Die in dieser Arbeit vorgestellten Simulationen aufsteigender fluider Partikel wurden mit dem CFD-Programm FS3D durchgeführt, welches auf der Volume-of-Fluid (VoF) Methode basiert. Die Validierung des Codes erfolgt durch Vergleich der numerischen Lösungen für schleichende Strömungen mit analytischen Lösungen, wobei eine gute Übereinstimmung festgestellt wird. Im ersten Teil der Dissertation werden Simulationen für den freien Aufstieg von Öltropfen in Wasser mit experimentellen Beobachtungen hinsichtlich der Aufstiegsgeschwindigkeit, der Tropfenform und der Bewegungsbahn verglichen. Die Aufstiegsgeschwindigkeiten und Widerstandsbeiwerte sind vergleichbar, die simulierten Tropfen sind jedoch deutlich flacher. Dieser Unterschied kann durch Verunreinigungen der Grenzfläche im Experiment verursacht sein. Der Übergang von einem gradlinigen Aufstieg zu zickzack-förmigen Aufstiegsbahnen kann mit Hilfe der Simulationen auf Instabilitäten im Nachlauf der Blasen zurückgeführt werden, die zu einer periodischen Wirbelablösung führen. Im zweiten Teil der Dissertation wird der Aufstieg von Blasen in linearen Scherströmungen untersucht. Steigen die Blasen in einer vertikalen Scherströmung auf, so beobachtet man eine seitliche Migration. Diese seitliche Migration der Blasen wird durch die sogenannte Liftkraft verursacht, deren Vorzeichen und Betrag von der Blasengröße und den Stoffeigenschaften der Flüssigkeit abhängt. Die Simulationen zeigen, daß das Vorzeichen der Liftkraft für eher sphärische Blasen durch den Bernoulli-Effekt erklärt werden kann. An stark deformierten Blasen hingegen wirkt die Liftkraft in umgekehrter Richtung. Dieses Phänomen tritt auch in den Simulationen auf. Verschiedene Hypothesen für die Ursache dieses Phänomens werden überprüft. Die bekannteste experimentelle Korrelation für die Liftkraft von Tomiyama u.a. (2002) wird durch Simulation von realen Flüssigkeiten mit bekannten Stoffeigenschaften wie auch von Modellfluiden mit willkürlichen Stoffeigenschaften validiert und weitgehend bestätigt. Die Lift-Korrelation hat demnach hinsichtlich der Stoffeigenschaften der Flüssigkeit einen größeren Geltungsbereich, als bisher experimentell überprüft wurde. The simulations presented in this thesis were performed with the CFD code FS3D which is based on the Volume of Fluid method. The code is validated using analytical solutions for creeping flows and a good agreement is observed between simulation and analytical solution. In the first part of the thesis, the free rise of oil drops in water is simulated and compared with experimental observations. The results show that the rising velocities and the drag coefficients are similar in both cases, but the simulated drops are flatter (more oblate). This difference may be caused by impurities of the particle surface (surfactants) in the experiments. The simulations show that the transition from rectilinear to periodic trajectories is caused by instabilities in the wake, which lead to a periodic vortex shedding. In the second part of the thesis, the rise of bubbles in linear shear flows is investigated. If bubbles rise in a vertical shear flow, a lateral migration can be observed. This migration is caused by the so called lift force. Sign and magnitude of the lift force depend on the size of the bubble and the material properties of the liquid. The simulation results show that the sign of the lift force on spherical bubbles can be explained by the Bernoulli effect. However, the lift force on more distorted bubbles acts in the opposite direction. This phenomenon can also be observed in the simulation. In this work several hypotheses for the reason of this phenomenon are checked. Furthermore, most common correlation for the lift force (developed by Tomiyama et al. in 2002) is validated for fluids of known material and model fluids with arbitrary material data. The correlation is valid in a wider range of fluid material properties than proved experimentally up to now.

