This paper discusses earth as a building material and the extent to which earth building technology has evolved over the years. In particular it addresses the adobe, compressed and rammed earth techniques of earth building as suitable techniques for Liberia consumption. In addition, the paper investigates the suitability of the Latosols soils of Liberia for earth building construction purposes using standardized earth building principles and requirements. A local Johnson City, Tennessee, earth sample found to have the same physical characteristics of the Latosols of Liberia was used to simulate Liberia soils to produce specimen blocks at different configurations of moisture content and stabilizers (Bentonite and cement). Following 14 days of cure, the blocks were tested for compressive strength. It was found that blocks produced from the natural soil with no stabilizer added were structurally adequate for building construction purposes. A cost-benefit analysis involving blocks with and without stabilizer (cement) added was also performed.

Finite Element Modeling of Ballistic Impact on a Glass Fiber Composite Armor Dan Davis Experiments measuring the ballistic performance of a commercially available fiberglass armor plate were used to guide the development of constitutive laws for a finite element model of the impact. The test samples are commercially available armor panels, made from E-glass fiber reinforced polyester rated to NIJ level III. Quasi-static tensile tests were used to establish material properties of the test panels. These properties were then used to create models in the explicit finite element code LSDYNA. Ballistic impact testing of the panels was conducted using a compressed gas gun firing spherical steel projectiles oriented normal to the test panel surface. The V50 ballistic limit of these panels was found to be approximately 560 m/s. Tuning parameters in the finite element models were adjusted to match the experimentally measured penetration depths and ballistic limits. Models were created in LSDYNA by adjusting the available material library types 3 and 59 for the target, and material type 15 for the projectile. Type 3 models are isotropic, and resulted in shear punch-out type failures of the plate that poorly replicated the test results. Type 59 takes orthotropic properties into consideration, and can analyze delamination when used with solid elements. Results with model type 59 were significantly better than those using type 3, however, this model was found to vastly underestimate the impact resistance of the plate. With significant adjustments to the material properties in the type 59 model, the LSDYNA simulations were found to better replicate the experimentally observed response of the panels. However, these deformations are questionable since they required quite unrealistic adjustments to the material properties.

Optimal print parameters for additively manufacturing 316L stainless steel using selective laser melting (SLM) at Cal Poly had previously been identified. In order to further support the viability of the current settings, tensile material characteristics were needed. Furthermore, reliable performance of the as-printed material had to be demonstrated. Any influence on the static performance of parts in the as-printed condition inherent to the SLM manufacturing process itself needed to be identified. Tensile testing was conducted to determine the properties of material in the as-printed condition. So as to have confidence in the experimental results, other investigations were also conducted to validate previous assumptions. Stereological relative density measurements showed that the as-printed material exhibited relative density in excess of 99%. Optical dimensional analysis found that the as-printed tensile specimens met ASTM E8 dimensional requirements in 14 out of 15 parts inspected. Baseline tensile tests indicated that the yield stress of the as-printed material is 24% higher than a cold-rolled alternative, while still achieving comparable ductility. The location of a tensile specimen on the build plate during the print was not found to have a significant effect on its mechanical properties. Theoretical behavior of notched tensile specimens based on finite element models matched experimental behavior in the actual specimens. Unique fracture behavior was found in both the unnotched reference and the most severe notch after microscopic inspection, and a root cause was proposed. Finally, extrapolating from previous studies and observing that experimental results matched theoretical models, it was determined that features inherent to SLM parts were not detrimental to the static performance of the as-printed material.

Hybrid carbon fiber reinforced composites are a new breed of materials that are currently being explored and characterized for next generation aerospace applications. Through the introduction of secondary reinforcements, such as alumina nanoparticles, hybrid properties including improved mechanical properties and stress sensing capabilities can be achieved. In order to maximize these properties, it is necessary to achieve a homogeneous dispersion of particulate filler. Utilizing the photoluminescent properties of alumina, it is possible to compare local levels of particle concentration through emission intensities as a way to determine the effectiveness of the tested manufacturing parameters in increasing material homogeneity. Parameters of these photoluminescence emissions have been established to be stress dependent, which allows for in situ residual stress measurements. It is shown here that the application of silane coupling agents as particle surface treatments improves particle dispersion when compared to untreated samples. Reactive silane coupling agent (RSCA) treatments were found to provide for greater dispersion improvements when compared to non-reactive silane coupling agents (NRSCA). Higher resolution investigations into these samples found that treatment with a reactive coupling agent altered the stress state of particles concentrated around the fiber from a tensile stress state to a compressive stress state. This is proposed to result from bonding of the reactive groups on the coupling agent to the organic groups on the carbon fibers which adjusts the stress state of the particle. Future mechanical tests will verify the effects of the particle surface functionalization treatments on mechanical properties of the composites.

