A method of inferring tropospheric gravity wave source characteristics from middle atmosphere observations has been adapted from previous studies for use with MF radar observations of the equatorial mesosphere-lower thermosphere at Christmas Island in the central Pacific. The nature of the techniques applied also permitted an analysis of the momentum flux associated with the characterised sources and its effects on the equatorial mean flow and diurnal solar thermal tide. An anisotropic function of gravity wave horizontal phase speed was identified as being characteristic of convectively generated source spectra. This was applied stochastically to a ray-tracing model to isolate numerical estimates of the function parameters. The inferred spectral characteristics were found to be consistent with current theories relating convective gravity wave spectra to tropospheric conditions and parameters characterising tropical deep convection. The results obtained provide observational constraints on the model spectra used in gravity wave parameterisations in numerical weather prediction and general circulation models. The interaction of gravity waves with the diurnal solar thermal tide was found to cause an amplification of the tide in the vicinity of the mesopause. The gravity wave-tidal interactions were highly sensitive to spectral width and amplitude. Estimates were made of the high frequency gravity wave contribution to forcing the MSAO with variable results. The data used in the analysis are part of a large archive which now has the potential to provide tighter constraints on wave spectra through the use of the methods developed here. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1352362 / Thesis (Ph.D.) -- University of Adelaide, School of Chemistry and Physics, 2009

Title: Convective storms and lower stratospheric moisture Author: Jindřich Šťástka Department: Department of Atmospheric Physics Supervisor: RNDr. Martin Setvák, CSc., Czech Hydrometeorological Institute Abstract: The primary focus of this thesis is to diagnose contributions to upper tropo- spheric and lower stratospheric (UTLS) water vapor from convective storms. The first parts of this work introduces two approaches used for a detection of lower stratospheric water vapor above convective storm tops - brightness temperature difference (BTD) technique and EOS MLS measurements. The BTD technique is based on brightness temperature difference between the water vapor absorp- tion and infrared window bands, assuming a thermal inversion above the cloud top level. The most frequently offered explanation of positive BTD values above convective storms is presence of warmer water vapor in the lower stratosphere. Furthermore, so called BTD anomalies were described and it was proposed an algorithm for objective detection of such BTD anomalies. Characteristics of pa- rameters describing BTD, BTD anomaly, infrared window brightness temperature were investigated during storms evolution on dataset of 320 storms from the area of Europe. The analysis of these characteristics proved highly probable conection between positive...

Submitted by Paulo Sérgio de Oliveira Júnior null (psergio.jr@hotmail.com) on 2017-11-17T14:41:41Z No. of bitstreams: 1 d_oliveira-jr_ps_thesis.pdf: 14260833 bytes, checksum: ebcb000a304456bb9bc42d8d1ccaa566 (MD5) / Approved for entry into archive by LUIZA DE MENEZES ROMANETTO (luizamenezes@reitoria.unesp.br) on 2017-11-17T17:10:17Z (GMT) No. of bitstreams: 1 oliveirajunior_ps_dr_prud.pdf: 14260833 bytes, checksum: ebcb000a304456bb9bc42d8d1ccaa566 (MD5) / Made available in DSpace on 2017-11-17T17:10:17Z (GMT). No. of bitstreams: 1 oliveirajunior_ps_dr_prud.pdf: 14260833 bytes, checksum: ebcb000a304456bb9bc42d8d1ccaa566 (MD5) Previous issue date: 2017-09-05 / Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) / PPP (Precise Point Positioning) is a positioning method by GNSS (Global Navigation Satellite Systems), based on SSR (State Space Representation) concept that can provide centimeter accuracy solutions. Real-time PPP (RT-PPP) is possible thanks to the availability of precise products, for orbits and clocks, provided by the International GNSS Service (IGS), as well as by its analysis centers such as CNES (Center National d'Etudes Spatiales). One of the remaining challenges on RT-PPP is the mitigation of atmospheric effects (troposphere and ionosphere) on GNSS signals. Thanks to recent improvements in atmospheric models, RT-PPP can be enhanced, allowing accuracy and centimeter initialization time, comparable to the current NRTK (Network Real-Time Kinematic) method. Such performance depends on topology of permanent stations networks and atmospheric conditions. The main objective of this project is to study the RT-PPP and the optimized infrastructure in terms of costs and benefits to realize the method using atmospheric corrections. Therefore, different configurations of a dense and regular GNSS network existing in France, the Orpheon network, are used. This network has about 160 sites and is owned by Geodata-Diffusion (Hexagon Geosystems). The work was divided into two main stages. Initially, ‘float PPP-RTK’ was evaluated, it corresponds to RT-PPP with improvements resulting from network corrections, although with ambiguities kept float. Further on, network corrections are applied to improve “PPP-RTK” where ambiguities are fixed to their integer values. For the float PPP-RTK, a modified version of the RTKLib 2.4.3 (beta) package is