The use of sunlight has always been a major goal in the design and operation of commercial buildings to minimize electrical consumption of artificial lighting systems. Glazing systems designed to allow optimal visible light transmission also allow significant unwanted direct solar heat gain caused by infrared light. Conversely, glazing systems that are designed to reflect unwanted direct solar heat gain significantly reduce the transmittance of visible light through windows. The goal of this research was to characterize the performance of water as gap-fill for double-glazing units in eliminating the compromises that exist in current glazing systems with respect to light and heat transmittance. An in situ test approach and computer simulations were conducted to measure the performance of water-filled glazing units against air-filled glazing units. The thermal transmittance and solar heat gain coefficient values obtained from both the field experiments and computer simulations, glazing units with air-fill proved better than the glazing units with non-flowing water-fill. However, the high convective coefficient and the high thermal mass of the water can be used to its advantage when it is allowed to flow at peak temperatures, thus, maintaining lower temperature swings indoor. This can lead to a reduction of about 50-70% direct solar heat and still maintain high visibility.

Microtruss materials are assemblies of struts or columns arranged periodically in space. The majority of past research efforts have focused on the key issue of microtruss architectural optimization. By contrast, this study focuses on the internal material structure at the level of the individual struts. Microstructural, geometrical, and material design techniques are used to improve their mechanical properties. The finite element method is used to verify and create predictive analytical models, explain the dependence of strut properties on geometry, material properties and failure mechanisms, and extend the strut design analysis into suggestions for the improvement of fabrication methods. Three strut design methods are considered. First, microstructural design is performed by considering the influence of strut geometry on the strain energy imparted during stretch bending. By using the perforation geometry to modify the location and magnitude of this strain energy, microtruss materials with lower density and higher strength can be fabricated. Second, structural sleeves of aluminum oxide and electrodeposited nanocrystalline nickel are used to reinforce architecturally optimized aluminum alloy microtruss assemblies, creating hybrid materials with high weight-specific strength. The mechanical properties are controlled by the interaction between material and mechanical failure; this interaction is studied through finite element analyses and a proposed analytical relationship to provide suggestions for further improvements. Finally, hollow cylindrical struts are fabricated from electrodeposited nanocrystalline nickel. The high strength to weight ratio achieved in these struts is due to the microstructural and cross-sectional efficiency of the material.

Microtruss materials are assemblies of struts or columns arranged periodically in space. The majority of past research efforts have focused on the key issue of microtruss architectural optimization. By contrast, this study focuses on the internal material structure at the level of the individual struts. Microstructural, geometrical, and material design techniques are used to improve their mechanical properties. The finite element method is used to verify and create predictive analytical models, explain the dependence of strut properties on geometry, material properties and failure mechanisms, and extend the strut design analysis into suggestions for the improvement of fabrication methods. Three strut design methods are considered. First, microstructural design is performed by considering the influence of strut geometry on the strain energy imparted during stretch bending. By using the perforation geometry to modify the location and magnitude of this strain energy, microtruss materials with lower density and higher strength can be fabricated. Second, structural sleeves of aluminum oxide and electrodeposited nanocrystalline nickel are used to reinforce architecturally optimized aluminum alloy microtruss assemblies, creating hybrid materials with high weight-specific strength. The mechanical properties are controlled by the interaction between material and mechanical failure; this interaction is studied through finite element analyses and a proposed analytical relationship to provide suggestions for further improvements. Finally, hollow cylindrical struts are fabricated from electrodeposited nanocrystalline nickel. The high strength to weight ratio achieved in these struts is due to the microstructural and cross-sectional efficiency of the material.

