Autothermal thermophilic aerobic digestion (ATAD) of sludge has been used to produce class A biosolids. With stringent EPA guidelines, more and more municipalities are looking to use this process for digestion of sludge. However the large polymer costs associated with dewatering these sludges has made the use of this technology unfavorable. Several studies have been conducted in the past which have looked into the mechanism leading to such a poor dewatering of sludge. Some of these studies have attributed the release of protein and polysaccharide during the high temperature digestion to be responsible for the poor dewatering. However the exact mechanism leading to the poor dewatering is still not totally clear. Laboratory scale studies were conducted to evaluate the mechanism leading to the poor dewatering of these sludges and also to be able to economically condition these sludges. ATAD sludge samples were collected from ATAD processing facilities in Ephrata, PA, Cranberry, PA, Titusville, FL and College Station, TX. The research included experiments evaluating the protein and polysaccharide concentrations in solution, cations and anions, iron and aluminum, zeta potential and capillary suction time. It was found that during digestion large amounts of protein and polysaccharide were released which were in the colloidal range, and the dewatering of each of these sludges became poorer as the amount of protein and polysaccharide in the solution increased. The release of protein and polysaccharide was related to the monovalent to divalent cation ratio and the iron and aluminum concentration in the sludge. Also during the digestion process, the pH of the sludge increased appreciably and the divalent cations precipitated out. The zeta potential of the ATAD digested sludge was also found to be positive. Different chemical coagulants were used to condition the sludge, but even with high polymer doses the dewatering of the sludge was not satisfactory. A combination of iron (or cationic polymer) followed by anionic polymer was found to improve the dewatering to a desired level. The use of this combination of sludge conditioning also provides an economical solution to the problem of dewatering. The role of iron in improving the dewatering of the sludges was found to be important, with the sludge dewatering being better for sludges with a high iron content. The combination of high pH, divalent cation precipitation, iron deficiency and biopolymer release all contribute to the poor dewatering of ATAD sludge. / Master of Science

Trimethylamine, (CH3)3N, (TMA), odors are often associated with limed and polymer conditioned sludges. This odor has a fishy smell and can be a nuisance to the community surrounding a wastewater treatment plant or land application site. Several factors are thought to determine the amount of TMA generated from limed biosolids. These are, the presence of cationic polymer, the polymer dose, the time between addition of polymer and lime stabilization, shear imparted on the sludge in the dewatering process and dewatered cake solids concentration. All of these were investigated in this study. The results showed that TMA could be generated from sludge that did not contain polymer but the concentrations were low compared to sludge conditioned with cationic polymer. As the polymer dose increased, the TMA increased. Shear also showed to play an important role for TMA production. In addition to higher shear increasing the polymer demand, shear in itself can increase TMA generation. However, the most important factor in generating TMA was the time between conditioning and liming. If this time was minimized, little TMA was produced, even at high polymer doses. Data also suggests that methanogens play an important role in the breakdown of TMA. / Master of Science

The costs of cleaning fine coal are substantially higher than those of cleaning coarse coal. Therefore, many many coal companies in the U.S. choose to discard fine coal (150 micron x 0) by means of 6-inch diameter hydrocyclones. The cyclone overflows are stored in fine coal impoundments, which create environmental concerns and represent loss of valuable national resources. The major component of the high costs of cleaning fine coal is associated with the difficulty in fine coal dewatering. Therefore, the availability of efficient of fine coal dewatering methods will greatly benefit companies. In the present study, three different novel dewatering aids have been tested. These include Reagents W (RW), Reagent U (RU), and Reagent V (RV). These reagents are designed to increase the contact angles of the coal samples to be dewatered, which should help decrease the Laplace pressure of the water trapped in filter cake and, hence, increase dewatering rate. They were tested on i) the fresh coal samples from Consolidation Coal Corporation's Buchanan Preparation Plant, ii) a composite drill core sample from the Smith Branch Impoundment, Pinnacle Mine Mining Company, and iii) a blend of coals from the Smith Branch Impoundment, thickener underflow, and thickener feed. The coal samples were used initially for laboratory-scale tests using a 2.5-inch diameter Buchner vacuum filter. The results showed that the use of the novel dewatering aids can reduce the cake moisture up to 50% over what can be achieved without using any dewatering aid. The use of the dewatering aids also increased the kinetics of dewatering by up to 6 times, as measured by cake formation times. On the basis of the laboratory test results, pilot-scale continuous vacuum filtration tests were conducted using a 2-feet diameter Peterson vacuum disc filter. The cake moistures obtained in the pilot-scale test work were similar to those obtained in the laboratory tests, while the fast dewatering kinetics observed in the laboratory tests was manifested as higher throughput. It was found that high-shear agitation is essential for achieving low cake moistures and high throughput. / Master of Science