used to take into account for the network corrections. First-order ionospheric effects were eliminated by the iono-free combination and zenith tropospheric delay estimated. The corrections were applied by introducing a priori constrained tropospheric parameters. Periods with different tropospheric conditions were chosen to carry out the study. Adaptive modeling based on OFCs (Optimal Fitting Coefficients) has been developed to describe the behavior of the troposphere, using estimates of tropospheric delays for Orpheon stations. This solution allows one-way communication between the server and the user. The quality of tropospheric corrections is evaluated by comparison to external tropospheric products. The gains achieved in convergence time to 10 centimeters accuracy were statistically quantified. Network topology was assessed by reducing the number of reference stations (up to 75%) using a sparse Orpheon network configuration to perform tropospheric modeling. This did not degrade the tropospheric corrections and similar performances were obtained on the user side. In the second step, PPP-RTK is realized using the PPP-Wizard 1.3 software and CNES real-time products for orbits, clocks and phase biases of satellites. RT-IPPP (Real-Time Integer PPP) is performed with estimation of tropospheric and ionospheric delays. Ionospheric and tropospheric corrections are introduced as a priori parameters constrained to the PPP-RTK of the user. To generate ionospheric corrections, it was implemented a solution aligned with RTCM (Real-Time Maritime Services) conventions, regarding the transmission of ionospheric parameters SSR, which is a standard Inverse Distance Weighting (IDW) algorithm. The choice of the periods for this experiment was made mainly with respect to the ionospheric activity. The comparison of the atmospheric corrections with the external products and the evaluation of different network topologies (dense and sparse) were also carried out in this stage. Statistically, the standard RT-IPPP takes ~ 25 min to achieve a 10 cm horizontal accuracy, which is significantly improved by our method: 46% (convergence in 14 min) with dense network corrections and 24% (convergence in 19 min) with the sparse network. Nevertheless, vertical positioning sees its convergence time slightly increased, especially when corrections are used from a sparse network solution. However, improvements in horizontal positioning due to external SSR corrections from a (dense or sparse) network are promising and may be useful for applications that depend primarily on horizontal positioning. / O PPP (Precise Point Positioning) é um método de posicionamento pelo GNSS (Global Navigation Satellite Systems), baseado no conceito SSR (State Space Representation) o qual pode fornecer soluções de acurácia centimétrica. O PPP em tempo real (RT-PPP) é possível graças à disponibilidade de produtos precisos, para órbitas e relógios, fornecidos pelo IGS (International GNSS Service), bem como por seus centros de análise, como o CNES (Centre National d’Etudes Spatiales). Um dos desafios restantes no RT-PPP é a mitigação dos efeitos atmosféricos (troposfera e ionosfera) nos sinais GNSS. Graças às melhorias recentes nos modelos atmosféricos, o RT-PPP pode ser aprimorado, permitindo tempo de inicialização com acurácia centimétrica, comparável ao atual método NRTK (Network Real-Time Kinematic). Esse desempenho depende da topologia das redes de estações permanentes e das condições atmosféricas. O objetivo principal deste projeto é estudar o RT-PPP e a infraestrutura optimizada em termos de custos e benefícios para realizar o método usando correções atmosféricas. Portanto, são utilizadas diferentes configurações de uma rede GNSS densa e regular existente na França, a rede Orphéon. Esta rede tem cerca de 160 estações, sendo propriedade da Geodata-Diffusion (Hexagon Geosystems). O trabalho foi dividido em duas etapas principais. Inicialmente, foi avaliado o "float PPP-RTK", que corresponde ao RT-PPP com melhorias resultantes de correções de rede, embora mantendo as ambiguidades como float. Em um segundo momento, as correções de rede são aplicadas para aprimorar o "PPP-RTK", onde ambiguidades são fixadas para seus valores inteiros. Para o float PPP-RTK, uma versão modificada do software RTKLib 2.4.3 (beta) é empregada de modo a levar em consideração as correções de rede. Os efeitos ionosféricos de primeira ordem são eliminados pela combinação iono-free e atraso zenital troposférico é estimado. As correções são aplicadas introduzindo parâmetros troposféricos a priori injuncionados. Períodos com diferentes condições troposféricas foram escolhidos para realizar o estudo. Uma modelagem adaptativa baseada em OFCs (Optimal Fitting Coefficients) foi implementada para descrever o comportamento da troposfera, utilizando estimativas de atraso troposférico para estações da rede Orphéon. Tal solução permite a comunicação unidirecional entre o servidor e o usuário. A qualidade das correções troposféricas foi avaliada através de comparação com produtos externos troposféricos. Os ganhos alcançados no tempo de convergência para acurácia de 10 centímetros foram quantificados estatisticamente. A topologia de rede foi avaliada reduzindo o número de estações de referência (em até 75%) usando uma configuração da rede Orphéon esparsa para realizar a modelagem troposférica. Isso não degradou as correções troposféricas e foram obtidas performances similares para os usuários simulados. Na segunda