Orientador: Delia B. Rodriguez-Amaya / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia de Alimentos / Made available in DSpace on 2018-08-03T16:18:22Z (GMT). No. of bitstreams: 1 Niizu_PatriciaYuasa_M.pdf: 1454667 bytes, checksum: 5eefddb8eda127476050205897ccb5ef (MD5) Previous issue date: 2003 / Resumo: Bancos de dados de fitoquímicos como carotenóides são muito importantes para servir como base de estudos epidemiológicos, inquéritos alimentares, programas e pesquisas para combater deficiências (como a hipovitaminose A) e prevenir doenças degenerativas. A determinação de novas fontes de luteína e zeaxantina, carotenóides relacionados à proteção contra degeneração macular e catarata pode significar um grande avanço na prevenção destas doenças. A análise dos carotenóides da Tropaeolum majus L. apresentada no capítulo 2, revelou que esta flor representa uma rica fonte de luteína (450 mg/g e 350 mg/g de luteína nas flores amarelas e alaranjadas, respectivamente). As folhas de Tropaeolum majus L. também apresentam valores altos de carotenóides quando comparadas às folhas em geral (136 mg/g de luteína, 69 mg/g de b-caroteno, 74 mg/g de violaxantina e 48 mg/g de neoxantina). Foram ainda identificados violaxantina, anteraxantina, zeaxantina, zeinoxantina, b-criptoxantina, (a-caroteno e b-caroteno na flor em quantidades muito pequenas. Os novos dados de composição de vegetais consumidos em saladas determinados no capítulo 3 concordam com a maioria dos resultados apresentados na literatura, mostrando que as folhas verdes são boas fontes de luteína (de 7,7 a 56,1 mg/g) e p-caroteno (de 2,7 a 35,3 mg/g), as cenouras de a-caroteno (35,0 mg/g) e b-caroteno (61,5 mg/g), enquanto o tomate de licopeno (35,4. mg/g). Outra fonte equivalente deste último carotenóide é a melancia (de 34,6 a 36 mg/g), conforme determinado no Capítulo 4, uma :truta consumida largamente no mundo inteiro, entretanto, pouco enfatizada como fonte de licopeno. Uma dieta rica e variada em frutas e vegetais fornece a gama de carotenóides relacionados com a proteção às doenças degenerativas e fortalecimento da resposta imunológi / Abstract: Databases on phytochemicals, such as carotenoids, are very important to serve as bases for epidemiological studies, dietary intake surveys, programs and research to combat deficiencies (such as vitamin A deficiency) and to prevent degenerative diseases. The search for new sources of lutein and zeaxanthin, carotenoids implicated in the protection against macular degeneration and cataract, may contribute to the prevention of these diseases. The determination of carotenoids in Tropaelum majus L., presented in Chapter 2, revealed the flower as rich source of lutein (450 mg/g and 350 mg/g of lutein in the yellow and orange flowers, respectively). The leaves of Tropaelum majus L also presented high levels of carotenoids (136 mg/g lutein, 69 mg/g b-carotene, 74 mg/g violaxanthin and 48 mg/g neoxanthin) compared to leaves in general. Violaxanthin, anteraxanthin, zeaxanthin, zeinoxanthin, b-cryptoxanthin, a carotene and b-carotene were also detected in the flower at very low amounts. New data on the composition of vegetables consumed in salads are presented in Chapter 3, which are in agreement with majority of the results in the literature, showing that green leaves are good sources of lutein (7.7 to 56.1 mg/g) and b-carotene (2.7 to 35.3 mg/g), carrot of a-carotene (35.0 mg/g) and b-carotene (61.5 mg/g), and tomato of lycopene (35.4 mg/g). As presented in Chapter 4, another equivalent source of the latter carotenoid is watermelon (34.6 to 36.0 mg/g), a fruit widely consumed in the entire world but rarely cited as source of lycopene. A diet rich and varied in fruits and vegetables provides the range of carotenoids associated with the protection against degenerative diseases and enhancement of the immunological system / Mestrado / Mestre em Ciência de Alimentos

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Commercial carrot processors produce up to 175,000 tons of carrot waste annually. Carrot Mash (CM) is the term referring to the waste by-product of peeled baby carrot processing. Transportation of carrot processing waste is expensive due to its high- water content (approx. 83-95%). High in bioactive compounds (carotenoids) and dietary fibers, it is expected that its conversion into a value-added by-product is of interest to the carrot processing industry. Hemicellulose-rich plant materials have proven to be a source of oligosaccharides, which are known for their beneficial prebiotic activity. The objectives of this research were to: 1) determine the effect of mechanical treatments on the extraction of water and bioactive compounds and evaluate the functional properties of carrot mash; 2) incorporate dried carrot mash into a beef patty and evaluate changes in pH, color, cooking yield, and texture; 3) apply an enzymatic treatment to carrot mash to promote the conversion of polysaccharides to oligosaccharides for prebiotic benefits. Mechanical separation of liquid and solid fractions by way of expeller pressing was efficient in extracting liquid while simultaneously increasing total solids by nearly 200%, the extraction of carotenoids by 1000%, and polyphenol content by nearly 97%. Mechanical treatments increased the fat binding capacity on average by 183% compared to untreated mash. The addition of unpressed carrot mash or expeller pressed carrot mash increased the cooking yield of a beef patty by 3-13% without significantly changing its textural properties. Enzymatically treating the carrot mash significantly increased the concentration of oligosaccharides up to 2.3%. These results suggest that carrot processing wastes can be physically and enzymatically modified and have an immense potential to be utilized as a functional ingredient in human food rather than being landfilled, composted or used as animal feed.

