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Les actions conjointes en faveur d’une meilleure isolation du bâti et de l’expansion des énergies renouvelables dans l’habitat jouent un rôle de premier plan dans la politique de réduction des gaz à effet de serre et la recherche d’une plus grande efficacité énergétique. La présente thèse vise à développer un système de stockage de chaleur par voie thermochimique dédié au chauffage solaire d’une maison individuelle. A cet effet, un matériau de stockage spécifique à été mis au point, à base de zéolithe et de sulfate de magnésium. Le principe, reposant sur un phénomène mixte d’adsorption physique de vapeur d’eau et de réaction chimique d’hydratation, est à caractère inter-saisonnier : en été, la chaleur issue de capteurs solaires thermiques à air est stockée par le matériau, qui se déshydrate selon une réaction endothermique ; en hiver, l’exothermicité de la réaction inverse est exploitée afin de chauffer l’habitat. Après un état de l’art des technologies de stockage thermique, un protocole de préparation de ce matériau composite innovant est établi. Des travaux de caractérisation sont alors entrepris à l’échelle micro et macroscopique. A partir de ces données expérimentales macroscopiques, le système de stockage est dimensionné en fonction des besoins en chaleur pour le chauffage d’une maison individuelle de type Bâtiment Basse Consommation. A l’issue de cette étude, un modèle de réacteur de stockage thermique est élaboré, afin d’interpréter les transferts couplés de matière et de chaleur intervenant dans le lit de matériau et d’optimiser le réacteur de stockage en conséquence. La validité du modèle est ensuite testée et discutée à la lumière des résultats expérimentaux. / The combined efforts promoting an improved insulation and a growth of renewable energies use in buildings play a key role in the road towards greenhouse gas reduction and better energy efficiency. This thesis purpose is to develop a chemicalbased thermal energy storage system devoted to solar space heating of single-family houses. A specific heat storage material has thus been created, made of zeolite and magnesium sulphate. The storage principle, based on a hybrid phenomenon between water vapour physical adsorption and chemical hydration reaction, is seasonal : during the summer, the material stores heat obtained from evacuated tube solar collectors using an endothermic dehydration reaction ; the stored heat is released by rehydration of the material during the winter to produce hot air dedicated to space heating. After a state of the art regarding thermal energy storage technologies, a preparation method is set up. Then, characterization studies of this innovative composite material have been performed, at both micro- and macroscopic scales. Thanks to the macroscopic experimental data, the system size is estimated to meet the space heating energy demand of a low energy single-family house. Afterwards, a thermochemical storage model is developed to understand the coupled heat and mass transfer occurring in the composite sorbent bed, and consequently optimize the reactor design. The model relevancy is finally discussed with respect to experimental results.

Tato diplomová práce se zabývá tématem výměny tepla v zásobníku tepla typu ”packed bed”. Cílem je popsat přenos tepla v zásobníku tepla obsahující kamínky malých průměrů, skrz který proudí horký vzduch. Toto je modelováno v prostředí MATLAB. Na začátku je krátký úvod do problematiky zahrnující ukládání tepla a jeho možné využití. Dále je uveden krátký přehled o základech přenosu tepla, typech přenosu tepla a termofyzikální vlastnosti systému vzduch-kámen. Ve třetí kapitole je představen zásobník tepla typu ”packed bed” a rozličné modely a dané podmínky jsou vysvětleny. Další kapitola se zabývá s numerickými metodami, převážně s metodou konečných diferencí použitou v této práci. Pátá kapitola se zaměřuje na obecnou optimalizaci daného problému přenosu tepla. Populačně založený metaheuristický optimalizační algoritmus zvaný Genetický algoritmus je popsán. Sestavení modelu je ukázáno v šesté kapitole, stejně jako prezentace výsledků získaných z programu MATLAB. V poslední kapitole je pak diskutován závěr a doporučení.