etapa, o PPP-RTK é realizado usando o software PPP-Wizard 1.3, bem como os produtos para tempo real do CNES de órbitas, relógios e biases de fase dos satélites. O RT-IPPP (Real-Time Integer PPP) é realizado com estimativa de atrasos troposféricos e ionosféricos. As correções ionosféricas e troposféricas são introduzidas como parâmetros a priori injuncionados no PPP-RTK do usuário. Para gerar correções ionosféricas, foi implementada uma solução alinhada com as convenções RTCM (Real-Time Maritime Services), em relação à transmissão de correções ionosféricas SSR, o qual é um algoritmo baseado na ponderação pelo inverso da distância (IDW – Inverse Distance Weighting). A escolha dos períodos para este experimento foi realizada principalmente em relação à atividade ionosférica. A comparação das correções atmosféricas com produtos externos, assim como a avaliação de diferentes topologias de rede (densa e esparsa) também foram realizadas nesta etapa. Estatisticamente, o RT-IPPP padrão leva ~ 25 min para alcançar uma acurácia horizontal de 10 cm, a qual é significativamente melhorada pelo método implementado: 46% (convergência em 14 min) com correções de rede densa e 24% (convergência em 19 min) com a rede esparsa. No entanto, o posicionamento vertical vê o seu tempo de convergência ligeiramente aumentado, especialmente quando as correções são usadas a partir de uma solução de rede esparsa. No entanto, as melhorias no posicionamento horizontal com o uso das correções de SSR externas de uma rede (densa ou esparsa) são promissoras e podem ser úteis para aplicações que dependem principalmente do posicionamento horizontal. / Le PPP (Precise Point Positioning) est une méthode de positionnement par GNSS (Global Navigation Satellite Systems), basée sur le concept SSR (State Space Representation), qui peut générer solutions de précision centimétrique. Le PPP en temps réel (RT-PPP) est possible grâce à la disponibilité des produits précis, pour les orbites et horloges, fournis par l’IGS (International GNSS Service), ainsi que par ses centres d'analyse, tels que le CNES (Centre National d'Etudes Spatiales). Un des défis restants sur le RT-PPP est la mitigation des effets atmosphériques (troposphère et ionosphère) sur les signaux GNSS. Grâce aux améliorations récentes des modèles atmosphériques, le RT-PPP peut être amélioré, ce qui permet une précision et un temps d'initialisation au niveau du centimètre, comparables à la méthode NRTK (Network Real-Time Kinematic) actuelle. De telles performances dépendent de la topologie du réseau de stations GNSS permanentes et des conditions atmosphériques. L'objectif principal de ce projet est d'étudier le RT-PPP et l'infrastructure optimisée en termes de coûts et d'avantages pour réaliser la méthode en utilisant des corrections atmosphériques. Pour cela, différentes configurations d'un réseau GNSS dense et régulier existant en France, le réseau Orphéon, sont utilisées. Ce réseau compte environ 160 sites, propriété de Geodata-Diffusion (Hexagon Geosystems). Le travail est divisé en deux étapes principales. Dans un premier temps, le mode «PPP-RTK flottant» a été évalué, il correspond au RT-PPP avec des améliorations issues des corrections de réseau, mais avec les ambiguïtés flottantes. Ensuite, des corrections de réseau sont appliquées pour améliorer le mode « PPP-RTK » où les ambiguïtés sont fixées à leurs valeurs entières. Pour le PPP-RTK flottant, une version modifiée du package RTKLib 2.4.3 (beta) est utilisée pour prendre en compte les corrections réseau. Les effets ionosphériques de premier ordre ont été éliminés par la combinaison iono-free et le retard troposphérique zénithal est estimé. Les corrections ont été appliquées en introduisant des paramètres troposphériques a priori contraints. Des périodes avec différentes conditions troposphériques ont été choisies pour réaliser l'étude. Une modélisation adaptative basée sur les OFCs (Optimal Fitting Coefficients) a été mise en place pour décrire le comportement de la troposphère, en utilisant des estimations des retards troposphériques pour les stations Orphéon. Cette solution permet une communication mono-directionnelle entre le serveur et l'utilisateur. La qualité des corrections troposphériques est évaluée par comparaison avec des produits troposphériques externes. Les gains réalisés sur le temps de convergence pour obtenir un positionnement de 10 centimètres de précision ont été quantifiés statistiquement. La topologie du réseau a été évaluée, en réduisant le nombre de stations de référence (jusqu'à 75%), via une configuration de réseau Orphéon lâche pour effectuer la modélisation troposphérique. Cela n'a pas dégradé les corrections troposphériques et des performances similaires ont été obtenues du côté de l'utilisateur. Dans la deuxième étape, le PPP-RTK est réalisé grâce au logiciel PPP-Wizard 1.3 et avec les produits temps réel CNES pour les orbites, les horloges et les biais de phase des satellites. Le RT-IPPP (Real-Time Integer PPP) est réalisé avec estimation des délais troposphériques et ionosphériques. Les corrections ionosphériques et troposphériques sont introduites en tant que paramètres a priori contraints au PPP-RTK de l'utilisateur. Pour générer des corrections ionosphériques, il a été mis en place une solution alignée avec les conventions RTCM (Real-Time Maritime Services) pour la transmission des paramètres ionosphériques SSR, un algorithme standard d'interpolation à distance inversée (IDW – Inverse Distance