Due to higher standards of living around the world, greater industries and larger infrastructures causes an increase of the global energy consumption. This harvest of energy puts a great stress on the global environment. With this development, it becomes increasingly important to utilize energy resources in the best possible way. Fans are components that are often used in the industry and in households. A common problem is that the fan is oversized. An oversized fan causes an excessive flow, which has to be adjusted in order to achieve the correct flow. This results in larger energy usage than the use of a properly sized fan. When designing a ventilation system calculations have to be made in order to determine the total pressure loss of the system. A series of simplifications are applied when using theoretical calculations. The total pressure loss of the system is assumed to be the sum of the pressure loss of each component in the system. This simplification ignores the separation distance that exists between each component. In reality, when air passes through the components, swirls emerge and a distortion of the velocity profile occurs. This causes large pressure losses due to friction losses occurring between the fluid and the pipe wall. The recommendation given in HVAC installations states that two 90 degree elbows should not be placed closer to each other than 6D (D representing the hydraulic diameter of the pipe) to thereby prevent large pressure drops. This dissertation will address the following questions: The recommendation in HVAC installations states that two 90 degree elbows should not be placed closer to each other than 6D (D representing the hydraulic diameter of the pipe) to thereby prevent large pressure drops. Does this recommendation conform with the empirical data obtained from conducted experiments?  What is the relation between the pressure drop and the separation distance between two 90 degree elbows? In this dissertation a series of experiments are conducted where pressure loss measurements are made within a circular ventilation duct with two integrated 90 degree elbows. Pressure loss measurements within a U-shaped piping system are made at five different fluid velocities each at 11 different separation distances between the two 90 degree elbows. By analysis of the obtained empirical data and by comparing it to the recommendation no results were found to validate this statement.

Seit mehr als einem Jahrhundert ist ein wachsendes wissenschaftliches Interesse an Tropfen und den Vorgängen bei deren Aufprall auf die verschiedensten Substrate zu verzeichnen, wohl auch durch die Fotografien von Worthington (1908) ausgelöst. Inzwischen wurden viele Erkenntnisse durch große Fortschritte bei der experimentellen Untersuchung (z.B. mittels Hochgeschwindigkeitsaufnahmen) und durch theoretische und computergestützte Untersuchung (z.B. durch skalenfreie und numerische Modellierung) gewonnen. Trotzdem bleibt durch die Vielfältigkeit und Komplexität der Phänomene während des Tropfenaufpralls sowie wegen der ständig erweiterten Anwendungsbereiche dieses Forschungsgebiet hochaktuell. Insbesondere sehr kleine und gleichzeitig sehr schnelle Tropfen (Tropfendurchmesser 10µm bis 100µm, Tropfengeschwindigkeit 10m/s bis 100m/s) kommen in vielen modernen Anwendungen vor (z.B. Verbrennungsmotoren, Tintenstrahldrucker, Reinigung von Oberflächen). In diesem wichtigen, aber für Untersuchungen schwer zugänglichen Parameterbereich gibt es immer noch offene Fragen. Die vorliegende Arbeit beschäftigt sich daher mit diesen schnellen Mikrotropfen in Bezug auf ihre Herstellung und den Aufprallvorgang auf ein festes, trockenes oder benetztes Substrat. Zunächst wird eine Methode zur Erzeugung eines Hochgeschwindigkeitssprays realisiert, welche auf dem durch Ultraschall gesteuerten Plateau-Rayleigh-Zerfall eines Flüssigkeitsstrahls beruht. Sie ermöglicht es, sowohl Tropfengröße als auch –geschwindigkeit präzise und mit hoher Reproduzierbarkeit über den gesamten oben angegebenen Parameterbereich einzustellen. Durch gezielte Manipulation eines Einzeltropfens durch elektrische Felder wird anschließend der Tropfenaufprall auf Substrate unterschiedlicher Benetzbarkeit mit sehr hoher zeitlicher Auflösung (ca. 100 Mio. Bilder pro Sekunde) bei gleichzeitig hoher räumlicher Auflösung (< 1µm) untersucht. Es zeigt sich, dass bekannte Modelle für langsamere und größere Tropfen im Millimeterbereich auch für schnelle Mikrotropfen Gültigkeit behalten. Somit ist bei gleichen dimensionslosen Kennzahlen (z.B. Reynolds-Zahl, Weber-Zahl, Ohnesorge-Zahl) eine skalenfreie Beschreibung des Tropfenaufpralls möglich. Schließlich wird die Methode zur Tropfenerzeugung auf einen für Anwendungen in der Reinigung relevanten Fall übertragen. Hierbei geht es um den Tropfenaufprall auf ein von einem Flüssigkeitsfilm überströmten Substrat. Es werden die während des Auftreffvorgangs auftretenden Geschwindigkeiten in der sich bildenden radialen Strömung in Abhängigkeit von verschiedenen Prozessparametern bestimmt. Aus den Ergebnissen lassen sich Aussagen über die zu erwartende Reinigungswirkung durch derartige Tropfen und den Einfluss der Prozessparameter treffen.