This thesis deals with computer modeling of temperature hysteresis during phase change, namely complete and partial phase change. There is performed a review of methods for modeling temperature hysteresis based on the enthalpy method and the effective heat capacity method. In the case of complete phase change, there are several methods that use the effective heat capacity method, as well as the heat source method, which, on the contrary, is a certain analogy of the enthalpy method. The following are works dealing with modelling of partial phase change, the most interesting of which is due to the validation method of static hysteresis and the method designed by Bony and Citherlet. The second part of this thesis deals with the hysteresis behavior of the material with phase change, which is organic paraffin RT 27. The input data obtained by differential scanning calorimetry was converted to the dependence of the enthalpy on temperature. These curves was represented by piecewise linear function. In the case of partial phase transformations, a modeling method based on the methods proposed by Bonym and Citherlet was designed. An one-dimensional model enabling thermal simulation of the material was implemented in the MATLAB software environment. The results obtained with this simulation are finally compared with a model that does not consider thermal hysteresis.

The need for heating and cooling in buildings constitutes a considerable part of the total energy use in a country and reducing this need is of outmost importance in order to reach national and international goals for reducing energy use and emissions. One important way of reaching these goals is to increase the proportion of renewable energy used for heating and cooling of buildings. Perhaps the largest obstacle with this is the often occurring mismatch between the availability of renewable energy and the need for heating or cooling, hindering this energy to be used directly. This is one of the problems that can be solved by using thermal energy storage (TES) in order to save the heat or cold from when it is available to when it is needed. This thesis is focusing on the combination of TES techniques and buildings to achieve increased energy efficiency for heating and cooling. Various techniques used for TES as well as the combination of TES in buildings have been investigated and summarized through an extensive literature review. A survey of the Swedish building stock was also performed in order to define building types common in Sweden. Within the scope of this thesis, the survey resulted in the selection of three building types, two single family houses and one office building, out of which the two residential buildings were used in a simulation case study of passive TES with increased thermal mass (both sensible and latent). The second case study presented in the thesis is an evaluation of an existing seasonal borehole storage of solar heat for a residential community. In this case, real measurement data was used in the evaluation and in comparisons with earlier evaluations. The literature reviews showed that using TES opens up potential for reduced energy demand and reduced peak heating and cooling loads as well as possibilities for an increased share of renewable energy to cover the energy demand. By using passive storage through increased thermal mass of a building it is also possible to reduce variations in the indoor temperature and especially reduce excess temperatures during warm periods, which could result in avoiding active cooling in a building that would otherwise need it. The analysis of the combination of TES and building types confirmed that TES has a significant potential for increased energy efficiency in buildings but also highlighted the fact that there is still much research required before some of the technologies can become commercially available. In the simulation case study it was concluded that only a small reduction in heating demand is possible with increased thermal mass, but that the time with indoor temperatures above 24 °C can be reduced by up to 20%. The case study of the borehole storage system showed that although the storage system worked as planned, heat losses in the rest of the system as well as some problems with the system operation resulted in a lower solar fraction than projected. The work presented within this thesis has shown that TES is already used successfully for many building applications (e.g. domestic hot water stores and water tanks for storing solar heat) but that there still is much potential in further use of TES. There are, however, barriers such as a need for more research for some storage technologies as well as storage materials, especially phase change material storage and thermochemical storage. / Behovet av värme och kyla i byggnader utgör en betydande del av ett lands totala energianvändning