Abstract Biological processes have been proven to be economical and effective for control of VOCs with concentration of <1,000 mg C/m3. This study armed to develop a biofilter packed only with fern chips for the removal of airborne isopropyl alcohol (IPA). A three-stage down-flow biofilter (2.2 m in height and 0.4 m¡Ñ0.4 m in cross-sectional area) was constructed for the performance test. The first stage serviced as a humidifier for the incoming gas and the following two stages, both packed with fern chips with a packing space of 0.30 m ¡Ñ 0.40 m ¡Ñ0.40 m, as trickling bed biofilters for the VOC removal. Air with a nearly constant IPA concentration of 100 mg/Am3 (@ an average temperature of 34 oC) and a flow rate in the range of 100-400 L/min was fed to the reactor in Phase I test. The flow rate gave an empty bed retention time (EBRT) in the range of 12-48 s for the gas flowing through the two bed media. Solutions of urea-N, phosphate-P, and milk powder were supplied daily to the fern chips for the microbial nutrition in Phase I experiment which lasted for 26 days. Following the Phase, Phase II test operated with a constant EBRT of 12 s and without any nutrient supplementation for 30 days. Experimental results show that with an influent gas temperature of 29-40oC (average 34 oC) and relative humidity of 43-93% (average 73%), with a proper moistening of the bed media, the effluent gas could achieved a temperature of 26-35oC (average 29 oC) and a relative humidity of 98%. The proceeding medium experienced a greater moisture variation (12-68%, average 38%) than that (65-82%, average 72%) of the following one. The former and the latter media had pH in the range of 6.11-7.78 (average 6.77) and 6.13-7.36 (average 6.59), respectively. With no additional nutrient supplementation for 30 days, approximately 98% of the influent IPA of 100 mg/m3 could be removed at the EBRT of as short as 12 s which corresponded to a loading of 60 g IPA/m3.h.

This study armed to develop a biofilter packed only with fern chips for the removal of air-borne propylene glycol monomethyl ether acetate (PGMEA). The fern chip biofilters could avoid the shortcomings of traditional media, such as compaction, drying, and breakdown, which lead to the performance failure of the biofilters. In the present study, a three stage down-flow biofilter (2.18 m in height and 0.4 m¡Ñ0.4 m in cross-sectional area) was constructed for the performance test. The first stage serviced as a humidifier for the incoming gas and the following two stages, both packed with fern chips of 0.30 m ¡Ñ 0.40 m ¡Ñ0.40 m, as trickling bed biofilters for the VOC removal. The experiment was divided into four phases. Operation conditions of an empty bed retention time (EBRT) of 1.60min and influent PGMEA concentrations of 9.33-329 (average 78.4) mg/m3 were used in the Phase I experiment which lasted for 99 days. An average PGMEA removal of only 68% was obtained in this phase. For improving the PGMEA removal in the following phases, a fixed dosage of milk powder of 1.0 g/(m3 media. day) added as aqueous milk suspension was added to the media for nutrition of the biofilms on the fern chip surfaces. After an additional operation time of 20 days (the 127th day from the startup time), a stable PGMEA removal of 91% was achieved. Following Phase II, PGMEA removals of 93 and 94% were obtained with EBRTs of 0.40 and 0.27 min, respectively, in Phases III and IV experiments. The results indicate that EBRT was not a key influencing factor to the PGMEA removal as long as the media had a high ability for the VOC degradation. Experimental data obtained from Phases II-IV reveal that with volumetric loadings (L) of less than 250 g PGMEA/(m3.h) to the up-streaming half of the whole media, 90% of the influent PGMEA could be removed in this half media. An additional 80% of the influent PGMEA to the following half media could be removed with L < 100 g PGMEA/(m3.h) to the half media. The PGMEA elimination capacities were proportional to the volumetric loadings of less than 250 g PGMEA/(m3.h). From the results, it could be proposed that for achieving over 93% of the PGMEA removal, appropriate operation conditions are media moisture content = 52-65%, media pH = 7.2-7.4, influent PGMEA concentration = 100-400 mg/Am3, EBRT = 0.27-0.40 min, and L to the whole media = 45-180 g PGMEA/(m3.h).