Weighting). Le choix des périodes pour cette expérience a été fait principalement en regard de l'activité ionosphérique. La comparaison des corrections atmosphériques avec les produits externes et l'évaluation de différentes topologies de réseau (dense et lâche) ont également été effectuées dans cette étape. Statistiquement le RT-IPPP standard prend ~25 min pour atteindre une précision horizontale de 10 cm, ce que nous améliorons significativement par notre méthode : 46% (convergence en 14 min) avec le réseau dense et 24% (convergence en 19 min) avec le réseau restreint. Néanmoins le positionnement vertical voit son temps de convergence légèrement augmenté, en particulier lorsque l'on utilise des corrections à partir d'une solution de réseau lâche. Cependant, les améliorations apportées au positionnement horizontal dues aux corrections atmosphériques SSR externes provenant d’un réseau (dense ou lâche) sont prometteuses et peuvent être utiles pour les applications qui dépendent principalement du positionnement horizontal. / CNPq: 229828/2013-2

O clima na Antártica tem um papel fundamental no balanço de energia global. Estudos sugerem que a atividade convectiva tropical e a circulação estratosférica exercem um papel importante sobre a circulação atmosférica nos extratrópicos. A temperatura do ar é uma variável sensível às mudanças na circulação, no entanto, ainda não foi investigada a importância da escala intra-sazonal na sua variabilidade sobre a Antártica. Neste trabalho estudou-se a variabilidade intra-sazonal da temperatura do ar a superfície na região da Península Antártica enfocando as interações trópicos-extratrópicos e troposfera-estratosfera na modulação de eventos extremos de temperatura naquela região. Foram utilizados dados diários de estações localizadas nos setores leste e oeste da Península Antártica no período de 1986-2002. A análise espectral dos dados ressaltou a importância da escala intra-sazonal na variabilidade da temperatura na Península Antártica, principalmente no período de inverno, primavera e verão. Baseado nestes resultados, os dados foram filtrados na escala intra-sazonal (banda de 20-100 dias) e posteriormente, obteve-se os extremos intra-sazonais frios e quentes para as três estações do ano, através dos quartis da distribuição dos dados. Os eventos extremos intra-sazonais de temperatura (EIT) foram mais intensos no inverno e mais fracos no verão. As características da circulação atmosférica intra-sazonal associada aos EIT foram obtidas através de composições defasadas das anomalias intra-sazonais da altura geopotencial em 200 hPa, vento zonal em 200 hPa e vento meridional em 850 hPa. Nas três estações do ano, observou-se nos eventos extremos intra-sazonais frios (EIF) a persistência de anomalias ciclônicas em altos níveis, a diminuição da intensidade do jato polar e uma advecção de ar frio em baixos níveis sobre a região de estudo. Uma situação oposta foi verificada nos eventos extremos intra-sazonais quentes (EIQ). De forma geral, observou-se um trem de ondas entre latitudes médias e altas no Hemisfério Sul (HS) durante os EIT, particularmente no inverno e primavera. Esta configuração mostrou-se semelhante a tele-conexão conhecida como Pacífico-Sul Americano (PSA). O papel do modo anular do HS sobre os EIT foi analisado através do cálculo de Funções Ortogonais Empíricas das anomalias intra-sazonais da altura geopotencial em 700 hPa ao sul de 20ºS. Sua estrutura foi mais intensa (mais fraca) nos EIF (EIQ) de inverno sobre a região de estudo. A interação troposfera-estratosfera no controle dos EIT foi investigada através do Fluxo Eliassen-Palm. Nas composições das anomalias intra-sazonais deste fluxo (EPIS), observou-se durante os EIF (EIQ) de inverno, um aumento da atividade de onda da baixa estratosfera (alta troposfera) para a alta troposfera (baixa estratosfera) sobre a região de estudo, associado à diminuição (aumento) da intensidade do jato polar. Na primavera, a atividade de onda foi mais intensa e verificou-se uma mudança na direção do fluxo EPIS quando comparado com os EIT de inverno. O fluxo EPIS e as anomalias intra-sazonais do vento zonal foram mais fracos no verão. As anomalias intra-sazonais da circulação atmosférica e da atividade de onda na troposfera e estratosfera foram observadas por cerca de 10 dias antes da observação dos EIT de inverno. Portanto, a atividade intra-sazonal nos extratrópicos e as interações troposfera-estratosfera são fatores relevantes para um melhor entendimento da variabilidade da temperatura sobre a Península Antártica. / The Antarctic climate plays a significant role for the global energy budget. Previous studies suggest that interactions tropics-extratropics and the dynamics of the stratosphere are important factors to understand climate variations in the extratropics. The air temperature near surface responds to changes in circulation in low and upper levels. However, no previous studies have objectively investigated the importance of intraseasonal variations in modulating temperature around the Antarctica Peninsula. The present study examines intraseasonal extreme anomalies of near surface air temperature in the Antarctica Peninsula, and investigates interactions tropics-extratropics and troposphere-stratosphere. Daily temperature data from stations located east and west of the Antarctica Peninsula during 1986-2002 are investigated. Spectral analyses indicate that intraseasonal anomalies in temperature records are statistically significant