Les polymères hydrosolubles sont utilisés dans diverses industries pour permettre la floculation, soit une séparation solide-liquide de particules présentes en suspension colloïdale. Afin de réduire les impacts environnementaux de l’exploitation des sables bitumineux en Alberta, l’industrie est à la recherche de nouveaux moyens et procédés pour traiter les résidus miniers permettant de séparer les matières solides et de récupérer l’eau. L’objectif des travaux présentés est d’améliorer la floculation, la densification et la déshydratation de ces résidus miniers aqueux par de nouveaux polymères synthétiques. Des homopolymères d’acrylamide de différentes masses molaires ont été synthétisés pour étudier l’influence de la masse molaire sur l’efficacité de floculation. Le taux initial de sédimentation (TIS) est le paramètre qui fut utilisé afin de comparer l’efficacité de floculation des différents polymères. Il a été possible de confirmer l’importance de la masse molaire sur l’efficacité de floculation et de déterminer une masse molaire minimale d’environ 6 MDa pour des polyacrylamides, afin d’obtenir l’efficacité de floculation maximale de suspensions colloïdales principalement composées de kaolin. Afin d’étudier l’effet des charges sur l’efficacité de floculation, des polymères anioniques et cationiques ont été synthétisés. Une série de copolymères d’acrylamide et d’acide acrylique ont été synthétisés comme polymères anioniques et deux séries de copolymères ont été synthétisés comme polymères cationiques, soit des copolymères d’acrylamide et de chlorure de diallyldiméthylammonium et des copolymères de 4-vinyl pyridine et de 1-méthyl-4-vinyl pyridinium. Il a été démontré que les charges anioniques des polymères avaient peu d’influence sur l’efficacité de floculation et que leur comportement en présence de sels était différent de ce que prévoyait la littérature. Il a aussi été démontré que les charges cationiques des polymères n’améliorent pas l’efficacité de floculation. Par la suite, des séries de copolymères amphiphiles, avec des monomères d’acrylamide, de N-alkylacrylamides et d’acrylonitrile, ont été synthétisés, pour étudier l’effet du caractère amphiphile sur la déshydratation des résidus miniers. Le pourcentage de déshydratation nette est le paramètre qui fut utilisé afin de comparer l’efficacité de déshydratation des différents polymères. Il a été possible de développer des copolymères amphiphiles qui améliorent l’efficacité de déshydratation par rapport à des homopolymères d’acrylamide. Il ne fut pas possible de déterminer une tendance entre la balance hydrophile/hydrophobe des copolymères amphiphiles et l’efficacité de déshydratation. / Water soluble polymers are extensively used in industry to achieve solid-liquid separations of particles in colloidal suspensions. In a way to reduce the environmental footprint of the mining exploitation, the oil sands industry is searching for new methods to treat tailings resulting from the extraction processes, by separating the solids and recycling the water. The objective of this work is to improve the flocculation and dewatering efficiency of the water-based tailings through the use of new synthetic polymers. Acrylamide homopolymers of different molecular weights were synthetized to study the effect of molecular weight on flocculation efficiency. Initial settling rate (ISR) was the parameter measured to characterize and compare the flocculation efficiencies. The important effect of polymer molecular weight on the flocculation efficiency was confirmed. The minimum molecular weight of polyacrylamide for optimal flocculation efficiency of kaolin colloidal suspensions has been determined to be around 6.8 MDa. To study the effect of charge on flocculation efficiency, anionic and cationic copolymers were synthetized. Copolymers of acrylamide and acrylic acid have been synthetized to study the effect of anionic charge, whereas copolymers of acrylamide and diallyldimethylammonium chloride and copolymers of 4-vinyl pyridine and 1-methyl-4-vinyl pyridinium have been synthetized to study the effect of cationic charge. Anionic copolymers have shown limited effect on the flocculation efficiency and their behaviour in salt solution was revealed to be different than expected from the literature. Cationic copolymers have shown no improvement in the flocculation efficiency. Amphiphilic copolymers were synthetized with acrylamide, N-alkylacrylamides and acrylonitrile monomers to study the effect of amphiphilicity on the dewatering efficiency of tailings. The net water release parameter was measured to compare the dewatering efficiency of the polymers. Amphiphilic copolymers that improve tailings’ dewatering, compared to polyacrylamide, were developed. Thus far, it was not possible to define a trend between hydrophilic/hydrophobic balance and dewatering efficiency of the copolymers.