<p>Organic thin film transistors (OTFTs) have attracted great attention in the last couple of decades due to their potential of cost reductions in manufacturing low-end electronic devices through solution processes. Currently, one of the major challenges facing the field of OTFTs is lack of high performance functional organic materials including both organic semiconductors and gate dielectrics for effective device integrations by solution deposition technologies. This thesis focuses on material designs, interfacial compatibilities, and device integrations for high performance OTFTs.</p> <p>Research progresses in the following areas are presented in this thesis. First, novel liquid-crystalline organic semiconductors, 2,5‟-bis-[2-(4-pentylphenyl)vinyl]-thieno(3,2-</p> <p><em>b</em>) thiophene and 2,5‟-bis-[2-(4-pentylphenyl)vinyl]-(2,2‟)bithiophene for OTFT applications were developed. Mobilities of the OTFTs fabricated from these semiconductors reached 0.15 cm2/V.s with high environmental stability. Such high performance is attributed to their ability to form highly ordered molecular structures. Second, a simple effective approach was developed for tuning solubility of a high mobility polythiophene system through engineering its molecular structure. OTFTs fabricated with the newly developed copolythiophenes from an environmentally benign non-chlorinated solvent showed excellent performance with mobility up to 0.18 cm2/V.s. Third, an effective approach to a solution processed gate dielectric Ph.D. Thesis – P. Liu, McMaster University, Chemical Engineering iv</p> <p>design was developed for all solution-processed flexible OTFTs. This was achieved through a dual-layer dielectric structure design comprised of a bottom layer with a UV-crosslinked poly(4-vinyl phenol-co-methyl methacrylate), (PVP-PMMA), and a top layer with a thermally crosslinked polysiloxane. This solution-processed dual-layer dielectric structure enabled all solution-processed high performance flexible OTFTs. Finally, flexible OTFTs were successfully integrated on plastic substrates (PET) from non-chlorinated solvents by using the copolythiophenes and the dual-layer dielectric. The integrated flexible devices showed good OTFT characteristics with mobility up to about 0.1 cm²/V.s.,</p> <p>well defined linear and saturated regions, and a close to zero turn-on voltage.</p> / Doctor of Philosophy (PhD)

Rice straw is a global and proliferate agricultural waste whose production grossly outstrips viable uses. Current disposal methods are not sustainable, and more convenient methods – such as incineration – exude poor environmental stewardship. Although the direct use of straw bales in building construction presents a practical and sustainable alternative, engineering challenges associated with using it prevent its wide adoption. The Stak Block – a composite formed from compressed rice straw and a heat-cured adhesive – may overcome challenges associated with straw bale building. However, the times and temperatures needed to cure the binder with straw are not well understood. Therefore, the goal of this thesis was to study straw cubes (in lieu of the full-scale Stak Block) to discern a time-temperature relationship. A finite element (FE) model of the Stak Block was created to simulate the heating process. The results of this study indicated that the adhesive may actually cure at temperatures less than 100°C. This data influenced the times and temperatures that binder-treated straw cubes were baked at for the first of several iterations. A chemical dye was used to discern if cubes had cured or not. In addition, mechanical testing was used to inspect cubes for curing and to support the results obtained from using a chemical dye. Results from cubes inspected with the chemical dye method were then used to develop an inverse relationship between time and temperature needed to cure the cubes – with the lowest observed cure temperature to be 65°C for 2 hours and the fastest cure time of 30 minutes at 150 and 125°C. Following the iterative experiments, an FE model of the cube was created and fitted to the results of the iterative experiments. Values for thermal conductivity (k = 0.1 W/m-K)and specific heat (Cp = 2000 J/kg-K) used to fit the FE cube model were applied appropriately to the Stak Block FE model in order to estimate curing times at different temperatures.

The hot working behavior of AISI 1018 steel was studied by hot-compression deformation tests on the Gleeble 1500 thermo-mechanical simulator at true strain values of -0.143 and -0.405, true strain rate values of 0.01 and 0.1, and working temperatures of 900°C and 1000°C. The tests show that a lower working temperature and lower true strain value results in a greater maximum compressive force. The apparent activation energy Qapp was calculated by using the Zener-Hollomon parameter combined with the low stress law. Qapp ­was calculated to be 311 kJ mol-1 K-1.

