tensile stiffness.

This thesis focuses on the micromechanical modeling of particulate viscoelastic composite materials in the quasi-static frequency domain to approximate macroscopic damping behavior and has two main objectives. The first objective is the development of a robust frequency dependent multiscale model. For this purpose, the self-consistent (SC) mean-field micromechanical model introduced by Cherkaoui et al [J. Eng. Mater. Technol. 116, 274-278 (1994)] is extended to include frequency dependence via the viscoelastic correspondence principal. The quasi-static model is then generalized using dilute strain concentration tensor formulation and validated by comparison with complex bounds from literature, acoustic and static experimental data, and established models. The second objective is SC model implementation as a tool for the design of high loss materials. This objective is met by integrating the SC model into a Compromise Decision Support Protocol (CDSP) to explore the microstructural design space of an automobile windshield. The integrated SC-CDSP design space exploration results definitively indicate that one microstructural variable dominates structure level acoustic isolation and rigidity: negative stiffness. The work concludes with a detailed description of the fundamental mechanisms leading to negative stiffness behavior and proposes two negative stiffness inclusion designs.

This thesis presents further experimentation and modeling for bump-type gas foil bearings used in oil-free turbomachinery. The effect of shaft temperature on the measured structural force response of foil bearings is of importance for reliable high temperature applications. During actual operation with shaft rotation, the bearing structural parameters are coupled to the effects of a hydrodynamic gas film layer, thus determining the overall bearing load performance. A 38.17 mm inner diameter foil bearing, Generation II, is mounted on an affixed non-rotating hollow shaft with an outer diameter of 38.125 mm. A cartridge heater inserted into the shaft provides a controllable heat source. The clearance between the shaft and the foil bearing increases with increasing shaft temperatures (up to 188°C). A static load (ranging from 0 N to 133 N) is applied to the bearing housing, while measuring the resulting bearing displacement, which represents the compliant structure deflection. Static load versus displacement tests render the bearing static structural stiffness. As the shaft temperature increases, the static test results indicate that the bearing structural stiffness decreases by as much as 70% depending on the bearing orientation. A dynamic load test setup includes a rigid shaft support structure and a suspended electromagnetic shaker. Dynamic load (from 13 N to 31 N) test results show that the test foil bearing stiffness increases by as much as 50% with amplitude of dynamic load above a lightly loaded region, nearly doubles with frequency up to 200 Hz, and decreases by a third as shaft temperature increases. A stick slip phenomenon increases the bearing stiffness at higher frequencies for all the amplitudes of dynamic load tested. The test derived equivalent viscous damping is inversely proportional to amplitude of dynamic load, excitation frequency, and shaft temperature. Further, the estimated bearing dry friction coefficient decreases from 0.52 to 0.36 with amplitude of dynamic load and stays nearly constant as shaft temperature increases. Test results identify static and dynamic bearing parameters for increasing shaft temperature. These experimental results provide a benchmark for predictions from analytical models in current development and are essential to establish sound design practices of the compliant bearing structure.

This research compares the leakage and rotordynamic characteristics of a slanted-tooth labyrinth seal to a conventional straight-tooth labyrinth. Detailed results comparing the rotordynamic coefficients and leakage parameters of a slanted-tooth see-through labyrinth seal and a straight-tooth see-through labyrinth seal are presented. The straight-tooth labyrinth seal used in this research was originally tested by Arthur Picardo. The slanted-tooth labyrinth seal was designed and fabricated to be identical to the straight-tooth labyrinth seal in terms of pitch, depth, and the number of teeth. The angle of inclination of the teeth in the slanted-tooth labyrinth seal was chosen to be 65° from the normal axis. The seals were tested at an inlet pressure of 70 bar-a (1015 psi-a), pressure ratios of 0.4, 0.5, and 0.6, rotor speeds of 10,200, 15,350, and 20,200 rpm, and a radial clearance of 0.2 mm (8 mils). The experiments were carried out at zero, medium, and high inlet preswirl ratios. The experimental results show only minute differences in the rotordynamic coefficients between the two seals. But, the slanted-tooth labyrinth seal leaked approximately 10% less than the straight-tooth labyrinth seal. A study of prediction versus experimental data was done. XLlaby was used for prediction. XLlaby was developed for a straight-tooth labyrinth seal design and did not do a good job in predicting the rotordynamic coefficients and the leakage rate.