The removal of water is an integral part of tissue paper production. Through air drying (TAD) is used for water removal when producing premium tissue grade products, however, at the price of higher energy demand. A better understanding of TAD may therefore lower the energy demand. The objective was to investigate the influence of formation, pulp type and grammage on non-uniform drying and air flow through sheets. A laboratory method, based on infrared thermography, was used to determine drying time and area-specific and mass-specific drying rates. Air flow rate and pressure drop were used to determine flow resistance and modified permeability. Pulp type had a large influence on the air flow through the sheet. Modified permeability, i.e. the material property describing the air flow through the fibre network, was strongly dependent on grammage for lower grammages, while it approached a constant value for higher grammages. In contrast to that, mass-specific drying rates were similar for the different pulp types at lower grammages, but proved to be grammage-dependent for higher grammages. Formation did not influence the drying speed to any large extent. The results illustrate that industrial TAD processes operate under very special process conditions due to the low grammage sheets.

O método de desaguamento por leitos de drenagem foi desenvolvido por Cordeiro a partir do ano de 1993 (CORDEIRO, 2001) para o desaguamento de lodos de Estações de Tratamento de Água. A sua aplicação para lodos de lagoas de estabilização de esgotos foi feita por Fontana et al. (2007). Este trabalho teve por objetivo avaliar a utilização de leitos de drenagem no desaguamento de lodos produzidos em reatores UASB. Para tanto foram realizados ensaios em laboratório, utilizando testes do tempo de drenagem, para avaliar a influência de diferentes doses e tipos de polímeros no desaguamento do lodo. Alguns geotêxteis foram utilizados como meio filtrante nos funis de Buchner e também avaliados pelo teste do tempo de drenagem. Após escolhidas a manta e o polímero que apresentaram os melhores resultados em laboratório, foram desenvolvidos ensaios em escala piloto, com a utilização de três unidades cobertas de leitos de drenagem, cada um com dimensões de 1,58 m x 1,09 m por 0,5 m de altura. Para a avaliação do efeito das diferentes doses de polímero em escala piloto, foram utilizadas doses de polímero de 0 a 8 g/kg de sólidos totais (peso seco) e mantida a taxa de aplicação de sólidos em 15 kgST/m².ciclo (a concentração de sólidos no lodo foi de aproximadamente 27 g/L). Os resultados indicaram que com doses de polímero =2 g/kgST (peso seco) obtinha-se teor de sólidos no lodo de cerca de 13% após 1 dia e 20% após 10 a 15 dias. Para se atingir teor de sólidos de 25 a 30% o período de secagem necessário foi de cerca de 30 dias. Embora que mesmo sem a aplicação de polímeros o comportamento do lodo fosse semelhante ao de lodos condicionados com polímero, em relação à evolução do teor de sólidos em função dos períodos de secagem, observou-se certa dificuldade na remoção do lodo desaguado e principalmente na limpeza das mantas geotêxteis. Para avaliar diferentes taxas de aplicação superficial de sólidos, foram ensaiadas taxas entre 9 e 22 kgST/m².ciclo. A evolução do teor de sólidos, ao longo do período de secagem dos 3 ensaios realizados, indicou que taxas mais altas de aplicação de sólidos não diminuem as velocidades de secagem, sugerindo que, inclusive, taxas mais altas poderiam ser ensaiadas. / The method of dewatering sludge through Drainage Beds was originally developed in 1993 by Cordeiro (CORDEIRO, 2001) with sludge from Water Treatment Plants. Fontana et al. (2007) used sludge from wastewater stabilization ponds with positive results. The purpose of this research is the evaluation of the drainage bed method to dewater sludge from UASB reactors. Several laboratory trials were performed, measuring drainage times to assess the influence of different polymer types and doses on sludge dewatering. Few geotextiles were used as filter on the drainage time test to evaluate their performance. Once the polymer and the geotextile that best performed in the laboratory were chosen, several pilot experiments were performed with the use of three covered units of drainage beds, each measuring 1.58m x 1.09m (width) x 0.5m (height). For the evaluation of different polymer conditioning doses on a pilot scale, doses from 0 to 8 g/kg of total solids (dry weight) were used and the applied rate of solids kept at 15 kgTS/m².cycle (the concentration of solids in the sludge was of approximately 27 g/L). Results indicated that with the use of polymer doses =2 g/kgTS (dry weight), approximately 13% of total solids in the sludge was observed after one day, which increased to approximately 20% after 15 days. To reach 25% to 30% of total solids in the sludge, the drying time required was circa 30 days. Even without the application of polymers, the behavior of sludge in terms of total solids during the drying period was similar to the sludge conditioned with polymers. Although, with the unconditioned sludge, some difficulty to remove the dewatered sludge cake was observed, mainly in cleaning of the geotextile sleeves. In order to evaluate different application rates of solids, the pilot experiments included rates between 9 and 22 kgTS/m².cycle. The behavior of the total solids in the cake during the drying period of the three experiments suggested that the higher rates of application of solids does not reduce the drying speed, indicating that higher rates can be targeted in future research projects.

Ce travail s'intéresse a` l'identification des mécanismes physiques en jeu lors de la déshydratation assistée thermiquement. Une cellule de filtration/compression a été instrumentée avec des capteurs de pression liquide. Ces mesures permettent de suivre la formation du gâteau de filtration, sa consolidation puis les évolutions thermomécaniques induites par l’apport de chaleur. Sous l'effet du chauffage, elles montrent l'apparition d’un gradient de pression liquide, qui induit un écoulement additionnel. Un modèle mathématique est ensuite proposé. Des caractérisations en cellule de compression/perméabilité sont utilisées pour de´terminer les lois d'évolution des propriétés du milieu poreux. Le modèle permet de retrouver les évolutions des grandeurs macroscopiques et locales mais pas les cinétiques. Ceci a été attribué au modèle de déformation du milieu poreux choisi. / In the scope of thermally assisted mechanical dewatering process, this work focuses on the identification of physical mechanisms involved in the thermally assisted mechanical dewatering. Operating conditions ensure that the water is expelled in liquid phase. An experimental study on talc and cellulose saturated suspensions highlights the gains in terms of final dry solid contend involved by the thermal intensification. The filtrationcompression test cell is instrumented with pore liquid sensors along the cake thickness that allows to measures the pressure of the interstitial liquid phase. Obtained data highlight an increase of the liquid pressure in the heated side of the cake during thermally assisted mechanical dewatering. Indeed, as the temperature increases the water density decrease. As the cake consolidation restricts the flow a liquid pressure gradient reappears inside the cake. As the temperatures on the filter side of the cake increase, the thermally induced liquid pressure gradient vanishes with an additional filtrate outflow. In order to measure the porous media properties a compression-permeability cell has been build. This apparatus allows permeability measurement to be conducted for different temperature and loading on the porous media. A physical model including the thermal pressurization has been implemented in COMSOL Multiphysics in order to simulate the process. The model confirms the thermal pressurization occurring during thermally assisted mechanical dewatering, but because of deviation in the calculated mechanical behavior and temperature of the porous media, the model can’t depict the experimental additional filtrate outflow.

Mit der Intensivierung der landwirtschaftlichen Produktion gewinnen Pumpstationen für die Be- und Entwässerung landwirtschaftlicher Nutzflächen zunehmend an Bedeutung. Zur Beseitigung schädlicher Bodennässe werden offene Gräben oder Dränrohrleitungen angelegt, welche das Wasser bei nicht vorhandener Vorflut einem Entwässerungsschöpfwerk zuleiten. Dieses Schöpfwerk fördert das Wasser aus einem Speicherraum (Mahlbusen) in den Vorfluter. In der DDR sind zahlreiche derartige Entwässerungsschöpfwerke vorhanden. (...)

