No description available.

Astrophysical phenomena such as self-annihilation of primordial black holes (PBHs), gamma ray bursts (GRBs), and supernovae are expected to produce single dispersed pulses detectable in the low end of the radio spectrum. Analysis of these pulses could provide valuable information about the sources, and the surrounding and intervening medium. The Eight-meter-wavelength Transient Array (ETA) is a radio telescope dedicated to the search for these pulses in an 18 MHz bandwidth centered at 38 MHz. ETA consists of 10 dual-polarized active dipoles providing an all-sky field of view. This thesis describes the results of a search campaign using ETA, namely, a Crab giant pulse (CGP) search. CGPs are already known to exist, and thus provide an excellent diagnostic for system performance. We found 11 CGP candidates in 14 hours of data. Although there has not been a single compelling detection (signal-to-noise ratio > 6), our analysis shows that at least a few of these candidates may be CGPs. We also explain the analysis preparation for PBH and GRB searches. Additionally, we describe the instrument and a software "toolchain" developed for the analysis of data that includes calibration, radio frequency interference (RFI) mitigation, and incoherent dedispersion. A dispersed pulse simulation code was developed and used to test the toolchain. Finally, improvements are suggested. / Master of Science

Yes / This paper presents a new method that provides the means to detect sunspots on full-disk solar images recorded by the Solar Diameter Imager and Surface Mapper (SODISM) on the PICARD satellite. The method is a totally automated detection process that achieves a sunspot recognition rate of 97.6%. The number of sunspots detected by this method strongly agrees with the NOAA catalogue. The sunspot areas calculated by this method have a 99% correlation with SOHO over the same period, and thus help to calculate the filling factor for wavelength (W.L.) 607nm.

Das IceCube Neutrino-Observatorium ist ein am geografischen Südpol im Eis installierter Neutrinodetektor. In IceCube werden Neutrinos mit Tscherenkow-Strahlung von Sekundärteilchen aus Neutrino Interaktionen detektiert. Für den Nachfolgedetektor IceCube-Gen2, werden neue und verbesserte Lichtdetektoren gesucht. Die vorliegende Arbeit beschreibt die Entwicklung eines dieser Lichtdetektoren. Dieser basiert auf Wellenlängen schiebenden und Licht leitenden Technologien. Der Detektor mit dem Namen "Wavelength-shifting Optical Module" (WOM) verwendet eine transparente Röhre, mit wellenlängenschiebender Farbe, als passiver Photonendetektor. Das in der Wellenlänge verschobene Licht wird durch Totalreflexion, zu kleinen PMTs an beiden Enden geleitet. Die Auswahl dieses Designs reduziert die Kosten und verbessert das Signal-Rausch-Verhältnis wesentlich, möglicherweise können mit dieser Lösung extragalaktische Supernova in zukünftigen Detektoren beobachtet werden. Als eine Kernkomponente wird die wellenlängenschiebende Röhre ausführlich untersucht. Verschiedene Messaufbauten und Auswertungsmethoden werden entwickelt, um diese im Anschluss zu untersuchen und zu bewerten. Iterative Verbesserungen der Materialien und des Farbauftrageverfahren als auch Messmethoden, resultieren in einer kombinierten Einfang-, Wellenlängenschiebe- und Transporteffizienz von 28,1 +/- 5,4 % der Röhre. Ein Model zur Beschreibung des Lichtverhaltens in der Röhre wird entwickelt um eine Diskrepanz zwischen Theorie und Messung zu untersuchen. Die Kombination zwischen Messung und Model, bestätigt die Aussagekraft des Models und zeigt, dass ein Großteil der Verluste beim Lichttransport zustande kommen. Darüber hinaus werden die physikalischen Eigenschaften des WOM in die IceCube Simulationsumgebung eingebaut. Der Vergleich zu einem Konkurrenzmodul zeigt eine Überlegenheit des WOM um den Faktor 1,05 +/- 0,07. Es werden Vorschläge und Ausblicke für Verbesserungen der Leistungsfähigkeit des WOMs gegeben. / The IceCube Neutrino Observatory is an in ice neutrino detector located at the geographic South Pole. In IceCube neutrinos are detected via Cherenkov light produced by secondary particles in neutrino interactions. For the upgraded detector IceCube-Gen2, new and improved light detectors are sought-after. This work describes the development of one of those light detectors based on a novel combination of wavelength-shifting and light-guiding technology. The detector named the Wavelength-shifting Optical Module (WOM) utilizes a large transparent tube, coated with wavelength-shifting paint as a passive photon detector. The wavelength-shifted light is guided via total internal reflection towards small active light detectors, at each end of the tube. This design reduces costs and improves the signal to noise ratio significantly, thereby potentially enabling extragalactic supernova detections in future detectors. As a core component, the wavelength-shifting tube is extensively investigated. Different measurement setups and evaluation techniques are developed and investigated. Iterative improvement of materials and coating techniques as well as measurement methods currently result in a combined photon capture, shift and transport efficiency of 28.1 +/- 5.4 % for the tube. Those results contrast the theoretical maximum of 74.5 %. A model is developed to describe the light propagation and loss processes in the tube and to understand the discrepancies between theory and measurement. The combination of the measurements with the model, validate the descriptive qualities of the model and show that most of the light is lost during the light propagation in the tube. Additionally, the physical properties of the WOM are included in the IceCube simulation framework. A comparison to a competing module showed that the WOM outperforms by a factor of 1.05 +/- 0.07 in photon detection numbers. Where applicable, suggestions and outlooks are given to enhance the performance of the WOM.