Finite element method and strip method are two widely used techniques for analyzing steel plate shear wall (SPSW) systems. Past research mostly focused on the prediction of lateral load capacity of these systems using these numerical methods. Apart from the lateral load carrying capacity, the lateral stiffness of the wall system needs to be determined for a satisfactory design. Lateral displacements and the fundamental natural frequency of the SPSW system are directly influenced by the lateral stiffness. In this study the accuracy of the finite element method and strip method of analysis are assessed by making comparisons with experimental findings. Comparisons revealed that both methods provide in general solutions with acceptable accuracy. While both methods offer acceptable solutions sophisticated computer models need to be generated. In this study two alternative methods are developed. The first one is an approximate hand method based on the deep beam theory. The classical deep beam theory is modified in the light of parametric studies performed on restrained thin plates under pure shear and pure bending. The second one is a computer method based on truss analogy. Stiffness predictions using the two alternative methods are found to compare well with the experimental findings. In addition, lateral stiffness predictions of the alternate methods are compared against the solutions provided using finite element and strip method of analysis for a class of test structures. These comparisons revealed that the developed methods provide estimates with acceptable accuracy and are simpler than the traditional analysis techniques.

Recent investigations in nanotechnology show that carbon nanotubes (CNT) have one of the most significant mechanical, electrical and optical properties. Interactions between those areas like electrical, optical and mechanical properties are also very promising in both research and industrial fields. Those unique characteristics are built by mainly the atomistic structure of the carbon nanotubes. In this thesis, the effects of vacant atoms on single walled carbon nanotubes (SWCNT) are investigated using matrix stiffness method. In order to use this technique a linkage between structural mechanics and molecular mechanics is established. A code has been developed to construct the SWCNT with the desired chirality, extracting the vacant atoms with the corresponding atomic bonds between the neighbor nodes and calculating the effect of those vacancies on its vibrational properties. A finite element software is also utilized for validation of the code and results. In order to investigate the convergence of the effect of those vacant nodes a numerous number of analyses have been carried out with randomly positioned vacant atoms. Also consecutive vacant nodes have been positioned in order to investigate the effect on the structural properties through the length of a CNT. In addition to those, as a case study, the reduction in Young&#039 / s modulus property because of the vacancies has also been investigated and the effects are tabulated in the report. It is concluded in this study that the any amount of vacant atoms have substantial effect on modal frequencies and Young&#039 / s modulus. Chirality and the position of the vacancies are the main parameters determining the structural properties of a CNT.

Resilient modulus is a property for bound and unbound pavement materials characterizing the elastic behavior of materials under dynamic repeated loading. Resilient modulus is an important design parameter for pavement structures because it represents the structural strength of pavement layers through which the thickness design is based on. In Turkey, the layer thickness design is performed using resilient modulus determined empirically from various published sources. Determining a layer modulus using empirical methods causes inaccurate design solutions, which directly affects the structural performance and the overall cost of pavement construction. In this study, the resilient moduli of bituminous mixtures are measured in the laboratory by the indirect tensile test procedure for eight asphalt concrete samples according to NCHRP and ASTM procedures. The measured moduli of samples based on the two procedures are compared with the predicted values calculated from various empirical methods using aggregate and binder properties. An evaluation of each estimation method is presented on the basis of its accuracy level. The results show that the Witczak predictive equation produces the closest estimation to the modulus of samples for both laboratory measurement methods.

The aim of this thesis is to analyze the kinematic and dynamic characteristics of a high-speed bearing system. The examined kinematic characteristics will include the maximal speed, fatigue life and stiffness of a bearing system. The stability and transmission force of a bearing system as well as the vibration of its shaft were the studied dynamic characteristics. These analyses were based on the kinemitics of bearing systems, rotor dynamics and elastohydrodynamic lubrication theory. According to these analyses, the interaction and consequence among these characteristics and the parameters of a bearing system will be explained. After these analyses, preliminary and simple design trends about a high-speed bearing system are going to be proposed.

The goal of this thesis is to study the role of single particle elasticity in the overall behavior of particulate systems. For this purpose, we use microgel particles, which are crosslinked polymer networks immersed in a solvent. In these systems, the amount of cross-linker determines their elasticity and ultimately the stiffness of the particle. For a system of hard spheres, the phase behavior is solely determined by the volume fraction occupied by the particles. Based on the volume fraction, liquid, crystal and glassy phases are observed. Interestingly, microgel particles display a richer and fascinating set of different behaviors depending on the particle stiffness. Previous results obtained in our group show that for highly cross-linked microgels, the glass phase disappears and there are only liquid and crystalline phases. By contrast, preliminary measurements indicate that for ultrasoft microgel particles the system does not show any signature of crystalline or glassy phases. The system seems to remain liquid irrespective of volume fractions. In this Thesis, we will address this striking result using light scattering as well as rheology, in order to access both static and dynamic properties in a wide range of length and time scales. In addition, we will also perform additional studies using very stiff microgels and use their swelling capabilities to change the volume fraction. We will use hydrostatic pressure to change the miscibility of the polymer network and thus change the microgel size; the use of this external variable allows fast equilibration times and homogeneous changes throughout the sample. By using neutron scattering techniques, we study the structural and dynamical properties of the system in its different phases involved.