[pt] O desconhecimento da existência de pesquisas sobre o comportamento do consumidor de cenoura Baby no Brasil estimulou a realização deste estudo exploratório, o qual tem como finalidade identificar aspectos relacionados às diferenças individuais que compõem o modelo de comportamento do consumidor. Mais especificamente, ele busca revelar as percepções e atitudes do consumidor em relação à cenoura Baby, os motivos que orientam sua preferência ou rejeição e as razões que estão limitando o seu consumo. Os dados foram coletados por meio de entrevistas individuais, observação pessoal e grupos de foco e avaliados sob os modelos multiatributos de Fishbein e Ponto Ideal. Os resultados sugerem uma atitude favorável em relação à cenoura Baby, mas a preferência é pela cenoura Comum. Diferentemente desta última, que é altamente acessível a todas as classes sociais graças a sua alta disponibilidade e preço baixo, a cenoura Baby está posicionada para um público com poder aquisitivo mais elevado, que é minoria. Ela é percebida como um produto sofisticado, e consumido apenas em situações especiais. Dentre as várias hipóteses e suposições que podem ser formuladas a partir deste estudo, recomenda-se testar se a cenoura Baby é, de fato, mais saborosa que a cenoura Comum e se ela realmente desperta o interesse das crianças. Os resultados poderão sugerir mudanças na estratégia de posicionamento, de modo a atender também o público infantil e, conseqüentemente, aumentar seu market share. / [en] There is no information available about Baby carrot consumer behavior in Brazil. This exploratory study aims to identify issues related to individual differences that build a consumer behavior model. Specifically, the goals of this study are to reveal the consumers´ perceptions and attitudes related to Baby carrot; the reasons that guide their choice or rejection; and the reasons which limit their consumption. Data were collected through personal interviews, personal observation and focus groups, and assessed using the multi-attributes Fishbein and Point Ideal models. The results suggest a favorable attitude regarding Baby carrot, but the preference is for the common carrot, which is highly accessible to all social classes due to its high availability and low price. Baby carrot is affordable to consumers with higher purchase power. It is perceived as a sophisticated product, and it is consumed only in special occasions. Among the various hypotheses and assumptions which may be formulated based on this study, it is recommended to test whether Baby carrot is, in fact, more palatable than the common carrot and if is really attractive to children. The results of this suggested study may suggest changes in strategy for market positioning in order to meet the public needs, including children, and thus increase market share of Baby carrot.

