Master of Science / Department of Civil Engineering / Kyle Riding / The durability of partial depth concrete repair is directly related to the bond strength between the repair material and existing concrete. The wait time effects of cementitous grouts, epoxy, acrylic latex, and polyvinyl acetate bonding agents were observed on bond strength. Three rapid repair materials were as a comparison to bond strength, as well as concrete samples with no bonding agents having dry conditions and saturated surface dry moisture condition. The bonding agents and rapid repair materials were tested in a controlled laboratory environment. Bond strength loss with wait times of 0, 2, 5, 10, and 30 minutes were observed when bonding agents were applied. The laboratory samples were loaded using a direct shear test. Field tests were performed using the same repair materials and bonding agents. When the agents were applied in the field the wait times used were 0, 15, 30, and 45 minutes. 7 day and 5 month pull off tensile tests were performed during the field experiment. The data from both experiments show that when using cement grout bonding agents the high bond strength can be obtained when the repair material is applied within 15 minutes of application of the cement grout, and after 15 minutes bond loss can be expected. Wait time didn't have a significant effect on epoxy and acrylic latex bonding agents as long as they were placed before setting. The polyvinyl acetate agent and repair materials can develop high bond strength in laboratory settings, but when used in the field the bond strengths experience loss. When not using bonding agents in a repair, adequate bond strength can be obtained when using saturated surface dry condition.

Structural engineers and architects have a responsibility for incorporating fire safety into their building designs in order to minimize loss of life and property. To meet this requirement, extensive research has been carried out, aimed at obtaining better understanding of the performance of steel and composite structures under fire conditions. Recent research indicates that the robustness of steel connections is vitally important to the fire resistance of steel-framed composite buildings. The development of effective connection models is a key issue in this research field. This PhD research is focused on the development of robust connection elements, for modelling steel connections at elevated temperatures. In this work, a robust simplified two-node connection element has been developed, for modelling the behaviour of the bolted end-plate connections between steel beam and column at elevated temperatures. The proposed numerical procedure is based on the model proposed by Huang (2011), incorporating additional developments to more precisely determine the tension, compression, and bending moment capacities of end-plate connections in fire. The proper failure criteria are proposed to calculate the tension capacity for each individual bolt row. In this new model, the connection failure due to bending, axial tension, compression and shear are considered. The influence of the axial force of the connected beam on the connection is also taken into account. This new model has the advantages of both the simple and component-based models. A total of 22 tests are used to validate the model. From these validations, it is evident that this new connection model has ability to accurately predict the behaviour of the end-plate connection at elevated temperatures, and can be used to represent the end-plate connections in supporting performance-based fire resistance design of steel-framed composite buildings. For modelling the behaviour of partial end-plate connections between steel beams and columns under fire conditions, a simplified robust 2-node connection element has also been developed. The rotational response of a partial end-plate connection at elevated temperatures comprises of two stages. These stages are due to the shift of the compression centre of the connection from the end of end-plate, to the centre of the beam bottom flange at large rotation. The model proposed in this research accounts for these two stage behaviours, representing the partial end-plate iv connection as a 2-node non-linear spring element. Characteristics of the spring, such as stiffness, tension, compression, shear strengths and bending moment resistance, are determined based on a component-based approach. This model therefore retains the advantages of both the simple and component-based models. Compared to normal component-based models, this simplified model has very good numerical stability under static solver condition, and is computationally efficient. Fourteen tests are used to validate the model, showing that the model is capable of accurately predicting the behaviour of partial end-plate connections under fire conditions. A series of numerical studies has been conducted on a 2D steel frame, subjected to ISO834 Fire and Natural Fire, in order to investigate the influences of the connections on the behaviour of steel structures. It is clear that the model can be used to represent the partial end-plate connections in performance-based fire resistance design of steel-framed composite buildings. According to full-scale fire tests, tensile membrane action within the concrete floor slabs plays an important role in affecting the fire resistance of composite buildings. It is well known that the development of tensile membrane actions relies on the vertical support along the edges of the slab panel. However, there is at present a lack of research into how vertical supports influence the tensile membrane actions of the slab. In this thesis, the performance of a generic three dimensional 45m x 45m composite floor subjected to ISO834 Fire and Natural Fire are investigated. Different vertical support conditions and three steel meshes are applied, in order to assess the impact of vertical supports on tensile membrane action of floor slabs. Unlike other existing large scale modelling which assumed that the connections behave as pinned or rigid for simplicity, the two robust 2-node connection element models described above are used to model the semi-rigid behaviour of end-plate and partial end-plate connections within the fire compartment. The impact of connections on the 3D behaviour of composite floors is taken into consideration. The load-transfer mechanisms of a composite floor, when connections fail due to axial tension, vertical shear and bending are investigated. Based on the results obtained, some design recommendations are proposed for enhancing the fire resistance of composite buildings.