La croissance continue du trafic Internet implique une augmentation de la consommation d'énergie en raison des nombreuses conversions optique à électronique(OEO) requises par les routeurs et les commutateurs. L'utilisation de réseaux transparents pourraient freiner cette croissance incontrôlée, mais le maintien des données dans le domaine optique a deux conséquences néfastes: une accumulation du bruit et des non-linéarités de l'amplification qui dégrade fortement les performances au niveau de la couche physique. et la contrainte de continuité de longueur d'onde (WCC) reflétant la conservation de la longueur d'onde du signal optique dans les réseaux optiques multiplexés en longueur d'onde (WDM) qui dégradent les performances du réseau, notamment sa probabilité de blocage. Les convertisseurs de longueur d'onde (WC) peuvent pallier la contrainte WCC, mais les seuls dispositifs suffisamment matures disponibles dans le commerce sont les WC basés sur OEO (OEO-WC). Cependant, leur coût augmente avec les débits binaires. D'autre part, des convertisseurs de longueur d'onde tout optique (AO-WC) ont été démontrés dans des laboratoires de recherche, avec toutefois une plage de conversion limitée et une dégradation du signal converti.Dans cette thèse, nous concevons la couche de transmission en utilisant deux ensembles de formats de modulation différents avec des plages de débits différentes; et par conséquent différents modèles d'estimation de performance. Au niveau du réseau, nos analyses montrent que la contribution des WC dépend des demandes de trafic servant à l’ordre dans un scénario de planification du réseau; qu'en utilisant des algorithmes fixed-alternate-routing (FAR) ou least-loaded-routing (LLR) et un algorithme d'affectation de longueur d'onde first-fit (FF), les AO-WCs offrent les mêmes améliorations de performances que les OEO-WC. De plus, nous identifions une plage de conversion et une cascadabilité optimale d’AO-WC qui montre que le LLR nécessite un nombre de conversions par canal inférieur au FAR. / The continuous growth of Internet traffic implies an increased power consumption due to the many optical-to-electronic (OEO) conversions required by routers and switches. Transparent networks could curb this uncontrolled growth, but keeping the data in the optical domain has two adverse consequences: physical layer impairments accumulation which strongly degrades the performance due to amplication noise and non-linearities; and the wavelength continuity constraint (WCC) to keep the opticalsignal's wavelength unchanged in wavelength-division-multiplexed (WDM) optical networks which degrades network blocking performance. Wavelength converters (WCs) can alleviate the WCC constraint, but the only commercially available devices are the OEO-based WCs (OEO-WCs), however, their cost increases with bit-rates. On the other hand, all-optical wavelength converters (AO-WCs) have been demonstrated in research laboratories albeit with a limited conversion range and a performance that degrades converted signal's quality.In this thesis, we design the transmission layer using two different modulation formats sets with different bit-rates ranges; and consequently different performance estimation models. At the network level, our analyses show that WCs' contribution depends on traffic demands serving ordering in the online traffic assumption; that using xed-alternate routing (FAR) or least-loaded routing (LLR) algorithms and first-fit (FF) wavelength assignment algorithm, AO-WCs give the same performance enhancement as OEO-WCs. Moreover, we identify an optimum AO-WC conversion range and cascadability which shows that LLR requires lower number of conversions per channel compared to FAR.

