Hot microelectrodes are very small electrodes (usually 1 100 µm in diameter), which have a surface temperature much higher than the temperature in the bulk solution. In this work, the heating is achieved by applying an alternating potential of very high frequency (100 MHz 2 GHz) and of high amplitude (up to 2.8 Vrms) to the microelectrode. As a result, very fast (on the order of milliseconds) changes in the temperature of the electrolyte solution surrounding the electrode can be achieved. Due to the size of the heated microelectrodes, the hot zone in solution is small. Therefore, the solution can be easily overheated and temperatures above the boiling point can be reached.<p> The purpose of this research was to investigate and understand the phenomena occurring at ac polarized microelectrodes and to propose new applications of these electrodes. Using both steady-state and fast-scan (10 V/s) cyclic voltammetry measurements, mass transport of redox species has been studied at ac heated microelectrodes. It has been established that the convection at hot-disk microelectrodes is driven primarily by the electrothermal flow of an electrolyte solution. In addition, other effects such as ac dielectrophoresis and Soret (nonisothermal) diffusion are also observed. Numerical simulations have been employed to predict the distribution of temperature in the hot zone, the direction and magnitude of the electrothermal force and the solution flow rate, as well as the voltammetric response of hot-disk microelectrodes. The results of the simulations agree well with the experimental observations. Theoretical findings of this PhD work are very important for the understanding of the fundamentals of high temperature electrochemistry, particularly mass transport. The proposed explanation of the convection mechanism is most likely applicable not only to ac polarized microelectrodes, but also to the microwave heated microelectrodes, since the only difference between these two heating methods is in the way of delivering electrical energy (wired vs. wireless). The results of the studies of Soret diffusion indicate that it contributes significantly to mass transfer of redox species at hot microelectrodes. Taking into account that the magnitude of the Soret effect has been considered negligible by other electrochemists, the results obtained in this work prove the opposite and show that Soret diffusion affects both the faradaic current and the half-wave potential of the redox reaction. Therefore, the Soret effect can not be ignored if working with hot microelectrodes.<p> Hot microelectrodes can have a number of interesting applications. The results of the initial investigations indicate that these electrodes can be successfully used in the arrangement for Scanning Electrochemical Microscopy (such a novel technique is termed Hot-Tip SECM). In addition, the observed dielectrophoretic and electrothermal convection effects can enhance the performance of the electrochemical sensors based on hot microelectrodes. This can lead to the improvement of the detection limits of many biologically important analytes, such as proteins, bacteria and viruses.

Due to a lack of fundamental knowledge about the role of molecular structures in molecular electronic devices, this research is focused on the development of instruments to understand the relation between device design and the electronic properties of electroactive components. The overall goal is to apply this insight to obtain a more efficient and reliable scheme and greater functional control over each component. This work developed a fabrication method for porphyrinoids on graphene-based field effect transistors (FETs), and a chemical sensing platform under an ambient environment by integrating a tip-enhanced Raman spectroscope (TERS), atomic force microscope (AFM), and electronic testing circuit. The study is divided into three aspects. The first is aimed at demonstrating fabrication processes of nanoscale FETs of graphene and porphyrinoid composites based entirely on scanning probe lithography (SPL). A nanoshaving mechanism was used to define patterns on octadecanethiol self-assembled monolayers on gold film evaporated on graphene flakes, followed by metal wet etching and/or oxygen plasma etching to develop patterns on Au films and graphene, respectively. The integrity and optoelectronic properties were examined to validate the processes. The second area of study focused on the development of the chemical sensing platform, enabling chemical changes to be monitored during charge transports under an ambient environment. The localized Raman enhancement was induced by exciting surface plasmon resonance in nanoscale silver enhancing probes made by thermal silver evaporation on sharp AFM tips. As the system was designed along an off-axis illumination/collection scheme, it was demonstrated that it was capable of observing molecular decomposition on opaque and conductive substrates induced by an electric bias. The third line of work proposed a novel TERS system and a probe preparation method. Silver nanowires mounted on AFM tips were used to locally enhance the Raman scattering. The observed Raman enhancement allows quick chemical analysis from a nanoscale region, and thus enables chemical mapping beyond the diffraction limit. Compared with other TERS geometries, the new optical design not only allows analysis on large or opaque samples, but also simplifies the design of the optical components and the alignment processes of the setup.