during summer, winter and spring in all stations. Based on these results, temperatures are band-filtered on intraseasonal timescales (20-100 days) and extreme anomalies are investigated in each season (spring, summer and winter) based on the quartiles of the distributions. Intraseasonal extreme temperature (IET) anomalies are more intense during winter than during summer. Variations in the atmospheric circulation during IET are investigated by performing composites of intraseasonal anomalies of the geopotential height in 200hPa, zonal wind in 200hPa and meridional wind in 850hPa. During the three seasons, cold IET are associated with persistent upper level cyclonic anomalies, easterly anomalies of the polar jet and cold advection in low levels over the Peninsula. Opposite features are observed during warm IET. An extratropical wave-train is observed during all IET with stronger intensity during winter and spring. This feature resembles the Pacific South American (PSA) teleconnection pattern. The Southern Hemisphere Annular mode during the IET, identified as the first Empirical Orthogonal Function (EOF) of the intraseasonal 700hPa geopotential height anomalies poleward of 20oS, is more intense (weak) during cold (warm) IET events during winter. The stratosphere-troposphere interaction during IET events was examined with composites of the Eliassen-Palm Flux intraseasonal anomalies (EPIS). During spring, the wave activity is more intense and the EPIS direction is opposite to winter. During summer, EPIS are weak. Intraseasonal anomalies in the circulation and the wave activity in the troposphere and stratosphere lead the IET during winter in about 10 days. Therefore, the intraseasonal activity in the extratropics and the interactions stratosphere-troposphere are important factors for a complete understanding of the temperature variability over the Antarctica Peninsula.

La présence des particules d’aérosols dans l’atmosphère influencent le bilan radiatif de notre planète et ainsi son équilibre climatique. Selon les différents mécanismes d’émission et processus de transports atmosphériques, les aérosols peuvent être entrainés dans la troposphère libre et ainsi y résider pendant plusieurs semaines. Les contributions optiques et radiatives des aérosols de troposphère libre par rapport à celles de la colonne atmosphérique sont encore mal évaluées du fait de la difficulté d’accès et du manque de mesures sur de longues périodes. Ces travaux de thèse se sont donc appuyés sur deux sites d’altitude présentant des topographies adéquates pour l’analyse des aérosols de troposphère libre : le site ACTRIS/GAW du puy de Dôme (PUY, 1 465 m, France) et le site ACTRIS/GAW de Chacaltaya (CHC, 5 240 m, Bolivie). Ces deux sites disposent d’un large jeu de données in-situ et de télédétection. Les résultats montrent ainsi l’importance de la prise en compte de la structure verticale de l’atmosphère et de l’effet de l’humidité sur les propriétés des aérosols dans l’analyse des mesures. Pour la première fois à notre connaissance, l’utilisation de ces techniques instrumentales depuis la station de mesures météorologiques la plus haute du monde (Chacaltaya) a permis d’établir les propriétés optiques des aérosols dans cette région largement influencée par la ville de La Paz et par les émissions de la forêt amazonienne. Les résultats montrent que l’influence des feux de forêt amazoniens à la fin de la saison sèche peut accroitre les propriétés optiques de l’aérosol à cette altitude d’un facteur de 3,5 en moyenne et celles de la troposphère libre de 28 à 80%. La station est d’ailleurs régulièrement influencée par les conditions de la troposphère libre (30% du temps en journée et 60% la nuit). Ce manuscrit présente également des méthodes originales pour la détermination des contributions optiques et radiatives des aérosols de troposphère libre avec l’utilisation conjointe des mesures in-situ, photométriques et LIDAR. Les résultats établissent ainsi des contributions optiques de la troposphère libre au-dessus du puy de Dôme variant de 20%en hiver à 80% en été en moyenne. L’utilisation du modèle de transfert radiatif SBDART permet d’évaluer les contributions radiatives correspondantes qui oscillent entre 13 et 40% pour les courtes longueurs d’onde, soit des forçages radiatifs de -1 W.m-2 à -10 W.m-2. Les différentes sources d’aérosols en surface influencent donc fortement la composition de la troposphère libre, qu’il est alors nécessaire de prendre en compte dans le bilan radiatif global de notre planète. / Atmospheric aerosols impact the earth radiative budget and its climate. Depending on their emission mechanisms and atmospheric transport processes, aerosols can be injected into the free tropophere where their lifetime is increased to up to several weeks. Optical and radiative properties of free tropospheric aerosols are still poorly known because of the difficulties to access high altitudes over long periods of time. The present work is based on two high altitude sites measurements: the ACTRIS/GAW station of puy de Dôme (PUY, 1 465 m, France) and the ACTRIS/GAW station of Chacaltaya (CHC, 5 240 m, Bolivia). These two sites are equipped with a unique set of both in-situ and remote sensing measurements. Results first show the importance of taking into account the vertical atmospheric structure and the hygroscopic properties of aerosols when combining in situ and remote sensing measurements. Measurements from the highest atmospheric station in the