och att reducera detta behov är av yttersta vikt för att nå nationella samt internationella mål för minskad energianvändning och minskade utsläpp. En viktig väg för att nå dessa mål är att öka andelen förnyelsebar energi för kylning och uppvärmning av byggnader. Det kanske största hindret med detta är det faktum att det ofta råder obalans mellan tillgången på förnyelsebar energi och behovet av värme och kyla, vilket gör att denna energi inte kan utnyttjas direkt. Detta är ett av problemen som kan lösas genom att använda termisk energilagring (TES) för att lagra värme eller kyla från när det finns tillgängligt till dess att det behövs. Denna avhandling fokuserar på kombinationen av TES och byggnader för att nå högre energieffektivitet för uppvärmning och kylning. Olika tekniker för energilagring, samt även kombinationen av TES och byggnader, har undersökts och sammanfattats genom en omfattande litteraturstudie. För att kunna identifiera byggnadstyper vanliga i Sverige gjordes även en kartläggning av det svenska byggnadsbeståndet. Inom ramen för denna avhandling resulterade kartläggningen i valet av tre typbyggnader, två småhus samt en kontorsbyggnad, utav vilka de två småhusen användes i en simuleringsfallstudie av passiv TES genom ökad termisk massa (både sensibel och latent). Den andra fallstudien som presenteras i denna avhandling är en utvärdering av ett existerande borrhålslager för säsongslagring av solvärme i ett bostadsområde. I detta fall användes verkliga mätdata i utvärderingen samt i jämförelser med tidigare utvärderingar. Litteraturstudien visade att användningen av TES öppnar upp möjligheter för minskat energibehov och minskade topplaster för värme och kyla samt även möjligheter till en ökad andel förnyelsebar energi för att täcka energibehovet. Genom att använda passiv lagring genom ökad termisk massa i byggnaden är det även möjligt att minska variationer i inomhustemperaturen och speciellt minska övertemperaturer under varma perioder; något som kan leda till att byggnader som normalt behöver aktiv kylning kan klara sig utan sådan. Analysen av kombinationen av TES och byggnadstyper bekräftade att TES har en betydande potential för ökad energieffektivitet i byggnader, men belyste även det faktum att det fortfarande krävs mycket forskning innan vissa av lagringsteknikerna kan bli kommersiellt tillgängliga. I simuleringsfallstudien drogs slutsatsen att en ökad termisk massa endast kan bidra till en liten minskning i värmebehovet, men att tiden med inomhustemperaturer över 24 °C kan minskas med upp till 20 %. Fallstudien av borrhålslagret visade att även om själva lagringssystemet fungerade som planerat så ledde värmeförluster i resten av systemet, samt vissa problem med driften av systemet, till en lägre solfraktion än beräknat. Arbetet inom denna avhandling har visat att TES redan används med framgång i många byggnadsapplikationer (t.ex. varmvattenberedare eller ackumulatortankar för lagring av solvärme) men att det fortfarande finns en stor potential i en utökad användning av TES. Det finns dock hinder såsom behovet av mer forskning för både vissa lagringstekniker samt lagringsmaterial, i synnerhet för lagring med fasändringsmaterial och termokemisk lagring.

Main purpose of this thesis is to explain the issue of waste heat from broader point of view. It´s substantial part therefore deals with various available methods of waste heat utilization and their analysis. Large part of the thesis is devoted to description and usage of heat exchangers, heat pumps and thermal energy storage. The main theme of the thesis is the use of waste heat from industrial laundry room. It also introduces the process of the professional maintenance service along with its specifications and parameters of waste streams from washing machines. Main goal of the practical part of the thesis is to design equipment which could be used to store waste heat from washing machines. This equipment is designed to be used for specific process in NETME Centre laboratory. In conclusion, thesis addresses the propposed equipment from the energetical and economical point of view.

The theoretical part of the diploma thesis deals with introduction to the issue of refrigeration systems with thermal energy storage. Possibilities of thermal energy storage with phase change are introduced. The thermodynamic principle of functioning of the particular refrigeration system type is explained here as well as its coefficient of performance and fundamental components. In addition, several examples of ice-making systems are discussed. In the practical part the design of a particular refrigeration system is calculated. The main part of the design is the cold evaporator with direct evaporation and the possibility of ice production and its usage for thermal energy storage. The calculation of the overall two-phase heat transfer is carried out.