Hot microelectrodes are very small electrodes (usually 1 100 µm in diameter), which have a surface temperature much higher than the temperature in the bulk solution. In this work, the heating is achieved by applying an alternating potential of very high frequency (100 MHz 2 GHz) and of high amplitude (up to 2.8 Vrms) to the microelectrode. As a result, very fast (on the order of milliseconds) changes in the temperature of the electrolyte solution surrounding the electrode can be achieved. Due to the size of the heated microelectrodes, the hot zone in solution is small. Therefore, the solution can be easily overheated and temperatures above the boiling point can be reached.<p> The purpose of this research was to investigate and understand the phenomena occurring at ac polarized microelectrodes and to propose new applications of these electrodes. Using both steady-state and fast-scan (10 V/s) cyclic voltammetry measurements, mass transport of redox species has been studied at ac heated microelectrodes. It has been established that the convection at hot-disk microelectrodes is driven primarily by the electrothermal flow of an electrolyte solution. In addition, other effects such as ac dielectrophoresis and Soret (nonisothermal) diffusion are also observed. Numerical simulations have been employed to predict the distribution of temperature in the hot zone, the direction and magnitude of the electrothermal force and the solution flow rate, as well as the voltammetric response of hot-disk microelectrodes. The results of the simulations agree well with the experimental observations. Theoretical findings of this PhD work are very important for the understanding of the fundamentals of high temperature electrochemistry, particularly mass transport. The proposed explanation of the convection mechanism is most likely applicable not only to ac polarized microelectrodes, but also to the microwave heated microelectrodes, since the only difference between these two heating methods is in the way of delivering electrical energy (wired vs. wireless). The results of the studies of Soret diffusion indicate that it contributes significantly to mass transfer of redox species at hot microelectrodes. Taking into account that the magnitude of the Soret effect has been considered negligible by other electrochemists, the results obtained in this work prove the opposite and show that Soret diffusion affects both the faradaic current and the half-wave potential of the redox reaction. Therefore, the Soret effect can not be ignored if working with hot microelectrodes.<p> Hot microelectrodes can have a number of interesting applications. The results of the initial investigations indicate that these electrodes can be successfully used in the arrangement for Scanning Electrochemical Microscopy (such a novel technique is termed Hot-Tip SECM). In addition, the observed dielectrophoretic and electrothermal convection effects can enhance the performance of the electrochemical sensors based on hot microelectrodes. This can lead to the improvement of the detection limits of many biologically important analytes, such as proteins, bacteria and viruses.

The deformation between interface, adhesion mechanism and the transparency of multi-layer flexible electronics composite were discussed. First, ITO (Indium Tin Oxide), Al (Aluminum) and ZnO (Zinc Oxide) were sputtered on a PET (Poly Ethylene Terephthalate) substrate by PVD (Physical Vapor Deposition) sequentially, to form ZnO/ITO/PET and ZnO/Al/PET which is the essential multi-layer structure in the transducer of flexible electronics. ITO/PET structure was widely applied to the touch panel. PET substrate possesses a good optical penetrability, low thermal expansion coefficient and lower price. However, the heat-resisting and chemical stability are poor. In this study, we explore the feasibility of the PDMS (Polydimethylsiloxane) substrate. It not only possesses good optical penetrability, but also exhibits higher PH selectivity than PET. In the analysis, the periodic external force was pressed on the flexible composite films to realize the difference between before and after experiment. Then the composite films were examined by nanoindentation and nanoscratch system (Berkovich and Conical probe with the radius of curvature of 20nm and 10um), four-point probe and spectrometer to measure the mechanical, electrical and optical properties, respectively. To investigate the effect of external force on these composite films, the interaction of films was discussed through external force testing by nanoscratch test.

