In this work, various components for low power RF telemetry applications have been investigated. These designed, fabricated and tested devices include radio frequency (RF) micro-electro-mechanical systems (MEMS) switches, single-pole-double-throw (SPDT) RF MEMS switches, nano fabricated capacitors and switching devices, and micromachined microstrip patch antennas.Coplanar waveguide (CPW) RF capacitive switches in shunt and series configuration were designed for high isolation, low insertion loss, and fast switching speed. Switches with > 35 dB isolation, < 0.3 dB insertion loss and switching speeds in the 10's of microseconds were fabricated and measured. These switches were packaged using photo-imagable resists and flip-chip bonding techniques. The MEMS shunt switch topology was also implemented into a single-pole-double-throw (SPDT) design by utilizing two such switches in a series and a shunt configuration, offset by a quarter wavelength section to provide a RF shor t at the input of the shunt switch in the off state. This type of design has the advantage of requiring a simple on-off (0 V and 35 V) bias supply to select the switch state.Also, the use of a focused ion beam (FIB) tool to mill sub-micron gaps in CPW transmission line structures was investigated. Nearly ideal capacitors in the micro- and mm- frequency range with capacitance of 8-12 fF were obtained using this milling technique. The FIB's capability to mill such small gaps at an oblique angle was also utilized to fabricate RF nano switches. These devices were switched with speeds of less than 300 ns with voltages of less than 20 V. Finally, solid state and packaged MEMS switches were integrated into a novel binary amplitude shift keyed (BASK) modulating RF telemetry system to provide the modulation of a redirected 10 GHz continuous wave (CW) signal. A pair of cross-polarized micromachined microstrip patch antennas was used in the system to receive the CW signal and re-transmit th e modulated signal. A transmission range of over 25 m was demonstrated with the solid state switch reflectenna.

In this research various techniques were used to study surface groups on carbon electrodes, including the spectroscopic techniques UV-Vis-NIR, FTIR, PAS, XPS and XAS, as well as the Boehm titration. The methods determined to give the best insight to the surface functionalities on the carbon were XPS, XAS and the Boehm titration. The Boehm titration methodology was standardized before use. An in situ method of examining surface groups using spectroscopy during electrochemistry was attempted. Spectroelectrochemistry is a useful way to gain information on how electrochemistry affects electrodes during experimentation; however, it was unsuccessful for the carbon used and remains to be developed. Polymerization of the copolymer of PANI and PPy as a potential electrode material for ECs was achieved by electrochemical cycling and was studied through spectroelectrochemical measurements. Overall, the research completed included the initial stages to studying electrodes for electrochemical capacitors using analytical, non-electrochemistry techniques in conjunction with electrochemistry.

The power transfer capability of a transmission line is determined by the magnitude of the voltage at each end of the line, angle difference of these voltages and the impedance of the line. This impedance is mainly inductive. Traditionally, fixed series capacitor banks have been used for series compensation. However, due to instability problems associated with loading transmission line close to their thermal limits, researchers have looked at other alternatives to line compensation by static devices such as fixed series capacitors. Flexible AC Transmission Systems (FACTS) has allowed power utilities to use existing transmission line networks close to their thermal limits without compromising stability of the power system. A FACTS series compensator is capable of influencing the transmission of power in a transmission line by dynamic control of the series compensating reactance inserted in the line. There are several different devices under the FACTS family, however, in this thesis only the Thyristor-Controlled Series Capacitor (TCSC) was considered. A TCSC comprises a fixed capacitor in parallel with a thyristor-controlled reactor (TCR). By varying the firing angle ex:. of the thyristors, the TCSC can be made to act in variable inductive or capacitive reactance mode. The thesis' overall objective was to design a practical TCSC for use in a research laboratory for further research initiatives. This thesis looks at different issues that need to be considered when designing and rating a TCSC compensator. In particular, the thesis examines the effects of different sizes of TCSC components on the rating of the device, the effects of harmonics on the TCSC ratings, sizing of TCSC's variable reactance, and the response time of TCSC to a step change in the firing angle. A mathematical model of a TCSC in a single-machine infinite bus (SMIB) system was developed and subsequently used in the initial design of the TCSC. Studies that were done using mathematical model of the TCSC module confirmed the ability of the TCSC controller to dynamically control the capacitive compensating reactance in the transmission line. The thesis then describes the development of a laboratory-scale TCSC for research investigations. Measured results from the laboratory demonstrate the ability of the TCSC series compensator to provide rapid control of series reactance of a transmission line. A detailed mathematical model of the SMIB equipped with TCSC module was developed, using parameter values of the laboratory scale prototype, to investigate power oscillation damping. Time-domain simulation results are presented in this thesis to demonstrate its ability to damp power swings in an electrical network. / Thesis (M.Sc.Eng.)-University of Natal, Durban, 2003.