As a preliminary starting point for the present study, physical and mechanical properties of polypropylene nanocomposites (PPNCs) for samples received from Queen's University Belfast have been evaluated. Subsequently, polymer/clay nanocomposite material has been produced at Bradford. Mixing and processing routes have been explored, and mechanical properties for the different compounded samples have been studied. Clay intercalation structure has received particular attention to support the ultimate objective of optimising tensile and fracture behaviour of isotropic and die-drawn PPNCs. Solid-state molecular orientation has been introduced to PPNCs by the die-drawing process. Tensile stress-strain measurements with video-extensometry and tensile fracture of double edge-notched tensile specimens have been used to evaluate the Young's modulus at three different strain rates and the total work of fracture toughness at three different notch lengths. The polymer composite was analyzed by differential scanning calorimetry, thermogravimetric analysis, polarizing optical microscopy, wide angle x-ray diffraction, and transmission electron microscopy. 3% and 5% clay systems at various compatibilizer (PPMA) loadings were prepared by three different mixing routes for the isotropic sheets, produced by compression moulding, and tensile bars, produced by injection moulding process. Die-drawn oriented tensile bars were drawn to draw ratio of 2, 3 and 4. The results from the Queen's University Belfast samples showed a decrement in tensile strength at yield. This might be explained by poor bonding, which refers to poor dispersion. Voids that can be supported by intercalated PP/clay phases might be responsible for improvement of elongation at break. The use of PPMA and an intensive mixing regime with a two-step master batch process overcame the compatibility issue and achieved around 40% and 50% increase in modulus for 3% and 5% clay systems respectively. This improvement of the two systems was reduced after drawing to around 15% and 25% compared with drawn PP. The work of fracture is increased either by adding nanoclay or by drawing to low draw ratio, or both. At moderate and high draw ratios, PPNCs may undergo either an increase in the size of microvoids at low clay loading or coalescence of microvoids at high clay loading, eventually leading to an earlier failure than with neat PP. The adoption of PPMA loading using an appropriate mixing route and clay loading can create a balance between the PPMA stiffness effect and the degree of bonding between clay particles and isotropic or oriented polymer molecules. Spherulites size, d-spacing of silicate layers, and nanoparticles distribution of intercalated microtactoids with possible semi-exfoliated particles have been suggested to optimize the final PPNCs property.

Conventional fiber reinforced polymers (FRPs) require polymers such as epoxies that are not biodegradable, which have a significant impact on the environment. The first phase of the thesis aims at replacing conventional polymers with sustainable bio-polymers. The tensile mechanical properties of glass-FRP (GFRP) laminates using two types of organic furfuryl alcohol bio-resins extracted from renewable resources, such as corncobs, were investigated. Results are compared to control specimens fabricated using conventional epoxy resin. It was shown that by careful selection of viscosity of bio-resin, and type and dosage of catalyst, similar mechanical properties to epoxy-GFRP can be achieved. The second and third phases consisted of durability testing of the bio-resin GFRP. A total of 160 tension coupons and 81 unconfined and confined concrete cylinders wrapped with bio-resin-GFRP were studied. Conditioning was achieved by immersion of the specimens in saline solutions with 3% salt concentration, at 23, 40 and 55 degrees Celcius, for up to 300 days. Specimens were compared to epoxy-GFRP specimens aged in the same environment. Deterioration was quantified by tensile testing of the coupons and compression testing of the cylinders at various stages of exposure. The bio-resin-GFRP showed 33% less tensile strength retention than the epoxy-GFRP. The epoxy-GFRP and bio-resin-GFRP wrapped cylinders had the same un-aged confined axial compressive strength (fcc’), essentially a strengthening ratio (fcc’/fc’) of 2.24. After 300 days, the (fcc’/fc’) ratio retentions for the bio-resin-GFRP was 73% at all temperatures. Using the Arrhenius model, it was predicted that 61% retention in tensile strength of the bio-resin-GFRP and 65% retention of the compressive strength of wrapped cylinders would occur after 100 years in an environment with a mean annual temperatures of 10 degrees Celcius. / Thesis (Master, Civil Engineering) -- Queen's University, 2013-08-24 00:02:25.683