Energy use index (EUI) is an important measure of energy use which normalizes energy use by dividing by building area. Energy use indices and associated coefficients of variation are computed for major industry categories for electricity and natural gas use in small and medium-sized plants in the U.S. The data is very scattered with the coefficients of variation (CoV) often exceeding the average EUI for an energy type. The combined CoV from all of the industries considered, which accounts for 8,200 plants from all areas of the continental U.S., is 290%. This paper discusses EUIs and their variations based on electricity and natural gas consumption. Data from milder climates appears more scattered than that from colder climates. For example, the ratio of the average of coefficient of variations for all industry types in warm versus cold regions of the U.S. varies from 1.1 to 1.7 depending on the energy sources considered. The large data scatter indicates that predictions of energy use obtained by multiplying standard EUI data by plant area may be inaccurate and are less accurate in warmer than colder climates (warmer and colder are determined by annual average temperature weather data). Data scatter may have several explanations, including climate, plant area accounting, the influence of low cost energy and low cost buildings used in the south of the U.S. This analysis uses electricity and natural gas energy consumption and area data of manufacturing plants available in the U.S. Department of Energy’s national Industrial Assessment Center (IAC) database. The data there come from Industrial Assessment Centers which employ university engineering students, faculty and staff to perform energy assessments for small to medium-sized manufacturing plants. The nation-wide IAC program is sponsored by the U.S. Department of Energy. A collection of six general energy saving recommendations were also written with Texas manufacturing plants in mind. These are meant to provide an easily accessible starting point for facilities that wish to reduce costs and energy consumption, and are based on common recommendations from the Texas A&M University IAC program.

Modern gas turbine engines require higher turbine-entry gas temperature to improve their thermal efficiency and thereby their performance. A major accompanying concern is the heat-up of the turbine components which are already subject to high thermal and mechanical stresses. This heat-up can be reduced by: (i) applying thermal barrier coating (TBC) on the surface, and (ii) providing coolant to the surface by injecting secondary air discharged from the compressor. However, as the bleeding off of compressor discharge air exacts a penalty on engine performance, the cooling functions must be accomplished with the smallest possible secondary air injection. This necessitates a detailed and systematic study of the various flow and geometrical parameters that may have a bearing on the cooling pattern. In the present study, experiments were performed in three regions of a non-rotating gas turbine blade cascade: blade platform, blade span, and blade tip. The blade platform and blade span studies were carried out on a high pressure turbine rotor blade cascade in medium flow conditions. Film-cooling effectiveness or degree of cooling was assessed in terms of cooling hole geometry, blowing ratio, freestream turbulence, coolant-to-mainstream density ratio, purge flow rate, upstream vortex for blade platform cooling and blowing ratio, and upstream vortex for blade span cooling. The blade tip study was performed in a blow-down flow loop in a transonic flow environment. The degree of cooling was assessed in terms of blowing ratio and tip clearance. Limited heat transfer coefficient measurements were also carried out. Mainstream pressure loss was also measured for blade platform and blade tip film-cooling with the help of pitot-static probes. The pressure sensitive paint (PSP) and temperature sensitive paint (TSP) techniques were used for measuring film-cooling effectiveness whereas for heat transfer coefficient measurement, temperature sensitive paint (TSP) technique was employed. Results indicated that the blade platform cooling requires a combination of upstream purge flow and downstream discrete film-cooling holes to cool the entire platform. The shaped cooling holes provided wider film coverage and higher film-cooling effectiveness than the cylindrical holes while also creating lesser mainstream pressure losses. Higher coolant-to-mainstream density ratio resulted in higher effectiveness levels from the cooling holes. On the blade span, at any given blowing ratio, the suction side showed better coolant coverage than the pressure side even though the former had two fewer rows of holes. Film-cooling effectiveness increased with blowing ratio on both sides of the blade. Whereas the pressure side effectiveness continued to increase with blowing ratio, the increase in suction side effectiveness slowed down at higher blowing ratios (M=0.9 and 1.2). Upstream wake had a detrimental effect on film coverage. 0% and 25% wake phase positions significantly decreased film-cooling effectiveness magnitude. Comparison between the compound shaped hole and the compound cylindrical hole design showed higher effectiveness values for shaped holes on the suction side. The cylindrical holes performed marginally better in the curved portion of the pressure side. Finally, the concept tip proved to be better than the baseline tip in terms of reducing mainstream flow leakage and mainstream pressure loss. The film-cooling effectiveness on the concept blade increased with increasing blowing ratio and tip gap. However, the film-coverage on the leading tip portion was almost negligible.