Layer-by-Layer (LbL) deposition of electrochemically active materials on porous carbon electrodes is a proven method to leverage both electrochemical double-layer capacitance and pseudocapacitance for charge storage on the same electrode. LbL coatings are held together by electrostatic attraction between adjacent layers of oppositely charged molecules. Previous studies have used Keggin polyoxometalates to great effect as the anionic layer in LbL electrode modification, but little effort has been devoted to cationic material selection and LbL process optimization. This work investigated alternatives to the conventional, electrochemically inert polydiallyldimethylammonium (PDDA) cation. The use of fuchsin molecular cations in LbL deposition improved the specific energy and specific power of modified electrodes. Fuchsin cation also rendered the environmentally harmful oxidative surface activation step unnecessary for LbL deposition. Process parameters were optimized for MWCNT/Fuchsin/POM samples, and post-LbL electrochemical polymerization was found to further improve the performance of these electrodes.

The focus of this thesis is on radio frequency magnetron sputtered aluminum oxide thin films developed for use as the gate dielectric for organic thin film transistors. The effect of top metal electrodes on the electrical characteristics of aluminum oxide metal-insulator-metal capacitors has been studied to determine an optimum material combination for minimizing the leakage current, while maximizing the breakdown field. The leakage current and breakdown characteristics were observed to have a strong dependence on the top electrode material. Devices with Al top electrodes exhibited significantly higher breakdown voltages compared to devices with Au, Ni, Cu and Ag electrodes. Introducing an Al diffusion barrier dramatically increased the breakdown field and reduced the leakage current for capacitors with Ag, Au and Cu top electrodes. The electrical characteristics were found to relate well to material properties, of the contacting metals, such as ionization potential and diffusion coefficient.

The focus of this thesis is on radio frequency magnetron sputtered aluminum oxide thin films developed for use as the gate dielectric for organic thin film transistors. The effect of top metal electrodes on the electrical characteristics of aluminum oxide metal-insulator-metal capacitors has been studied to determine an optimum material combination for minimizing the leakage current, while maximizing the breakdown field. The leakage current and breakdown characteristics were observed to have a strong dependence on the top electrode material. Devices with Al top electrodes exhibited significantly higher breakdown voltages compared to devices with Au, Ni, Cu and Ag electrodes. Introducing an Al diffusion barrier dramatically increased the breakdown field and reduced the leakage current for capacitors with Ag, Au and Cu top electrodes. The electrical characteristics were found to relate well to material properties, of the contacting metals, such as ionization potential and diffusion coefficient.

Well dispersed aqueous suspensions containing single-walled carbon nanotubes (SWCNTs) from bulk powders were prepared with surfactant and without surfactant by acid functionalization. SWCNT coated electrodes were then prepared from the SWCNT aqueous suspensions using various methods to create uniform nanoporous networks of SWCNTs on various substrates and stainless steel (SST) current collectors for use as ultracapacitor electrodes. Drop coating, high voltage electro-spraying (HVES), inkjet printing, and electrophoretic deposition (EPD) methods were evaluated. Optical and scanning electron microscope images were used to evaluate the SWCNT dispersion quality of the various electrodes. Ultimately an EPD process was established which reliably produced uniform SWCNT nanoporous networks on SST substrates. The prepared SWCNT coated electrodes were characterized using cyclic voltammetry and their capacitance was determined. A correlation between extended EPD processing times, EPD processing temperatures, and electrode capacitance was quantified. Optimum EPD processing occurs where linear capacitance gains were observed for processing times less than 10 minutes. At processing times between 10 – 60 minutes a non-linear relationship demonstrated diminishing capacitance gains with extended EPD processing times. Likewise, optimum EPD processing occurs when the processing temperature of the SWCNT suspension is raised above room temperature. At processing temperatures from 45°C to 60°C an increase in capacitance was observed over the room temperature (22°C) electrodes processed for the same durations. Conversely, for processing temperatures less than room temperature, at 5°C, a decrease in capacitance was observed. It was also observed that SWCNT electrodes processed at 60°C processing temperatures resulted in 4 times the capacitance of 5°C electrodes for the same processing times, when the durations were 8 minutes or less. For samples with raised processing temperatures the time dependent capacitance gains were observed to be significantly diminished beyond 10 minute processing times. The SWCNT network thickness was also correlated to EPD processing temperature and capacitance. A linear relationship was identified between the SWCNT network thickness and the capacitance of the electrode. It was also observed that elevated processing temperatures increase the EPD deposition rate of SWCNTs, produce thicker SWCNT networks, and thus create electrodes with higher capacitance than electrodes processed at lower EPD processing temperatures. EPD of SWCNTs was demonstrated in this work to be an effective method for the fabrication of SWCNT ultracapacitor electrodes. Characterization of the process determined that optimal EPD processing occurs within the first 10 minutes of processing time and that elevated processing temperatures yield higher SWCNT deposition rates and higher capacitance values. In this work the addition of SWCNT nanoporous networks to SST electrodes resulted in increases in capacitance of up to 398 times the capacitance of the uncoated SST electrodes yielding a single 1cm2 electrode with a capacitance of 91mF and representing an estimated specific capacitance for the processed SWCNT material of 45.78F/g.