Med ett växande energibehov i världen, sinande energikällor i form av fossila bränslen och en miljö som vi under en längre tid har förorenat behövs det nya energiformer som är mer långsiktiga och framförallt miljövänliga. En sådan energiform är biogas. Biogasprocessen är dock inte helt optimerad. Flera av de substrat som används idag tar lång tid att röta och bryts bara ner till viss del i processen eller innehåller onödigt mycket vatten, vilket ger höga transportkostnader. Med syfte att göra biogasprocessen mer ekonomisk lönsam utvärderas i denna rapport på uppdrag från E.ON några olika förbehandlingstekniker: Ångexplosion, extrusion, avvattning och kalkbehandling. Förhoppningen är att dessa ska kunna öka lönsamheten för storskalig biogasproduktion och kanske möjliggöra biogasproduktion från tidigare obrukbara substrat som fjädrar och halm.  För att jämföra och utvärdera förbehandlingsteknikerna utfördes batchrötningsförsök i 330 ml flaskor med obehandlade och förbehandlade substrat. De flesta förbehandle substraten gav snabbare nedbrytning och några gav även högre metanutbyte än de obehandlade. Fjädrar och halm, som från början hade ett lågt utbyte, påverkades mest av förbehandlingen. Ångexploderade fjädrar gav efter 44 dagars rötning 141% högre metanutbyte och extruderad halm gav 22% högre metanutbyte än obehandlad.  För ekonomiska beräkningarna användes en referensanläggning med en förutbestämd substratmix: 12500 ton majs och 11500 ton hästgödsel. Att tillgå för referensanläggningen finns dessutom fjädrar. Cambis THP-anläggning för ångexplosion visade sig vara alldeles för dyr för referensanläggningen. En THP-anläggning kräver en större biogasanläggning där en större mängd svårnedbrytbara substrat rötas för att bli lönsam. En extruder skulle kunna vara lönsam för för refernsanläggningen om hästgödseln som de har tillgång till innehåller halm som strömaterial. En investering i en extruder bara för att förbehandla majsensilage visade sig inte lönsam.  Avvattning av gödsel gav signifikant lägre utbyte av biogas per torrvikt men signifikant högre utbyte per våtvikt. Avvattningsutrustningen från Splitvision, som testades, var för dyr för att bli lönsam. Först när gården låg 4 mil från biogasanläggningen blev det billigare att avvattna gödsel och transportera den jämfört med att transportera den obehandlad. Andra avvattningsutrustningar i studien var billigare i drift så det finns möjligheter att tekniken kan bli lönsam med någon av dessa. / The world needs new energy sources that are durable for long time and which not affect the environment negatively. Biogas fulfills those demands. The biogas process is however not completely optimized. Several of the substrates used today for biogas production are slowly degraded and only partly digested in the process. Other substrates consist of unnecessarily much water which makes transportation costly. To optimize the process and make the biogas process more profitable, several pretreatment techniques are evaluated by direction of E.ON in this report: steam explosion, extrusion, lime treatment and dewatering. The hope is that one of those could increase the profitability and hopefully also enable substrates that not are working today like feathers and straw. To compare and evaluate the different pretreatment batch digester, experiments were carried out during 31-44 days for untreated and pretreated substrates. Most pretreated substrates were faster degraded than untreated and some also gave a higher methane yield. Chicken waste feathers and wheat straw, which had low methane yields untreated, were affected most by pretreatment. Steam exploded feathers gave after 44 days of digestion 141% higher methane yield and extruded straw gave 22% higher methane yield than untreated samples of the same substrate. A reference plant with a substrate mixture of 12500 tonnes of maize silage and 11500 tons of horsemanure annually was used to make economical calculations. Additionally, chicken waste feathers waste could be included. Obtainable for the reference plant were also chicken waste feathers. Steam explosion appeared to be too expensive for a plant in the size of the reference plant. Its large capacity could probably make it profitable for a much larger biogas plant running on a lot of hard digestible substrates. An extruder could be a profitable investment for the reference plant if the plant gets horse manure with straw as bedding material. To just use the extruder to pretreat maize silage could not make the investment profitable. Dewatering of manure gave significantly lower methane yield per dry weight but significantly higher methane yield per wet weight. The increase in methane yield per wet weight makes the substrate better for transportation. The dewatering equipment from Splitvision tried in this study had too high operational costs and was too expensive to make dewatering particularly profitable. Only when the farm was situated farther away than 40km from the biogas plant it was cheaper to dewater the manure before transport than to transport the manure without any pretreatment. Other dewatering equipments evaluated in this study had much lower operational costs and among those an equipment that