This study armed to develop a biofilter packed only with fern chips for the removal of air-borne low concentration VOCs (volatile organic compounds) emitted from semiconductor manufacturing industries. The fern chip biofilters could avoid the shortcomings of traditional media, such as compaction, drying, and breakdown, which lead to the performance failure of the biofilters. Performance of biofiltration for removal of simulated semiconductor manufacturing emitted gases consisting of IPA (isopropyl alcohol), acetone, HMDS (hexamethylene disilazane), PGME (propylene glycol monomethyl ether), and PGMEA (propylene glycol monomethyl ether acetate) was studied in a pilot-scale biofilter consisted of two columns (40-cmW x 40-cmL x 70-cmH acrylic column) arranged in series. Each column was packed with fern chips to a packing volume of around 56 L (0.40 m¡Ñ0.40 m¡Ñ0.35 mH). A sprinkler was set over the packed fern chips for providing them with water and nutrition solutions. Liquid leached from both layers of chips were collected in the bottom container of the column. The experiment lasted for 182 days which was divided into four phases with varying influent gas flow rates and VOC concentrations. Gas samples collected around 3 times per week from the influent as well a the first and second stage effluents were analyzed for VOC concentrations. On a weekly basis, fern chips sampled from each column were also analyzed for getting pH, moisture, and the absorbed VOC content of the chips. Phase shifted if it obtained a quasi-steady state which was judged by the nearly unchanging VOC removal efficiencies. Operation conditions of an empty bed retention time (EBRT) of 1.50 min and influent VOC concentrations of 159-284 mg/m3 were used in the Phase I experiment which lasted for 15 days. Nutrition of 1.34 g milk powder/m3.d was used in this phase and the conditions gave an average volumetric VOC loading (L) of 15.1 g/m3.h. Effluent VOC concentrations were 3-18 mg/m3 and an average VOC removal of 96% was obtained in this phase. An EBRT of 0.75 min, L of 11.44 g/m3.h, and nutrition of 1.34 g milk powder/m3.d were used in the Phase II experiment. VOCs in the gas could be removed from 90-126 to 1-19.6 mg/m3 and an average efficiency of 94% was obtained. Following Phase II, an average VOC removal of only 48% was obtained with an EBRT of 0.75 min, nutrition of 2.0 g milk powder/m3.d, and L of 22.8 g/m3.h in Phases III experiment during the 56-97th days from the startup time. Additional nitrogen (urea) and phosphorus (potassium dihydrogen phosphate) was added to the media from the 105th day and the VOC removal increased to 80% at the 107th day. An average VOC removal of around 93% was obtained in phase III experiment. The results showed that enough nutrition is essential to the successful performance for the biofiltration process. Phase IV experiment lasted for 59 days with an EBRT of 0.75 min, L of 34.1 g/m3.h, and nutrition of 2.0-6.0 g/m3.d. During the initial period of this phase, media pH dropped from 7.8 to 5.8 due to an excess nitrogen (ammonium chloride) addition as high as 12.35 g N/m3.d which resulted in nitrification reaction in the media. By stopping nitrogen, increasing milk powder dosing, and addition of NaHCO3 at the 140th day, pH restored to 7.5 in the following days. VOC removal increased to an average of 92% in the rest operation days. From the results, it could be proposed that for achieving over 90% of the VOC removal, appropriate operation conditions are media moisture content = 52-65%, media pH = 7-8, influent VOC concentration = 150-450 mg/Am3, EBRT = 0.75 min, and L to the whole media = 11-34 g/m3.h.