This thesis describes a new Laser-Assisted Spray Pyrolysis technique developed to grow nanoparticle coatings with controllable particle sizes. In this method, droplets of a precursor formed by a nebulizer are injected into a growth chamber using SF6 carrier gas. An experimental study and a computational model to investigate the particle size dependence on various growth parameters have been carried out. The results show that heating of 1.5and#61549;m droplets of metalorganic precursor in a carrier gas using a CO2 laser resulted in the formation of TiC and Fe3O4 particles with diameters in the range of 50-60nm. Also the results show that by reducing the concentration of the metal organic precursor the diameter of the deposited particles can be reduced.

Ion contaminants from Printed Circuit Board (PCB) assembly processes pose a high reliability risk because they result in damaged circuits. Therefore, it is essential to understand the level of ionic species on the electronic circuitry as well as the reliability risks caused by these contaminants. There are a number of approaches available in the industry to assess the reliability risks ; for example, the water drop test (WDT) is one of the techniques used to determine the propensity of an ionic contaminant to cause electrical short failures by dendrite formation. The objective of this research is to determine the time to cause the failures, known as electrochemical migration (ECM) failures. A test vehicle was developed for the WDT to obtain the time to cause ECM failure in presence of different anions. The time to form dendritic bridges that cause short circuits was determined as a function of the different anions and the spacings between PCB pads. The experimental method involved dispensing aqueous solutions containing common inorganic and organic acid anions onto test vehicles, applying electrical bias voltages and measuring the time to form dendrites. Specially designed test structures cells were created to contain the test solutions. At each of the test cells, a cavity held the solution and constant current was applied through different metal geometries. To be representative of popular board finishes, test vehicle boards incorporated both Sn-Pb Hot Air Soldering Level (HASL) and Pb free HASL surface finishes.

In aerospace industry and other major mechanical industry systems, engineering components that are subjected to cyclic loads often lead to progressive crack growth that eventually results in struc-tural fracture. The damage tolerance design which is based on the assumption of pre-existed flaws in a structure is an important approach in aircraft industry since it is impossible to have flaw-free manufactured components.In this thesis work, an evaluation of crack propagation models was carried out. Fatigue crack growth threshold and fatigue crack growth rate models were evaluated. A method to present ex-perimental data available was developed to evaluate uncertainties in fatigue life models for more accurate predictions. Currently, a software that is used for predicting crack propagation life is NASGRO. The study has been made for two types of materials: a nickel-iron-based alloy (Inconel 718 forging) and titanium alloys (Ti 6-4 both forging and casting).A threshold model is in the normal case developed for each temperature. A method to model fatigue threshold (ΔKth) has been suggested by assuming temperature independence of ΔKth. In this method, a new threshold model was created by making use of an A/P (Actual/Predicted) plot so that all measured threshold values are on the conservative side of the minimum model. With this method, an understanding of fatigue threshold model was improved over the other method due to the possibilities to model ΔKth with average and minimum threshold values for each load ratio (ΔKth, R).Moreover, a method to investigate which set of parameters that best represent the crack growth behaviour has been suggested. In this method the best set of parameters were chosen to be the set of parameters giving the best fit to the available (da/dN, ΔK) points. The comparison between this method and the method with the set of parameters that give minimum scatter in the A/P values was done.Crack growth rate da/dN log curves were plotted as function of stress intensity range ΔK for R-ratio values ranging from -2 to 0.9 for the two different methods. A distinctive difference between the two methods was observed in Paris region at high temperatures (5500C-6500C) which becomes more obvious at lower R-ratios. Predicting crack propagation rate model with set of parameters giving minimum standard deviation in da/dN points was shown to be less conservative than that of parameter sets giving lowest scatter in A/P. Using both evaluation methods, da/dN versus ΔK plots of Inconel718forging were compared to da/dN (ΔK) plots for the pre-existing data at 5500C for R-ratios ranging from 0 to 0.8. An overall R-ratio influence was observed throughout for both ΔKth and da/dN.