makes dewatering profitable might therefore be found. The world needs new energy sources that are durable for long time and which not affect the environment negatively. Biogas fulfills those demands. The biogas process is however not completely optimized. Several of the substrates used today for biogas production are slowly degraded and only partly digested in the process. Other substrates consist of unnecessarily much water which makes transportation costly. To optimize the process and make the biogas process more profitable, several pretreatment techniques are evaluated by direction of E.ON in this report: steam explosion, extrusion, lime treatment and dewatering. The hope is that one of those could increase the profitability and hopefully also enable substrates that not are working today like feathers and straw. To compare and evaluate the different pretreatment batch digester, experiments were carried out during 31-44 days for untreated and pretreated substrates. Most pretreated substrates were faster degraded than untreated and some also gave a higher methane yield. Chicken waste feathers and wheat straw, which had low methane yields untreated, were affected most by pretreatment. Steam exploded feathers gave after 44 days of digestion 141% higher methane yield and extruded straw gave 22% higher methane yield than untreated samples of the same substrate. A reference plant with a substrate mixture of 12500 tonnes of maize silage and 11500 tons of horsemanure annually was used to make economical calculations. Additionally, chicken waste feathers waste could be included. Obtainable for the reference plant were also chicken waste feathers. Steam explosion appeared to be too expensive for a plant in the size of the reference plant. Its large capacity could probably make it profitable for a much larger biogas plant running on a lot of hard digestible substrates. An extruder could be a profitable investment for the reference plant if the plant gets horse manure with straw as bedding material. To just use the extruder to pretreat maize silage could not make the investment profitable. Dewatering of manure gave significantly lower methane yield per dry weight but significantly higher methane yield per wet weight. The increase in methane yield per wet weight makes the substrate better for transportation. The dewatering equipment from Splitvision tried in this study had too high operational costs and was too expensive to make dewatering particularly profitable. Only when the farm was situated farther away than 40km from the biogas plant it was cheaper to dewater the manure before transport than to transport the manure without any pretreatment. Other dewatering equipments evaluated in this study had much lower operational costs and among those an equipment that makes dewatering profitable might therefore be found.

Mature fine tailings (MFT), as a mixture of residual bitumen, sand, silt, fine clay particles and water, are a byproduct of oil sands extraction. The large volume, and poor consolidation and water release ability of MFT have been causing significant economic and environmental concerns. Therefore, several studies have been implemented on finding innovative dewatering/disposal techniques. As a result, different methods have been introduced and tested at a laboratory or a field scale, yet very few of these are commercially used in the oil sands industries. Despite the extensive research, an optimal solution has not been found due to the lack of technical or economic feasibility. In the present study, a novel approach that consists of the rapid dewatering of MFT by using a super absorbent polymer (SAP) to produce dense MFT is proposed. A comprehensive laboratory investigation on the geotechnical characteristics and behavior before and after treatment of MFT is conducted. The effects of SAP based dewatering and freeze/thaw cycles on the undrained shear strength of dewatered MFT by using a vane shear apparatus are studied. Furthermore, the ability of recycled SAP to dewater and densify MFT is assessed. Finally, this study provides the results of consolidation and hydraulic conductivity testing to evaluate the void ratio versus effective stress and hydraulic conductivity of MFT. The effects on the behavior and characteristics of MFT after amendment with usage of recycled SAP are also investigated. The results indicate that SAP has the ability to significantly dewater, densify and increase the undrained shear strength of MFT. Furthermore, when subjected to freeze/thaw cycles, the MFT dewatered with SAP shows an additional increase in strength and solid content. It is also found to be possible to regenerate the polymer (still within sachets) through light thermal drying, and the regenerated SAP can still significantly dewater and thus increase the shear strength and solid content of the MFT. In addition, the obtained high solid content affects and improves the compressibility of the material, thus resulting in low initial void ratios. On the other hand, low hydraulic permeability that is derived from low initial void ratios and consolidation is improved by the freeze/thaw process due to the interconnected voids created during the freezing process.