Jerusalem artichoke has been cultivated in various regions without any special breeding technique. On the other hand, in food industry it does not have a wide usage area. Hence, in food industry its use as a potato substitute in some products is believed to be increasing its economical value. As a first attempt chips and crisps produced from Jerusalem artichoke was analyzed for texture, sensory, color, oil and moisture content. Jerusalem artichoke chips were fried in a bench top deep fat fryer for 120s, 180s and 240s at 160&deg / C, 170&deg / C, 180&deg / C and 190&deg / C. When microwave oven was used samples were cooked for 60s, 75s, 90s, 105s, 120s, 135s and 150s at 600 Watt and 900 Watt. Rheological properties of Jerusalem artichoke puree were investigated and Xanthan gum (2%wb) and sodium metabisulphite (1%wb) added for the desired puree consistence and color. After the production of puree Jerusalem artichoke flour was produced and water added to this flour then dough obtained again. Rheological behaviour of the original puree and these prepared from the containing 1- 4.5 and 1 - 5.0 part water were quite similar. In the light of the experimental results obtained as frying temperature and treatment time increased, moisture content and lightness of the Jerusalem artichoke products have decreased but a*and b* values, hardness, fracture and oil content increased. The best results for frying of Jerusalem artichoke seem to be 180&deg / C with about 240s treatment time for the chips and the same temperature for 180s for the crisps. As microwave power level and duration of treatment increased, moisture content and lightness of the microwave cooked Jerusalem artichoke products have decreased, but a* and b* values increased. Hardness and fracturability values of the products first increased with time and then decreased. When microwave oven was used, the best results were obtained for about 105s treatment time at 600W for the Jerusalem artichoke chips and about 60s processing time at 900W for the crisp. Since treatment time for cooking was significantly reduced when microwave cooking was used, this method could be recommended as an alternative to conventional deep fat frying, as oil is not used as well.

This study armed to develop a biotrickling biofilter packed only with fern chips for the removal of air-borne low concentration VOCs (volatile organic compounds) emitted from a solvent refinery located in Kaohsiung county of southern Taiwan. The fern chips could avoid the shortcomings of traditional media, such as compaction, drying, and breakdown, which lead to the performance failure of the biofilters. A pilot-scale biofilter (0.80 mL ¡Ñ 0.75 mW ¡Ñ 1.50 mH) packed with 0.24 m3 fern chips was used for the performance study. The study was conducted in the plant by drawing vented gas streams from two distillation columns and two solvent storage vessels. The gas streams contain aromatics and oxygenated hydrocarbons such as benzene, alcohols, and esters. Results indicated that suitable nutrition rates are 10, 100, and 10 g/m3.d, respectively, of milk powder, Urea-N, and K2HPO4-P, accompanied with a water spraying rate of 125 L/m3.d. Around 85% of VOCs in the influent gas with concentrations of 600-3,200 ppm (as CH4) could be removed under an average loading of 60 g VOC (as methane)/m3.h. A test indicated that odor intensity (expressed as dilution to threshold (D/T) ratio) of the influent gas could be reduced from around 7,330 to 73.