This report aims to increase the scientific knowledge about long-term prospects for the adhesive and adhesive joints for bonding of stainless steels. The effects of water, temperature and chemicals on the adhesive and adhesive joints are investigated. Stainless steel plates are pretreated with a primer and isopropanol, there after joined together with single lap modeling. The strength of the joint is tested with a tensile test and additionally a watertightness test is performed to determine if the joints are watertight. For this project three versions of stainless steels is used and two different technologies of two- part adhesives, silicone and silane-modified polymer and one technology of tape, a double coated acrylic foam tape are tested. The result shows that all the adhesives fails cohesively and that tape fails partly adhesively. Result shows that all tests are affected by water, temperature and chemicals on different levels but tape is affected the most with a minimum of 40% loss in shear strength. Watertightness test shows that aged tape joints are not watertight. The polymer shows no signs of decreasing in shear strength and is watertight, but does become more viscous by aging. The report shows that a possible combination of adhesive and pretreatment that can withstand the effects of water, temperature and chemicals is found. The polymer presents a possibility to bond stainless steel with a simple pretreatment. Tape didn’t pass the test in a suitable way but presents opportunities if a sufficient pretreatment can be found.

Due to the findings of extensive damage on geogrids used in a road embankment in northern Sweden, the Swedish Transport Administration (TRV) started to investigate the reason of these damages. Since the geogrids were installed at low temperature, below 0°C, it was suspected that the damages were connected the low temperature. To analyse whether low temperatures have an influence on the extent of installation damages, both a half-scale setup and temperature controlled tensile tests have been carried out on geogrids. In total five different types of geogrids have been tested; 3 extruded polypropylene geogrids, 1 woven PET geogrid, and 1 welded PET geogrid. All geogrids had an aperture size of approximately 35 mm and specified tensile strength of approximately 40 kN/m. The Half-scale tests was conducted by building a small road embankment inside a freeze container, at the Luleå University of Technology (LTU). The embankment contained crushed aggregate, type 0-70 mm, and geogrids. The purpose of the half-scale test was to simulate installation of geogrids at different temperatures and thereby investigate whether low temperatures have an influence on the rate of installation damages. The half-scale test was done for each type of geogrid at the temperatures: +20°C, -20°C and -30°C. First, the geogrid was covered by 150 mm of crushed aggregate. Then a vibratory plate (160 kg) was used to compact the crushed aggregate. After each installation, the crushed aggregate was removed carefully by vacuum suction. The geogrid was removed and then analysed by visual control and tensile tests conducted according to ISO 10319:2008 (wide width tensile test). Results from the half-scale tests indicate that 2 out of 5 of the tested geogrids were affected by the testing procedure. The results indicate that: -        one of the geogrids of polyprophylene (here referred to as G2) was more damaged at lower temperatures compared to installation at +20° C. -        the geogrid of woven PET (here referred to as G5) was less damaged at lower temperatures compared to installation at +20° C. Results for the other geogrids are either inconsistent or shows no significant variation of the measured parameters as function of temperature. Hence, these results cannot be interpreted as damage during installation. Temperature controlled tensile tests were done by tensile testing single strands from the geogrids to failure, inside a temperature controlled chamber. The purpose of these tests was to investigate how the strength properties of the geogrids are affected by low temperature. The test was repeated 5 times for each geogrid and temperature (+20°C, 0°C, -10°C and -20°C). Force and strain was measured during the tests. The results from the temperature controlled tensile tests show that the maximum strain decreases with lower temperature for all tested geogrids. The maximum strain decreased by 16% - 49% when the temperature dropped from +20°C to -20°C. The results show that the tensile strength increases with lower temperature for all tested geogrids except for the welded PET geogrid (here referred to as G1). For G1 the tensile strength decreased by approximately 7% at a temperature drop from +20°C to -20°C. For the woven PET geogrid (G5) and the polypropylene geogrids (G2-G3) the tensile strength increased between 13%-45% at a temperature drop from +20°C to -20°C. The E-modulus increased at lower temperature for all tested geogrids. The secant E-modulus at 2% strain increased by 13%-71% at a temperature drop from +20°C to -20°C. Summarized conclusions from the tests: Strength properties changed for all tested geogrids as the temperature decreased. All tested geogrids got stiffer at lower temperatures. The magnitude of the effects is different for different geogrids. The tensile strength increased with lower temperature for all tested geogrids except for the welded PET geogrid, which got lower tensile strength at lower temperature. The half-scale test indicates that the amount of installation damages at geogrids can be dependent of the temperature at installation. However, these indications can only be seen at two out of five tested geogrids. The effect cannot be connected to a specific step in the installation procedure and cannot be explained by the results from the temperature controlled tensile tests. The results from the half-scale test have a statistically low reliability since only one installation for each temperature and geogrid type was done. The compaction equipment used during the test was small, and had low compaction energy compared to a vibratory roller compactor commonly used in construction work. With respect to the discussion above, further studies should be focusing on developing the half-scale test. It is suggested that the test is scaled up to a full-scale test in order to simulate a real installation as close as possible. The test should also be conducted several times for each geogrid at each temperature in order to enable statistical analyses.