Wavelength-discriminating systems typically consist of heavy benchtop-based instruments, comprising diffractive optics, moving parts, and adjacent detectors. For simple wavelength measurements, such as lab-on-chip light source calibration or laser wavelength tracking, which do not require polychromatic analysis and cannot handle bulky spectroscopy instruments, lightweight, easy-to-process, and flexible single-pixel devices are attracting increasing attention. Here, a device is proposed for monotonously transforming wavelength information into the time domain with room-temperature phosphorescence at the heart of its functionality, which demonstrates a resolution down to 1 nm and below. It is solution-processed from a single host–guest system comprising organic room-temperature phosphors and colloidal quantum dots. The share of excited triplet states within the photoluminescent layer is dependent on the excitation wavelength and determines the afterglow intensity of the film, which is tracked by a simple photodetector. Finally, an all-organic thin-film wavelength sensor and two applications are demonstrated where this novel measurement concept successfully replaces a full spectrometer.

Raman spectroscopy is a powerful tool in the field of biomedicine for disease diagnosis owing to its potential to provide the molecular fingerprint of biological samples. However due to the inherent weak nature of the Raman process, there is a constant quest for enhancing the sensitivity of this technique for enhanced diagnostic efficiency. This thesis focuses on achieving this goal by integrating advanced methods with Raman spectroscopy. Firstly this thesis explores the applicability of a laser based fluorescence suppression technique – Wavelength Modulated Raman Spectroscopy (WMRS) - for suppressing the broad luminescence background which often obscure the Raman peaks. The WMRS technique was optimized for its applications in single cell studies and tissue studies for enhanced sensing without compromising the throughput. It has been demonstrated that the optimized parameter would help to chemically profile single cell within 6 s. A two fold enhancement in SNR of Raman bands was demonstrated when WMRS was implemented in fiber Raman based systems for tissue analysis. The suitability of WMRS on highly sensitive single molecule detection techniques such as Surface Enhanced Raman Spectroscopy (SERS) and Surface Enhanced Resonance Raman Spectroscopy (SERRS) was also explored. Further this optimized technique was successfully used to address an important biological problem in the field of immunology. This involved label-free identification of major immune cell subsets from human blood. Later part of this thesis explores a multimodal approach where Raman spectroscopy was combined with Optical Coherence Tomography (OCT) for enhanced diagnostic sensitivity (>10%). This approach was used to successfully discriminate between ex-vivo adenocarcinoma tissues and normal colon tissues. Finally this thesis explores the design and implementation of a specialized fiber Raman probe that is compatible with surgical environments. This probe was originally developed to be compatible with Magnetic Resonance Imaging (MRI) environment. It has the potential to be used for performing minimally invasive optical biopsy during interventional MRI procedures.

Fault localization is the process of realizing the true source of a failure from a set of collected failure notifications. Isolating failure recovery within the network optical domain is necessary to resolve alarm storm problems. The introduction of the monitoring trail (m-trail) has been proven to deliver better performance by employing monitoring resources in a form of optical trails - a monitoring framework that generalizes all the previously reported counterparts. In this dissertation, the m-trail design is explored and a focus is given to the analysis on using m-trails with established lightpaths to achieve fault localization. This process saves network resources by reducing the number of the m-trails required for fault localization and therefore the number of wavelengths used in the network. A novel approach based on Geographic Midpoint Technique, an adapted version of the Chinese Postman’s Problem (CPP) solution and an adapted version of the Traveling Salesman’s Problem (TSP) solution algorithms is introduced. The desirable features of network architectures and the enabling of innovative technologies for delivering future millimeter-waveband (mm-WB) Radio-over-Fiber (RoF) systems for wireless services integrated in a Dense Wavelength Division Multiplexing (DWDM) is proposed in this dissertation. For the conceptual illustration, a DWDM RoF system with channel spacing of 12.5 GHz is considered. The mm-WB Radio Frequency (RF) signal is obtained at each Optical Network Unit (ONU) by simultaneously using optical heterodyning photo detection between two optical carriers. The generated RF modulated signal has a frequency of 12.5 GHz. This RoF system is easy, cost-effective, resistant to laser phase noise and also reduces maintenance needs, in principle. A revision of related RoF network proposals and experiments is also included. A number of models for Passive Optical Networks (PON)/ RoF-PON that combine both innovative and existing ideas along with a number of solutions for m-trail design problem of these models are proposed. The comparison between these models uses the expected survivability function which proved that these models are liable to be implemented in the new and existing PON/ RoF-PON systems. This dissertation is followed by recommendation of possible directions for future research in this area.