A study of the condensation of hydrocarbons and zeotropic hydrocarbon mixtures in smooth horizontal tubes was conducted. Measurements of condensation heat transfer coefficients and frictional pressure drop were taken over a range of mass fluxes (G = 150 – 450 kg m-2 s-1), a range of reduced pressures (Pr = 0.25 - 0.95), for two tube diameters (D = 7.75 and 14.45 mm), several working fluid-to-coolant temperature differences (ΔTLM = 3 – 14°C) and temperature glides (ΔTGlide) between 7 - 14°C. The wide range of conditions investigated in this study provides considerable insight on the transport phenomena influencing condensation in pure fluids and their mixtures. The trends in heat transfer coefficient and frictional pressure gradient are discussed and compared with the predictions of correlations from the literature. The results of the experiments, combined with previous flow visualization studies on hydrocarbons, were used to develop physically consistent heat transfer and frictional pressure gradient models that are applicable to pure fluids and zeotropic mixtures. A framework was developed for zeotropic mixture condensation that recommends a specific modeling approach based on the observed trends in the heat transfer coefficient and the points of deviations from pure fluid trends. The documentation of the condensation heat transfer and pressure drop behavior of environmentally friendly refrigerants, and the development of accurate correlations, will facilitate their widespread introduction as a working fluid for refrigeration cycles. Furthermore, the accurate pure fluid models, which serve as a baseline case for zeotropic mixture modeling, yield more effective predictions of zeotropic mixture condensation, which will lead to increased efficiencies of chemical processing plants.

Mandarin Chinese is said to be a radical pro-drop language, in the sense that verbal arguments in this language can be dropped rather freely. However, in this dissertation, I show that the omission of arguments in Mandarin Chinese is in fact constrained by various conditions. First, I demonstrate that the availability of a discourse topic is insufficient to license empty categories in Mandarin Chinese by showing that subject and object positions cannot be left empty at random. Some empty subject positions are neither true instances of nominal ellipsis nor variables bound by discourse topics; instead, they are a side effect of verb or vP movement followed by TP-ellipsis. Next, I address the issue of when objects can be "dropped" in Mandarin Chinese. I argue that structural parallelism built on verbal identity between sentences plays an important role in licensing `objectless' sentences. I propose that the mechanism responsible for the creation of such sentences is V-stranding VP-ellipsis rather than argument ellipsis. In the last part of this dissertation, I show that, although we cannot rely on the strength of discourse alone to account for empty categories, the concept of topic-hood is nevertheless implicated in the appearance of certain empty argument positions in sentences used in monologues. I claim that subject pro in Mandarin Chinese must have as its antecedent an element located in an A'-position, which can be overt or covert. In addition, I suggest that the differences between Italian, Japanese, and Mandarin Chinese with respect to the use of subject pro can be boiled down to the featural properties of the covert topic TOP preceding subject pro: this covert topic has inherently valued phi-features in Italian and Japanese, while its counterpart in Mandarin Chinese does not. / Linguistics