world (Chacaltaya), provide for the first time to our knowledge, the aerosol optical properties from this region of the world, segregated into mixing layer aerosols and free tropospheric aerosols.The site is both influenced by anthropogenic emissions from the nearby city, La Paz and pristine emissions from the Amazonian forest. From these measurements, we observe that biomass burning emissions can increase column aerosol optical properties by an average factor of 3,5 and the free tropospheric aerosol optical properties between 28 and 80%. The station is regularly influenced by free tropospheric conditions (30% of the time during daytime and 60% during nighttime). This manuscript is also presenting original methods for retrieving the optical and radiative aerosol contributions from the free tropospheric layer to the total atmospheric column using a combination of in-situ, photometric and LIDAR measurements. Results show that free tropospheric contributions above puy de Dôme station vary from 20% during winter to 80% during summer. The use of the radiative transfer model SBDART allows to evaluate the corresponding shortwave radiative contributions of free tropospheric aerosols between 13 and 40% (between -1 and -10 W.m-2). Thus, the different surface aerosol emissions influence significantly the free tropospheric composition which is essential for radiative budget determination.

The objective of this study was to provide an adequate model of the k-factor for scientific radio planning in South Africa for terrestrial propagation. An extensive literature survey played an essential role in the research and provided verification and confirmation for the novelty of the research on historical grounds. The approach of the research was initially structured around theoretical analysis of existing data, which resulted from the work of J. W. Nel. The search for analytical models was extended further to empirical studies of primary data obtained from the South African Weather Service. The methodology of the research was based on software technology, which provided new tools and opportunities to process data effectively and to visualise the results in an innovative manner by a means of digital terrain maps (DTMs) and spreadsheet graphics. MINITAB / Thesis (PhD)--University of Pretoria, 2005. / Electrical, Electronic and Computer Engineering / unrestricted

Orographic Rossby waves are the main mechanism by which the jet streams meander aroundthe Earth and have possibly far-reaching impacts on weather and climate (chapter 1). Hence,they are of particular importance to study and this project should serve as a starting point inwhat to consider when trying to model these waves. For example, we have to account forpressure gradients, Coriolis effect, orography, potential vorticity conservation and also Earth’scurvature at this scale. These are covered in detail in ch. 2 and adapted to the Shallow WaterEquations. In addition, some entry-level numerical techniques for solving these equations arepresented throughout ch. 2.4 and then implemented for the global-scale Shallow WaterEquations with conserved potential vorticity in ch. 3. The model is validated to work for typicalshallow water flows in a bath tub and passes common tests like the Gaussian curve test (ch.4.1). However, when considering atmospheric flows (ch. 4.2) it becomes evident that ourmodel, as well as our numerical methods are lacking and cannot reproduce Rossby waves ina stable manner. Hence, a heavily modified version of Hogan’s model (Hogan, n.d) isemployed with a simplified numerical scheme. With these corrections, orographic Rossbywaves appear to naturally form at appropriate locations. However, they do not fully exhibit theexpected behaviours discussed in ch. 2.2. Even Hogan’s model appears to have severelimitations as waves propagate in the wrong direction. Hence, this study is not complete andwarrants further development in order to be useful. / Orografiska Rossby-vågor är den huvudsakliga mekanismen genom vilken jetströmmarnaslingrar runt jorden och kan ha en omfattande inverkan på väder och klimat (kapitel 1). Därförär de av särskild betydelse att studera och detta projekt bör fungera som en utgångspunkt förvad man måste överväga när man försöker modellera dessa vågor. Till exempel så måste vi tahänsyn till tryckgradienter, Coriolis-effekten, orografi, potentiell vorticitetsbevarande och ävenjordens krökning på denna skala. Dessa beskrivs i detalj i kap. 2 och anpassas tillrörelseekvationerna för grunt vatten (Saint-Venant-ekvationerna). Därefter presenteras någranumeriska tekniker på grundläggande nivå för att lösa dessa ekvationer i kap. 2.4, varvid desedan implementeras för de globala Saint-Venant-ekvationerna med bevarad potentiellvorticitet i kap 3. Modellen är validerad för typiska grunda vattenflöden i ett badkar ochpasserar vanliga numeriska tester så som Gauss-kurvtestet (kap. 4.1) och bore-testet. Mennär vi överväger atmosfäriska flöden (kap. 4.2) blir det tydligt att våra modeller och numeriskametoder är primitiva och inte kan reproducera Rossby-vågor på ett stabilt sätt. Därmed,modifierar vi Hogans modell (Hogan, n.d) för att passa vår modell vilket resulterar orografiskaRossby-vågor. Dock så är dessa förskjutna och stämmer inte riktigt överens med teorin i kap.2.2. Även Hogans modell visar sig ha allvarliga begränsningar då vågorna propagerar i felriktning. Därmed är denna studie ej komplett och kräver ytterligare utveckling för att varaanvändbar.