Cette thèse a été réalisée initialement dans le cadre du projet Stockage Thermique Appliqué à l’extension de Production d’énergie Solaire thermodynamique (STARS) soutenu par l'Agence De l'Environnement et de la Maîtrise de l'Energie (ADEME).L’objectif du projet est de développer une solution de stockage thermique adaptée à la technologie Fresnel à génération directe de vapeur avec une zone de stockage de chaleur latente. Dans une unité de stockage latent, le nitrate de sodium (NaNO3) a été choisi comme matériau à changement de phase (MCP) et l’acier faiblement allié a été envisagé comme matériau de structure du conteneur et de l’échangeur thermique. La contribution de la thèse se positionne au niveau de l’étude de la corrosion et de la durabilité des matériaux de structure (conteneur et échangeur) en contact avec le MCP. L’objectif est de déterminer une loi de vitesse de corrosion qui permettrait de dimensionner les parois de l’échangeur et de développer des protocoles utilisant les techniques électrochimiques afin de suivre in-situ l’état de la corrosion au sein de l’unité de stockage. Les travaux présentés dans ce manuscrit portent sur l’étude expérimentale de la corrosion de l’acier dans le nitrate de sodium fondu à 340°C en fonction des paramètres expérimentaux tels que la présence d’impuretés (oxydes, chlorures), l’atmosphère gazeuse et le cyclage thermique. L’étude par mesures gravimétriques met en évidence la formation d’une couche de corrosion protectrice en surface de l’acier et la production de nitrite de sodium (NaNO2) par la réaction de corrosion. Cette couche constituée principalement de Fe2O3 (insoluble dans NaNO3 fondu) a été caractérisée par différentes méthodes d’analyse de surface (DRX, XPS). L’évolution de l’épaisseur de la couche de corrosion obtenue par cette technique montre une cinétique de corrosion logarithmique dans NaNO3 pur et une cinétique linéaire en présence d’une teneur importante en impuretés chlorures (10 mol%). L’étude électrochimique a apporté des indications sur le comportement du fer (et de l’acier) dans NaNO3 fondu. En combinant ces données avec les observations expérimentales issues des essais de corrosion nous avons pu proposer un mécanisme réactionnel pour la corrosion de l’acier en milieu nitrate fondu. L’étude par spectroscopie d’impédance électrochimique a permis de valider le mécanisme réactionnel proposé. A l’aide de ce mécanisme, les paramètres cinétiques puis la valeur du courant de corrosion ont été déduits par simulation des diagrammes d’impédance. L’analyse de la variation du courant de corrosion en fonction du temps permet de calculer l’épaisseur de la couche de corrosion et de la comparer à celle obtenue par gravimétrie. Un bon accord entre les valeurs obtenues par différentes techniques a été observé.Au cours de ce travail, nous avons également montré la possibilité d’utiliser les techniques électrochimiques pour l’instrumentalisation des installations industrielles afin de suivre in-situ l’évolution de la composition du MCP et l’état d’avancement de la corrosion de l’acier.Enfin, ce travail a montré que l’acier faiblement allié est adapté pour être utilisé dans une unité de stockage latent avec le nitrate de sodium comme matériau à changement de phase. / This thesis was originally performed as part of the STARS project (Stockage Thermique Appliqué à l’extension de Production d’énergie Solaire thermodynamique) which was supported by ADEME (l'Agence De l'Environnement et de la Maîtrise de l'Energie). The objective is to develop a thermal storage system using latent heat from a phase change material (PCM) in order to match with Fresnel technology using direct steam generation. Sodium nitrate (NaNO3) has been selected as PCM and low-alloy steel has been considered as candidate material to build the container and the heat exchanger of a latent heat storage system. The contribution of this thesis is to provide better understanding of the corrosion of the candidate material in contact with the PCM. This thesis aims to determine a corrosion rate law which helps design the thickness of the heat exchanger’s wall and to develop protocols using electrochemical technics to follow in-situ corrosion process in the latent heat storage system. The work presented in this manuscript focuses on experimental study of corrosion of low-alloy steel in molten NaNO3 (340°C) in function of different parameters: presence of impurities (oxides, chlorides), atmosphere and thermal cycling. Gravimetric measurements reveal the formation of a protective corrosion layer on the steel’s surface and the production of sodium nitrite (NaNO2) by corrosion reaction. The corrosion layer consisting mainly of Fe2O3 (insoluble in molten NaNO3) was characterized by surface analytical methods (XRD, XPS). Variation of the thickness of corrosion layer obtained by gravimetric methods shows logarithmic kinetics in pure NaNO3 and linear kinetics in the presence of 10mol% of impurity chlorides. Electrochemical study has provided indications on the iron (and steel) behavior in molten NaNO3. By combining results of this study with experimental observations from gravimetric study, we were able to propose a corrosion mechanism of the steel in molten NaNO3. This mechanism was then validated by electrochemical impedance spectroscopy study. Kinetics parameters and value of corrosion current were deduced by the simulation of impedance diagrams using the proposed mechanism. The thickness of corrosion layer was calculated by analyzing the variation of the corrosion current with time. These values present a good agreement with values obtained by gravimetric study.In this work, we also show the possibility of using electrochemical measurements at industrial scale to follow in-situ the evolution of the PCM's composition and the corrosion state. Finally, this work has shown that low-alloy steel is suitable for using in a latent heat storage system with NaNO3 as phase change material.