The widespread use of microprocessor chips in high performance applications like graphics simulators and low power applications like mobile phones, laptops, medical applications etc. has made power estimation an important step in the manufacture of VLSI chips. It has become necessary to estimate the power consumption not only after the circuits have been laid out, but also during the design of the modules of the microprocessor at higher levels of design abstraction. The design of a microprocessor is complex and is performed at multiple layers of abstraction before it finally gets manufactured. The processor is first conceptually designed using blocks at the system level, and then modeled using a high-level language (C, C++, SystemC). This enables the early development of software applications using these high-level models. The C/C++ model is then translated to a hardware description language (HDL), that typically corresponds to the register transfer level (RT-Level). Once the processor is defined at the RT-Level, it is synthesized into gates and state elements based on user-defined constraints. In this thesis, novel techniques to estimate the power consumed by the microprocessor circuits at the gate level and RT-level of abstraction are presented. At the gate level, the average power consumed by microprocessor circuits is straight-forward to estimate, as the implementation is known. However, estimating the maximum or peak instantaneous power consumed by the microprocessor as a whole, when it is executing instructions, is a hard problem due to the high complexity of the state space involved. An hierarchical approach to estimate the peak power using powerful search techniques and formal tools is presented in this thesis. This approach has been extended and applied to solve the problem of estimating the maximum supply drop. Details on this extension and a discussion of promising results are also presented. In addition, this approach has been applied to explore the possibility of minimizing the leakage component of power dissipation, when the processor is idle. At the register transfer level, estimating the average power consumed by the circuits of the microprocessor is by itself a challenging problem. This is due to the fact that their implementation is unknown at this level of abstraction. The average power consumption directly depends on the implementation. The implementation, in turn, depends on the performance constraint imposed on the microprocessor. One of the factors affecting the performance of the microprocessor, is the speed of operation of its circuits. Considering these factors and dependencies (for making early design decisions at the RT-Level), a methodology that estimates the power vs. delay curves of microprocessor circuits has been developed. This will enable designers to make design decisions for even rudimentary designs without going through the time consuming process of synthesis. / text

The heterogeneous condensation of a vapour onto a substrate is a key step in a wide range of chemical and physical process that occur in both nature and technology. For example, dust and pollutant aerosol particles, ranging in size from several microns down to just a few nanometers, serve as cloud condensation nuclei in the atmosphere, and nanoscale structured surfaces provide templates for the controlled nucleation and growth of variety of complex materials. While much is known about the general features of heterogeneous nucleation onto macroscopic surfaces, much less is understood about both the dynamics and thermodynamics of nucleation involving nanoscale heterogeneities. The goal of this thesis is to understand the general features of condensation of vapours onto different types of nanoscale heterogeneity that range in degree of solubility from being insoluble, to partially miscible through to completely miscible. The heterogeneous condensation of the Lennard-Jones vapour onto an insoluble nanoscale seed particle is studied using a combination of molecular dynamics simulations and thermodynamic theory. The nucleation rate and free energy barrier are calculated from molecular dynamics using the mean first passage time method. These results show that the presence of a weakly interacting seed has no effect on the formation of small cluster embryos but accelerates the rate by lowering the free energy barrier of the larger clusters. A simple phenomenological model of film formation on a small seed is developed by extending the capillarity based liquid drop model. It captures the general features of heterogeneous nucleation, but a comparison with the simulation results show that the model significantly overestimates the height of the nucleation barrier while providing good estimates of the critical film size. A non-volatile liquid drop model that accounts for solution non-ideality is developed to describe the thermodynamics of partially miscible and fully miscible droplets in a solvent vapour. The model shows ideal solution drops dissolve always spontaneously, but partially miscible drops exhibit a free energy surface with two minima, associated with a partially dissolved drop and a fully dissolved drop, separated by a free energy barrier. The solubility transition between the two drops is shown to follow a hysteresis loop as a function of system volume similar to that observed in deliquescence. A simple lattice gas model describing the absorption of mono-layers of vapour onto the particle is also developed. Finally, molecular dynamics simulation of miscible and partially miscible binary Lennard-Jones mixtures are also used to study this system. For all cases studied, condensation onto the drop occurs spontaneously. Sub-monolayers of the solvent phase form when the system volume is large. At smaller system volumes, complete film formation is observed and the dynamics of film growth are dominated by cluster-cluster coalescence. Some degree of mixing into the core of the particle is observed for the miscible mixtures for all volumes. However, mixing of the solvent into the particle core only occurs below an onset volume for the partially miscible case, suggesting the presence of a solubility transition similar to the one described by the thermodynamic model.