The main subject of this diploma thesis is to make a proposal to improve the optical access network for the transmission of Triple play services. I would here to the reader clarify method of proposal of optical network. There are described the kinds of optical access networks with parameters, for which we must look by their construction. There are described the modern methods of construction optical network too. In the theoretical part are discussed used architecture of networks too. I met here known standards, which I compared for big importance by their choice. A reason of construction of optical network are services known like Triple play. These services together with their problems and parameters are here discussed too. At the end of theoretical part I listed here measuring method for getting negative attribute distorting the led signal. In practical part the locality witch use the optical signal as the source of information is ordered. These network use unfit connections and has less possibilities than usual and this is the reason, why is the network not able to supply Triple play in requested quality. At first the analysis of ordered network was needed. Situation was complicated by the fact, that it has been prohibited entrance to me. The structure of network and network parts was known and documented by me. I made the proposals to improve this network in practical part. By the first proposal remained original kind of access network FTTB, but used new parts with higher performance. By the second proposal I made the network FTTH, by which it was possible to use the last haul optical cables with treatment and using new elements. It was needed to create solution by flat units. The resulting proposals are here evaluated, compared and cost evaluated. For rejection of access to optical network I did not make measuring, so I made simulation for variant FTTH for getting some parameters negative acting transmission.

M. Tech. (Department of Chemistry, Faculty of Applied and Computer Science), Vaal University of Technology / Cadmium and cobalt complexes of urea and thiourea were synthesized using ethanol as a solvent. All complexes were refluxed at 70 - 80 °C, left to cool at room temperature, washed with methanol and acetone to remove impurities and dried at an open environment. The characterization of complexes was done using FTIR spectroscopy, elemental analysis and TGA. The complexes were found to coordination with the ligands through sulphur and oxygen atoms to the metal, instead of nitrogen. These were as results of wavelength shifting from high to low frequency from spectra of the complexes as compare to their free ligands. These observations make these complexes good candidates for the possible use in synthesis of metal sulphides or oxides nanoparticles. Thermogravimetric analyses of all the complexes were conducted to check the stability of use as precursors for nanoparticles at low and high temperature. A number of thiourea and urea complexes with cadmium and cobalt have been prepared and used in the preparation of metal sulphides/oxides nanoparticles. Complexes start to decompose at low temperature about 100°C and the last decomposition step was at about 800-900°C, which is convenient to thermal decomposition of precursors in the high boiling solvents or capping agent to prepare surface capped metal sulphides/oxides nanoparticles. The complexes were easy to synthesize, low cost and stable in air and were obtained in reasonable yields. All the complexes reported in this study have been used as single source molecular precursor in the preparation of cadmium oxide, cadmium sulphide, cobalt oxide, cobalt sulphide nanoparticles (normal) and as mixture of any two complexes to form core-shells nanoparticles. Quality nanoparticles synthesis requires three components: precursors, organic surfactants and solvents. The synthesis of the nanoparticles can be thought of as a nucleation event, followed by a subsequent growth period. Both the nucleation and growth rates were found to be dependent upon factors such as temperature, growth time, and precursor concentration. For a continuous flow system the residence time (at nucleation and growth conditions) was also found to be important. In order to separate the nucleation and growth events, injection techniques were employed to achieve rapid nucleation of nanoparticles with final size dictated by the growth temperature and/or residence time through the growth zone of the reaction system. Good crystalline normal nanoparticles were obtained from thermolysis of the precursors in hexadecylamine (HDA) as the capping agent at fixed concentrations, temperature and time. All nanoparticles showed a blue-shift in band edges with good photoluminescence behaviour which is red-shifted from their respective band edges and XRD patterns, the crystal structure are in hexagonal phase. The particles showed rods, spheres and hexagonal shapes. Nucleation and growth mechanism brings new avenue in nanostructures called core-shells, which have been reported to have improved luminescence, quantum yields, decreased fluorescence lifetimes, and benefits related to the tailoring of the relative band-gap positions between the two materials. In this study cadmium and cobalt complexes of urea and thiourea were separately dispersed in TOP and injected separately (allowing nucleation/core to occur, followed by the shell) in hot HDA at 180ºC for 1hour to yield core-shell nanoparticles. Parameters, such as concentration, temperature and capping molecule as factor affecting nucleation and growth of the core-shells were monitored. The core-shell nanoparticles were characterized by UV/Vis spectroscopy, XRD and TEM. We observed spherical, tripod, bipods, hexagonal and irregular shaped nanoparticle as the concentration of the precursors was increasing, however we were able to form core-shells nanoparticles in one set of experiment 1:3 CdS-CdO, which are assumed to be a reverse type I coreshells nanoparticles. Exciton absorption peaks at higher energy than the fundamental absorption edge of bulk indicate quantum confinement effect in nanoparticles as a consequence of their small size. XRD patterns, crystals range from hexagonal, cubic and mixture of hexagonal and orthorhombic. A low temperature studies were also conducted a mixture of hexagonal and sphererical shapes with sheets like onion morphology were observed. / NRF HUB & SPOKES (VUT)