Worldwide there is an increasing demand of natural resources. In future, non renewable resources get substituted by renewable resources in the energetic sector as well as in the material sector. That implies a stronger usage of renewable resources especially - wood. In 2009 there was a usage of 77 million cubic meters of wood for material applications and a quantity of 55 million cubic meters for energetic applications in Germany alone. Furthermore, there is an increasing demand on wood for energetic purposes. In 2007 this problematic development led to the first supply bottlenecks. To meet the increasing demands of the future, Short Rotation Coppices (SRC) can help to improve the wood provision. An SRC is a planting of fast growing coppice on agricultural areas, which is managed more intensively than usual forestry practices for a quicker production of wooden biomass. With a comparative LCA of conventional wood and wood from SRC the present study evaluates if wood from SRC is reasonable to cover the increasing demand of wood for material and energetic purposes in an environmental friendly way. A comprehensive literature research regarding LCAs of wood and wooden products shows that there are no previous studies comparing the two types of wood. Hence, the present study examines a particleboard production as the material scenario and the combustion of woodchips in a firing system as the energetic scenario to compare the ecological advantages and disadvantages of wood from SRC and conventional wood. The LCA is implemented with the Gabi software designed by PE International. Data is obtained from previous LCA studies evaluating the production of wood, the particleboard production and the combustion of wood. Additionally, data from the Ecoinvent database is used. Functional units are the production of 1m3 particleboard and the production of 1 MJ of thermal energy. The LCIA is implemented with the “Ecoindicator” as endpoint- and “CML 2001” as midpoint approach to cover broad range of environmental issues. Moreover a sensitivity analyses shows the impact of decisive variables on the results of “Ecoindicator” and “CML 2001”. Results reveal that outcomes of the LCIA are dependent of the assessment method and the processed part of trees from conventional forestry. The present study shows, that with an efficient land use, wood from SRC can help to cover the increasing demand of wood for material and energetic purposes in a sustainable way. However, an immediate usage of wood for energetic purposes has to be seen critical. Instead, a cascaded and sustainable utilization of wood is recommendable to counteract climate change and to improve the efficient use of the renew-able resource - “wood”.

Detta examensarbete utreder lönsamheten i en systemlösning för termiskt akviferenergilager tillsammans med ny VVS-teknisk lösning i fastigheterna kv Hästskon 9 och 12 vid en föreslagen framtida helrenovering. Dessutom utreds förutsättningar för miljöklassning i energi- och miljöcertifieringssystemet Miljöbyggnad avseende energianvändning, dagsljuskomfort, solvärmelast och termisk komfort för om- och tillbyggnadsförslaget med målsättning på nivå GULD. Genom att utnyttja akviferen under fastigheterna kvarteret Hästskon 9 och 12 idag kan man åstadkomma mycket låg energianvändning med en säsongsenergiverkningsgrad via kylmaskiner för värme- och kylaförsörjning på 5,6. En LCC-kalkyl visar att det finns en energikostnadsbesparing för fastighetsägaren Vasakronan omkring 3,65 MSEK per år jämfört med dagens situation om den beskrivna akviferlösningen används. Det ger en återbetalningstid om cirka 4,5 år på investeringen som måste göras. Energiklassning i Miljöbyggnadssystemet för befintliga fastigheter är troligtvis möjlig utan andra åtgärder än akviferlagersystemet, men då med BRONS eller möjligtvis SILVER nivå. Vid ett framtida om- och tillbyggnadsförslag får fastighetsägaren cirka 13 000 m² ytterligare uthyrbar lokalyta för handelslokaler och kontor. Trots detta kan energianvändningen minska ännu mer tack vare en säsongsenergiverkningsgrad via kylmaskiner för värme- och kylaförsörjning på 7,0 då SEB:s datakylanläggning kvarstår med värmeåtervinning på fastigheternas värmesystem, värme- och kylsystem byggs om för låg värmebärartemperatur och hög köldbärartemperatur, luftbehandlingssystem optimeras för låg fläktelenergi och hög värmeåtervinningsgrad, glaslösningar väljs med hänsyn till begränsad solinstrålning och byggnadens klimatskärm tilläggsisoleras i viss omfattning. Energikostnadsbesparingen