A anemia causada por deficiência de ferro é a forma mais comum de todas as anemias e afeta grande parcela da população mundial, especialmente o grupo materno-infantil: lactentes, pré-escolares, escolares, gestantes e nutrizes. A carência acarreta atraso no desenvolvimento psicomotor e cognitivo de crianças menores de dois anos, além de diminuição da eficiência da função imune, e agravamento de doenças infecciosas. O presente estudo teve por objetivos avaliar a disponibilidade de ferro em alimentos fontes deste e de vitamina A, ovo (o), cenoura (c) e couve (cv), bem como verificar a interação do ferro com α e ß-caroteno, e com outros interferentes. As misturas foram de ovo com cenoura e ovo com couve em diferentes proporções (1:1), (1:1,5), (1:2), (1:2,5) e (1:3) e também dos 3 alimentos sozinhos, totalizando 13 amostras. As amostras, após pré-preparo e cocção, foram submetidas às análises de composição centesimal, ferro, taninos, ácido fítico, ácido oxálico, α- e β- caroteno e ferro dialisável. Os dados foram submetidos à análise estatística empregando o teste de Tukey, regressão polinomial e correlação, utilizando o software SAS (1996). Os valores para umidade variaram de 83,93 a 95,74 g/100g, apresentando diferenças significativas entre as distintas amostras, assim como para proteínas (0,55 a 7,22g /100g) e extrato etéreo (0,21a 5,94 g/100g). Foi observado que em relação à umidade, extrato etéreo, proteínas, cinzas e β-caroteno houve correlação significativa para o ferro dialisável, sendo que para umidade e β-caroteno essa correlação foi positiva e para os demais componentes foi negativa. Os teores para taninos, fitatos e oxalatos variaram de 0,78 a 1,40 mEqcatequina/g, 0,17 a 0,42 mg/g, e 0,06 a 0,30% respectivamente. A amostra 2 (1o:1,5c) apresentou teores mais elevados de taninos (1,40 mEqcatequina/g), e as amostras 6 (1o:1cv) e 7 (1o:1,5cv) apresentaram teores mais elevados de oxalato e teores de ferro dialisável mais baixo, em relação às outras misturas. O teor de α-caroteno para as amostras contendo cenoura variou de 2.435,27 a 4.609,83 µg/100g. Quanto ao β-caroteno observou-se variações de 2.406,75 a 7.881,55 µg/100g, sendo evidenciado valores mais elevados para as amostras com cenoura. Numericamente, as misturas com maior proporção de cenoura e couve apresentaram os maiores resultados para o ferro dialisável, que variou entre 0,99 a 7,43%, sendo que a amostra 5 (1o:3c) apresentou o melhor resultado, seguida pelas amostras 1, 2, 3, 4, 8, 9 e 10. Pelos resultados obtidos pode-se concluir que as misturas com maior proporção de cenoura e couve aumentaram a disponibilidade do ferro, principalmente pelo maior conteúdo de ß-caroteno. Não houve interferência significativa dos antinutricionais sobre o ferro dialisável, embora os taninos e ácido oxálico atuaram como fatores limitantes quando observados os valores numéricos nas amostras com maiores concentrações de cenoura e couve. O ß-caroteno apresentou correlação positiva significativa com o ferro dialisável, exercendo influência na redução do efeito dos antinutricionais, especialmente dos fitatos, na disponibilidade do ferro, principalmente nas amostras com cenoura. Assim, pode ser recomendada a utilização de misturas de alimentos como ovo e cenoura, sendo que este último deve estar em maiores proporções em refeições destinadas a populações carentes em ferro. / The anemia caused by iron deficiency, is the form more common of all the anemias and it affects large portion of the world population, especially the maternal-infantile group: infants, child-school, children, pregnant woman and nutrizes, carting delay in the development psicomotor and cognitive of smaller children two years old, besides decrease of the efficiency of the immune function, and worsening of infectious diseases. This research aims to estimate the iron availability in food iron sources and vitamin A, egg (e), carrot (c) and cabbage (cb), as well as to verify the interaction of the iron with α, ß-carotene and with other interferents, being mixed the foods in study, resulted 13 food mixtures in different proportions (1:1), (1:1.5), (1:2), (1:2.5) and (1:3) include three food alone. The food mixtures, after prepare and cooking, was submitted the analyses of centesimal composition, levels of iron, tannin, phytic acid, oxalic acid, α, ßcarotene and in vitro iron dialysability. The statistical analysis was determinate by SAS System include polynomial regression and correlation. The values for moisture varied from 83.93 to 95.74 g/100g, showing significant differences among the different mixtures, as well as for proteins (0.55 to 7.22 g/100g) and fat (0.21 to 5.94 g/100g). There was significant correlation with regard to moisture, fat, protein, ash and ß-carotene to in vitro iron dialysability, being positive correlation to moisture and ß-carotene, and negative to other components. The levels of tannins, phytate and oxalates ranged 0.78 to 1.40 mEqcatequina/g, 0.17 to 0.42mg/g and 0.06 to 0.30%, respectively. The mixture 2 (1e:1.5c) showed high levels of tannins (1.40mEqcatequina/g), and the mixtures 6 (1e:1cb) and 7 (1e:1.5cb) high levels of oxalates, and lower levels of in vitro dialysability iron, in relation to the other mixtures. The values for α- carotene to mixtures with carrot ranged 2,435.27 to 4,609.83 µg/100g. With regard to ß-carotene, ranged variations to 2,406.75 from 7,881.55 µg/100g, being observed higher levels for the mixtures with carrot. The numbers showed that the mixtures with larger carrot and cabbage proportion showed the bigger results for the in vitro dialysability iron, ranges to 0.99 from 7.43 %, and the sample 5 (1e:3cb) it presented the bigger value, proceeded by the mixtures 1, 2, 3, 4, 8, 9 and 10. It’s concluded that the mixtures with larger carrot and cabbage proportion increased the iron availability, especially for the largest content of ß-carotene. There was not significant interference of antinutritional in the in vitro iron dialysability, although tannins and oxalates were an inhibitor when observed the numeric values in the mixtures with larger carrot and cabbage concentrations. The ß-carotene showed significant positive correlation with in vitro iron dialysability, increasing influence in the reduction of the antinutritional factors effect, especially phytates, in the iron availability, mainly in the mixtures with carrot. Therefore, the use of food mixtures as egg and carrot can be recommended, and this last one should be in larger proportions in meals destined to lacking populations in iron.