<p>One of the major cost factors in mechanical pulp production is the electrical energy input. Much of the research in this field has therefore been devoted to an understanding of the mechanisms in the refining process and, consequently, to find ways of reducing the electrical energy consumption. Shear and compression are probably the main types of fibre deformation occurring in refiners for collapsing and fibrillating the fibres into a suitable pulp. In current refiners, the repeated mechanical action of the bars on the fibres consumes large amounts of energy in a treatment of mechanical fibres that is almost random.</p><p>Fundamental studies of the deformation of wood have indicated that a combination of shearing and compression forces is highly beneficial in terms of fibre deformation with a low energy demand. Pure compression is able to permanently deform the fibre but requires a substantial amount of work, while pure shearing, although being much less energy demanding, does not lead to any permanent deformations. A more suitable application of the shear and compression forces on the wood fibres during the refining process could be a way to develop fibres at a lower energy demand. These ideas have been studied in this work trying to find new ways of saving energy in the mechanical pulping process.</p><p>The first paper in this thesis discusses the way of producing wood shavings and the introduction of shear/compression deformations in these, as well as the potential benefits of using them instead of wood chips as raw material for TMP production. With the shaving process, high deformations in the wood cells were achieved by the shear and compression forces. This led to energy savings of about 25% at a given tensile index, when compared to traditional chips. The quality of the pulp produced from wood shavings was found to be better than that of the pulp produced from wood chips, when it came to strength properties (except for tear index) and optical properties at comparable energy levels.</p><p>Another way of reducing energy consumption in refining involving a limited shear combined with compression forces for the mechanical treatment of both wood chips and coarse fibres was also studied. This work shows that such a kind of treatment resulted in a high degree of fibre collapse at low energy demands. The thick-walled transition fibres could even be permanently deformed. Furthermore, refining trials, utilising shear and compression pre-treated chips, showed that the strength properties, except for tear index, along with the optical properties of a TMP could be improved and the electrical energy consumed could be reduced by approx. 100 kWh/tonne, when compared to untreated chips.</p><p>The results from the pilot trials described in this work could be used as a starting point for further implementation in the industry, in order to identify the most efficient way of producing mechanical pulp with a lower consumption of electrical energy.</p>

<p>Reactive Black 5 and Procion Red MX 5B, an azo and anthraquinone dye repectively were decoulorized by mean of microorganisms growing on wood chips. The process consisted of three reactors, two anaerobic reactors and one aerobic reactor. The anaerobic process was used in order to make it possible to break the nitrogen bond of the azo group, (-N=N-) and the aerobic one to increase the possibility for the degradation of possible intermediates. After pumping wastewater through the system it was shown that mixtures or Reactive Black 5 and Procion Red MX 5B were efficiently decolourised at 50 mg/l as well as 200 mg/l of each of the dyes.</p><p><strong> </strong></p>

This research estimates nitrogen removal from stormwater runoff using a denitrifying bioretention system using the USEPA Storm Water Management Model Version 5 (SWMM-5). SWMM-5 has been used to help planners make better decisions since its development in 1971. A conventional bioretention system is a type of Low Impact Development (LID) technology, which designed without a media layer specifically for achieving nitrogen removal. More recently studies have showed that high TN removal efficiencies are possible when incorporating a denitrification media layer. These systems are known as denitrifying bioretention systems, or alternative bioretention systems. LID projects are currently being designed and developed in Sarasota County, Florida. These projects include a bioretention cell retrofit project on Venice East Blvd., in Venice, FL where thirteen bioretention cells will be developed. Although implementation of LID has already begun in southwest Florida, little research exists on whether these systems are effective at reducing non-point sources of nutrients. Therefore, the overall goal of this research project was to investigate the performance of a proposed bioretention system in Venice, FL to treat non-point sources of nitrogen from stormwater runoff. An alternative bioretention cell (ABC) model was designed to conceptually address water routing through a layered bioretention cell by separating the model into treatment layers- the layers where the nitrification and denitrification reactions are expected to occur within an alternative bioretention system (i.e., nitrification is assumed to occur in the sand media layer, and denitrification in the wood chip media layer). The bioretention cell configuration was based largely on the development plans provided by Sarasota County; however, the configuration incorporated the same electron donor media for denitrification that was used in a prior study (i.e., wood chips). Site-specific input parameters needed to calibrate the ABC model were obtained from laboratory analyses, the literature, and the US Geological website (websoilsurvey.nrcs.usda.gov). Using a mass balance approach, and the hydraulic residence time (HRT) values from the results of a previous study, first-order loss rate coefficients for both nitrification and denitrification (k1 and k2, respectively) were estimated. The rate coefficients were then used to develop treatment expression for nitrification and denitrification reactions. The treatment expressions were used to estimate the annual load reductions for TKN, NO3--N, and TN at the Venice East Blvd. bioretention retrofit site. Six storm events were simulated using a range of nitrogen concentrations. The simulation results showed minimal nitrification removal rates for storm events exceeding 1 inch, due to the planned bioretention system area being only 1% of the subcatchment area. A new ABC model was created (based on EPA bioretention cell sizing guidelines), to be 6% of the subcatchment area. Both systems were used to estimate TN removal efficiencies. The larger sized ABC model results showed average TKN, NO3--N and TN reductions of 84%, 96%; and 87%, respectively; these are comparable to results from similar studies. Results indicate that adequate nitrogen attenuation is achievable in the alternative bioretention system, if it is sized according to EPA sizing guidelines (5-7%).