ökar då ytterligare framåt 4,8 MSEK per år jämfört med dagens situation. Även om SEB:s datakylanläggning faller bort vid en ombyggnad finns ändå möjligheten att självständigt försörja fastigheten med egenproducerad värme via ytterligare en värmepump, vilket avlägsnar beroendet av SEB IT:s datahall för värmeproduktion och ändå ger en energikostnadsbesparing på 4,25 MSEK per år jämfört med dagens situation. Vid en sådan lösning blir den specifika energianvändningen enligt BBR 2012:s definition endast cirka 30 kWh/m² Atemp, år. Denna siffra är mycket lägre än nybyggnadskraven i BBR 2012 och i klass med nyproducerade byggnader med borrhålsenergilager. Utifrån analysen av Miljöbyggnadssystemets indikatorer för energianvändning, solvärmelast, dagsljuskomfort och termisk komfort bedöms det möjligt att klassa kvarteret Hästskon 12 och 9 vid om- och tillbyggnad i klass GULD med vissa förändringar av om- och tillbyggnadsförslaget. För att uppnå klass GULD med hänsyn till dagsljuskomfort och solvärmelast krävs särskild anpassning av glasning på S-huset, M-husets fasad mot Malmskillnadsgatan, samt en stor ljusgård i H-huset för att släppa in tillräckligt mycket dagsljus samtidigt som man åstadkommer effektiv solavskärmning. / This thesis investigates the viability of a system solution for aquifer thermal energy storage along with new HVAC technical solutions in real estates Hästskon 9 and 12 at a proposed future renovation. It also explores opportunities for certification in the Swedish energy and environmental certification system Miljöbyggnad (Environmental Building) regarding energy consumption, daylight comfort, solar heat load and thermal comfort for the renovation and extension proposal of Hästskon 12 with the goal of the GOLD level. By exploiting the aquifer in the properties Hästskon 9 and 12 today, very low energy consumption is achievable with seasonal energy efficiency via chillers for heating and cooling supply of 5.6. The LCC analysis shows that there are energy cost savings for property owner Vasakronan of about 3.65 million SEK per year compared to the current situation, if the described aquifer thermal energy storage solution is used. This gives a payback time of approximately 4.5 years in the investment to be made. Certification in the Miljöbyggnad system for existing buildings is probably possible with the aquifer thermal energy storage, but with BRONZE or possibly SILVER level. In the future refurbishment and extension proposal, the property owner adds about 13 000 m² of additional rentable commercial premises and offices. Nevertheless, the energy use of the properties decreases further owing to a seasonal energy efficiency via chillers for heating and cooling supply of 7.0 when the data centre refrigeration equipment for tenant SEB persists with heat recovery on the properties' heating systems, heating and cooling systems are adapted for low heat carrier temperature and high brine water temperature, ventilation systems are designed for low fan electricity demand and high heat recovery rate, glass solutions chosen are based on limited solar radiation and the building envelope is additionally insulated to some extent. Energy cost savings are furthered to 4.8 million SEK per year compared to the current situation. Even if the data centre refrigeration equipment for tenant SEB is closed down in a future refurbishment scenario, there is possibility to independently supply the property with its own heat produced by an additional heat pump, which removes the dependence of tenant SEB's data centre for heat supply and yet provides an energy saving of 4.25 million SEK per year compared the current situation. Such a solution will result in specific energy with the BBR 2012 (Swedish building regulations) definition of only about 30 kWh / m² Atemp, year. This figure is much lower than new construction requirements of BBR 2012 and on par with virgin buildings with borehole energy storage system. Based on the analysis of the Miljöbyggnad system indicators for energy, solar thermal load, daylight comfort and thermal comfort it is possible to certify Hästskon 12 and 9 in a future refurbishment and extension at GOLD level with some changes in the refurbishment proposal. In order to achieve GOLD level with respect to daylight comfort and solar heat load, special adaptation of the glazing on the S building, M building's facade facing Malmskillnadsgatan, and a large atrium in the H-building is required to let in enough natural light while still providing effective solar shading.