In situ planetary effective thermal conductivity measurements are typically made using a long needle-like probe, which measures effective thermal conductivity in the probe‟s radial (horizontal) direction. The desired effective vertical thermal conductivity for heat flow calculations is assumed to be the same as the measured effective horizontal thermal conductivity. However, it is known that effective thermal conductivity increases with increasing compressive pressure on granular beds and horizontal stress in a granular bed under gravity is related to the vertical stress through Jaky‟s at-rest earth pressure coefficient. No research has been performed previously on determining the anisotropic effective thermal conductivity of dry granular beds under compressive uniaxial pressure. The objectives of this study were to examine the validity of the isotropic property assumption and to develop a fundamental understanding of the effective thermal conductivity of a dry, noncohesive granular bed under uniaxial compression. Two experiments were developed to simultaneously measure the effective vertical and horizontal thermal conductivities of particle beds. One measured effective thermal conductivities in an atmosphere of air. The second measured effective thermal conductivities in a vacuum environment. Measurements were made as compressive vertical pressure was increased to show the relationship between increasing pressure and effective vertical and horizontal thermal conductivity. The results of this experiment show quantitatively the conductivity anisotropy for different materials. Based on the effective thermal conductivity models in the literature and results of the two experiments, a simple model was derived to predict the increase in effective vertical and horizontal thermal conductivity with increasing compressive vertical applied pressure of a granular bed immersed in a static fluid. In order to gain a greater understanding of the anisotropic phenomenon, finite element simulations were performed for a vacuum environment. Based on the results of the finite element simulations, the simple derived model was modified to better approximate a vacuum environment. The experimental results from the two experiments performed in this study were used to validate both the initial simple model and the modified model. The experimental results also showed the effects of mechanical properties and size on the anisotropic effective thermal conductivity of granular beds. This study showed for the first time that compressive pressure-dependent effective thermal conductivity of granular beds is an anisotropic property. Conduction through the fluid has been shown to have the largest contribution to the effective thermal conductivity of a granular bed immersed in a static fluid. Thermal contact resistance has been shown to have the largest influence on anisotropic effective thermal conductivity of a granular bed in a vacuum environment. Finally, a discussion of future work has been included.

Due to the multi-tasking and miniaturization of electronic devices, faster heat transfer is required from the device to avoid the thermal failure. Die-attached polymer adhesives are used to bond the chips in electronic packaging. These adhesives have to hold strong mechanical, thermal, dielectric, and moisture resistant properties. As polymers are insulators, heat conductive particles are inserted in it to enhance the thermal flow with an attention that there would be no electrical conductivity as well as no reduction in dielectric strength. This thesis focuses on the characterization of polymer nanocomposites for thermal and electrical properties with experimental and computational tools. Platelet geometry of hexagonal boron nitride offers highly anisotropic properties. Therefore, their alignment and degree of orientation offers tunable properties in polymer nanocomposites for thermal, electrical, and mechanical properties. This thesis intends to model the anisotropic behavior of thermal and dielectric properties using finite element and molecular dynamics simulations as well as experimental validation.

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第18096号 / 理博第3974号 / 新制||理||1573(附属図書館) / 30954 / 京都大学大学院理学研究科化学専攻 / (主査)准教授 中西 和樹, 教授 北川 宏, 教授 竹腰 清乃理 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

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Ash deposits in commercial coal-fired boilers frequently pose serious maintenance challenges and decrease thermal efficiency. A better understanding of fundamental thermal transport properties in ash deposits can help mitigate their negative effects. In order to characterize the thermal properties of boiler-side deposits, this work presents a thermal transport model and in-situ measurements of effective thermal conductivity in coal ash deposits. A simple model of the thermal transport through an ash deposit, with and with out slagging, was developed. The model approximates the deposit by dividing it into four regimes: particulate, sintered, solidified slag, and molten slag. The development of this model was auxiliary to the primary focus of this study: the in-situ measurement of effective thermal conductivity of ash deposits. Deposits of loosely-bound particulate ash were obtained experimentally using a down-fired drop tube reactor. Pulverized coal was fired and deposits were collected on an instrumented deposition probe. An approach is presented for making in-situ measurements of the temperature difference across the ash deposits, the thickness of the deposits, and the total heat transfer rate through the ash deposits. Using this approach, the effective thermal conductivity was determined for coal ash deposits formed under oxidizing and reducing conditions. Three coals were tested under oxidizing conditions: IL #6 Crown III coal, IL #6 Patiki coal and WY Corederro coal. The WY coal exhibited the lowest range of effective thermal conductivities (ke =0.05 to 0.175 W/mּK) while the IL #6 coals showed higher effective thermal conductivities (ke =0.2 to 0.5 W/mּK). The IL #6 Crown III coal and the WY Corederro coal were also tested under reducing conditions. A comparison of the ash deposits from these two coals, formed under oxidizing or reducing conditions, showed larger effective thermal conductivities in deposits formed under reducing conditions. The IL #6 Crown III coal exhibited the greatest increase (as high as 50%) in ke, under reducing conditions, over that measured in oxidizing conditions. For all of the experiments conducted, an increase in effective thermal conductivity with deposit thickness was observed, with sintering likely causing the increase in ke.