Les effets d’échelle sur la résistance mécanique des matériaux, i.e. le fait que plus un échantillon de matière est grand, plus, en moyenne, sa contrainte à rupture sera faible, déjà soulignées par Leonardo da Vinci et Edmée Mariotte il y a des siècles, demeurent de nos jours un problème crucial pour établir des règles de sécurité et de conception de grandes structures à partir de données de laboratoire. Ces effets d’échelle sont généralement expliqués soit par une approche déterministe qui prédit une résistance asymptotique non nulle mais, par construction, ne tient pas compte des fluctuations de la résistance moyenne et de leur dépendance vis-à-vis de la taille, ou d'une approche statistique basée sur la théorie du maillon le plus faible qui implique une résistance nulle pour un système de taille infini.Récemment, un cadre alternatif a été proposé sur la base d’une interprétation de la rupture en compression des matériaux hétérogènes comme une transition de phase critique entre un état intact et un état rompu. Cette interprétation libère les hypothèses de base de la théorie du maillon le plus faible comme la fragilité extrême et l’indépendance entre évènements de microfracturation et prédit qu’un système de taille infinie conservera une résistance mécanique non nulle (σ_∞ ) mais une variabilité associée de la résistance nulle. En appliquant ce cadre critique, les effets d’échelle statistique sur la résistance en compression du béton, un matériau quasi-fragile typique et important en génie civil, sont étudiés dans cette thèse.A partir d’une importante série d’expériences de compression uniaxiale (527 essais) qui a été réalisée sur des échantillons du béton de quatre tailles différentes et trois microstructures différentes, nous démontrons (i) l’échec de la théorie du maillon le plus faible dans ce cas ; et au lieu de cela (ii) la pertinence du cadre critique pour tenir compte des effets d’échelle sur la résistance à rupture en compression du béton, en termes de valeur moyenne, de fluctuation associées et de probabilité de défaillance. A partir d’une analyse détaillée de la microstructure de nos matériaux, nous montrons que la structure des pores, plutôt que les aggrégats, joue un rôle important sur les effets d’échelle sur la résistance à rupture en compression. Dans ce cadre, la résistance asymptotique (σ_∞ ) représente la véritable résistance caractéristique en compression (f_ck ), qui est une propriété essentielle pour la conception de structures à grande échelle et pour le contrôle de la qualité du béton.En conséquence du rôle important de la structure des pores sur les effets d’échelle sur la résistance en compression des bétons à faible porosité, lors de l'estimation de la résistance caractéristique à partir d'une série d'essais avec une seule taille d'échantillon, une condition sur cette taille par rapport à la taille caractéristique de la structure des pores est proposée. / Size effects on mechanical strength, i.e. the fact that larger structures fail under lower stresses than smaller ones, already highlighted by Leonardo da Vinci and Edmée Mariotte centuries ago, remain nowadays a crucial problem to establish structural design rules and safety regulations from an upscaling of laboratory data. These size effects are generally explained either from a deterministic energetic approach that predicts a non-vanishing asymptotic strength but, by construction, does not account for fluctuations around the mean strength and their size dependence, or from a statistical approach based on the weakest-link theory that implies a vanishing strength towards large scales.Recently, an alternative framework has been proposed based on an interpretation of compressive failure of heterogeneous materials as a critical transition from an intact to a failed state. This critical interpretation releases the underlying hypotheses of the weakest-link theory, pure brittleness and the independence of damage events, while predicting a non-vanishing asymptotic mean strength (σ_∞ ) but vanishing intrinsic fluctuations at large scales. The application this framework to the statistical size effects on compressive strength of concrete, a typical quasibrittle material of tremendous importance in civil engineering, is investigated in this thesis.From an extensive series of uniaxial compression experiments (527 tests) carried out on concrete samples with four different sizes and three different microstructures, we demonstrate (i) the failure of the weakest-link theory in this case, and instead (ii) the pertinence of the critical framework to account for size effects on compressive strength of concrete, in terms of average strength, associated fluctuations, and probability of failure. From a detailed analysis of the microstructural disorder of our materials, we show that the pore structure, rather than the concrete mix, plays a significant role on size effects on strength. In this framework, the asymptotic strength (σ_∞ ) represents the genuine characteristic compressive strength (f_ck ) of the material, a key property for the dimensioning large-scale structures from an upscaling of small-scale laboratory mechanical tests and for the quality control of concrete.As a consequence of the leading role of the pore structure in controlling the size effects on compressive strength of low-porosity concretes, when estimating the characteristic (asymptotic) strength from a series of tests with a single sample size, a condition on this size with respect to the characteristic scale of pore structure is proposed to be fulfilled.