Master of Science / Department of Mechanical and Nuclear Engineering / Gurpreet Singh / 3D-printing is a popular manufacturing technique for making complex parts or small quantity batches. Currently, the applications of 3D-printing are limited by the material properties of the printed material. The processing parameters of commonly available 3D printing processes constrain the materials used to a small set of primarily plastic materials, which have relatively low strength and electrical conductivity. Adding filler materials has the potential to improve these properties and expand the applications of 3D printed material. Carbon nanomaterials show promise as filler materials due to their extremely high conductivity, strength, and surface area. In this work, Graphite, Carbon Nanotubes, and Carbon Black (CB) were mixed with raw Acrylonitrile Butadiene Styrene (ABS) pellets. The resulting mixture was extruded to form a composite filament. Tensile test specimens and electrical conductivity specimens were manufactured by Fused Deposition Method (FDM) 3D-printing using this composite filament as the feedstock material. Weight percentages of filler materials were varied from 0-20 wt% to see the effect of increasing filler loading on the composite materials. Additional tensile test specimens were fabricated and post-processed with heat and microwave irradiation in attempt to improve adhesion between layers of the 3D-printed materials. Electrical Impedance Spectroscopy tests on 15 wt% Multiwalled Carbon Nanotube (MWCNT) composite specimens showed an increase in DC electrical conductivity of over 6 orders of magnitude compared to neat ABS samples. This 15 wt% specimen had DC electrical conductivity of 8.74x10−6 S/cm, indicating semi-conducting behavior. MWCNT specimens with under 5 wt% filler loading and Graphite specimens with under 1 wt% filler loading showed strong insulating behavior similar to neat ABS. Tensile tests showed increases in tensile strength at 5 wt% CB and 0.5 wt% MWCNT. Placing the specimens in the oven at 135 °C for an hour caused increased the stiffness of the composite specimens.

In packaging industries, the demand for usage of Low Density Poly Ethylene foil is of profound interest. In the past, research was carried out on finite and infinite plates with varying crack lengths but having constant crack width. In this thesis, a detailed analysis on crack initiation is carried out on finite plates by varying width of the hole. The hole shapes for stress analysis include circle, ellipse and rectangular notch. Initially, maximum stress is found out using Linear Elastic Fracture Mechanics (LEFM) theory and compared with Finite element method (FEM) results. Secondly using Elastic Plastic Fracture Mechanics theory (EPFM), critical stress and geometric function are evaluated theoretically by Modified Strip Yield Model (MSYM) and numerically by ABAQUS. Finally, a tensile test is conducted to validate the theoretical and numerical results.  By varying the width of the hole, a study on the parameters like critical stress, geometric function is presented. A conclusion is drawn that the effect of hole width should be considered when calculating fracture parameters.