A Comparison Study of Composite Laminated Plates with Holes under Tension A study was conducted to quantify the accuracy of numerical approximations to deem sufficiency in validating structural composite design, thus minimizing, or even eliminating the need for experimental test. Error values for stress and strain were compared between Finite Element Analysis (FEA) and analytical (Classical Laminated Plate Theory), and FEA and experimental tensile test for two composite plate designs under tension: a cross-ply composite plate design of [(0/90)4]s, and a quasi-isotropic layup design of [02/+45/-45/902]s, each with a single, centered hole of 1/8” diameter, and 1/4" diameter (four sets total). The intent of adding variability to the ply sequences and hole configurations was to gauge the sensitivity and confidence of the FEA results and to study whether introducing enough variability would, indeed, produce greater discrepancies between numerical and experimental results, thus necessitating a physical test. A shell element numerical approximation method through ABAQUS was used for the FEA. Mitsubishi Rayon Carbon Fiber and Composites (formerly Newport Composites) unidirectional pre-preg NCT301-2G150/108 was utilized for manufacturing—which was conducted and tested to conform to ASTM D3039/D3039M standards. A global seed size of 0.020, or a node count on the order of magnitude of 30,000 nodes per substrate, was utilized for its sub-3% error with efficiency in run-time. The average error rate for FEA strain from analytical strain at a point load of 1000lbf was 2%, while the FEA-to-experimental strains averaged an error of 4%; FEA-to-analytical and FEA-to-tensile test stress values at 1000lbf point load both averaged an error value of 6%. Suffice to say, many of these strain values were accurate up to ten-thousandths and hundred-thousandths of an in/in, and the larger stress/strain errors between FEA and test may have been attributed to the natural variables introduced from conducting a tensile test: strain gauge application methods, tolerance stacks from load cells and strain gauge readings. Despite the variables, it was determined that numerical analysis could, indeed, replace experimental testing. It was observed through this thesis that a denser, more intricate mesh design could provide a greater level of accuracy for numerical solutions, which proves the notion that if lower error rates were necessitated, continued research with a more powerful processor should be able to provide the granularity and accuracy in output that would further minimize error rates between FEA and experimental. Additionally, design margins and factors of safety would generally cover the error rates expected from numerical analysis. Future work may involve utilizing different types of pre-preg and further varied hole dimensions to better understand how the FEA correlates with analytical and tensile test results. Other load types, such as bending, may also provide insight into how these materials behave under loading, thus furthering the conversation of whether numerical approximations may one day replace testing all together.

This thesis evaluates the application of a simplified analysis procedure as implemented in version 16 of CSiBridgeTM for design of bridges crossing earthquake fault ruptures. The fault-rupture response spectrum analysis (FR-RSA) approximation method has been proved adequate for both straight and curved ordinary bridges, but lacked a comfortable interface to accommodate the method users. Computers and Structure, Inc. has implemented the FR-RSA procedure into CSiBridgeTM, a user-friendly integrated 3-D bridge design software, as an added seismic design feature. By combining the response of the bridge due to the quasi-static displacement from the fault strike-slip rupture and the pseudo-dynamic displacement from the earthquake response spectrum analysis, a combined seismic demand is approximated using the software. The CSiBridgeTM bridge model creation process and application of FR-RSA as the Caltrans Fault Crossing Seismic Design Request is explained and evaluated in this thesis. In order to validate the implementation of FR-RSA in CSiBridgeTM v.16, the bridge demands for a three span and a four span curved bridge crossing earthquake fault rupture zones from the analytical models developed in Open System for Earthquake Engineering Simulation (OpenSees) and CSiBridgeTM v.16 are compared and discussed. It was found that the displacement demands from the abutments and bents were comparable from the two programs, supporting the correct application of the approximation method. This thesis also presents recommendations for improving the analysis function of CSiBridgeTM v.16 for bridges crossing fault ruptures.

Pitting corrosion is a prevalent form of corrosive damage that can weaken, damage, and initiate failure in corrosion-resistant metallic materials. For instance, 304 stainless steel is commonly utilized in various structures (e.g., miter gates, heat exchangers, and storage tanks), but is prone to failure through pitting corrosion and stress corrosion cracking under mechanical loading, regardless of its high corrosion resistance. In this study, to better understand the pitting corrosion damage development, controlled corrosion experiments were conducted to generate pits on 304 stainless steel specimens with and without mechanical loading. The pit development over time was characterized using a high-resolution laser scanner. In addition, to achieve scalable and automatic assessment of pitting corrosion conditions, two convolutional neural network-based computer vision algorithms were adopted and implemented to evaluate the efficacy of networks to identify existence of pitting damage. One was a newly trained convolutional neural network (CNN) using MATLAB software, while the other one was a retrained version of GoogLeNet. Overall, the experimental results showed that time is the dependent variable in predicting pit depth. Meanwhile, loading conditions significantly influence pit morphology. Under compression loading, pits form with larger surface opening areas, while under tension loading, pits have smaller surface opening areas. Deep pits of smaller areas are dangerous for structural members, as they can lead to high stress concentrations and early stress corrosion cracking (SCC). Furthermore, while the training library was limited and consisted of low-resolution images, the retrained GoogLeNet CNN showed promising potential for identifying pitting corrosion based on the evaluation of its performance parameters, including the accuracy, loss, recall, precision, and F1-measure.