Tantalum carbide (TaC) and hafnium carbide (HfC) possess extremely high melting points, around 3900 oC, which are the highest among the known materials. TaC and HfC exhibit superior oxidation resistance under oxygen deficient and rich environments, respectively. A versatile material can be expected by forming solid solutions of TaC and HfC. However, the synthesis of fully dense solid solution carbide is a challenge due to their intrinsic covalent bonding which makes sintering challenging. The aim of the present work is to synthesize full dense TaC-HfC solid solutions by spark plasma sintering with five compositions: pure HfC, HfC-20 vol.% TaC (T20H80), HfC- 50 vol.% TaC (T50H50), HfC- 80 vol.% TaC (T80H20), and pure TaC. To evaluate the oxidation behavior of the solid solutions carbides in an environment that simulates the various applications, an oxygen rich, plasma assisted flow experiment was developed. While exposed to the plasma flow, samples were exposed to a temperature of approximately 2800 oC with a gas flow speed greater than 300 m/s. Density measurements confirm near full density was achieved for all compositions, with the highest density measured in the HfC-contained samples, all consolidated without sintering aids. Confirmation of solid solution was completed using x-ray diffraction, which had an excellent match with the theoretical values computed using Vegard’s Law, which confirmed the formation of the solid solutions. The solid solution samples showed much improved oxidation resistance compared to the pure carbide samples, and the T50H50 samples exhibited the best oxidation resistance of all samples. The thickness of the oxide scales in T50H50 was reduced more than 90% compared to the pure TaC samples, and more than 85% compared to the pure HfC samples after 5 min oxidation tests. A new Ta2Hf6O17 phase was found to be responsible for the improved oxidation performance. Additionally, the structure of HfO2 scaffold filled with molten Ta2O5 was also beneficial to the oxidation resistance by limiting the availability of oxygen.

The primary goals of this project were to examine the amount of lateral force resisted by a single-bay mortise-tenon connected timber moment frame, and to introduce ductile behavior into the mortise-tenon connections by adding a steel sleeve around a traditional wood peg. This research aimed to provide proof that traditional timber frames are capable of ductile racking while reliably complying with ASCE 7-10 building code drift speci! cations, implying an increase in the ASCE 7-10 ductility factor (R) for wood frames when used as lateral force resisting elements. A secondary goal was to promote traditional heavy timber framing as a main structural system. Modern structural framing is dominated by light-wood, steel, and concrete framing. The exploration in this project aspires to demonstrate that heavy timber frames can achieve comparable lateral performance and frame behavior to other current lateral systems, reassuring the reliability of traditional timber frames.

This investigation was undertaken to develop plastic design aids to be used in the direct design of optimum frames. It uses the concept of minimum weight of plastically designed steel frames, and the concept of linear programming to obtain general solutions. Among the special characteristics of this study are: A. The integration of both gravity and combined loading conditions into one linear programming problem. B. The application of the revised simplex method to the dual of a parametric original problem. C. The application of A and B above in the development of design aids for the optimum design of symmetrical single-bay, single-story portal frame. Specifically, design graphs for different height to span ratios and different vertical load to lateral load ratios are developed. The use of these graphs does not require the knowledge of linear programming or computers on the part of the designer.