The further usage of vegetable and plant waste from juice pressing industry as textile dyes is presented in this thesis. The thesis is focused on β-carotene (C40H56) dyestuff extracted from orange peel and carrot residue. The three organic solvents; ethyl acetate, petroleum ether and hexane/acetone (1:1 v/v) were used for the extraction. The analysis of the extract was done by RP-HPLC with a C18 column. The yield and the purity of the extracted β-carotene were determined. The highest yield was achieved with petroleum ether whereas the other two solvents were nearly as good. The highest and purest amount on β-carotene was found in the extracts of carrots. The dyeing process was continued with β-carotene dyestuff of orange peel and carrot residue extracted from 27 g of residue on 0,8 g cotton in the dyeing ratio 1:50. Unmordant and post mordanted bleached and mercerized cotton fabric was dyed. 10% alum of the weight fraction of cotton was used as mordant. Colour measurements (K/S, C*, L*, a*, b*, h and ΔE) and fastness properties as light- (ISO-Norm B02) and wash fastness (ISO 105 – C) were tested. Fair light fastness grades were achieved by β-carotene dyestuff of orange peel residue dyed on cotton fabric. Poorer were the grades for β-carotene dyestuff of carrot residue for both unmordanted and mordanted samples. The wash fastness couldn’t achieve reasonable results neither for β-carotene dyestuff from carrots nor orange peel residue, dyed on cotton fabric. / Program: Master programme in Textile Engineering

The replacement of artificial with natural dyes is one of the most challenging research fields in the food production area. Recent studies have shown that some frequently used synthetic colours, called the “Southampton 6 Colours” may be linked with hyperactivity in children. The purpose of this work is to analyse the degradation behaviour of black carrot, a natural, red dye commonly used for colouring food products, and subsequently improve its stability during heat and storage conditions. The stability of the black carrot mixture to heat exposure was investigated at a range of pH values by heat-treating aqueous solutions in a domestic oven at around 180oC to maintain the temperature at 100oC and the powdered material in a furnace at 180oC (typical baking conditions). 1H NMR (800 MHz) spectroscopy was used for the assignment of the aromatic chemical shifts of the black carrot mixture by overlaying them with the characterised 1H NMR chemical shifts of the individual components separated by RP-HPLC. Integration of high-resolution 1H NMR (800 MHz) spectra was used to follow the relative degradation of each of the components. Different procedures for the complexation of black carrot with metal oxides were developed, for which colourants of different colour shades were prepared. Spectroscopic techniques were used to follow the degradation of the complexes which were heat-treated at 180oC. Nano-scale investigation of the metal oxide powders was also carried out. The optimised colourants were tested on a bench scale and subsequently on an industrial scale in food pilot procedures. The successful complexes produced were found to be more heat stable compared to the commercial black carrot dye. The developed technologies are cheap and easy-to-produce methods to create intense heat and storage stable coloured pigments which can be used for the replacement of existing artificial dyes during food processing.