Three experiments were conducted to examine the effect of association strength on TOT (tip-of-the-tongue states) and recall. Two hundred nineteen undergraduate students studied pictures and names of 24 imaginary animals that were presented on a large computer screen. The strength of association between the cue and target was manipulated by varying the number of times the picture and the name were presented simultaneously, while keeping the number of presentations for each picture or the target constant across conditions. After the study phase, participants were cued by each picture to recall the imaginary animal names. Participants were asked to rate their strength of TOT on a scale ranging 0 to 3 for each item if they could not think of the name at the moment. Participants also made subjective judgments as to how many times they saw the picture and name of the animal co-occur on the same screen at the study phase, and then they performed a recognition test at the end. The results indicated that the frequency and strength of TOTs linearly increased as a function of number of co-occurrences; the correlation between TOT strength and the participants?? subjective estimation of number of co-occurrences was greater than the correlation between TOT strength and the actual number of co-occurrences. This pattern of results was found even when recall increased along with the increase in number of co-occurrences and was more pronounced particularly when recall was reduced either by interference (Experiment 1) or by increased number of critical items (Experiments 2 & 3) and also by a reduced number of co-occurrence conditions and an increased gap between one level to the next (Experiment 3). Results suggest that an increase in association strength concomitantly increases TOT strength especially when the activation of the target is under threshold for recall and that people may use rules of thumb, or heuristic when they report TOTs by estimating the strength of the cue-target association.

Energy use index (EUI) is an important measure of energy use which normalizes energy use by dividing by building area. Energy use indices and associated coefficients of variation are computed for major industry categories for electricity and natural gas use in small and medium-sized plants in the U.S. The data is very scattered with the coefficients of variation (CoV) often exceeding the average EUI for an energy type. The combined CoV from all of the industries considered, which accounts for 8,200 plants from all areas of the continental U.S., is 290%. This paper discusses EUIs and their variations based on electricity and natural gas consumption. Data from milder climates appears more scattered than that from colder climates. For example, the ratio of the average of coefficient of variations for all industry types in warm versus cold regions of the U.S. varies from 1.1 to 1.7 depending on the energy sources considered. The large data scatter indicates that predictions of energy use obtained by multiplying standard EUI data by plant area may be inaccurate and are less accurate in warmer than colder climates (warmer and colder are determined by annual average temperature weather data). Data scatter may have several explanations, including climate, plant area accounting, the influence of low cost energy and low cost buildings used in the south of the U.S. This analysis uses electricity and natural gas energy consumption and area data of manufacturing plants available in the U.S. Department of Energy's national Industrial Assessment Center (IAC) database. The data there come from Industrial Assessment Centers which employ university engineering students, faculty and staff to perform energy assessments for small to medium-sized manufacturing plants. The nation-wide IAC program is sponsored by the U.S. Department of Energy. A collection of six general energy saving recommendations were also written with Texas manufacturing plants in mind. These are meant to provide an easily accessible starting point for facilities that wish to reduce costs and energy consumption, and are based on common recommendations from the Texas A&M University IAC program.

Thesis (M.S.)--Oregon State University, 2010. / Printout. Includes bibliographical references (leaves 111-114). Also available on the World Wide Web.

Previous research has indicated aperiodicity in the positions of tip vortices emitted from a helicopter rotor blade in hover. The objective of the current study is to develop an analysis of the tip vortex aperiodicity in hover and to validate it with measurements on a reduced-scale, 1m diameter, four-bladed rotor. A “vortex ring emitter model” (VREM) was developed to study the statistics of the tip vortices emitted from a rotor blade during hover. In order to better model the rotor wake, a number of independent vortex blobs were used to describe a vortex ring. An empirical model for viscosity was also considered which helped model the core radius growth of the vortex ring with vortex age. A parametric analysis was then performed to obtain a comprehensive qualitative and quantitative convergence study of the time step, viscosity parameter, initial core size, number of rings shed, number of blobs and overlap factor. It was observed that the solution converged rapidly for all the parameters used. The locations of tip vortex cores for vortex ages ranging from 0◦ to 260◦ were measured on the reduced-scale rotor using a stereo PIV system. The blade loading for the reduced scaled rotor was Ct /σ = 0.044 and the blade rotational speed was 1520 RPM, which corresponds to a tip Reynolds number of 248,000. The 95 % confidence region for the position of tip vortex cores exhibited an anisotropic, aperiodic pattern, approximating an ellipse. It was seen that the principal axis of this ellipse appeared to be aligned perpendicular to the slipstream boundary. The analytical model showed good correlation with experimental data in terms of the orientation and extent of the anisotropy. Moreover, an estimate of the total thrust produced and spanwise loading along the rotor blade was also obtained and compared with Blade Element Momentum Theory (BEMT). It was seen that by using more blobs to represent a vortex ring, the solution converged to the BEMT estimate. / text