Le Sénégal, pays aride, connait un effet de sécheresse croissant. Le pays est confronté à un problème d’ensablement, de perte de fertilité et de compaction des sols. Des plants d’A. senegal et de P. juliflora en association ou non avec les microorganismes sont étudiés pour savoir en quoi ces espèces peuvent contribuer à la fixation des dunes mouvants et à l’amélioration de la productivité des terres. Des plants inoculés aux champignons mycorhiziens et au Rhizobium sont plantés à Sangalkam, Bandia et Bambey pour être récoltés un an après et analysés. Une autre expérience montée en serre a consisté à faire pousser les mêmes espèces sur le même type de sol à différents niveaux de compaction avec un tiers du lot occupé par les plants inoculés. Les résultats ont montré que le taux de mycorhisation atteint son pic sur sols pauvres en phosphore. L’inoculation a augmenté la production de biomasse tout en réduisant la taille des vaisseaux du bois racinaire. Elle augmente aussi le % de cellulose en fonction du diamètre racinaire et de l’âge. % qui augmente avec la résistance à la traction de la racine, source de meilleur ancrage et de résistance à l’arrachement. Une augmentation du niveau de compaction du sol diminue significativement le taux de mycorhisation et le nombre de nodule des racines. Elle favorise les racines fines au détriment des grosses racines. Ceci affecte positivement l’architecture racinaire au profit d’un meilleur ancrage. Le P. juliflora est mieux pour la lutte contre l’érosion éolienne l’ensablement et la perte de fertilité dans la zone des Niayes. L’A. senegal peut contribuer à l’amélioration de la fertilité tout en adaptant son système racinaire face à la compaction du sol. / An increasing drought effect is known in Senegal, arid country who is confronted to a silting problem, a decline in overall land fertility and soils compaction. Seedling of A. senegal and P. juliflora in association or no with microorganism are studied to know some what these species can contribute to the moving dune fixing and improvement land productivity. Seedling inoculated to mycorrhizas and Rhizobium are planted in Sangalkam, Bandia and Bambey and are harvested one year after for analyzed. Another experience in greenhouse consisted to grow up the same species on the same type of soil with different levels of compaction and a share occupied by inoculated seedlings. Results showed that the rate of mycorhisation reached his peak on soils poor in phosphorus. The inoculation increased the production of biomass while reducing the size of root wood vessels. She also increases it % of cellulose according to root diameter and age. % that increases with the root tensile strength, spring of better anchorage and resistance of extortion. An increase of soil compaction level decreases, meaningfully, the rate of mycorhisation and the number of root nodule. She favored the fine roots to detriment of thick roots. She affects positively root’s morphology in aid of better anchorage. P. juliflora is better for the struggle against the wind erosion the silting and loss of fertility in the Niayes area. A. senegal can contribute to the improvement of fertility while adapting its root system facing soil compaction.

Charles University in Prague Faculty of Pharmacy in Hradec Králové Department of Pharmaceutical Technology Student: Šárka Hávová Supervisor: PharmDr. Jitka Mužíková, Ph.D. Title of diploma thesis: A study of compaction process and properties of tablets with hypromellose and α-lactose monohydrate Thesis studied the co-processed dry binder RetaLac® from the aspect of his compressibility and dissolution of the active ingredient from tablets. RetaLac® contains α-lactose monohydrate and hypromellose in the identical proportion. The same parameters were tested in the corresponding physical mixtures of FlowLac® 100 with various types of hypromellose (Metolose® 100 SR, Metolose® 4000 SR, Metolose® 100 000 SR) and compared with the substance RetaLac® . Compressibility was evaluated by means of the energy profile of compression and tensile strength of tablets. Salicylic acid was used as the model active ingredient. Dissolution testing was performed using the method of the rotating basket.