The addition of rare earth (RE) alloying elements is a promising method for improving the strength, ductility and overall formability of magnesium (Mg) alloys. However, the underlying mechanism for this phenomenon remains unclear. An investigation on the effect of the rare earth element, scandium (Sc), on binary Mg-Sc alloys has been pursued. Tension and compression tests were performed on a series of dilute binary Mg-Sc alloys at temperatures of 298 K, 78 K and 4.2 K. As a reference, pure Mg was also investigated for comparative purposes. Differences in tension and compression stress-strain curves highlighted distinct activated mechanisms, where slip dominated in tension and twinning governed compression. The observed increase in ductility and prolonged necking was attributed to a weaker basal texture, enhanced twinning and non-basal slip. A decreased work hardening rate suggests an improvement in dislocation recovery with Sc addition. In compression, Mg-Sc alloys followed Fleischer’s theory of solution hardening, where stress scales with concentration, c, as c^1/2; however, there was a very weak fit with both Fleischer and Labusch models under tension. The strengthening rate displayed by Mg-Sc was relatively weak compared to previously studied Mg-RE systems. However, considering the estimated misfit parameters, the size and modulus misfit was not enough to account for the strengthening rate. The results suggest that hardening of the twinning mode may influence strength. Constitutive modelling, based on a self-consistent plasticity model, was used to characterize the deformation behaviour. The simulations predicted an increased relative activity of non-basal <c+a> slip with Sc addition, supporting experimental results and proposed mechanisms in literature. The results of Mg-Sc alloys have been connected to theories that identify a decrease in stacking fault energy (SFE) as the determining factor for increased strength and ductility of Mg-RE alloys. A comparison of the SFE of previously studied REEs with Sc, demonstrated strong evidence towards the theory’s validity. Sc has been shown to only moderately reduce the SFE of Mg and hence, the present experimental results have shown a moderate increase in strength and ductility. Additional modelling and detailed dislocation analysis are suggested as future steps to further support this theory. / Thesis / Master of Applied Science (MASc)

Cellular metals made from aluminum, titanium, or other metals are becoming increasingly popular for use in structural components of automobiles, aircraft, and orthopaedic implants. Civil engineering applications remain largely absent, primarily due to poor understanding of the material and its structural properties. However, the material features a high stiffness to weight ratio, excellent energy dissipation, and low thermal conductivity, suggesting that it could become a highly valuable new material in structural engineering. Previous attempts to characterize the mechanical properties of steel foam have focused almost exclusively upon uniaxial compression tests, both in experimental research and in computational simulations. Further, computational simulations have rarely taken the randomness of the material’s microstructure into account and have instead simplified the material to a regular structure. Experimental tests have therefore been performed upon both hollow spheres and PCM steel foams to determine compressive, tensile, and shear properties. Computational simulations which accurately represent the randomness within the microstructure have been validated against these experimental results and then used to simulate other material scale tests. Simulated test matrices have determined macroscopic system sensitivity to various material and geometrical parameters.

Currently, various needs from industry, science and national defense strategy demand materials with cutting-edge ultra-high temperature performances. Typical applications of ultra-high temperature materials (UHTMs) are supersonic airplanes, gas turbines and rocket nozzles which usually require continuous service of critical components at temperatures higher than 1600°C. Creep resistance is a critical criterion in designing materials for these applications. Traditional creep characterization methods, however, due to limitations on cost, accuracy and most importantly temperature capability, gradually emerge as a bottleneck. Since 2004, a group of researchers in the University of Massachusetts, Amherst have been designing a new high temperature characterization scheme that can break through the limits of traditional methods. Their method is based on non-contact creep tests conducted with Electrostatic levitation (ESL) facilities in NASA Marshall Space Flight Center in Huntsville Alabama. The tested sample is levitated in electric field and is heated as well as rotated with specially positioned laser beam. After certain amount of time, the sample deforms under centripetal forces. By comparison of the shape of the deformed sample with results from finite element simulation, creep behavior of the tested material can be characterized. Based on the same theory, this thesis presents a computational creep characterization method based on non-contact method. A finite element model was built to simulate non-contact creep behavior and results were compared to ESL experiments to determine the creep characteristic. This method was validated both theoretically and numerically and then applied to creep characterization of a promising ultra-high temperature composite from General electric (GE).