Tropospheric oxidation modulates pollution chemistry and greenhouse gas lifetimes. The hydroxyl radical (OH) is the primary oxidant and the main sink for methane, the second-most influential anthropogenic contributor to climate change. OH is produced following the photolysis of ozone, an oxidant, respiratory irritant and greenhouse gas. Trends in methane or ozone are frequently attributed to their sources, but sink-driven variability is less often considered. I investigate the influence of fluctuations in turbulent loss to the Earth’s surface, also known as deposition, on tropospheric ozone concentrations and chemistry over the relatively polluted eastern United States. I use idealized sensitivity simulations with the global chemistry-climate model AM3 to demonstrate that coherent shifts in deposition, on the order recently observed at a long-term measurement site, affect surface ozone concentrations as much as decreases in its precursor emissions have over the past decade. I conclude that a sub-regional deposition measurement network is needed to confidently attribute trends in tropospheric ozone. Next, I turn to the remote marine troposphere to evaluate two theoretical proxies for variability in the methane sink, OH, with observations from the NASA Atmospheric Tomography (ATom) aircraft campaign. The low concentration and short lifetime of OH preclude the development of a representative measurement network to track its fluctuations in space and time. This dearth of constraints has led to discrepancies in the methane lifetime across models that project atmospheric composition and climate. Observational and modeling studies suggest that few processes control OH fluctuations in relatively clean air masses, and the short OH lifetime implies that it is at steady-state (total production is equal to loss). I leverage this chemistry by evaluating a convolution of OH drivers, OH production scaled by the lifetime of OH against its sink with carbon monoxide, as a potential “steady-state” proxy. I also assess the predictive skill of formaldehyde (HCHO), an intermediate product of the methane and OH reaction. I find that both proxies broadly reflect OH on sub-hemispheric scales (2 km altitude by 20° zonal bins) relative to existing, well-mixed proxies that capture, at best, hemispheric OH variability. HCHO is produced following methane loss by reaction with OH and reflects the insolation influence on OH, while the steady-state proxy demonstrates a stronger relationship with OH and offers insight into its sensitivity to a wider array of drivers. Few components—water vapor, nitric oxide, and the photolysis rate of ozone to singlet-d atomic oxygen—dominate steady-state proxy variance in most regions of the remote troposphere, with water vapor controlling the largest spatial extent. Current satellite instruments measure water vapor directly, and other retrievals like nitrogen dioxide columns or aerosol optical depth or could be used to infer nitric acid or the rate of ozone photolysis. Thus satellite observations may be used to derive a steady-state proxy product to infer OH variability and sensitivity in the near-term. HCHO is also retrieved from satellite instruments, and an OH product using satellite-observed HCHO columns is already in development. The relatively high fluctuation frequency of HCHO or the steady-state proxy advances our insight into the connection between OH and its drivers. The observed steady-state proxy demonstrates a widespread sensitivity to water vapor along the ATom flight tracks, and I conclude that an improved and consistent representation of the water vapor distribution is a necessary step in constraining the methane lifetime across global chemistry-climate models.