Main memory system performance is crucial for high performance microprocessors. Even though the peak bandwidth of main memory systems has increased through improvements in the microarchitecture of Dynamic Random Access Memory (DRAM) chips, conventional on-chip memory systems of microprocessors do not fully take advantage of it. This results in underutilization of the DRAM system, in other words, many idle cycles on the DRAM data bus. The main reason for this is that conventional on-chip memory system designs do not fully take into account important DRAM characteristics. Therefore, the high bandwidth of DRAM-based main memory systems cannot be realized and exploited by the processor. This dissertation identifies three major performance-related characteristics that can significantly affect DRAM performance and makes a case for DRAM characteristic-aware on-chip memory system design. We show that on-chip memory resource management policies (such as prefetching, buffer, and cache policies) that are aware of these DRAM characteristics can significantly enhance entire system performance. The key idea of the proposed mechanisms is to send out to the DRAM system useful memory requests that can be serviced with low latency or in parallel with other requests rather than requests that are serviced with high latency or serially. Our evaluations demonstrate that each of the proposed DRAM-aware mechanisms significantly improves performance by increasing DRAM utilization for useful data. We also show that when employed together, the performance benefit of each mechanism is achieved additively: they work synergistically and significantly improve the overall system performance of both single-core and Chip MultiProcessor (CMP) systems. / text

This thesis employs computational and experimental methods to explore hotspot cooling and high heat flux removal from a 3-D stacked chip using thermoelectric and microfluidic devices. Stacked chips are expected to improve microelectronics performance, but present severe thermal management challenges. The thesis provides an assessment of both thermoelectric and microfluidic technologies and provides guidance for their implementation in the 3-D stacked chips. A detailed 3-D thermal model of a stacked electronic package with two dies and four ultrathin integrated TECs is developed to investigate the efficacy of TECs in hotspot cooling for 3-D technology. The numerical analysis suggests that TECs can be used for on demand cooling of hotspots in 3-D stacked chip architecture. A strong vertical coupling is observed between the top and bottom TECs and it is found that the bottom TECs can detrimentally heat the top hotspots. As a result, TECs need to be carefully placed inside the package to avoid such undesired heating. Thermal contact resistances between dies, inside the TEC module, and between the TEC and heat spreader are shown to significantly affect TEC performance. TECs are most effective for cooling localized hotspots, but microchannels are advantageous for cooling large background heat fluxes. In the present work, the results of heat transfer and pressure drop experiments in the microchannels with water as the working fluid are presented and compared to the previous microchannel experiments and CFD simulations. Heat removal rates of greater than 100 W/cm2 are demonstrated with these microchannels, with a pressure drop of 75 kPa or less. A novel empirical correlation modeling method is proposed, which uses finite element modeling to model conduction in the channel walls and substrate, coupled with an empirical correlation to determine the convection coefficient. This empirical correlation modeling method is compared to resistor network and CFD modeling. The proposed modeling method produced more accurate results than resistor network modeling, while solving 60% faster than a conjugate heat transfer model using CFD. The results of this work demonstrate that microchannels have the ability to remove high heat fluxes from microelectronic packages using water as a working fluid. Additionally, TECs can locally cool hotspots, but must be carefully placed to avoid undesired heating. Future work should focus on overcoming practical challenges including fabrication, cost, and reliability which are preventing these technologies from being fully leveraged.