A prototype sensor array was developed for use with laboratory automation to permit closed-loop control of liquid-levels in a multiwell microplate geometry. A simple electrical model for non-contact capacitance-based fluid sensors was extended to describe a fluid-level dependency. The new model shows that a charge-transfer based capacitance transducer employing a liquid-specific calibration can be used to obtain an output signal that varies linearly with the liquid-level when fringe-field effects are negligible. The calibration also compensates for liquid-to-liquid conductivity and permittivity differences. / The sensor was tested using sodium chloride (NaCl) and ethanol solutions to simulate the range of conductivity and permittivity typical in biological and chemical research. Measured capacitance was a second-order function of liquid volume due to fringe-field effects and was compensated for by adding a hardware-based calibration. Liquid-volume measurement error averaged 0.2% of the 120mul fill volume with a standard deviation of 0.6% (&lt; mul). The maximum absolute error for all liquids was 2.7% (3mul).

The objective of this work is to electrospin poly(acrylonitrile) (PAN) based nanofibers with controlled diameter and to stabilize and carbonize them for developing meso-porous carbon for application as electrochemical capacitor electrodes. A sacrificial polymer, poly(styrene-co-acrylonitrile) (SAN) has been used to control porosity. Carbon nanotubes (CNT) have been used to increase electrode conductivity and hence power density. The study has been divided into two parts. In part I, electrospinning behavior of PAN and PAN/CNT has been studied. The diameter of electrospun PAN fibers was monitored as a function of polymer molecular weight, solution concentration, solution flow rate, distance between the spinneret and the target, and the applied voltage. Bead free PAN fibers of 60 nm diameter have been electrospun. Various electrospun fibers have been characterized by wide angle X-ray diffraction and by Raman spectroscopy. Electrospinning process has been observed by high speed photography. In part II, the electrospun PAN, PAN/SAN, and PAN/SAN/CNT fiber mats were stabilized, carbonized, and processed into electrochemical capacitor electrodes. The performance of the electrochemical capacitors was tested by the constant current charge/discharge and cyclic voltammetry in 6 molar potassium hydroxide aqueous solution. The surface area and pore size distribution of the electrodes were measured using N2 adsorption and desorption. The effect of surface area and pore size distribution on the capacitance performance has been studied. The capacitance performance of various carbonized electrospun fibers mats have been compared to those of the PAN/SAN/CNT film, carbon nanotube bucky paper, and activated carbon pellet. The capacitance of PAN/SAN/CNT fiber mat over 200 F/g (at a current density of 1 A/g) and the power density approaching 1 kW/kg have been observed. Addition of 1 wt% carbon nanotubes in PAN/SAN, improves the power density by a factor of four. For comparison, the capacitance of single wall carbon nanotube bucky paper at a current density of 1 A/g is about 50 F/g.

Some of the challenges associated with the multi-objective optimization on a modern power system were addressed in this work. Optimization of reactive resources was performed in order to simultaneously optimize several criteria: transmission losses, distribution losses, voltage stability, etc. The optimization was performed simultaneously on the entire power system; transmission and distribution subsystems included. The inherent physical complexity of modeling together transmission and distribution systems was considered first. After considering all pros and cons for such a task, a model of the entire power system was successfully developed. The inherent mathematical complexity of high-dimensional optimization space was handled by introducing the decoupling principle. System is first decoupled in several independent models and optimizations were performed on each part of the system. An algorithm is developed that properly combines the independent solutions to reach the overall system optima. The principle of algorithm synthesis is used to reduce the size of the solution space. Deterministic algorithms are used to locate the local optima which are subsequently refined by probabilistic algorithm. The algorithm is applied on a "real-life" test system and it is shown that the obtained solutions outperform the solution obtained with the conventional algorithms.