L'objectif général de la thèse est de caractériser la distribution géographique, les cycles saisonniers et l'évolution récente de l'ozone et du monoxyde de carbone dans la haute troposphère - basse stratosphère (UT - LS) au-dessus de huit régions d'intérêt, aux moyennes latitudes de l'hémisphère Nord. Pour cela, nous avons analysé les observations aéroportées IAGOS. Nous avons montré une tendance positive de l'ozone dans l'UT sur 1994 - 2013, et une tendance négative du monoxyde de carbone liée à la décroissance des émissions en surface. Nous avons comparé les mesures à la simulation de composition chimique sur le climat récent issue du modèle MOCAGE dans l'exercice d'intercomparaison CCMI. Pour ce faire, nous avons développé une nouvelle méthode permettant de projeter les mesures IAGOS sur le maillage du modèle et de traiter ainsi 20 ans d'observations. Cette méthode s'est révélée pertinente pour évaluer la simulation et pourrait être étendue à d'autres simulations et d'autres modèles. / The overall objective of the thesis is to characterize the geographical distribution, seasonal cycles and recent trends of ozone and carbon monoxide in the upper troposphere- lower stratosphere (UT-LS) over eight regions of interest, in the northern mid-latitudes. For this purpose, we first analyzed the IAGOS airborne observations. We have shown a positive trend in ozone in the UT over 1994-2013, and a negative trend in carbon monoxide, the latter being linked to the decrease in surface emissions. We then compared the observations to the recent climate chemical composition simulation performed by the MOCAGE model in the CCMI intercomparison exercise. To do this, we have developed a new method to project IAGOS measurements onto the model grid, allowing us to process long observation periods. This method has proven to be relevant for evaluating the simulation and could be extended to other simulations and models.

Rainfall is one of the central features of Earth’s climate. Understanding the physical mechanisms that control it has deep social impacts on water and food security. In this thesis, we use a series of idealized single column models to reveal mechanisms driving steady-state precipitation both in the tropics and in the global mean. These mechanisms yield a deeper understanding of precipitation in model outputs (Chapter 1), observations (Chapter 2), and projections for a warming climate (Chapter 3). Chapter 1 centers around model development. We use the single column model version of NCAR’s Community Earth System Model (CESM) to better understand its simulation of tropical rainfall under various representations of radiation, convection, and circulation. Using a variety of existing methods – the weak temperature gradient (WTG), damped gravity wave (DGW), and spectral weak temperature gradient (SWTG) method – we parameterize the column’s large-scale dynamics and consider the response of steady-state tropical precipitation to changes in relative sea surface temperature (SST). Radiative cooling is either specified or interactive, and the convective parameterization is run using two different values of a parameter that controls the degree of convective inhibition (CIN) required to cap a convective plume. Under all three methods, circulation strength is decreased when greater CIN is required, that is, when convection is allowed to occur more easily. This effect is shown to come from increased static stability in the column’s reference radiative-convective equilibrium profile and results in decreased rainfall over warm SSTs. This argument can be extended to aquaplanet simulations in CESM, which show that the warmest regions in the tropics rain less when greater CIN is required to cap a convective plume. This suggests that the parameter in CESM which controls the degree of convective inhibition significantly affects the strength of the model’s intertropical convergence zone (ITCZ). In Chapter 2, we use a similar set of idealized models to better understand the observed climatology of tropical rainfall. The distribution of climatological rainfall over tropical oceans can be thought of as primarily the result of two mechanisms: conditional instability in the free troposphere and convergence in the boundary layer. We modify the SWTG method to assess the relative influence of these mechanisms. In its original configuration, the SWTG method applies the weak temperature gradient approximation to the full depth of the troposphere without consideration of the stronger horizontal temperature and pressure gradients in the planetary boundary layer (PBL). To account for convergence in the PBL induced by these stronger pressure gradients, we modify the SWTG method to include an externally-specified vertical mass flux at the PBL top. When forced using the climatological SST and 850 hPa vertical velocity taken from observation-based reanalysis data, the Forced SWTG method reproduces most features of the observed annual mean tropical rainfall climatology. Its predictions remain largely unchanged when it is forced by a spatially uniform SST field. Insofar as the boundary layer convergence field can be interpreted as an external forcing on the column, this would indicate that it controls the precipitation field. However, local column stability likely also plays a role in determining PBL convergence, so this method does not fully untangle the causality behind the climatological precipitation field. In Chapter 3, we shift our perspective from column dynamics to column radiative transfer. Global mean rainfall is known to be constrained by the atmosphere's column-integrated radiative cooling. However, the surface temperature dependence of this radiative constraint on mean rainfall, and the mechanisms which set it, are not well understood. We present a simple spectral model for changes in the clear-sky column-integrated radiative cooling with surface warming. We find that surface warming increases column-integrated radiative cooling – and thus mean rainfall – by decreasing atmospheric transmission in spectral regions with significant longwave emission, that is, by closing the water vapor window. Water vapor's spectroscopy implies a hydrological sensitivity whose magnitude is roughly set by surface Planck emission, and which peaks near tropical surface temperatures. We also examine the role of carbon dioxide and shortwave heating, which primarily act to mute the hydrological response to warming. We validate our findings using line-by-line calculations. Overall, we demonstrate that idealized frameworks, such as those provided by single column models, can elucidate mechanisms controlling tropical and global-mean precipitation. However, the relevance of these results to more complex simulations and observations is tempered by the extent to which our simplifying assumptions neglect important physics.