Thesis (MA. Agricultural Management (Animal Production)) -- University of Limpopo, 2014 / This study determined the effect of carrot meal supplementation on productivity and carcass characteristics of Arbor acres broiler chickens aged one to six weeks. Experiment I determined the effect of carrot meal supplementation on productivity of Arbor acre broiler chicks aged one to 21 days. Two hundred unsexed Arbor acre broiler chickens were randomly assigned to five treatments with five replicates, each replicate having ten birds. A completely randomized design was used in the first experiment. The treatments were 0 (UA0), 20 (AU20), 50 (AU50), 75 (AU75) or 100 (AU100) g of carrot meal supplementation per kg DM feed. Quadratic equations were used to determine levels of carrot meal supplementation for optimal feed intake, metabolisable energy intake and nitrogen retention of Arbor acre broiler chickens aged one to 21 days. Linear equations were used to determine relationships between carrot meal supplementation and productivity variables. Dietary carrot meal supplementation had no (P>0.05) effect on growth rate, live weight and feed conversion ratio of unsexed Arbor acre broiler chickens aged one to 21 days. Carrot meal supplementation, however, improved (P<0.05) metabolisable energy intake and nitrogen retention of the chickens. Dietary metabolisable energy intake and nitrogen retention of the chickens were optimized at different carrot meal supplementation levels of 40.5 and 53.57 g/kg DM feed, respectively. No chicken deaths were recorded. Experiment II determined the effect of carrot meal supplementation on productivity and carcass characteristics of female Arbor acre broiler chickens aged 22 to 42 days. The chickens were randomly allocated to five treatments with five replicates, each having 10 birds, in a completely randomized design. The supplementation levels were 0 (FA0), 20 (FA20), 50 (FA50), 75 (FA75), or 100 (FA100) g of carrot meal per kg DM feed. Quadratic equations were used to determine levels of carrot meal supplementation for optimal feed intake, feed conversion ratio, live weight, metabolisable energy intake and nitrogen retention of broiler chickens aged 22 to 42 days. Linear equations were used to determine relationships between carrot meal supplementation and production variables. Dietary carrot meal supplementation had no (P>0.05) effect on growth rate, live weight and carcass parts of female Arbor acre broiler chickens aged 22 to 42 days. Carrot meal supplementation improved (P<0.05) feed intake, feed conversion ratio, metabolisable energy intake and nitrogen retention of Arbor acre broiler chickens aged vi 22 to 42 days. Dietary feed intake, feed conversion ratio, live weight, metabolisable energy intake and nitrogen retention were optimized at different dietary carrot meal supplementation levels of 52.8, 63.8, 38.0, 42.0 and 44.3 g/kg DM feed, respectively. Dietary carrot meal supplementation had no effect (P>0.05) on tenderness and flavour of female Arbor acre broiler meat. Broiler chickens on diets supplemented with 20, 50 or 100 g of carrot meal per kg DM feed produced meat with better (P<0.05) juiciness values than those of meat from chickens not supplemented with dietary carrot meal and those supplemented with 75 g/kg DM feed. There was a positive relationship between carrot meal supplementation and chicken meat juiciness. It is concluded that carrot meal supplementation improved (P<0.05) metabolisable energy intake and nitrogen retention of unsexed Arbor acre broiler chickens aged one to 21 days. However, carrot meal supplementation had no effect (P>0.05) on growth rate, live weight and feed conversion ratio of unsexed Arbor acre broiler chickens aged one to 21 days. Carrot meal supplementation improved (P<0.05) intake, feed conversion ratio, metabolisable energy and nitrogen retention of female Arbor acre broiler chickens aged 22 to 42 days. However, carrot meal supplementation did not (P>0.05) improve growth rate and live weights of the chickens.

Plant parasitic nematodes have long been known to cause extensive crop losses through reduced yields, shortened productive life, or lowered value of produce. The rood knot nematode, Heterodera marioni, is cosmopolitan. It destroys crops and causes economic losses equal to those of any other plant parasitic speies. in 1948 this nematode caused an estimated loss to the carrot raising industry in Iron County, Utah of approximately $15,000. No estimates for the years prior to 1948 are available; however, reports of the county agent (14) for Iron County show that carrot production in the Cedar Valley is decreasing, and is possibly due to this nematode. The importance of the root knot nematode to the carrot industry in the Cedar Valley was Recognized by farmers at harvest time in 1948. Experimental applications of soil fumigants were tried on many farms with varying success in the spring of 1949. (See figure 1 page 2). One of these experimental plots showed spectacular results. When carrots were harvested in the fall those grown in fumigated soil were found to be of the highest quality and were growing in excellent stands; wheras, the carrots grown in unfumigated soil produced poorer stands of poor quality carrots. Before any conclusions as to the practical value of soil fumigants in carrot raising can be reached, additional tests must be conducted in the area. The fact remains that the root knot nematode is present in the area and causes damage to carrots. If carrots, or any other susceptible crops, are to be grown on economical method of controlling this nematode must be found.